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At least 307 records · Page 17

Smoke-Point Properties of Nonbuoyant Round Laminar Jet Diffusion Flames

The laminar smoke-point properties of non-buoyant round laminar jet diffusion flames were studied emphasizing results from long-duration (100-230 s) experiments at microgravity carried out in orbit aboard the space shuttle Columbia. Experimental conditions included ethylene- and propane-fueled flames burning in still air at an ambient temperature of 300 K, pressures of 35-130 kPa, jet exit diameters of 1.6 and 2.7 mm, jet exit velocities of 170-690 mm/s, jet exit Reynolds numbers of 46-172, characteristic flame residence times of 40-302 ms, and luminous flame lengths of 15-63 mm. Contrary to the normal-gravity laminar smoke point, in microgravity the onset of laminar smoke-point conditions involved two flame configurations: closed-tip flames with soot emissions along the flame axis and open-tip flames with soot emissions from an annular ring about the flame axis. Open-tip flames were observed at large characteristic flame residence times with the onset of soot emissions associated with radiative quenching near the flame tip: nevertheless, unified correlations of laminar smoke-point properties were obtained that included both flame configurations. Flame lengths at laminar smoke-point conditions were well correlated in terms of a corrected fuel flow rate suggested by a simplified analysis of flame shape. The present steady and nonbuoyant flames emitted soot more readily than non-buoyant flames in earlier tests using ground-based microgravity facilities and than buoyant flames at normal gravity, as a result of reduced effects of unsteadiness, flame disturbances, and buoyant motion. For example, present measurements of laminar smokepoint flame lengths at comparable conditions were up to 2.3 times shorter than ground-based microgravity measurements and up to 6.4 times shorter than buoyant flame measurements. Finally, present laminar smoke-point flame lengths were roughly inversely proportional to pressure to a degree that is a somewhat smaller than observed during earlier tests both at microgravity (using ground-based facilities) and at normal gravity,

Urban, D. L.↗

Satellite-based Assessment of Fire Impacts on Ecosystem Changes in West Africa

Fires bum many vegetated regions of the world to a variety of degrees and frequency depending on season. Extensive biomass burning occurs in most parts of sub-Saharan Africa, posing great threat to ecosystem stability among other real and potential adverse impacts. In Africa, such landscape-scale fires are used for various agricultural purposes, including land clearing and hunting, although there may be a limited number of cases of fires ignited by accident or due to arson. Satellite remote sensing provides the most practical means of mapping fires, because of their sudden and aggressive nature coupled with the tremendous heat they generate. Recent advancements in satellite technology has enabled, not only the identification of fire locations, but also the measurement of fire radiative energy (FRE) release rate or power (FRP), which has been found to have a direct linear relationship with the rate of biomass combustion. A recent study based on FRP measurements from the Moderate-resolution imaging Spectro-radiometer (MODIS) sensor aboard the Terra and Aqua satellites revealed that, among all the regions of the world where fires occur, African regions rank the highest in the intensity of biomass burning per unit area of land during the peak of the burning season. In this study, we will analyze the burning patterns in West Africa during the last several years and examine the extent of their impacts on the ecosystem dynamics, using a variety of satellite data. The study introduces a unique methodology that can be used to build up the knowledge base from which decision makers can obtain scientific information in fomulating policies for regulating biomass burning in the region.

Ichoku, Charles↗

NASA Multipoint LDI Development

Multipoint Lean-Direct-Injection (LDI) is a combustor concept in which a large number of fuel injectors and fuel-air mixers are used to quickly and uniformly mix the fuel and air so that ultralow levels of NO, are produced. Each fuel injector has an air swirler associated with it for fuel-air mixing and to establish a small recirculation and burning zone. A concept in which there are 36 fuel injectors in the space of a conventional single fuel injector has been tested in a flame tube. A greater than 80 percent reduction in NO, at high power conditions (400 psia, 1000 "Finlet) was achieved. Alternate concepts with 9,25,36 or 49 fuel injectors are being investigated in flame tube tests for their low NO, potential and with fuel staging to improve the turn-down ratio at low power conditions. A preliminary sector concept of a large engine design has been successfully tested at inlet conditions of 700 psia and 1100 O F . This concept had one half the number of fuel injectors per square inch as the flame tube configuration with 36 fuel injectors, and the NO, reduction was 65 percent of the ICAO standard. Future regional engine size sector tests are planned for the 2nd quarter of FY02 and large engine size sector tests for the 1st quarter of FY03.

Tacina, Robert↗

DNS of Hydrodynamic Instabilities of Laminar H2/O2/N2 Flames at Elevated Pressure

The atypical combustion properties of hydrogen have long provided an interest for hydrogen-enriched combustion, emphasized in recent years by increasingly stringent emission regulations. Significant work has been focused on the small hydrocarbon(C1-C3)/hydrogen blends, but much less is known about the effect of hydrogen on heavier hydrocarbon combustion, of interest for the aviation and automotive industry. In this work, we perform direct numerical simulations (DNS) of spherically expanding laminar n-dodecane/H2 flames in a constant-volume vessel at elevated pressure and a range of hydrogen seeding levels. A low Mach number model is used to represent the gas and flame dynamics allowing for a temporally varying, spatially homogeneous pressure field, while also enabling numerical evolution of the system numerically at time step sizes governed by the advective CFL limit rather than acoustic processes. We use an adaptive mesh refinement (AMR) approach to tackle the large separation of scales associated with high pressure premixed flame surfaces propagating in a laboratory-scale closed domain. We incorporate detailed chemistry and transport models for the reacting flow and focus the analysis on the effects of the pressure rise on the flame propagation characteristics and morphology as the hydrogen content is increased. The presence of fast diffusive H2 and the pressure rise results in dramatic thinning of the flame and the potential onset of hydrodyanmic and theromdiffusive instabilities. We assess the potential role of these instabilities on the ability to accurately measure laminar burning speed experimentally based on the mean flame surface propagation speed.

high pressure↗

Hybrid combustion modeling approach for turbulent jet ignition in natural-gas pre-chamber spark-ignition engines at high EGR

Here, this study presented a hybrid modeling approach for simulating turbulent jet ignition and combustion processes in a natural-gas pre-chamber spark-ignition engine operating under exhaust gas recirculation (EGR) diluted conditions. In-depth analyses of experimental data and simulation results from previous work [Chinnathambi et al., ICEF2021-67836; Kim et al., Fuel 409: 137815, 2026] revealed two key findings: (i) the magnitude of pressure difference between the pre-chamber and main chamber ($∆P_{PC-MC}$) was positively correlated with the combustion duration from the moment of $∆P_{PC-MC}=0$ to the point of 5% mass fraction burned, with larger $∆P_{PC-MC}$ associated with longer duration; and (ii) the turbulent combustion regime in the main chamber transitioned from the broken reaction zone to the corrugated flamelet regime, with the Karlovitz number exceeding 100 immediately after turbulent hot jets were ejected from nozzles, coinciding with observed local extinction events. To accurately simulate the entire combustion process, a hybrid approach was developed under Reynolds-Averaged Navier Stokes framework, combining the G-equation model for pre-chamber combustion with the multi-zone well-stirred reactor approach and a turbulence-chemistry interaction (TCI) submodel for main chamber combustion. The TCI submodel accounted for the attenuation of reaction rates due to turbulent strain and modeled local extinction by suppressing reaction rates under certain flow and flame conditions. When applied to three EGR rate conditions toward the dilution limit, the hybrid modeling approach accurately reproduced experimental data in terms of cylinder pressure, apparent heat release rate, and the observed positive correlation, including the delayed onset of main chamber combustion—a feature not captured by existing combustion models.

computational fluid dynamics simulation↗

Stochastic Optimization to Find Optimum Beginning-of-Life Core Configuration of Stable Salt Reactor with Online Refueling

A stochastic optimization method has been developed to find an optimum equilibrium cycle core configuration of the waste-burning stable salt reactor, which is a fast-spectrum molten salt reactor with frequent online refueling. An optimum core configuration was determined with the goal of minimizing radial power peaking. Because of the vast number of potential candidate core configurations, stochastic optimization was applied based on simulated annealing and an additional acceleration method, which screened out unpromising core configurations. It has been demonstrated that the developed stochastic optimization method successfully finds the optimal core configuration regardless of the initial guess and outperforms the gradient descent approach. In addition, it has been observed that the use of a so-called out-in core configuration as the initial guess speeds up convergence of the iterative solution more than five times. Based on the searched optimum equilibrium cycle core configuration, new beginning-of-life (BOL) core configurations have been developed. In conclusion, the new BOL core configurations will be used in developing optimum refueling strategies.

Moltex static salt reactor↗

A new interpretation of luminous blue stars

A major revision of current theoretical ideas about the brightest blue stars must be made if Carson's (1976) radiative opacities are adopted in stellar models. Unlike earlier opacities, these exhibit a large 'bump' due to CNO ionization, which leads to very strong central condensation, convective instability, and pulsational instability in hot diffuse stellar envelopes. Despite a number of theoretical uncertainties, the new picture of the structure of very luminous stars is reasonably successful in accounting for a variety of previously unexplained observations. The stellar models for the phase of core hydrogen burning predict large radii and rather cool effective temperatures for O stars and a spreading out of the main-sequence band in the H-R diagram toward luminous cool supergiants for masses higher than about 20 solar masses. In massive X-ray binary systems, circular orbits and supergiant-like visual companions are expected to be quite common. Long-period variability is predicted to exist for massive blue supergiants of luminosity class Ia. The models for helium stars predict large radii and rather cool effective temperatures for Wolf-Rayet stars, as well as multimodal pulsational instability and, possibly, surface turbulence for these stars.

Stothers, R.↗

Parametric Studies of the Ejector Process within a Turbine-Based Combined-Cycle Propulsion System

Performance characteristics of the ejector process within a turbine-based combined-cycle (TBCC) propulsion system are investigated using the NPARC Navier-Stokes code. The TBCC concept integrates a turbine engine with a ramjet into a single propulsion system that may efficiently operate from takeoff to high Mach number cruise. At the operating point considered, corresponding to a flight Mach number of 2.0, an ejector serves to mix flow from the ramjet duct with flow from the turbine engine. The combined flow then passes through a diffuser where it is mixed with hydrogen fuel and burned. Three sets of fully turbulent Navier-Stokes calculations are compared with predictions from a cycle code developed specifically for the TBCC propulsion system. A baseline ejector system is investigated first. The Navier-Stokes calculations indicate that the flow leaving the ejector is not completely mixed, which may adversely affect the overall system performance. Two additional sets of calculations are presented; one set that investigated a longer ejector region (to enhance mixing) and a second set which also utilized the longer ejector but replaced the no-slip surfaces of the ejector with slip (inviscid) walls in order to resolve discrepancies with the cycle code. The three sets of Navier-Stokes calculations and the TBCC cycle code predictions are compared to determine the validity of each of the modeling approaches.

Georgiadis, Nicholas J.↗

COVID-19 Lockdowns Drive Decline in Active Fires in Southeastern United States

Fire is a common ecosystem process in forests and grasslands worldwide. Increasingly, ignitions are controlled by human activities either through suppression of wildfires or intentional ignition of prescribed fires. The Southeastern United States leads the nation in prescribed fire, burning ca. 80% of the countries extent annually. The COVID-19 pandemic radically changed human behavior as workplaces implemented social-distancing guidelines and provided an opportunity to evaluate relationships between humans and fire as fire management plans were postponed or cancelled. Using active fire data from satellite-based observations, we found that in the Southeastern United States, COVID-19 led to a 21% reduction in fire activity compared to the 2003-2019 average. The reduction was more pronounced for federally managed lands, up to 41% below average compared to the past 20-years (38% below average compared to the past decade). Declines in fire activity were partly affected by an unusually wet February before the COVID-19 shutdown began in mid-March 2020. Despite the wet spring, the predicted number of active fire detections was still lower than expected, confirming a COVID-19 signal on ignitions. In addition, prescribed fire management statistics, reported by US federal agencies, confirmed the satellite observations, and showed that following the wet February and before the mid-March COVID-19 shutdown, cumulative burned area was approaching record highs across the region. With fire return intervals in the Southeastern United States as frequent as 1-2 years, COVID-19 fire impacts will contribute to an increasing backlog in necessary fire management activities, affecting biodiversity and future fire danger.

Biological Sciences↗

Formation Process of Particles and Cloud Condensation Nuclei Over the Amazon Rainforest: The Role of Local and Remote New-Particle Formation

Understanding the formation processes of particles and cloud condensation nuclei (CCN) in pristine environments is a major challenge in accurately assessing anthropogenic radiative forcing. Here, using a state-of-the-art model that systematically simulates the chemical processes controlling new-particle formation (NPF) and multi-scale chemical transport, we find that NPF contributes ~90% of the particle number and ~80% of the CCN at 0.5% supersaturation (CCN0.5%) in the pristine Amazon boundary layer during the wet season. The corresponding contributions are only ~30% and ~20% during the dry season because of prevalent biomass burning. In both seasons, about half of the NPF-induced particles and ~85% of the NPF-induced CCN0.5% in the boundary layer originate from the long-range transport of new particles formed hundreds to thousands of kilometers away. Moreover, about 50–65% of the NPF-induced particles and 35–50% of the NPF induced CCN0.5% originate from the downward transport of new particles formed in the free troposphere.

54 ENVIRONMENTAL SCIENCES↗

Characterizing the performance of a POPS miniaturized optical particle counter when operated on a quadcopter drone

We first validate the performance of the Portable Optical Particle Spectrometer (POPS), a small light-weight and high sensitivity optical particle counter, against a reference scanning mobility particle sizer (SMPS) for a month-long deployment in an environment dominated by biomass burning aerosols. Subsequently, we examine any biases introduced by operating the POPS on a quadcopter drone, a DJI Matrice 200 V2. We report the root mean square difference (RMSD) and mean absolute difference (MAD) in particle number concentrations (PNCs) when mounted on the UAV and operating on the ground and when hovering at 10 m. When wind speeds are low (less than 2.6 m s –1 ), we find only modest differences in the RMSDs and MADs of 5 % and 3 % when operating at 10 m altitude. When wind speeds are between 2.6 and 7.7 m s –1 the RMSDs and MADs increase to 26.2 % and 19.1 %, respectively, when operating at 10m altitude. No statistical difference in PNCs was detected when operating on the UAV in either ascent or descent. We also find size distributions of aerosols in the accumulation mode (defined by diameter, d, where 0.1 ≤ d ≤ 1 µm) are relatively consistent between measurements at the surface and measurements at 10 m altitude, while differences in the coarse mode (here defined by d > 1 µm) are universally larger. Our results suggest that the impact of the UAV rotors on the POPS PNCs are small at low wind speeds, but when operating under a higher wind speed of up to 7.6 m s –1 , larger discrepancies occur. In addition, it appears that the POPS measures sub-micron aerosol particles more accurately than super-micron aerosol particles when airborne on the UAV. These measurements lay the foundations for determining the magnitude of potential errors that might be introduced into measured aerosol particle size distributions and concentrations owing to the turbulence created by the rotors on the UAV.

47 OTHER INSTRUMENTATION↗

Red supergiants and neutrino emission. II.

Investigation of the variation with stellar mass of the ratio of the numbers of blue and red supergiants. Statistical data for supergiants in young open clusters and subgroups of associations are collected to supplement a more restricted list presented earlier. Improved methods are used to identify hydrogen-burning supergiants, as well as faint supergiant remnants of binary mass exchange, and to arrange the bright evolved supergiants in order of their masses. Neither of these two operations requires knowledge of stellar distances or luminosities. Relevant published work on stellar evolution, rotation, mass loss, and duplicity is used to predict upper and lower limits on the blue-to-red ratio. It is concluded that the observed paucity of very massive red supergiants (and of carbon stars) confirms and extends the trend previously observed, and thereby supports the idea of neutrino-induced acceleration of the carbon burning and later phases of evolution; the h and chi Persei association shows the same dependence of the blue-to-red-ratio on stellar mass as do other clusters and associations; and a moderate decrease of the blue-to-red ratio is observed with increasing galactocentric distance in the Galaxy (as in M33) and seems to be due to a relative scarcity of extremely young stars in distant galactic regions.

Stothers, R.↗

Overall fluctuating pressure levels on prospective space shuttle launch configurations at Mach numbers from 0.8 to 2.2

Overall fluctuating pressure levels of seven space shuttle launch configurations are presented. The model was a 4-percent-scale space shuttle vehicle, tested in both a 11- by 11-foot transonic wind tunnel and a 9- by 7-foot supersonic wind tunnel. Mach numbers varied from 0.8 to 2.2, and the angle of attack range was from -8 deg to 8 deg at angles of sideslip of -5 deg, and 5 deg. The model configurations included both series-burn and parallel-burn configurations, two canopy configurations, two positions of the orbiter nose relative to the HO tank nose and two HO tank nose-cone angles (15 deg and 20 deg). The fluctuating pressure levels are presented in three forms.

Dods, J. B., Jr.↗

Effects of preferential diffusion on the burning intensity of curved flames

Using the Bunsen flame as a model curved flame, the coupled influence of preferential diffusion and flame stretch on the burning intensity of lean and rich mixtures of methane, propane, butane, ethylene, and hydrogen with air has been experimentally studied. The results substantiate theoretical predictions and quantify previous experimental observations that, for mixtures whose effective Lewis numbers (Le) are less than unity, the flame temperature is less than the adiabatic flame temperature. This temperature also decreases towards the flame tip, which has the largest curvature and therefore may locally extinguish. The dominance of diffusional transport in influencing the intensity of curved flames is demonstrated by showing that the tip opening of the highly diffusive hydrogen/air flames occurs at constant hydrogen equivalence ratios of about 1.15 to 1.20, being almost independent of the flow intensity and uniformity.

Mizomoto, M.↗

Investigation of Ammonia Carrier Materials for Next Generation Ammonia Dosing System - CRADA 334 (Abstract)

Lean-burn gasoline and diesel engines can offer substantially higher fuel efficiency, good driving performance, and reduced carbon dioxide emission compared to stoichiometric gasoline engines. Various catalyst technologies have been developed to remove the pollutants from these engines. For example, a three-way catalyst (TWC) is used to remove hydrocarbons (HC), carbon monoxide (CO), and nitrogen oxides (NOx) from gasoline engines during the stoichiometric conditions. During the lean-burn conditions, a TWC or a diesel oxidation catalyst (DOC) is used to control HC and CO emissions. NOx is removed by either lean NOx trap catalyst (LNT) that can store NOx under lean conditions and reduce NOx under rich conditions, or selective catalytic reduction catalyst (SCR) that can selectively remove NOx with a reducing agent. Among the NOx reduction catalyst technologies, SCR offers a number of advantages, including excellent NOx reduction efficiency over a wide range of temperatures and overall lower system cost. In fact, the SCR technology using ammonia (NH3) as reductant has been proven effective and used commercially for the removal of NOx emissions from stationary sources since the 1970s. Currently, SCR is being used to meet the NOx emission standards for diesel engines in Europe and North America, and also being considered for meeting the future NOx emission standards for lean-burn gasoline engines. Because of the challenges associated with storage, handling and transportation of ammonia on a vehicle, aqueous urea solution (e.g., Diesel Exhaust Fluid, AdBlue) has been developed as ammonia storage compound for mobile applications. When the aqueous urea solution is sprayed into exhaust gas stream, urea is decomposed to release ammonia, which then reduces NOx over the downstream SCR catalyst. Although aqueous urea solution technology has enabled automakers and engine manufacturers to meet the current NOx emission standards, this process of releasing ammonia requires a hot exhaust gas and sufficient mixing, creating challenges for low temperature NOx emission control and aftertreatment system packaging. For these reasons, alternative technologies have been developed as ammonia sources (e.g., solid urea, ammonium carbamate, metal ammine chloride) during the past few years. These technologies promise more convenient handling and distribution of ammonia sources, and help maximize the low-temperature performance of SCR catalysts and reduce the overall system volume and weight. However, none of these alternative technologies can be successfully implemented without the industry consensus. Therefore, the USCAR SCR work group, which is comprised of representatives from GM, Ford, and Chrysler, has decided to investigate the potential alternative ammonia carriers, define common standard vehicle interfaces, and address personal and environmental safety concerns with part suppliers and chemical companies. Under this CRADA Project, USCAR and Battelle will investigate alternative ammonia carrier materials that are currently under development. Based on the data and information derived under the CRADA project, the USCAR SCR work group plans to build the consensus and make recommendations for the industry.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Investigation of Ammonia Carrier Materials for Next Generation Ammonia Dosing System - CRADA 334 (Abstract)

Lean-burn gasoline and diesel engines can offer substantially higher fuel efficiency, good driving performance, and reduced carbon dioxide emission compared to stoichiometric gasoline engines. Various catalyst technologies have been developed to remove the pollutants from these engines. For example, a three-way catalyst (TWC) is used to remove hydrocarbons (HC), carbon monoxide (CO), and nitrogen oxides (NOx) from gasoline engines during the stoichiometric conditions. During the lean-burn conditions, a TWC or a diesel oxidation catalyst (DOC) is used to control HC and CO emissions. NOx is removed by either lean NOx trap catalyst (LNT) that can store NOx under lean conditions and reduce NOx under rich conditions, or selective catalytic reduction catalyst (SCR) that can selectively remove NOx with a reducing agent. Among the NOx reduction catalyst technologies, SCR offers a number of advantages, including excellent NOx reduction efficiency over a wide range of temperatures and overall lower system cost. In fact, the SCR technology using ammonia (NH3) as reductant has been proven effective and used commercially for the removal of NOx emissions from stationary sources since the 1970s. Currently, SCR is being used to meet the NOx emission standards for diesel engines in Europe and North America, and also being considered for meeting the future NOx emission standards for lean-burn gasoline engines. Because of the challenges associated with storage, handling and transportation of ammonia on a vehicle, aqueous urea solution (e.g., Diesel Exhaust Fluid, AdBlue) has been developed as ammonia storage compound for mobile applications. When the aqueous urea solution is sprayed into exhaust gas stream, urea is decomposed to release ammonia, which then reduces NOx over the downstream SCR catalyst. Although aqueous urea solution technology has enabled automakers and engine manufacturers to meet the current NOx emission standards, this process of releasing ammonia requires a hot exhaust gas and sufficient mixing, creating challenges for low temperature NOx emission control and aftertreatment system packaging. For these reasons, alternative technologies have been developed as ammonia sources (e.g., solid urea, ammonium carbamate, metal ammine chloride) during the past few years. These technologies promise more convenient handling and distribution of ammonia sources, and help maximize the low-temperature performance of SCR catalysts and reduce the overall system volume and weight. However, none of these alternative technologies can be successfully implemented without the industry consensus. Therefore, the USCAR SCR work group, which is comprised of representatives from GM, Ford, and Chrysler, has decided to investigate the potential alternative ammonia carriers, define common standard vehicle interfaces, and address personal and environmental safety concerns with part suppliers and chemical companies. Under this CRADA Project, USCAR and Battelle will investigate alternative ammonia carrier materials that are currently under development. Based on the data and information derived under the CRADA project, the USCAR SCR work group plans to build the consensus and make recommendations for the industry.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Turboelectric Distributed Propulsion in a Hybrid Wing Body Aircraft

The performance of the N3-X, a 300 passenger hybrid wing body (HWB) aircraft with turboelectric distributed propulsion (TeDP), has been analyzed to see if it can meet the 70% fuel burn reduction goal of the NASA Subsonic Fixed Wing project for N+3 generation aircraft. The TeDP system utilizes superconducting electric generators, motors and transmission lines to allow the power producing and thrust producing portions of the system to be widely separated. It also allows a small number of large turboshaft engines to drive any number of propulsors. On the N3-X these new degrees of freedom were used to (1) place two large turboshaft engines driving generators in freestream conditions to maximize thermal efficiency and (2) to embed a broad continuous array of 15 motor driven propulsors on the upper surface of the aircraft near the trailing edge. That location maximizes the amount of the boundary layer ingested and thus maximizes propulsive efficiency. The Boeing B777-200LR flying 7500 nm (13890 km) with a cruise speed of Mach 0.84 and an 118100 lb payload was selected as the reference aircraft and mission for this study. In order to distinguish between improvements due to technology and aircraft configuration changes from those due to the propulsion configuration changes, an intermediate configuration was included in this study. In this configuration a pylon mounted, ultra high bypass (UHB) geared turbofan engine with identical propulsion technology was integrated into the same hybrid wing body airframe. That aircraft achieved a 52% reduction in mission fuel burn relative to the reference aircraft. The N3-X was able to achieve a reduction of 70% and 72% (depending on the cooling system) relative to the reference aircraft. The additional 18% - 20% reduction in the mission fuel burn can therefore be attributed to the additional degrees of freedom in the propulsion system configuration afforded by the TeDP system that eliminates nacelle and pylon drag, maximizes boundary layer ingestion (BLI) to reduce inlet drag on the propulsion system, and reduces the wake drag of the vehicle.

Felder, James L.↗

Extreme Molecular Complexity Resulting in a Continuum of Carbonaceous Species in Biomass Burning Tar Balls from Wildfire Smoke

Biomass burning emits a wide range of carbonaceous particles into the atmosphere and has negative impacts on human health and the Earth’s radiative balance. Nonvolatile spherical organic aerosol particles, commonly known as tar balls, represent one of the most abundant particles in aged biomass burning smoke. However, the detailed molecular-level composition of ambient tar balls is largely unknown but critical to access their environmental impacts. Ambient aerosol samples collected during a wildfire event, which were ~90% tar balls by number fraction, were analyzed using ultrahigh resolution Orbitrap Elite mass spectrometry with four complementary ionization modes. Our results show the molecular composition of tar balls to be complex, composed of over 10,000 molecular formulas. Model estimated saturation mass concentrations and relative humidity dependent glass transition temperatures were consistent with low volatility and solid morphology as expected for tar balls. Room-temperature evaporation kinetics showed that these particles were composed of ~90% non-volatile species. The molecular complexity detected here signifies a continuum of carbonaceous species, ranging from C3 to C45 with continuous ranges of oxygenation and hydrogen saturation for each Cn. Approximately 24% of molecular formulas were estimated the be highly aromatic, which could indicate chemical compounds with negative health effects, and which may contribute to visible light absorption. The carbon continuum observed here has significant implications for the molecular characterization of atmospheric organic matter. The level of complexity detected here should not be ignored in future studies and we demonstrate that multiple analytical methods may be required to suitably interpret this complexity on a molecular level.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗