Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Chemical initiation”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 307 records · Page 17
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Flash Graphene from Plastic Waste

In this work, an approach to upcycling plastic waste (PW) products is presented. The method relies on flash Joule heating (FJH) to convert PW into flash graphene (FG). In addition to FG, the process results in the formation of carbon oligomers, hydrogen, and light hydrocarbons. In order to make high quality graphene, a sequential alternating current (AC) and direct current (DC) flash is used. Here, the FJH process requires no catalyst and works for PW mixtures, which makes the process suitable for handling landfill PW. The energy required to convert PW to FG is ~ 23 kJ/g or ~ $125 in electricity per ton of PW, potentially making this process economically attractive for scale-up. The FG was characterized by Raman spectroscopy and had a I 2D /I G peak ratio up to 6 with a low-intensity D band. Moreover, transmission electron microscopy and X-ray diffraction analysis show that the FG is turbostratic with an interlayer spacing of 3.45 Å. The large interlayer spacing will facilitate its dispersion in liquids and composites. Analysis of FG dispersions in 1% Pluronic aqueous solution shows that concentrations up to 1.2 mg/mL can be achieved. The carbon oligomers that distilled from the process were characterized by Fourier-transform infrared spectroscopy and have chemical structures similar to the starting PW. Initial analysis of gas phase products shows the formation of considerable amounts of hydrogen along with other light hydrocarbons. Since graphene is naturally occurring and it shows a low toxicity profile, this could be an environmentally beneficial method to upcycle PE.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2024

Toward an integrated multi-gigahertz ionizing particle diagnostic

Needs arising at both current and future accelerator facilities call for the development of radiation-hardened position-sensing diagnostics that can operate with multi-GHz repetition rates. Such instruments are likely to also have applications in the diagnosis of rapid plasma behavior. Here, building on the recent work of our Advanced Accelerator Diagnostics Collaboration, we are exploring the development of integrated multi-GHz ionizing particle detection systems based on chemical-vapor deposition diamond sensors, with the initial goal of producing a quadrant detector that can determine the intensity and centroid position of a particle beam at a repetition rate between 5 and 10 GHz. Results from our initial high-speed characterization work are presented, including those from a single-channel sensor with a GHz response. Approaches to achieving multi-GHz (5–10 GHz) rate capability, including the design of a dedicated Application Specific Integrated Circuit and the use of 3D RF-solver computer aided design software, are presented and discussed in more detail. 3D RF simulations suggest clean pulses of duration less than 250 ps (FWHM less than 125 ps) can be achieved with the approaches developed by this work.

43 PARTICLE ACCELERATORS↗
DOE OSTI2022

Differences in chemical evolution between isolated and embedded prestellar cores

Models of prestellar cores often assume that the cores are isolated from their environment – material outside the core boundary plays no role in the subsequent evolution. This is unlikely to be the case in reality, where cores are located within hierarchically substructured molecular clouds. Here, we investigate the dynamical and chemical evolution of prestellar cores, modelled as Bonnor–Ebert spheres, and show that the density of the ambient medium has a large impact on the resulting chemical properties of the cores. Models embedded in high-density, low-temperature surroundings have greatly enhanced abundances of several molecules, such as CO and CS, compared to models with more diffuse surroundings, corresponding to relatively isolated cores. The predicted intensities and profile shapes of molecular lines are also affected. The density of the ambient medium has a stronger effect on the chemical evolution than whether the cores are initially in or out of equilibrium. This suggests that the impact of environment cannot be neglected when modelling chemistry in prestellar cores; the results of these models are highly sensitive to the assumptions made about the core surroundings.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2024

Viscosities of the Baryon-Rich Quark-Gluon Plasma from Beam Energy Scan Data

Here, this work presents the first Bayesian inference study of the (3 + 1)D dynamics of relativistic heavy-ion collisions and quark-gluon plasma viscosities using an event-by-event (3 + 1)D hydrodynamics + hadronic transport theoretical framework and data from the Relativistic Heavy Ion Collider Beam energy scan program. Robust constraints on initial state nuclear stopping and the baryon chemical potential-dependent shear viscosity of the produced quantum chromodynamic (QCD) matter are obtained. The specific bulk viscosity of the QCD matter is found to exhibit a preferred maximum around $\sqrt{s_{NN}}$ = 19.6 GeV . This result allows for the alternative interpretation of a reduction (and/or increase) of the speed of sound relative to that of the employed lattice-QCD based equation of state for net baryon chemical potential μ B ~0.2(0.4) GeV .

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2022

On the combustion of n-butyl acetate droplets

This paper presents an experimental and numerical study of the combustion of isolated n‑butyl acetate droplets in the standard atmosphere. Numerical simulations are reported using a model that incorporates unsteady gas and liquid transport, variable properties, and radiation. Three skeletal mechanisms of n‑butyl acetate, derived from a large detailed mechanism comprised of 819 species and 52,698 reactions, were used in the numerical simulations to evaluate the influence of the kinetic mechanism on burning. The reduced mechanisms comprised 212 species and 5413 reactions, 157 species and 3089 reactions, and 105 species and 1035 reactions. The numerical model did not include soot formation, though qualitatively mild sooting was noted only for droplets larger than 0.7 mm. The numerical predictions were in good agreement with experimental measurements of droplet and flame diameters. Flame extinction was numerically predicted which was attributed to a decrease of the characteristic diffusion time relative to the chemical time as droplet burned. Effects of initial droplet diameter on the evolution of maximum gas temperature (Tmax) and peak mole fractions of CO2 and CO are also examined numerically.

09 BIOMASS FUELS↗
NASA NTRS1974

Heat conduction controlled combustion for scramjet applications

The use of heat conduction flame generated in a premixed supersonic stream is discussed. It is shown that the flame is controlled initially by heat conduction and then by chemical reaction. Such a flame is shorter than the diffusion type of flame and therefore it requires a much shorter burner. The mixing is obtained by injecting the hydrogen in the inlet. Then the inlet can be cooled by film cooling.

Ferri, A.↗
NASA NTRS1991

Advanced Photovoltaic Experiment, S0014: Preliminary Flight Results and Post-Flight Findings

The Advanced Photovoltaic Experiment (APEX) is an LDEF experiment designed to provide reference solar cell standards for laboratory measurements as well as to investigate the solar spectrum and the effects of long term exposure of solar cells to the LEO environment. Silicon and gallium arsenide solar cells were flown with the appropriate instrumentation to periodically measure cell performance and temperature. The experimental objectives, the design employed to realize these objectives and the solar cells and instrumentation selected for the flight are presented. A discussion of the flight data returned are included. Preliminary results from the post flight analysis of the absolute cavity radiometer, the digital solar angle sensor, and the Barr Associates narrow bandpass optical filters are also presented. The initial findings of work to determine the chemical nature of contamination layers on APEX are also presented.

Brinker, David J.↗
NASA NTRS1993

The interaction of high voltage systems with the environments of the Moon and Mars

High voltage systems designed for use on the lunar and Martian surfaces or in orbit will interact with environmental components such as electrically charged dust, low pressure atmospheres, ionospheric plasmas and neutrals, and chemically reactive species. As the Space Exploration Initiative (SEI) advances from the realm of feasibility study to that of conceptual design, guidelines will be required to ensure that these effects are properly accounted for. A first step in providing such guidelines is the prioritization of interactions for each of the space or surface environments that will be encountered. For those issues that are identified as high priority, the state of environmental knowledge, emphasizing essential data, must be determined. This report describes possible means of obtaining such information, including ground tests, modeling and analysis, and flight experiments. The development of computational tools which will enable engineers to simulate and thereby quantify the interactions will be especially considered. Our analysis is drawn from various study and workshop activities undertaken within the last two years.

Hillard, G. Barry↗
NASA NTRS1993

Comparisons of selected laser beam power missions to conventionally powered missions

Earth-based laser sites beaming laser power to space assets have shown benefits over competing power system concepts for specific missions. Missions analyzed in this report that show benefits of laser beam power are low Earth orbit (LEO) to geosynchronous Earth orbit (GEO) transfer, LEO to low lunar orbit (LLO) cargo missions, and lunar-base power. Both laser- and solar-powered orbit-transfer vehicles (OTV's) make a 'tug' concept viable, which substantially reduces cumulative initial mass to LEO in comparison to chemical propulsion concepts. Lunar cargo missions utilizing laser electric propulsion from Earth-orbit to LLO show substantial mass saving to LEO over chemical propulsion systems. Lunar-base power system options were compared on a landed-mass basis. Photovoltaics with regenerative fuel cells, reactor-based systems, and laser-based systems were sized to meet a generic lunar-base power profile. A laser-based system begins to show landed mass benefits over reactor-based systems when proposed production facilities on the Moon require power levels greater than approximately 300 kWe. Benefit/cost ratios of laser power systems for an OTV, both to GEO and LLO, and for a lunar base were calculated to be greater than 1.

Bozek, John M.↗
NASA NTRS1994

The Rationale/Benefits of Nuclear Thermal Rocket Propulsion for NASA's Lunar Space Transportation System

The solid core nuclear thermal rocket (NTR) represents the next major evolutionary step in propulsion technology. With its attractive operating characteristics, which include high specific impulse (approximately 850-1000 s) and engine thrust-to-weight (approximately 4-20), the NTR can form the basis for an efficient lunar space transportation system (LTS) capable of supporting both piloted and cargo missions. Studies conducted at the NASA Lewis Research Center indicate that an NTR-based LTS could transport a fully-fueled, cargo-laden, lunar excursion vehicle to the Moon, and return it to low Earth orbit (LEO) after mission completion, for less initial mass in LEO than an aerobraked chemical system of the type studied by NASA during its '90-Day Study.' The all-propulsive NTR-powered LTS would also be 'fully reusable' and would have a 'return payload' mass fraction of approximately 23 percent--twice that of the 'partially reusable' aerobraked chemical system. Two NTR technology options are examined--one derived from the graphite-moderated reactor concept developed by NASA and the AEC under the Rover/NERVA (Nuclear Engine for Rocket Vehicle Application) programs, and a second concept, the Particle Bed Reactor (PBR). The paper also summarizes NASA's lunar outpost scenario, compares relative performance provided by different LTS concepts, and discusses important operational issues (e.g., reusability, engine 'end-of life' disposal, etc.) associated with using this important propulsion technology.

Borowski, Stanley K.↗
NASA NTRS2001

High-Pressure Synthesis of Metal-Ceramic Nano-Composites

The major problems in fabrication of nano-crystal line materials form nano-powders are: (1), coarsening of the initial nano-size grains, (2), insufficient densification (high concentration of pores), and, (3), conversion of diamond into graphite (for diamond-based ceramics). We have developed a novel technique of the synthesis of nano-composite materials applying very high (up to about 10 GPa) pressures. In this technique, one component is pre-compacted and placed next to another having a lower melting point temperature. The whole sample is pressed and the temperature raised above the melting point of the second component, what results in the melt getting pressed into the (nano-size) pores of the compact. Upon subsequent crystallization the melt forms the second nanophase. The process is fast, on the order of seconds, and the temperatures are relatively low what prevents, or at least significantly reduces coarsening of the starting nanophase grains. Also, conversion of diamond into graphite can be prevented. The technique allows for control of the final product properties through a proper selection of (1) the initial compact density and grain size, (2) chemical composition of the source, and (3) the temperature and pressure of the process. The application of the technique to the synthesis of SiC and diamond with Si, Ge, and different metals. Results of the in-situ investigation of the synthesis process by synchrotron X-ray diffraction technique will be presented.

Gierlotka, S.↗
NASA NTRS1993

The mechanosensory calcium-selective ion channel: key component of a plasmalemmal control centre?

Mechanosensory calcium-selective ion channels probably serve to detect not only mechanical stress but also electrical, thermal, and diverse chemical stimuli. Because all stimuli result in a common output, most notably a shift in second messenger calcium concentration, the channels are presumed to serve as signal integrators. Further, insofar as second messenger calcium in turn gives rise to mechanical, electrical, and diverse chemical changes, the channels are postulated to initiate regulatory feedbacks. It is proposed that the channels and the feedback loops play a wide range of roles in regulating normal plant function, as well as in mediating disturbance of normal function by environmental stressors and various pathogens. In developing evidence for the physiological performance of the channel, a model for a cluster of regulatory plasmalemmal proteins and cytoskeletal elements grouped around a set of wall-to-membrane and transmembrane linkers has proved useful. An illustration of how the model might operate is presented. It is founded on the demonstration that several xenobiotics interfere both with normal channel behaviour and with gravitropic reception. Accordingly, the first part of the illustration deals with how the channels and the control system within which they putatively operate might initiate gravitropism. Assuming that gravitropism is an asymmetric expression of growth, the activities of the channels and the plasmalemmal control system are extrapolated to account for regulation of both rate and allometry of cell expansion. Finally, it is discussed how light, hormones, redox agents and herbicides could in principle affect growth via the putative plasmalemmal control cluster or centre.

NASA Program Space Biology↗
NASA NTRS2005

Extracting Quantitative Data from Lunar Soil Spectra

Using the modified Gaussian model (MGM) developed by Sunshine et al. [1] we compared the spectral properties of the Lunar Soil Characterization Consortium (LSCC) suite of lunar soils [2,3] with their petrologic and chemical compositions to obtain quantitative data. Our initial work on Apollo 17 soils [4] suggested that useful compositional data could be elicited from high quality soil spectra. We are now able to expand upon those results with the full suite of LSCC soils that allows us to explore a much wider range of compositions and maturity states. The model is shown to be sensitive to pyroxene abundance and can evaluate the relative portion of high-Ca and low-Ca pyroxenes in the soils. In addition, the dataset has provided unexpected insights into the nature and causes of absorption bands in lunar soils. For example, it was found that two distinct absorption bands are required in the 1.2 m region of the spectrum. Neither of these bands can be attributed to plagioclase or agglutinates, but both appear to be largely due to pyroxene.

Noble, S. K.↗
NASA NTRS2004

Advanced Constituents and Processes for Ceramic Composite Engine Components

The successful replacement of metal alloys by ceramic matrix composites (CMC) in hot-section engine components will depend strongly on optimizing the processes and properties of the CMC microstructural constituents so that they can synergistically provide the total CMC system with improved temperature capability and with the key properties required by the components for long-term structural service. This presentation provides the results of recent activities at NASA aimed at developing advanced silicon carbide (Sic) fiber-reinforced hybrid Sic matrix composite systems that can operate under mechanical loading and oxidizing conditions for hundreds of hours at 2400 and 2600 F, temperatures well above current metal capability. These SiC/SiC composite systems are lightweight (-30% metal density) and, in comparison to monolithic ceramics and carbon fiber-reinforced ceramic composites, are able to reliably retain their structural properties for long times under aggressive engine environments. It is shown that the improved temperature capability of the SiC/SiC systems is related first to the NASA development of the Sylramic-iBN Sic fiber, which displays high thermal stability, creep resistance, rupture resistance, and thermal conductivity, and possesses an in-situ grown BN surface layer for added environmental durability. This fiber is simply derived from Sylramic Sic fiber type that is currently produced at ATK COI Ceramics. Further capability is then derived by using chemical vapor infiltration (CVI) to form the initial portion of the hybrid Sic matrix. Because of its high creep resistance and thermal conductivity, the CVI Sic matrix is a required base constituent for all the high temperature SiC/SiC systems. By subsequently thermo- mechanical-treating the CMC preform, which consists of the S ylramic-iBN fibers and CVI Sic matrix, process-related defects in the matrix are removed, further improving matrix and CMC creep resistance and conductivity.

Yun, H. M.↗
NASA NTRS2016

Design and Delivery of a Filter for Removal of Siloxanes from the ISS Atmosphere

Dimethylsilanediol (DMSD) has been identified as a problematic chemical contaminant aboard ISS. This contaminant was initially identified in the ISS condensate and in the Water Processor Assembly (WPA) product water in 2010 when an increasing total organic carbon (TOC) trend was detected in the water produced by the WPA. DMSD is not a crew health hazard at the levels observed in the product water, but it may degrade the performance of the Oxygen Generation System (OGS) which uses product produced by the WPA for electrolysis. In addition, DMSD can prevent the effective operation of the WPA catalytic reactor, and necessitates early replacement of Multifiltration Beds in the WPA. An investigation into the source of DMSD has determined that polydimethylsiloxanes (PDMSs) are hydrolyzing in the Condensing Heat Exchanger (CHX) to form DMSD. PDMSs are prevalent aboard ISS from a variety of sources, including crew hygiene products, adhesives, caulks, lubricants, and various nonmetallics. TPDMSs are also implicated in CHX hydrophilic coating degradation, rendering it hydrophobic and adversely affecting its ability to effectively transmit water to the condensate bus. Eventually this loss in performance results in water droplets in the air flow out of the CHX core, which can lead to microbial growth in the air ducts and can impact the performance of downstream systems. Design concepts have now been developed for removing PDMS in the air stream before it can reach the CHX core, thus preventing degradation of the coating and decomposition of the PDMS to DMSD. This paper summarizes the current status of the effort to deliver filters to ISS for removing PDMSs from the atmosphere before they can adversely impact the performance of the CHX coating and the WPA.

Carter, Layne↗
DOE OSTI2023

Development and Performance of RFD Crab Cavity Prototypes for HL-LHC AUP

The US will be contributing to the HL-LHC upgrade at CERN with the fabrication and qualification of RFD crabbing cavities in the framework of the HL-LHC Accelerator Upgrade Project (AUP) managed by Fermilab. AUP received Critical Decision 3 (CD-3) approval by DOE in December 2020 launching the project into the production phase. The electro-magnetic design of the cavity was inherited from the LHC Accelerator Research Program (LARP) but needed to be revised to meet new project requirements and to prevent issues encountered during beam tests performed at CERN in the R&D phase. Two prototype cavities were manufactured in industry and cold tested. Challenges specific to the RFD cavity were the stringent interface tolerances, the pole symmetry, and the higher-order-mode impedance spectrum. Chemical processing and heat treatments were performed initially at FNAL/ANL and are now being transferred to industry for the production phase. HOM dampers are manufactured and validated by JLAB. A summary of cold test results with and without HOM dampers is presented.

43 PARTICLE ACCELERATORS↗
NASA NTRS1976

Introductory study of the chemical behavior of jet emissions in photochemical smog

Jet aircraft emissions data from the literature were used as initial conditions for a series of computer simulations of photochemical smog formation in static air. The chemical kinetics mechanism used in these simulations was an updated version which contains certain parameters designed to account for hydrocarbon reactivity. These parameters were varied to simulate the reaction rate constants and average carbon numbers associated with the jet emissions. The roles of surface effects, variable light sources, NO/NO2 ratio, continuous emissions, and untested mechanistic parameters were also assessed. The results of these calculations indicate that the present jet emissions are capable of producing oxidant by themselves. The hydrocarbon/nitrous oxides ratio of present jet aircraft emissions is much higher than that of automobiles. These two ratios appear to bracket the hydrocarbon/nitrous oxides ratio that maximizes ozone production. Hence an enhanced effect is seen in the simulation when jet exhaust emissions are mixed with automobile emissions.

Whitten, G. Z.↗
DOE OSTI2020

Nomenclature, Chemical Abstracts Service Numbers, Isomer Enumeration, Ring Strain and Stereochemistry: What Does Any of This Have to do with an International Chemical Disarmament and Non-Proliferation Treaty?

The Chemical Weapons Convention (CWC) is an international disarmament and non-proliferation treaty that mandates a comprehensive ban on chemical weapons. This treaty entered-into-force in 1997 and has a nearly universal membership of world states. The CWC provides definitions for what constitutes a chemical weapon and describes chemicals for which verification measures and regulatory oversight are required. These chemicals, which must be declared to the Organisation for the Prohibition of Chemical Weapons (OPCW) for verification purposes, appear in three Schedules within the CWC. The schedules list specific chemical substances and families of chemicals defined by molecular structure descriptions that allow a range of specified variable groups. The text of an international treaty provides a basis for laws and regulatory requirements at international and national levels that must be enacted to comply with treaty obligations. These laws and regulations must account for the “chemistry” that is described in the treaty text, which has been negotiated and agreed upon by world governments. In this paper, we look at some of the chemicals described within the CWC and discuss how atoms and molecules, nomenclature and Chemical Abstracts Service (CAS) numbers, isomer enumeration, ring strain and stereochemistry influence the obligations of States to an international treaty. The material draws upon the authors’ experiences from an interactive “Science for Diplomats” initiative that has provided a forum for engaging with chemical disarmament decision makers to aid in their understanding of fundamental concepts in chemistry that have impact on treaty implementation. We hope this article will spark interest from chemistry students and educators in the provision of science advice for policymakers and provide policymakers with an appreciation of the complexity and importance of understanding the language of chemistry in support of a world free of chemical weapons.

Organic Chemistry, Alkanes/Cycloalkanes, Applicati↗