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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 307 records · Page 17
All sourcesNASA NTRSDOE OSTI
NASA NTRS1953

Smoke Studies of Secondary Flows in Bends, Tandem Cascades, and High-turning Configurations

Flow-visualization studies, using smoke, were made of the secondary flows in rectangular bends, tandem cascades, and high-turning configurations. The roll-up of the wall boundary layer of a rectangular bend forms a passage vortex near the suction surface similar to that previously observed for cascades. The vortex so formed then shifts out into the main stream. Because of leading-edge effects, the boundary-layer flows in bends were found to be sufficiently different from the flows in blade rows to make direct application of bend results to blade rows inadvisable. Passage vortices are shown, in the tandem-cascade study, to resist turning with the main stream through which they pass and to disturb the flow in subsequent blade rows. This disturbance may explain in part the appreciable size of the losses sometimes attributed to secondary flows in turbomachines despite the fact that the energy involvement in vortex formation is slight. Tip-flow studies of high-turning blades with relative motion between blades and end wall indicated that if the relative sizes of the passage vortex forces, the tip clearance forces, and the blade-scraping effects are properly controlled, it may be possible to improve the blade-tip loading characteristics in turbomachine.

CASCADES↗
NASA NTRS1953

A comparison of typical national gas turbine establishment and NACA axial-flow compressor blade sections in cascade at low speed

Comparative cascade tests of the NGTE (National Gas Turbine Establishment of Great Britain) 10C4/30C50 and NACA 65-(12)10 axial flow compressor blade sections were conducted in a 5-inch low-speed cascade tunnel at the Langley Laboratory at air-inlet angles of 30 degrees, 45 degrees, and 60 degrees and a solidity of 1.0 by using the porous-wall technique. These NACA data for the NGTE 10C4/30C50 section were also compared with data from NGTE design charts for the same section. British and NACA incompressible cascade force-analysis equations are included.

CASCADES, EXPERIMENT↗
NASA NTRS1995

Cascade Error Projection: An Efficient Hardware Learning Algorithm

A new learning algorithm termed cascade error projection (CEP) is presented. CEP is an adaption of a constructive architecture from cascade correlation and the dynamical stepsize of A/D conversion from the cascade back propagation algorithm.

learning algorithm pattern recognition cascade err↗
NASA NTRS2020

Solar Wind Turbulence Around Mars: Relation Between The Energy Cascade Rate And The Proton Cyclotron Waves Activity

The first estimation of the incompressible energy cascade rate at magnetohydrodynamic (MHD) scales in the plasma upstream of the Martian bow shock is obtained, making use of magnetic field and plasma observations provided by Mars Atmosphere and Volatile EvolutioN (MAVEN) over 600 orbits. In particular, the energy cascade rate is computed for events with and without proton cyclotron wave (PCW) activity, for time intervals when MAVEN was in the solar wind with no magnetic connection to the bow shock. It is shown that the nonlinear cascade of energy at the MHD scales is slightly amplified when PCWs are present in the plasma, around the Martian perihelion. In addition, the analysis of the normalized cross helicity and residual energy for the turbulent fluctuations shows the presence of Alfvenic and non-Alfvenic fluctuations in a magnetic dominant regime for the majority of the cases.

solar wind↗
DOE OSTI2024

A One‐Pot Biocatalytic Cascade to Access Diverse l ‐Phenylalanine Derivatives from Aldehydes or Carboxylic Acids

Abstract Nonstandard amino acids (nsAAs) that are l ‐phenylalanine derivatives with aryl ring functionalization have long been harnessed in natural product synthesis, therapeutic peptide synthesis, and diverse applications of genetic code expansion. Yet, to date, these chiral molecules have often been the products of poorly enantioselective and environmentally harsh organic synthesis routes. Here, we reveal the broad specificity of multiple natural pyridoxal 5′‐phosphate (PLP)‐dependent enzymes, specifically an l ‐threonine transaldolase, a phenylserine dehydratase, and an aminotransferase, toward substrates that contain aryl side chains with diverse substitutions. We exploit this tolerance to construct a one‐pot biocatalytic cascade that achieves high‐yield synthesis of 18 diverse l ‐phenylalanine derivatives from aldehydes under mild aqueous reaction conditions. We demonstrate the addition of a carboxylic acid reductase module to this cascade to enable the biosynthesis of l ‐phenylalanine derivatives from carboxylic acids that may be less expensive or less reactive than the corresponding aldehydes. Finally, we investigate the scalability of the cascade by developing a lysate‐based route for preparative‐scale synthesis of 4‐formyl‐ l ‐phenylalanine, a nsAA with a bio‐orthogonal handle that is not readily market‐accessible. Overall, this work offers an efficient, versatile, and scalable route with the potential to lower manufacturing costs and democratize synthesis for many valuable nsAAs.

Anderson, Shelby R. [Department of Chemical and Bi↗
DOE OSTI2020

Cascade decays of heavy Higgs bosons through vectorlike quarks in two Higgs doublet models

We study cascade decays of heavy neutral Higgs bosons through vectorlike quarks. We focus on scenarios where decay modes into pairs of vectorlike quarks are not kinematically open which extends the sensitivity of the LHC to larger masses. Assuming only mixing with the third family of standard model quarks the new decay modes of heavy Higgs bosons are: H → t 4 t → Wbt, Ztt, htt and H → b 4 b → Wtb, Zbb, hbb, where t 4 (b 4 ) is the new up-type (down-type) quark mass eigenstate. In the numerical analysis we assume the CP even Higgs boson in the two Higgs doublet model type-II but the signatures are relevant for many other scenarios. We identify the region of the parameter space where these decay modes are significant or can even dominate, and thus they provide the best opportunities for the simultaneous discovery of a new Higgs boson and vectorlike quarks. We further explore the reach of the High Luminosity LHC for two representative decay modes,t 4 → Zt → ℓℓt and b 4 → Zb → ℓℓb, and found that cross sections at a 0.1 fb level can be probed with simple cut based analyses. We also find that the rates for Higgs cascade decays can be much larger than the rates for a single production of vectorlike quarks. Furthermore, the reach for vectorlike quarks in Higgs cascade decays and pair production extends to comparable masses.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2024

Dark fluxes from electromagnetic cascades

We study dark sector production in electromagnetic (EM) cascades. This problem requires accurate simulations of Standard Model (SM) and dark sector processes, both of which impact angular and energy distributions of emitted particles that ultimately determine flux predictions in a downstream detector. We describe the minimal set of QED processes which must be included to faithfully reproduce a SM cascade, and identify a universal algorithm to generate a dark sector flux given a Monte-Carlo simulation of a SM shower. We provide a new tool, "Image missing", which simulates EM cascades with associated dark vector production, and compare it against existing literature and “off the shelf” tools. The signal predictions at downstream detectors can strongly depend on the nontrivial interplay (and modelling) of SM and dark sector processes, in particular multiple Coulomb scattering and positron annihilation. We comment on potential impacts of these effects for realistic experimental setups.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2018

{sup 232,234,236}U Removal from Contaminated Waste Uranium Hexafluoride in a Double Cascade

Two schemes with double cascades are presented for purifying waste uranium hexafluoride with high {sup 232,234,236}U content. A large flow of native uranium hexafluoride and a low flow of waste uranium hexafluoride are fed into the first cascade. One of the external outgoing streams contains low-enrichment uranium hexafluoride with prescribed {sup 235}U concentration <5%. The {sup 235}U concentration of the second outgoing stream coincides with the feed concentration of waste uranium hexafluoride. {sup 232,234,236}U concentration reduction occurs in this stream, corresponding to purified waste uranium hexafluoride. The obtained products can be used effectively for enrichment in a cascade meeting ASTM C 996–15 specifications for low-enrichment commercial uranium.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2018

Mathematical Modeling of Nonstationary Separation Processes in a Cascade of Gas Centrifuges for Separation of Tungsten Isotopes

We have developed and program-realized a mathematical model of nonstationary separation processes proceeding in cascades of gas centrifuges for separation of multicomponent isotope mixtures. With the help of this model we have calculated the parameters of nonstationary separation processes proceeding in the cascades of gas centrifuges for tungsten isotope separation. It has been shown that the model adequately describes the nonstationary processes in the cascade and is suitable for calculating their parameters during separation of multicomponent isotope mixtures.

42 ENGINEERING↗
DOE OSTI2019

Vehicle detection based on visual attention mechanism and adaboost cascade classifier in intelligent transportation systems

Robust and efficient vehicle detection is an essential task in intelligent transportation systems (ITS). Unfortunately, due to a great diversity of vehicle profiles and outdoor illumination conditions, it is a challenge to detect vehicles effectively. This paper proposes a method for high-performance vehicle detection based on visual attention mechanism and AdaBoost cascade classifier. Our method constructs the structural Haar features and extracts the features of samples using structural Haar features and trains an AdaBoost cascade classifier. Then we use the visual attention mechanism to extract the target candidate region. At last, we generate detecting sub-windows in the candidate region and discriminate them with the cascade classifier to realize vehicle detection. We compare the performance of this method against two variants, one using MB–LBP features and another using Haar features. The experimental results demonstrate satisfactory performance for the proposed method in term of training speed, detecting speed and detecting accuracy.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2016

The effect of alloying nickel with iron on the supersonic ballistic stage of high energy displacement cascades

Previous experimental and theoretical studies suggest that the production of extended defect structures by collision cascades is inhibited in equiatomic NiFe, in comparison to pure Ni. It is also known that the production of such extend defect structures results from the formation of subcascades by high-energy recoils and their subsequent interaction. A detailed analysis of the ballistics of 40 keV cascades in Ni and NiFe is performed to identify the formation of such subcascades and to assess their spatial distribution. It is found that subcascades in Ni and NiFe are created with nearly identical energies and distributed similarly in space. This suggests that the differences in production of extended defect structures is not related to processes taking place in the ballistic phase of the collision cascade. Lastly, these results can be generalized to other, more chemically complex, concentrated alloys where the elements have similar atomic numbers, such as many high-entropy alloys.

36 MATERIALS SCIENCE↗
DOE OSTI2015

Bifurcations analysis of turbulent energy cascade

This note studies the mechanism of turbulent energy cascade through an opportune bifurcations analysis of the Navier–Stokes equations, and furnishes explanations on the more significant characteristics of the turbulence. A statistical bifurcations property of the Navier–Stokes equations in fully developed turbulence is proposed, and a spatial representation of the bifurcations is presented, which is based on a proper definition of the fixed points of the velocity field. The analysis first shows that the local deformation can be much more rapid than the fluid state variables, then explains the mechanism of energy cascade through the aforementioned property of the bifurcations, and gives reasonable argumentation of the fact that the bifurcations cascade can be expressed in terms of length scales. Furthermore, the study analyzes the characteristic length scales at the transition through global properties of the bifurcations, and estimates the order of magnitude of the critical Taylor-scale Reynolds number and the number of bifurcations at the onset of turbulence.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2015

Superradiant cascade emissions in an atomic ensemble via four-wave mixing

We investigate superradiant cascade emissions from an atomic ensemble driven by two-color classical fields. The correlated pair of photons (signal and idler) is generated by adiabatically driving the system with large-detuned light fields via four-wave mixing. The signal photon from the upper transition of the diamond-type atomic levels is followed by the idler one which can be superradiant due to light-induced dipole–dipole interactions. We then calculate the cooperative Lamb shift (CLS) of the idler photon, which is a cumulative effect of interaction energy. We study its dependence on a cylindrical geometry, a conventional setup in cold atom experiments, and estimate the maximum CLS which can be significant and observable. Manipulating the CLS of cascade emissions enables frequency qubits that provide alternative robust elements in quantum network. - Highlights: • Superradiance from a cascade atomic transition. • Correlated photon pair generation via four-wave mixing. • Dynamical light–matter couplings in a phased symmetrical state. • Cooperative Lamb shift in a cylindrical atomic ensemble.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2012

Annealing simulation of cascade damage in -Fe- Damage energy and temperature dependence analyses

In this paper, kinetic Monte Carlo method was applied to investigate the long time evolution of cascade damage prepared by molecular dynamics simulations in -Fe up to recoil energy of more than 200 keV. We conducted thorough investigation on how the surviving defects vary with cascade damage energy and annealing temperature. The results can be used for input parameters of rate equations to simulate microstructural evolution under irradiation. The study also suggested that neighboring sub-cascades evolves almost independently during annealing, and that the temperature dependence of the annealing results can be explained by the temperature dependence of vacancy-migration and vacancy-dissociation probabilities.

99 GENERAL AND MISCELLANEOUS↗
DOE OSTI2026

Enabling event-by-event precision in γ-ray cascades for neutron-induced reactions

Neutron-induced γ-ray spectra provide key inputs for modern active interrogation applications. A precise modeling of the nuclear reaction and subsequent emission of γ rays is challenging and often impossible due to limitations on evaluated data file formats and nuclear transport simulation codes. We present a framework that addresses these challenges by combining experimental data and reaction-model calculation outputs into an extended candidate version of the Generalized Nuclear Data Structure (GNDS) file, the successor format for the legacy Evaluated Nuclear Data File (ENDF-6). This proposed GNDS hierarchical format contains all the necessary ingredients for inline γ-ray cascade reproduction with event-by-event precision, including continuum–continuum and continuum–discrete transitions following neutron-capture and inelastic neutron scattering reactions. Cascade-event generation based on our approach demonstrates improved energy conservation on an event-by-event basis and permits the use of γ-γ coincidences in applications. This work offers, for the first time, a method to generate neutron-capture and inelastic neutron-scattering γ-ray cascades where energy conservation, correlations, and experimental primaries are fully accounted for.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2015

Zinc promotes proliferation and activation of myogenic cells via the PI3K/Akt and ERK signaling cascade

Skeletal muscle stem cells named muscle satellite cells are normally quiescent but are activated in response to various stimuli, such as injury and overload. Activated satellite cells enter the cell cycle and proliferate to produce a large number of myogenic progenitor cells, and these cells then differentiate and fuse to form myofibers. Zinc is one of the essential elements in the human body, and has multiple roles, including cell growth and DNA synthesis. However, the role of zinc in myogenic cells is not well understood, and is the focus of this study. We first examined the effects of zinc on differentiation of murine C2C12 myoblasts and found that zinc promoted proliferation, with an increased number of cells incorporating EdU, but inhibited differentiation with reduced myogenin expression and myotube formation. Furthermore, we used the C2C12 reserve cell model of myogenic quiescence to investigate the role of zinc on activation of myogenic cells. The number of reserve cells incorporating BrdU was increased by zinc in a dose dependent manner, with the number dramatically further increased using a combination of zinc and insulin. Akt and extracellular signal-regulated kinase (ERK) are downstream of insulin signaling, and both were phosphorylated after zinc treatment. The zinc/insulin combination-induced activation involved the phosphoinositide 3-kinase (PI3K)/Akt and ERK cascade. We conclude that zinc promotes activation and proliferation of myogenic cells, and this activation requires phosphorylation of PI3K/Akt and ERK as part of the signaling cascade. - Highlights: • Zinc has roles for promoting proliferation and inhibition differentiation of C2C12. • Zinc promotes activation of reserve cells. • Insulin and zinc synergize activation of reserve cells. • PI3K/Akt and ERK cascade affect zinc/insulin-mediated activation of reserve cells.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2024

Cell-Free Systems Biology: Characterizing Central Metabolism of Clostridium thermocellum with a Three-Enzyme Cascade Reaction

Genetic approaches have been traditionally used to understand microbial metabolism, but this process can be slow in nonmodel organisms due to limited genetic tools. An alternative approach is to study metabolism directly in the cell lysate. This avoids the need for genetic tools and is routinely used to study individual enzymatic reactions but is not generally used to study systems-level properties of metabolism. Here we demonstrate a new approach that we call “cell-free systems biology”, where we use well-characterized enzymes and multienzyme cascades to serve as sources or sinks of intermediate metabolites. This allows us to isolate subnetworks within metabolism and study their systems-level properties. To demonstrate this, we worked with a threeenzyme cascade reaction that converts pyruvate to 2,3-butanediol. Although it has been previously used in cell-free systems, its pH dependence was not well characterized, limiting its utility as a sink for pyruvate. We showed that improved proton accounting allowed better prediction of pH changes and that active pH control allowed 2,3-butanediol titers of up to 2.1 M (189 g/L) from acetoin and 1.6 M (144 g/L) from pyruvate. The improved proton accounting provided a crucial insight that preventing the escape of CO 2 from the system largely eliminated the need for active pH control, dramatically simplifying our experimental setup. We then used this cascade reaction to understand limits to product formation in Clostridium thermocellum, an organism with potential applications for cellulosic biofuel production. We showed that the fate of pyruvate is largely controlled by electron availability and that reactions upstream of pyruvate limit overall product formation.

09 BIOMASS FUELS↗
DOE OSTI2025

Spatially Aligned Binary Single-Site Catalyst on Defective SiO 2 for Cascading Reactions

Capitalizing on the success of single-atom catalysts (SACs), dual-atom catalysts (DACs) have emerged as a new frontier in heterogeneous catalysis. However, most SACs and DACs studies seek to uniformly distribute the catalytic sites on the support material, which can hinder their effectiveness in intricate multistep cascading reactions. Particularly, it is a grand challenge to precisely control the spatial distribution of two different single sites forming binary sites so that reactants and intermediates contact the catalytic sites in the exact sequence required by the reaction steps. Here, in this work, we report a new type of binary single-site catalyst, Cu 1 –Zr 1 @SiO 2 , with Cu 1 and Zr 1 sites spatially aligned with the reaction sequence of the cascade reactions. The catalyst is synthesized by a modified reverse microemulsion approach, with single Cu sites anchored by nonbridging oxygen hole centers, which were induced by doping single Zr sites into SiO 2 . Low-energy ion scattering spectroscopy (LEIS) reveals that the outermost surface of the catalyst contains only Cu single sites, while the Zr sites are dispersed in the bulk. The catalytic performance is demonstrated in ethanol conversion to butenes, a model cascade reaction which includes ethanol dehydrogenation and aldol condensation steps. The precisely spatially controlled binary sites enable ethanol to first undergo dehydrogenation to acetaldehyde on Cu sites, followed by aldol condensation of acetaldehyde on Zr sites. As a result, C 3+ olefins selectivity as high as 77.0% (56.0% selectivity of butenes) is achieved by suppressing ethylene formation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗