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At least 307 records · Page 17

Studies related to primitive chemistry. A proton and nitrogen-14 nuclear magnetic resonance amino acid and nucleic acid constituents and a and their possible relation to prebiotic

Preliminary proton nuclear magnetic resonance (NMR) studies were made to determine the applicability of this technique for the study of interactions between monomeric and polymeric amino acids with monomeric nucleic acid bases and nucleotides. Proton NMR results for aqueous solutions (D2O) demonstrated interactions between the bases cytosine and adenine and acidic and aromatic amino acids. Solutions of 5'-AMP admixed with amino acids exhibited more complex behavior but stacking between aromatic rings and destacking at high amino acids concentration was evident. The multisite nature of 5'-AMP was pointed out. Chemical shift changes for adenine and 5'-AMP with three water soluble polypeptides demonstrated that significant interactions exist. It was found that the linewidth-pH profile of each amino acid is unique. It is concluded that NMR techniques can give significant and quantitative data on the association of amino acid and nucleic acid constituents.

Manatt, S. L.↗

Lithium cell test results

Three lithium SO2 cells, two lithium CF cells, and a vinyl chloride cell, all with crimped seals, and all strictly experimental, were independently discharged on resistors. Three temperatures were used and several different storage temperatures. Discharge rate generally on the nominal discharges were 0.1 amp, 0.5 amp, and 1 amp. Tests results show that the crimp seals are inadequate, especially for the SO2 cells. Normal discharges present no hazards. All cells discharge to zero. The problem of lithium cell explosions, such as occurred during off-limits testing, is discussed.

Bragg, B. J.↗

Effect of positive pulse charge waveforms on cycle life of nickel-zinc cells

Five amp-hour nickel-zinc cells were life cycled to evaluate four different charge methods. Three of the four waveforms investigated were 120 Hz full wave rectified sinusoidal (FWRS), 120 Hz silicon controlled rectified (SCR), and 1 kHz square wave (SW). The fourth, a constant current method, was used as a baseline of comparison. Three sealed Ni-Zn cells connected in series were cycled. Each series string was charged at an average c/20 rate, and discharged at a c/2.5 rate to a 75% rated depth. Results indicate that the relatively inexpensive 120 Hz FWRS charger appears feasible for charging 5 amp-hour nickel-zinc cells with no significant loss in average cycle life when compared to constant current charging. The 1-kHz SW charger could also be used with no significant loss in average cycle life, and suggests the possibility of utilizing the existing electric vehicle chopper controller circuitry for an on-board charger. There was an apparent difference using the 120 Hz SCR charger compared to the others, however, this difference could be due to an inadvertent severe overcharge, which occurred prior to cell failure. The remaining two positive pulse charging waveforms, FWRS and 1 kHz, did not improve the cycle life of 5 amp-hour nickel-zinc cells over that of constant current charging.

Smithrick, J. J.↗

Aminoacyl-nucleotide reactions - Studies related to the origin of the genetic code and protein synthesis

In the present paper, a report is presented on the effect of pH and carbonate on the hydrolysis rate constants of N-blocked and free aminoacyl adenylate anhydrides. Whereas the hydrolysis of free aminoacyl adenylates seems principally catalyzed by OH(-), the hydrolysis of the N-blocked species is also catalyzed by H(+), giving this compound a U-shaped hydrolysis vs. pH curve. Furthermore, at pH's less than 8, carbonate has an extreme catalytic effect on the hydrolysis of free aminoacyl-AMP anhydride, but essentially no effect on the hydrolysis of N-blocked aminoacyl-AMP anhydride. Furthermore, the N-blocked aminoacyl-AMP anhydride is a very efficient generator of peptides using free glycine as acceptor. The possible significance of the observations to prebiological peptide synthesis is discussed.

Mullins, D. W., Jr.↗

The discharge mechanism of the high-temperature arc

The mechanism of the high temperature Ar arc is interpreted considering those essential points in which it deviates from the known arcs based on earlier measurements and experiments. The following points are discussed individually: the charge carrier balance, the energy balance, the volt amp characteristics, and the difference between high temperature arcs in Ar and N. Besides the volt amp characteristic of a 10 mm long arc in Ar between 10 and 200 amp, the anode fall, cathode fall, and arc gradient were obtained with the aid of probes. The difference between Ar and N arcs are attributed to variations of the heat conditions and electrical conditions at different temperatures of the gas.

Busz-Peuckert, G.↗

The 250AH/90A active lithium-thionyl chloride cell for Centaur-G application

A high rate active Li/SOCl2 cell was designed for use in a 28 volt, 250 amp-hour space battery system. The lithium battery is being considered as a replacement of its heavier silver-zinc counterpart on board the Centaur-G booster rocket which is used to launch payloads from the Space Shuttle cargo bay into deep-space. Basically a feasibility study, this development effort is demonstrating the ability of the lithium cell to deliver up to 90 amps safely at power densities of approximately 25 watts per pound. Test data on 4 prototype units is showing an energy density of 85 watt-hours per pound and 9.0 watt-hours/cu in. The cells tested typically delivered 280 to 300 amp-hours under ambient temperature test conditions using alternating continuous loads of 90, 55, and 20 amperes throughout life. Data from four cells tested are presented to demonstrate the capability of Li/SOCl2 technology for a C/3 discharge rate in active and hermetic cell units.

Zolla, A. E.↗

Network, system, and status software enhancements for the autonomously managed electrical power system breadboard. Volume 1: Project summary

This volume (1 of 4) gives a summary of the original AMPS software system configuration, points out some of the problem areas in the original software design that this project is to address, and in the appendix collects all the bimonthly status reports. The purpose of AMPS is to provide a self reliant system to control the generation and distribution of power in the space station. The software in the AMPS breadboard can be divided into three levels: the operating environment software, the protocol software, and the station specific software. This project deals only with the operating environment software and the protocol software. The present station specific software will not change except as necessary to conform to new data formats.

Mckee, James W.↗

Network, system, and status software enhancements for the autonomously managed electrical power system breadboard. Volume 4: Graphical status display

This volume (4 of 4) contains the description, structured flow charts, prints of the graphical displays, and source code to generate the displays for the AMPS graphical status system. The function of these displays is to present to the manager of the AMPS system a graphical status display with the hot boxes that allow the manager to get more detailed status on selected portions of the AMPS system. The development of the graphical displays is divided into two processes; the creation of the screen images and storage of them in files on the computer, and the running of the status program which uses the screen images.

Mckee, James W.↗

Cartographic products in Space Shuttle earth observations operations

A description is given of the Automated Planning Mission Planning System (AMPS), a computer cartographic system developed by NASA in response to the need to streamline support for an increasing number and frequency of Shuttle missions and to enhance the quality of products produced for mission support. AMPS is menu driven and can plot orbit tracks and revolution times and site boundaries on Mercator projection maps. As an overall site selection process approaches, AMPS reduces the possibility of errors, is time effective, improves SSEOP products, and is adaptable for other related applications.

Lulla, Kamlesh↗

Study of high pressure and high current arcs in the cathode region of an arc heater

This paper investigates the behavior of high pressure, high current arcs in the downstream electrode region (cathode) of an arc heater. Computations are done for operating pressures in the range 50 atm to 200 atm and load currents in the range 6000 amp to 18,000 amp. At high pressures, due to the high current carrying capability of the dense gas, spot size remains reasonably small even for high load currents. Its value is 1.1 mm for a 50 atm arc with a load current of 18,000 amp. By increasing pressure it can be reduced further. Smaller spot size may allow us to design thinner electrode rings. Spot temperatures are high enough to cause ablation of the electrode material. In order to reduce material ablation at very high currents, the operating pressure must also be high and the arc should be rotated.

Durgapal, Prabha↗

Advances in the design of common pressure vessel nickel hydrogen batteries for aerospace applications

Over 7000 low-earth-orbit (LEO) cycles were demonstrated on a full-size aerospace common pressure vessel (CPV) prototype. The battery demonstrated the capability of the basic CPV design to meet the life and reliability requirements of aerospace missions. Subsequent design modifications have been employed to address the shortcomings of the original design and several new prototypes have been fabricated. These include a 12-cell 125 amp-hour geosynchronous earth-orbit (GEO) battery and a 22-cell 10.5 amp-hour LEO battery. Cells for an 80-cell battery intended to demonstrate the high voltage capability of the CPV design have also been fabricated. In addition, assembly of a 20-cell aircraft starting battery prototype is in progress, and testing of a group of 12-volt, 160 amp-hour terrestrial batteries is continuing.

Zagrodnik, Jeffrey P.↗

Investigation into the common mode rejection ratio of the physiological signal conditioner circuit

The common mode rejection ratio (CMRR) of the single operational amplifier (op amp) differential amplifier and of the three operational amplifier differential amplifier was investigated. The three op amp differential amplifier circuit is used in the signal conditioner circuit which amplifies signals such as the electromyograph or electrocardiogram. The investigation confirmed via SPICE modeling what has been observed by others in the recent literature that the CMRR for the circuit can be maximized without precision resistor values or precisely matched op amps. This can be done if one resistor in the final stage can be adjusted either by a potentiometer or by laser trimming in the case of hybrid circuit fabrication.

Obrien, Edward M.↗

Test Report - Fault Current Through Graphite Filament Reinforced Plastic

Tests were performed to determine the damage to samples of composite material when a current carrying wire is shorted to the surface of the composite material, and to determine whether enough current can flow through the material to blow a fuse before damage can occur. Fault current tests were performed on samples of graphite epoxy materials. Samples consisted of six layers of IM7 graphite fiber mat in Hercules 8552 epoxy resin. A variable power supply provided up to 35 amps of current. The high voltage side of the power supply was attached to a wire at the end of a hinged arm, and the low side was attached to the edge of the sample. To test joints, the return was connected to the edge of one sample, and the high side was shorted to the top of the other sample. Tests show that when current exceeds approximately 5 amps, the graphite glows, and the epoxy melts out at the shorted contact. At higher current levels the epoxy burns. At voltages above 15 volts the epoxy outer coat is easily broken, and fire, flame, and a rise in current occur suddenly. When joints are introduced, resistance is increased, and the maximum current resulting from a short circuit to the graphite epoxy is reduced. This condition can easily result in fault current lower than the circuit breaker limit and higher than the 5 amp ignition level. The shorting contact and the joint become hot spots with melting epoxy, smoke, and fire.

Evans, R. W.↗

A Comparison of the Automated Meteorological Profiling System High Resolution Flight Element to the Kennedy Space Center 50 MHz Doppler Wind Profiler

Wind profile measurement and the simulation of aerodynamic loads on a launch vehicle play an important role in determining launch capability and post launch assessment of the vehicle's performance. To date, all United States range certified wind profile measurement systems have been based on balloon tracking. Since the 1960's, the standard used by the National Aeronautics and Space Administration and the Air Force at the Cape Canaveral Air Station (CCAS) for detailed wind profile measurements has been the radar tracked, aerodynamically stabilized Jimsphere balloon system. Currently, the Air Force is nearing certification and operational implementation of the Automated Meteorological Profiling System (AMPS) at CCAS and Vandenburg Air Force Base (VAFB). AMPS uses the Global Positioning System for tracking the Jimsphere balloon. It is anticipated that the AMPS/Jimsphere, named the High Resolution Flight Element (HRFE), will have equivalent, or better resolution than the radar tracked Jimsphere, especially when the balloon is far downrange, at a low elevation angle. By the 1980's, the development of Doppler Wind Profilers (DWP) had become sufficiently advanced to justify an experimental measurement program at Kennedy Space Center (KSC). In 1989 a 50 MHz DWP was installed at KSC. In principal, the 50 MHz DWP has the capability to track the evolution of wind profile dynamics within 5 minutes of a launch. Because of fundamental differences in the measurement technique, there is a significant time and space differential between 50 MHz DWP and HRFE wind profiles. This paper describes a study to quantify these differences from a sample of 50 MHz DWP/HRFE pairs obtained during the AMPS certification test program.

Roberts, Barry C.↗

Performance and Abuse Testing of 5 Year Old Low Rate and Medium Rate Lithium Thionyl Chloride Cells

Most cells survived the 3 amp (A) over-discharge at room temperature for 2 hours. The cell that failed was the LTC-114 after high rate discharge of 500 mA similar to the results of the 1 A over-discharge test. Most cells opened during 0.05 Ohm short circuit test without incident but three LTC-111 cells exploded apparently due to a lack of a thermal cutoff switch. The LTC-114 cells exposed to a hard short of 0.05 Ohms recovered but the LTC-114 cells exposed to a soft short of 1 Ohm did not. This is probably due to the activation of a resetable fuse during a hard short. Fresh cells tend to survive exposure to higher temperatures than cells previously discharged at high rate (1 Amp). LTC-111 cells tend to vent at lower temperatures than the all LTC-114 cells and the LTC-115 cells that were previously discharged at rates exceeding 1 Amp.

Frerker, Rick↗

Integrating Wind Profiling Radars and Radiosonde Observations with Model Point Data to Develop a Decision Support Tool to Assess Upper-Level Winds for Space Launch

On the day-of-launch, the 45th Weather Squadron (45 WS) Launch Weather Officers (LWOs) monitor the upper-level winds for their launch customers to include NASA's Launch Services Program and NASA's Ground Systems Development and Operations Program. They currently do not have the capability to display and overlay profiles of upper-level observations and numerical weather prediction model forecasts. The LWOs requested the Applied Meteorology Unit (AMU) develop a tool in the form of a graphical user interface (GUI) that will allow them to plot upper-level wind speed and direction observations from the Kennedy Space Center (KSC) 50 MHz tropospheric wind profiling radar, KSC Shuttle Landing Facility 915 MHz boundary layer wind profiling radar and Cape Canaveral Air Force Station (CCAFS) Automated Meteorological Processing System (AMPS) radiosondes, and then overlay forecast wind profiles from the model point data including the North American Mesoscale (NAM) model, Rapid Refresh (RAP) model and Global Forecast System (GFS) model to assess the performance of these models. The AMU developed an Excel-based tool that provides an objective method for the LWOs to compare the model-forecast upper-level winds to the KSC wind profiling radars and CCAFS AMPS observations to assess the model potential to accurately forecast changes in the upperlevel profile through the launch count. The AMU wrote Excel Visual Basic for Applications (VBA) scripts to automatically retrieve model point data for CCAFS (XMR) from the Iowa State University Archive Data Server (http://mtarchive.qeol.iastate.edu) and the 50 MHz, 915 MHz and AMPS observations from the NASA/KSC Spaceport Weather Data Archive web site (http://trmm.ksc.nasa.gov). The AMU then developed code in Excel VBA to automatically ingest and format the observations and model point data in Excel to ready the data for generating Excel charts for the LWO's. The resulting charts allow the LWOs to independently initialize the three models 0-hour forecasts against the observations to determine which is the best performing model and then overlay the model forecasts on time-matched observations during the launch countdown to further assess the model performance and forecasts. This paper will demonstrate integration of observed and predicted atmospheric conditions into a decision support tool and demonstrate how the GUI is implemented in operations.

Bauman, William H., III↗

Advanced Modular Power Approach to Affordable, Supportable Space Systems

Recent studies of missions to the Moon, Mars and Near Earth Asteroids (NEA) indicate that these missions often involve several distinct separately launched vehicles that must ultimately be integrated together in-flight and operate as one unit. Therefore, it is important to see these vehicles as elements of a larger segmented spacecraft rather than separate spacecraft flying in formation. The evolution of large multi-vehicle exploration architecture creates the need (and opportunity) to establish a global power architecture that is common across all vehicles. The Advanced Exploration Systems (AES) Modular Power System (AMPS) project managed by NASA Glenn Research Center (GRC) is aimed at establishing the modular power system architecture that will enable power systems to be built from a common set of modular building blocks. The project is developing, demonstrating and evaluating key modular power technologies that are expected to minimize non-recurring development costs, reduce recurring integration costs, as well as, mission operational and support costs. Further, modular power is expected to enhance mission flexibility, vehicle reliability, scalability and overall mission supportability. The AMPS project not only supports multi-vehicle architectures but should enable multi-mission capability as well. The AMPS technology development involves near term demonstrations involving developmental prototype vehicles and field demonstrations. These operational demonstrations not only serve as a means of evaluating modular technology but also provide feedback to developers that assure that they progress toward truly flexible and operationally supportable modular power architecture.

Oeftering, Richard C.↗

Bypass Diode Temperature Tests of a Solar Array Coupon Under Space Thermal Environment Conditions

Tests were performed on a 56-cell Advanced Triple Junction solar array coupon whose purpose was to determine margin available for bypass diodes integrated with new, large multi-junction solar cells that are manufactured from a 4-inch wafer. The tests were performed under high vacuum with coupon back side thermal conditions of both cold and ambient. The bypass diodes were subjected to a sequence of increasing discrete current steps from 0 Amp to 2.0 Amp in steps of 0.25 Amp. At each current step, a temperature measurement was obtained via remote viewing by an infrared camera. This paper discusses the experimental methodology, experiment results, and the thermal model.

Wright, Kenneth H., Jr.↗