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This annual report summarizes the compliance results of state and alternative fuel provider fleets covered by the Energy Policy Act of 1992 (EPAct) for model year 2011/fiscal year 2012.
California State University, Los Angeles, has partnered with the Department of Energy in addressing the workforce preparation and public education needs of the fuel cell industry and the US economy through a comprehensive set of curriculum development and training activities: * Developing and offering several courses in fuel cell technologies, hydrogen and alternative fuels production, alternative and renewable energy technologies as means of zero emissions hydrogen economy, and sustainable environment. * Establishing a zero emissions PEM fuel cell and hydrogen laboratory supporting curriculum and graduate students teaching and research experiences. * Providing engaging capstone projects for multi-disciplinary teams of senior undergraduate students. * Fostering partnerships with automotive OEMs and energy providers. * Organizing and participating in synergistic projects and activities that grow the program and assure its sustainability.
The Chicago Department of Transportation (CDOT) and our partners, I-GO Carshare and the Chicago Department of Fleet and Facility Management teamed up in support of our mutual goal of advancing the local electric vehicle market and demonstrating electrification of fleet vehicles. By increasing the use of electric and hybrid-electric vehicles this project provides a public benefit by reducing harmful emissions and the transportation sector’s dependence on petroleum in Chicago. The Chicago Climate Action Plan (CCAP) is the climate change mitigation and adaptation strategy adopted by the City of Chicago (City). CCAP calls for improved fleet efficiency, reduced fossil fuel use, and encourages vehicle electrification to reduce emissions from the transportation sector. Alternative fuels and advanced vehicle technologies play a critical role in helping the City achieve CCAP’s goals. In fact, CCAP calls for a 10 percent increase in the use of alternative fuel vehicles in Chicago by 2020.
Here, this article analyzes road transport in India to explore linkages between air pollution and climate change policies in the transportation sector. Five teams modeled five policy scenarios – fuel efficiency, electrification, alternative fuels, modal shifts, and moderation in transport demand – to explore which policy brings the largest synergetic effects in reducing carbon dioxide (CO 2 ) and particulate matter (PM 2.5 ) emissions. The teams also modeled the comprehensive scenario which included policy measures from individual scenarios. The paper concludes that all of the measures provide strong co-benefits in reducing air pollutant and CO 2 emissions. The modeling results show that increased energy efficiency of passenger and freight vehicles has the largest protentional for reducing both CO 2 and PM 2.5 emissions. It is possible to reach even a larger reduction of air pollutants and CO 2 emissions by combining several policy measures in the comprehensive scenario.
Uranium mononitride (UN) is one of the ceramic nuclear fuel alternatives to oxide fuel considered for light water reactors and advanced reactor designs. Properties like self- and fission gas diffusivity need to be better understood, given that they influence key fuel performance phenomena such as fission gas swelling and release. In particular, the radiation induced athermal (D 3 ) diffusivity remains challenging to accurately predict and has only been sparsely characterized in UN, despite its importance as it likely governs diffusion at the low temperatures this high-thermal-conductivity fuel form may operate. Molecular Dynamics simulations are used to estimate the mean square displacement induced by a primary knock-on atom (PKA) with a given kinetic energy. These results are combined with the PKA energy distributions obtained from binary collision approximation calculations to obtain the displacement due to a particular fission fragment. Finally, this is combined with experimental fission fragment yields to determine the displacement due to an average fission event and, thus, express the athermal diffusivity as a function of the fission rate density. These results are in excellent agreement with available experimental data. In conclusion, a particular importance is given to the understanding and the quantification of the variability of these results.
Uranium mononitride (UN) is one of the ceramic nuclear fuel alternatives to oxide fuels considered for light water reactor and advanced reactor designs, as it presents significant advantages such as high uranium density (better economics) and high thermal conductivity and melting point (increased safety). Self- and fission gas diffusivities need to be better understood, given that they influence key fuel performance phenomena like swelling and fission gas release. Recently, radiation enhanced diffusivity was investigated in UN by means of cluster dynamics simulations relying on empirical potential-based parameterizations, the reliability of which highly depends on the interatomic potential accuracy. Here, in this work, we refine this approach by determining, using ab-initio calculations, the properties of defect clusters containing vacancies, self-interstitials and Xe impurities. We also consider larger clusters than previous studies. The obtained dataset (formation enthalpies, entropies, and migration barriers) is used to parameterize a cluster dynamics model of mobile clusters, and to calculate the defect cluster concentrations under irradiation. This gives us access to the radiation enhanced self- and fission gas diffusivities. Although the resulting diffusivities are close to the values reported in the literature, we find important qualitative differences in the diffusion mechanisms. Capturing the correct mechanisms is crucial to properly describe the chemistry and fission rate dependence of the model.
Biodiesel is a renewable fuel with the potential to displace a portion of petroleum use. However, as with any alternative fuel, in order to be a viable choice it must be compatible with the emissions control devices. The finished biodiesel product can contain up to 5 ppm Na+K and 5 ppm Ca+Mg, and these metal impurities can lead to durability issues with the devices used to control emissions in diesel vehicles. Significant work has been performed to understand how the presence of these metals impacts each individual component of diesel emissions control systems, and this chapter summarizes the findings of these research efforts.
We report Hydrogen (H 2 ) is a prospective zero-carbon and high-energy-density fuel alternative to fossil fuels for generating power and clean energy. Ammonia (NH 3 ) is a promising H 2 (17.7%) carrier, which can easily overcome the challenges associated with H 2 storage and transportation. Thermocatalytic ammonia decomposition reaction (ADR) is an effective way to produce clean H 2 but it relies on the use of expensive and rare ruthenium (Ru)-based catalysts at elevated temperatures (>500 °C), hence is not sustainable and economically feasible. Herein, we report a synergistic strategy to design a heterostructured Ru-free catalyst, consisting of CoNi alloy nanoparticles well-dispersed on a MgO–CeO 2 –SrO mixed oxide support with potassium promotion. The resulting K–CoNi alloy –MgO–CeO 2 –SrO catalyst presents 97.7% and 87.5% NH 3 conversion efficiency at 450 °C at gas hourly space velocities (GHSVs) of 6000- and 12 000-mL h -1 g cat -1 , respectively. At 500 °C, the H 2 production rate (57.75 mmol g cat -1 min -1 ) becomes comparable to that of most of the reported Ru-based catalysts. The catalyst stability has been successfully demonstrated in both a fixed-bed reactor under high pressure (120 h at 5.0 bar) and a membrane reactor prototype (600 h at 1.5 bar) at 500 °C. High-temperature in situ XPS analysis, temperature-programmed desorption/reduction, and density functional theory calculations have been carried out to elucidate the possible active sites and performance enhancement mechanisms. This work highlights the importance of constructing optimal interfaces between active metal nanoparticles and oxide support for boosting the NH 3 to H 2 conversion efficiency and long-term stability.
The advances in polymer electrolyte fuel cell (PEFC) technologies over the past few decades and particularly over the past few years, have been very impressive. The promise of PEFC-based fuel cell electric vehicles (FCEVs) as long range EVs of zero emissions, high conversion efficiency, and fit for use of fuels from renewable sources, was recognized by pioneers of this technology some 40 years ago, facing at the time significant skepticism. The eventual commercial introduction of FCEVs in 2015 was enabled by the impressive accomplishments of scientists, engineers, and policymakers over that period of time. Among those responsible for the fuel cell community's success, few, if any, have had more impact than Dr. Shimshon Gottesfeld. He is a distinguished fuel cell educator, a passionate fuel cell and alternative fuel advocate, and a pioneering fuel cell innovator, responsible for several critical contributions that helped demonstrate the commercial viability of polymer electrolyte fuel cells. His impact on the field is seen through specific technical accomplishments, the scientists he has mentored, the teams he has led in different topical areas, and his activities as organizer and speaker in technical fuel cell meetings. We are honored to dedicate this focus issue of the Journal of The Electrochemical Society, entitled 'Advances in Modern Polymer Electrolyte Fuel Cells in Honor of Shimshon Gottesfeld,' to Dr. Gottesfeld for his accomplishments in the area of PEFC science and technology.
This is the seventh edition of the Vehicle Technologies Market Report, which details the major trends in U.S. light-duty vehicle and medium/heavy truck markets as well as the underlying trends that caused them. This report is supported by the U.S. Department of Energy s (DOE) Vehicle Technologies Office (VTO), and, in accord with its mission, pays special attention to the progress of high-efficiency and alternative-fuel technologies. After opening with a discussion of energy and economics, this report features a section each on the light-duty vehicle and heavy/medium truck markets, and concluding with a section each on technology and policy. The first section on Energy and Economics discusses the role of transportation energy and vehicle markets on a national (and even international) scale. For example, Figures 12 through 14 discuss the connections between global oil prices and U.S. GDP, and Figures 22 and 23 show U.S. employment in the automotive sector. The following section examines Light-Duty Vehicle use, markets, manufacture, and supply chains. Figures 27 through 63 offer snapshots of major light-duty vehicle brands in the United States and Figures 70 through 81 examine the performance and efficiency characteristics of vehicles sold. The discussion of Medium and Heavy Trucks offers information on truck sales (Figures 90 through 94) and fuel use (Figures 97 through 100). The Technology section offers information on alternative fuel vehicles and infrastructure (Figures 105 through 118), and the Policy section concludes with information on recent, current, and near-future Federal policies like the Corporate Average Fuel Economy standard (Figures 130 through 137). In total, the information contained in this report is intended to communicate a fairly complete understanding of U.S. highway transportation energy through a series of easily digestible nuggets. Suggestions for future expansion, additional information, or other improvements are most welcome.
This is the seventh edition of this report, which details the major trends in U.S. light-duty vehicle and medium/heavy truck markets. This report is supported by the U.S. Department of Energy s (DOE) Vehicle Technologies Office (VTO), and, in accord with its mission, pays special attention to the progress of high-efficiency and alternative-fuel technologies. After opening with a discussion of energy and economics, this report features a section each on the light-duty vehicle and heavy/medium truck markets, and concluding with a section each on technology and policy. The first section on Energy and Economics discusses the role of transportation energy and vehicle markets on a national (and even international) scale. For example, Figures 12 through 14 discuss the connections between global oil prices and U.S. GDP, and Figures 21 and 22 show U.S. employment in the automotive sector. The following section examines Light-Duty Vehicle use, markets, manufacture, and supply chains. Figures 27 through 69 offer snapshots of major light-duty vehicle brands in the United States and Figures 73 through 85 examine the performance and efficiency characteristics of vehicles sold. The discussion of Medium and Heavy Trucks offers information on truck sales (Figures 94 through 98) and fuel use (Figures 101 through 104). The Technology section offers information on alternative fuel vehicles and infrastructure (Figures 109 through 123), and the Policy section concludes with information on recent, current, and near-future Federal policies like the Corporate Average Fuel Economy standard (Figures 135 through 142). In total, the information contained in this report is intended to communicate a fairly complete understanding of U.S. highway transportation energy through a series of easily digestible nuggets. Suggestions for future expansion, additional information, or other improvements are most welcome.
Sylvatex technology blends renewable components into diesel to create a low-carbon, blended fuel with significantly cleaner emissions. Sylvatex MicroX blendstock uses low-cost inputs to produce both the fuel additive and alternative fuel products. LBNL worked with to evaluate various hydrolysates and explore different feedstocks that can be grown as commodities and used to produce the renewable surfactant.
The thermal stability of aircraft gas turbines fuels was investigated. The objectives were: (1) to design and build an aircraft fuel system simulator; (2) to establish criteria for quantitative assessment of fuel thermal degradation; and (3) to measure the thermal degradation of Jet A and an alternative fuel. Accordingly, an aircraft fuel system simulator was built and the coking tendencies of Jet A and a model alternative fuel (No. 2 heating oil) were measured over a range of temperatures, pressures, flows, and fuel inlet conditions.
The need for fuel cell and alternative fuels has become increasingly important in that the U.S. spends 1 billion dollars per week to import oil, and is expected to import 80-100 billion per year in oil by the year 2010. These imports account for half of our oil supply. If 20% of the U.S. vehicle fleet were powered by fuel cells there would be: an offset 1.1 million barrels of oil per day; and a reduction of 2 million tons per year of regulated air pollutants. Fueling fuel cells with hydrogen from reformed natural gas results in more than 90% reduction in regulated emissions, and a 70% reduction in CO2, a greenhouse gas. And fueling fuel cells with hydrogen from renewables (wind, solar geothermal, hydro) results in total elimination of all emissions. When fuel cells become commercialized: they will improve America's economic competitiveness; and the regions where they are produced will benefit economically.
There is a growing interest in the use of fuel cells as a power source for all-electric aircraft propulsion as a means to substantially reduce or eliminate environmentally harmful emissions. Among the technologies under consideration for these concepts are advanced proton exchange membrane (PEM) and solid oxide fuel cells (SOFCs), alternative fuels and fuel processing, and fuel storage. A multidisciplinary effort is underway at the NASA Glenn Research Center to develop and evaluate concepts for revolutionary, nontraditional fuel cell power and propulsion systems for aircraft applications. As part of this effort, system studies are being conducted to identify concepts with high payoff potential and associated technology areas for further development. To support this effort, a suite of component models was developed to estimate the mass, volume, and performance for a given system architecture. These models include a hydrogen-air PEM fuel cell; an SOFC; balance-of-plant components (compressor, humidifier, separator, and heat exchangers); compressed gas, cryogenic, and liquid fuel storage tanks; and gas turbine/generator models for hybrid system applications. First-order feasibility studies were completed for an all-electric personal air vehicle utilizing a fuel-cell-powered propulsion system. A representative aircraft with an internal combustion engine was chosen as a baseline to provide key parameters to the study, including engine power and subsystem mass, fuel storage volume and mass, and aircraft range. The engine, fuel tank, and associated ancillaries were then replaced with a fuel cell subsystem. Various configurations were considered including a PEM fuel cell with liquid hydrogen storage, a direct methanol PEM fuel cell, and a direct internal reforming SOFC/turbine hybrid system using liquid methane fuel. Each configuration was compared with the baseline case on a mass and range basis.
This presentation provides a summary of primarily laser-based measurement techniques we use at NASA Glenn Research Center to characterize fuel injection, fuel/air mixing, and combustion. The report highlights using Planar Laser-Induced Fluorescence, Particle Image Velocimetry, and Phase Doppler Interferometry to obtain fuel injector patternation, fuel and air velocities, and fuel drop sizes and turbulence intensities during combustion. We also present a brief comparison between combustors burning standard JP-8 Jet fuel and an alternative fuels. For this comparison, we used flame chemiluminescence and high speed imaging.
VTO's Technology Integration Program supports a broad technology portfolio that includes alternative fuels, energy efficient mobility systems and technologies, and other efficient advanced technologies that can reduce transportation energy costs for businesses and consumers. The program provides objective, unbiased data and real-world lessons learned to inform future research needs and support local decision making. It also includes projects to disseminate data, information, and insight, as well as online tools and technology assistance to cities and regions working to implement alternative fuels and energy efficient mobility technologies and systems.
This document summarizes the progress of VTO Technology Integration projects supported during the fiscal year 2023. VTO's Technology Integration Program supports a broad technology portfolio that includes alternative fuels, energy efficient mobility systems and technologies, and other efficient advanced technologies that can reduce transportation energy costs for businesses and consumers. The program provides objective, unbiased data and real-world lessons learned to inform future research needs and support local decision making. It also includes projects to disseminate data, information, and insight, as well as online tools and technology assistance to cities and regions working to implement alternative fuels and energy efficient mobility technologies and systems.