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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 307 records · Page 17
All sourcesNASA NTRSDOE OSTI
NASA NTRS1974

Polarization in a mineral absorption band

A theoretical and experimental study was undertaken to examine the polarimetric properties of light reflected from a particulate surface in the spectral region (0.7 to 1.1 micrometer) of a mineral electronic-transition absorption band. The purpose of the investigation was to show that spectral polarimetry is an alternative diagnostic tool to absolute reflectivity measurements for some applications, notably the determination of absorption-band positions for the lunar surface. The major results are: (1) polarization increases significantly in an absorption band at large phase angles; (2) the wavelength of the maximum of the polarization variation corresponds directly with the center of the absorption band; (3) the amount of increase of polarization for minerals with an absorption band is dependent on particle size; and (4) the fractional change of polarization with wavelength is greater for mixtures with transparent minerals than with absorbing minerals. The magnitude of change, however, is greater for mixtures with absorbing minerals.

Pieters, C. E.↗
NASA NTRS1974

Possible H2/+/ ultraviolet spectrum of Jupiter

An ultraviolet spectral probe for a hydrogen-rich planetary atmosphere, such as that of Jupiter, is suggested, utilizing discrete lines in the H2(+) 2p pi u - /s sigma g electronic transition. For the Jovian atmosphere, the dominant mechanism for exciting H2(+) to its 2p pi u state appears to be photoexcitation, principally through absorption of the solar Lyman-alpha line. The critical role of corrections to the Born-Oppenheimer approximation in the use of an H2(+) probe is discussed.

Wu, F.-M.↗
NASA NTRS1974

Scanner observations of selected cool stars

Photoelectric spectral scans at 30 A resolution of nine dwarfs, ten giants, and six supergiants with spectral types G0 to M5 are presented. (All stars were observed every 4 A from 3300 to 7000 A.) Absorption features observed at this resolution coincide with: strong atomic lines of Fe I, Fe II, Ca I, Ca II, Mg I, and Na I; vibrational bands of the electronic transitions of TiO, MgH, CaH, SiH, AlH, CN, CH, C2, OH, and NH. The dependences of the 3740-A Fe I blend and the 3440-A depression on temperature are discussed.

Fay, T. D., Jr.↗
NASA NTRS1976

Intensity measurements for the /2, O/ gamma-band of O2, b 1Sigma-g/+/ - X 3Sigma-g/-/

Line intensities for the P sub P and P sub Q branches of the (2-O) vibrational band of the magnetic dipole electronic transition for the oxygen red system at 6280 A were measured, and the sum of the R sub R and R sub Q branch intensities was taken. A large number of repetitive spectral scans were required for accuracy, because of low absorption values even at optical path lengths from 300 to 600 m. A total of 557 individual measurements of P-branch lines yielded an intensity value for the P-branches, and equivalent widths for 24 spectral scans yielded an intensity value for the R-branch. R-branch to P-branch intensity ratios were taken for the A-band, B-band, and gamma-band (respectively, O-O at 7620 A, 1-O at 6880 A, and 2-O at 6280 A). Intensities for some rotational lines are found, and effects of combined rotation-vibration interaction are probed.

Miller, J. H.↗
NASA NTRS1976

Electron impact excitation of the Meinel band system of N2/+/

The emission spectrum of the Meinel band system of N2(+) was obtained in the region between 0.72 and 1.6 micrometers by electron impact excitation of N2. The relative excitation function is presented for the (0, 0) band from 22 to 120 eV. Cross sections of the Meinel bands that fall in this region were measured relative to the (2, 0) Meinel band. The results obtained are in good agreement with previously published values below 1.1 micrometers except for the (0, 0) band which is 30% higher. The electronic transition moment at large internuclear distances is found to agree with theoretical estimates.

Mandelbaum, D.↗
NASA NTRS1976

Mercury - Spectral reflectance measurements /0.33-1.06 microns/ 1974/75

The spectral reflectance (0.32-1.06 microns) of Mercury was measured during two elongations, September-October 1974 and March 1975. The spectra are much improved over the previously available measurements. The reflectance increases almost linearly with wavelength, and no electronic transition absorption bands are evident to the precision of the data. The new spectra agree very well with the reflectance of mature lunar mare and upland soils and are not similar to those of any other observed solar system object. This suggests that the surface materials and the weathering processes controlling their optical properties are similar for both the moon and Mercury. Differences between the spectra for the two-observation periods may indicate differences in the average composition for the different regions of Mercury observed.

Vilas, F.↗
NASA NTRS1976

Electronic states of Zn2 - Ab initio calculations of a prototype for Hg2

The electronic states of Zn2 are investigated by ab initio polarization configuration-interaction calculations. Molecular states dissociating to Zn(1S) + Zn(1S, 3P, 1P) and Zn(3P) + Zn(3P) are treated. Important effects from states arising from Zn(+)(25) + Zn(-)(2P) are found in the potential-energy curves and electronic-transition moments. A model calculation for Hg2 based on the Zn2 curves and including spin-orbit coupling leads to a new interpretation of the emission bands in Hg vapor.

Hay, P. J.↗
NASA NTRS1977

Comment on the relation between the nonadiabatic coupling and the complex intersection of potential energy curves

Simple relations are discussed that provide a correspondence between the complex intersection of two potential surfaces and the nonadiabatic coupling matrix element between those surfaces. These are key quantities in semiclassical and quantum mechanical theories of collision induced electronic transitions. Within the two state approximation, the complex intersection is shown to be directly related to the location and magnitude of the peak in the nonadiabatic coupling. Two cases are considered: the avoided crossing between two potential surfaces; and the spin orbit interaction due to a P-2 halogen atom. Comparisons are made between the results of the two-state model and the results of ab initio quantum chemical calculations.

Jaffe, R. L.↗
NASA NTRS1977

MCSCF + Cl wavefunctions and properties of the X2-Pi and A2-Pi states of ClO

A multiconfiguration, self-consistent field plus configuration-interaction calculation has been performed on the X2-Pi and A2-Pi electronic states of ClO. The values of certain molecular properties computed from the wavefunctions agree well with those from experiment. The sum of the squares of the computed electronic transition moments between the X2-Pi and A2-Pi states at 3.07 bohr is 1.75 a.u., which corresponds to the experimental result of 1.58 plus or minus 0.20 a.u. The computed ground state dipole moment at the experimental equilibrium separation is 1.232 D, which compares well with two experimental results of 1.18 plus or minus 0.12 and 1.239 plus or minus 0.010 D. The value of the computed dissociation energy is 2.75 eV, which agrees well with the experimental value of 2.803 plus or minus 0.001 eV.

Arnold, J. O.↗
NASA NTRS1977

Statistical equilibrium in cometary C2. I

Swan-band emission from the C2 molecule provides important information for a study of the physical processes occurring in comets. It is, therefore, a disturbing factor that many quantitative Swan-band observations are in clear contradiction of predictions of resonance fluorescence excitation of the Swan bands. A description is presented of an investigation involving an application of resonance fluorescence theory to C2. The investigation takes into account all important electronic transitions which determine the population distribution of the lowest energy states. It is found that the previous discrepancy for the brighter band sequences disappears.

Swamy, K. S. K.↗
NASA NTRS1977

Comment on the relation between the nonadiabatic coupling and the complex intersection of potential energy curves

Simple relations are discussed that provide a correspondence between the complex intersection of two potential surfaces and the nonadiabatic coupling matrix element between those surfaces. These are key quantities in semiclassical and quantum-mechanical theories of collision-induced electronic transitions. Within the two-state approximation, the complex intersection is shown to be directly related to the location and magnitude of the peak in the nonadiabatic coupling. Two cases have been considered: (1) the avoided crossing between two potential surfaces, and (2) the spin-orbit interaction due to a 2P halogen atom. Comparisons are made between the results of the two-state model and the results of ab initio quantum chemical calculations.

Jaffe, R. L.↗
NASA NTRS1979

Altered rock spectra in the visible and near infrared

The author has identified the following significant results. Visible and near-infrared (0.35 to 2.5 micron m) bidirectional reflection spectra recorded for a suite of well-characterized hydrothermally altered rock samples typically display well defined bands caused by both electronic and vibrational processes in the individual mineral constituents. Electronic transitions in the iron-bearing constituent minerals produce diagnostic minima near 0.43, 0.65, 0.85, and 0.93 micron m. Vibrational transitions in clay and water-bearing mineral constituents produce characteristic single or multiple features over limited spectral ranges near 1.4, 1.75, 1.9, 2.2, and 2.35 micron m. The most abundant feature-producing minerals present in these rocks are hematite, goethite, and alunite. Others frequently present are jarosite, kaolinite, potassium micas, pyrophyllite, montmorillonite, diaspore, and gypsum. The spectral region near 2.2 micron m is particularly important for detecting altered rocks by remote sensing.

Hunt, G. R.↗
NASA NTRS1978

Spectral studies of SiCl4 + N2O + Ar and SiH4 + Ar mixtures in a shock tube in 160-550 nm range

Gases containing SiO, SiO2, SiH, and Si2 were produced in the reflected-shock region of a shock tube by heating SiCl4 + N2O + Ar and SiH4 + Ar mixtures with shock waves. Spectral absorption characteristics were measured in the 160-550 nm wavelength range and in the 2800-3600 K temperature range and compared to calculated values. The sums of the squares of electronic transition moments at equilibrium separation were derived. It was found that absorption by SiO2 and other known bands of SiO, SiH, and Si2 were too weak to be measured. The cross section of absorption by a continuum, believed due to SiH, varied from 2.5 x 10 to the -17th sq cm at 280 nm to 1.6 x 10 to the -18th sq cm at 440 nm.

Park, C.↗
NASA NTRS1978

Stratospheric-related research using the shock tube

The capabilities of shock tubes used in stratospheric-related research are considered, and the results of three independent shock tube research projects are reported. The studies are concerned with the evaluation of stratospheric ozone depletion. In the first experiment, photoabsorption cross sections of Freon 11 and 12 at stratospheric temperatures were measured using rarefaction waves. In the second experiment, reaction-rate coefficients were determined from measurements made behind reflected shock waves. In the third experiment, electronic-transition moments of the O2 Schumann-Runge system and the A2Pi-X2Pi system of ClO were deduced from intensity measurements made behind the incident shock.

Cooper, D. M.↗
NASA NTRS1979

Radiation absorption by the C2 band systems for Jupiter entry conditions

Revised values of the absorption cross sections for seven electronic band systems of C2 have been calculated using recently published experimental data for the electronic transition moments. Using these revised C2 cross section values, computations were made for the radiating flow field over a Jupiter entry probe with coupled ablation injection from a carbon-phenolic heat shield. Results are presented which show that radiation absorption within the ablation layer for the spectral range of 4 to 6 eV is less than that predicted using previous C2 absorption cross section values. The effect of the reduced radiation absorption by the C2 molecule is an increase in the radiative heating rates and ablation mass loss rates for the Jupiter entry conditions considered in the study.

Sutton, K.↗
NASA NTRS1979

Ion-molecule processes in lasers

Three classes of molecular electronic transition lasers produced by hybrid pumping of high pressure rate gas mixtures are discussed. These are (1) rare gas dimer lasers (such as excited Ar2, Kr2, and Xe2) lasing in the VUV, (2) rare gas halide lasers or excimer lasers (such as KrF, ArF, and XeCl excimers) lasing in the UV, and (3) the charge transfer molecular ion laser (such as N2/+/) lasing in the visible range. Laser excitation methods and kinetic sequences are examined for these lasers.

Laudenslager, J. B.↗
NASA NTRS1979

The dispersed fluorescence spectrum of NaAr - Ground and excited state potential curves

Potential curves for the ground state and the first excited state of NaAr were determined. The van der Waals molecule NaAr was prepared by supersonic free jet expansion of a mixture of sodium, argon, and helium. The electronic transition from the ground state to the first excited state A2pi was excited by a tunable dye laser and the resulting fluorescence was studied. The dispersed fluorescence spectra show discrete and diffuse features, corresponding to transitions from excited vibrational levels of the A state to bound and unbound levels of the x state. The characteristic reflection structure in the bound-free spectra permits an unambiguous assignment of the vibrational numbering in the A state, and this assignment together with previously measured spectroscopic constants are used to calculate the potential curve of the A state. The discrete structure in the fluorescence spectra is used to determine the potential curve of the x state in the well region, and the repulsive part of the X curve is then deduced through trial-and-error simulation of the bound-free spectra.

Tellinghuisen, J.↗
NASA NTRS1980

X-ray lasers. Citations from the International Aerospace Abstracts data base

Various aspects of X-ray lasers are discussed in approximately 122 citations. Included are laser plasmas and outputs, plasma radiation, far ultraviolet radiation, gamma rays, optical pumping, optical resonators, and electron transitions. Laser applications, laser materials, and laser fusion are also included.

Mauk, S. C.↗