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At least 289 records · Page 16

Energy Efficient Waste Heat Coupled Forward Osmosis for Effluent Water Management at Coal-Fired Power Plants

This project sought to evaluate the technical and economic viability of the Aquapod©, a transformational low energy (<200 kJ/kg water) waste heat coupled forward osmosis (FO) technology, to manage effluents, meet cooling water demands, and achieve water conservation in a coal-fired power plant environment. The Aquapod© process is innovative because it is heat-driven, avoids the evaporation of water, and uses no toxic chemicals such as ammonia or amines. The Aquapod© process accomplishes this using an aqueous two-phase system (ATPS) coupled FO process. The evaluation revealed that the Aquapod© process offers a pathway to exploit waste heat resources within a power plant to achieve flue-gas desulfurization (FGD) wastewater volume reduction and water recovery with minimal pretreatment. Water recovery of 80% from FGD wastewater was achieved with minimal pretreatment, exceeding the project target of 50%. The estimated electrical energy of 2.16 kWh/m 3 of water produced for the Aquapod© process met the project target of < 3.6 kWh/m 3 . The heat required for the process operation was approximately 186 kJ/kg of produced water, which was slightly lower than the project target of 200 kJ/kg. The estimated treatment cost for installing and operating the Aquapod© process in conjunction with a spray dryer evaporator to achieve zero-liquid discharge (ZLD) of the 100 gpm FGD wastewater was $13.24/m 3 over a 30-year lifetime. As a point of reference, this study’s host power plant currently incurs a cost of $3.70/m 3 – $8.87/m3 on a discharged volume basis to discharge its wastewater into the publicly owned treatment works (POTW) after physical-chemical treatment. Therefore, the Illinois power plant would incur an incremental cost increase of $4.37/m 3 – 9.54/m 3 to achieve ZLD using the Aquapod© and spray dryer combination. Ample opportunities exist to further lower the ZLD capital and operating costs in the next design iteration to attain pipe parity at the higher end of the site treatment costs.

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PV DMFA [SWR-21-105]

The Photovoltaic Dynamic Material Flow Assessment (PV DMFA) model (also referred to here as “The model”) is a computational framework written in Python based on utility-scale PV electricity generation to quantify time-series stocks and flows of PV materials primarily in crystalline silicon PV technologies. The model evaluates cradle-to-cradle life cycle of utility-scale solar PV systems in the United States in the period 2000-2100. PV DMFA serves as a sustainability analysis tool to assess the impacts of different material circularity practices (i.e., reduce, reuse/refurbish, remanufacture, and recycle), PV module design shifts and sensitivity of material processing and technology related parameters to material installations, waste creation and raw material depletion in PV material supply chains. This tool enables advanced planning for future material needs and informs sustainable pathways for PV material management in the circular economy. This tool could be helpful to a wide range of stakeholders; Particularly, researchers and manufacturers looking for technoeconomic and/or environmental life cycle analysis (LCA) feedback for renewable energy (RE) systems.

Khalifa, SherifA.↗

Potential for Evaporation and In Situ Reaction of Organic Compounds in Hanford Supplemental LAW

The presence of regulated organic species in Hanford nuclear tank waste is assessed in this report, along with fate of the organics and possible evaporative treatment. A narrowed list of regulated organic species of concern is developed based upon published analyses, chemical properties like aqueous solubility, and chemical reactivity under alkaline conditions. Published analyses include tank headspace and liquid samples, review of chemical reagents formerly used at Hanford, and the Tank Waste Information Network System (TWINS). This work supports possible stabilization of Hanford Supplemental Low Activity Waste (SLAW) by grouting.

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Colloid-Facilitated Actinide Transport in a Cementitious-Impacted SRS Groundwater

The objective of this report is to provide a literature review relevant to the question of whether colloid facilitated transport of plutonium is enhanced in a cementitious groundwater system on the Savannah River Site (SRS). Contaminant transport is commonly described as taking place in a system with a mobile aqueous phase and an immobile solid phase. There has been an increasing awareness of a third phase, a mobile solid phase, also referred to as a mobile colloidal phase. Mobile colloids consist of organic and/or inorganic submicron-particles that move with groundwater flow. When radionuclides are associated with the mobile colloids, the net effect is that radionuclides can move faster through the subsurface system than would be predicted by transport models that do not include mobile colloids. It is important to distinguish between subsurface colloids and subsurface mobile colloids. The subsurface environment includes an enormous reservoir of colloids, but only a tiny fraction, if any, are mobile. Mobile colloid formation is commonly described as involving a three-step process: genesis, stabilization, and transport. It was concluded that there is a strong likelihood that submicron colloids of plutonium exist near the source term, (i.e., the genesis step is likely completed). While such particles have not been directly detected, it is highly likely that plutonium could either attach to submicron particles in the sediment or that submicron plutonium fragments exist at the source. However, the tendency for these plutonium colloids to move in the SRS subsurface is extremely low, especially in engineered cementitious environments where the ionic strength of the solution and the elevated concentrations of divalent cations greatly curtails colloid suspension stability (i.e., the stabilization step is likely not completed). Together these data strongly indicate that plutonium-bearing colloids would likely exist in the near field of a tank closure facility, but the colloids would be unlikely to be mobile, thereby providing a vector for enhanced transport. Under cementitious leachate impacted groundwater conditions, it is reasonable to assume plutonium transport occurs primarily as a two-phase system, a mobile aqueous phase and an immobile solid phase.

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Code Standard Evaluation for ASME AG-1-2019, Section FL

ASME AG-1 Section FL Deep Bed Sand Filters includes a requirement to use Special Test Sections to provide a representative assessment of the filter efficiency. The SRPPF project design basis is to test the entire filter bed (versus a representative sample) following the same basis methodology to test the existing filters at the Savannah River Site. Using a combination of: 1) the filter testing experience at SRS since the early 1970’s, 2) the methodology found in ASME AG-1 for testing high capacity HEPA filter housings and 3) requirements for stack or duct sampling systems published by the Environmental Protection Agency (EPA), the Special Test Sections methodology for Deep Bed Sand (DBS) filters in ASME AG-1 Section FL has been replaced with a methodology to test the entire DBS filter system.

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Investigating Uranium Corrosion in Magnesium-containing Sludge Using X-ray Tomography - 20042

One of the current primary concerns within the British nuclear community is the decommissioning of legacy storage ponds in Sellafield Cumbria, where nuclear fuel cladding material (a Mg-Al alloy) resides along with fuel metallic swarf. Corrosion of the immersed metallic elements, which has been occurring over the storage period, has resulted in the formation of what is commonly known as Corroded Magnox Sludge. The behaviour of uranium metal within this particular environment and, more significantly, the identity of the corrosion products that may have formed is currently unknown. The present study attempts to shed some light on these aspects by investigating simplified surrogate systems, mimicking storage ponds. (authors)

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FY2022 Filter Test for TRU Waste Drum Prototype Unit

Continuing last year’s (fiscal year 2021) work, a prototype instrument and an NPI-6 Integrated Work Document (IWD) were developed to assess the functionality of filters on transuranic waste containers (commonly called 55 Gallon ring-top drums) without requiring the removal of the drum lid. The purpose of this work is to determine the air flow and pressure characteristics associated with filter clogging, filter pressure drop at a fixed flow rate, and leakage around the lid seal. The FY22 objectives included: (A) Development of prototype device, (B) Drafting an IWD document, (C) Defining a filter clogging parameter, (D) Assessing filter damage due to over-pressure events, and (E) A path forward to obtain approval of the system safety filters in compliance with P101-16 Industrial Ventilation – non HVACR (LANL 2022).

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Techno-economic feasibility of borehole thermal energy storage system connected to geothermal heat pumps for seasonal heating load of two buildings in Fairbanks, Alaska

Borehole thermal energy storage (BTES) is an effective solution for managing imbalanced heating and cooling loads in cold regions. This study evaluated the long-term feasibility of a BTES system in the Fairbanks area, Alaska, through building energy modeling, resource characterization, and numerical modeling. The system was designed to store waste heat from a nearby coal power plant during summer and provide thermal energy during winter to geothermal heat pumps supplying heating loads in two buildings. Heating load profiles were modeled for the buildings using EnergyPlus, and the results indicated the annual heating load was 5.6 times greater than the cooling load. 40 borehole heat exchangers were pre-designed approximately 100 m away from the two buildings in terms of land availability and regulatorily optimized depth. The 20-year performance of the designed BTES system under two operational scenarios—one with a 5-year preheating period and one without—was numerically modeled using subsurface temperature and properties characterized through the literature review and thermal response tests. Both scenarios demonstrated that the BTES has the capacity to fully cover the heating loads in the two buildings throughout the 20-year lifetime. Production temperatures at central wells were 33 % higher on average than at outer wells in both scenarios. The 5-year preheating period increased subsurface and extraction temperatures, and correspondingly annual average and total thermal energy production was higher for 8 years than in the scenario without the preheating period. These results highlight the long-term reliability and sustainability of the BTES system in meeting heating demands over its lifetime, with the preheating period offering potential performance improvements. Implementing the BTES system in cold regions with high heating demand, such as Fairbanks, Alaska, could provide a long-term, sustainable energy solution for managing imbalanced heating and cooling loads.

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Artificial Intelligence Application to D and D - 20492

As aging facilities across the DOE complex await decommissioning, there is an ongoing need to understand any changes in the structural conditions. Many of these facilities were built over 50 years ago and, in some cases, these facilities have gone beyond the expected operational lifetime. Many facilities have been placed in a state of 'cold and dark,' sitting unused and awaiting decommissioning. Especially challenging are the aging facilities that provide unique operational/production capabilities to support critical DOE missions and cannot be shut down. In any of these scenarios, the structural integrity of these facilities may become compromised as time passes. It is critical that adequate inspections be performed on a continual basis and that the data collected undergoes sufficient analysis to support timely identification of any new or worsening structural issues as well as prompt needed maintenance and repairs to maintain the facilities in a safe condition. In recent days, Artificial Intelligence (AI) [1] and its application to various domains are growing at fast speed. FIU is performing research in this area and exploring the associated technologies to solve nuclear decommissioning problems. Artificial intelligence refers to the capability of a program to autonomously act, react and adapt to the working environment. AI enables the machine to behave like humans and perform the cognitive functions such as 'learning' and 'problem solving'. AI systems gradually moving from traditional approaches (algorithms and expert systems) towards more efficient and advanced technologies (machine learning [1] and deep learning [2] [3]). AI is the study of algorithms and statistical models that is being used by computers to perform specific tasks without using explicit instructions. FIU is working to develop a pilot-scale infrastructure to implement structural health monitoring using AI technologies with focus on machine learning, deep learning. This research is focused on Computer Vision/Image Classification area of AI applications. This can also be expanded to other areas of AI related to Object Recognition and Character Recognition in images. In addition to utilizing existing data sets, FIU will collect and investigate image and video data using FIU test-bed mockups to monitor structural health of the facility. Resulting data will be processed and analyzed using machine learning/deep learning technologies. The proposed pilot system is intended to serve as a starting point to engage the DOE field sites on related data sets and their decision making needs. It is anticipated that proposed machine learning/deep learning technologies can be effectively employed using anomaly detection to solve EM challenges in surveillance and maintenance of the D and D facilities. FIU will work with research stakeholders to identify applications at various sites and other DOE facilities. (authors)

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Conceptual Model Testing Related to SDU 6 Drainwell Observations

From its inception in the early 1950s through the end of the Cold War in the early 1990s, the Savannah River Site (SRS) produced nuclear materials for national defense in five reactors. Additionally, irradiated reactor fuel and target tubes were dissolved in nitric acid to recover plutonium and uranium using the PUREX (Plutonium Uranium Reduction EXtraction) process. Liquid waste from these chemical separations processes was then stored onsite in 51 underground tanks. Eight waste storage tanks have been operationally closed (i.e. cleaned and grouted) and the remaining tanks hold a mixture of liquids, insoluble solids, and precipitated salts (SRMC-LWP-2022-00001), the latter generated by evaporating water from the liquid waste. Waste is currently being retrieved from tanks and separated into 1) high-radioactivity, low-volume, and 2) low-radioactivity, high-volume components, principally through the Salt Waste Processing Facility (SWPF) (SRMC-LWP-2023-00001). The former waste stream is vitrified in the Defense Waste Processing Facility (DWPF), stored onsite, and destined for offsite disposal in a deep geologic repository. The latter stream is mixed with dry cementitious materials in the Saltstone Production Facility (SPF) and the wet slurry placed in onsite Saltstone Disposal Units (SDUs) within the Saltstone Disposal Facility (SDF), where it hardens into a cement waste form termed saltstone. A low-infiltration surface cover system will be placed over the SDF at closure, where SDUs will then be in the subsurface post-closure (SRR-CWDA-2019-00001).

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Hanford Immobilized Low-Activity Waste Transportation System Testing Results - 20043

The immobilized low-activity waste (ILAW) transportation system is a first-of-a-kind system that is being designed and tested to transport ILAW glass-filled containers from Hanford's Waste Treatment and Immobilization Plant (WTP) Low-Activity Waste (LAW) Facility to the Integrated Disposal Facility (IDF) burial trench for permanent disposal. A prototype design and fabrication of one transport trailer and four engineered ILAW pallets was completed in mid-2018. Prototype qualification testing to verify adequacy of the design was completed in 2019 by Washington River Protection Solutions (WRPS) and affiliate ATKINS SNC-Lavalin Group. Prototype testing was completed to advance design maturation across all operational and facility interfaces, and under adverse environmental and operating conditions, including thermal assessment of the system at peak projected temperatures. Test design, observation, and feedback was well represented and supported by all ILAW Transportation System interfacing organizations: WTP constructor Bechtel National, Inc.; IDF operator CH2M (CHPRC); transportation contractor Mission Support Alliance (MSA); the U. S. Department of Energy Richland Operations Office (DOE/RL) and Office of River Protection (DOE/ORP); and Washington State Department of Ecology. This paper presents the results of prototype qualification testing and opportunities for design improvements based on testing. Changes to the final design as a result of prototype testing include improvements in safety, ergonomics, operational flexibility, and As-Low-As-Reasonably-Achievable (ALARA) applications. (authors)

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Technology and Innovation Roadmap

This Technology and Innovation Roadmap outlines the Hanford Tank Waste Operations & Closure, LLC (H2C) strategic approach for advancing the Hanford Tank Waste Treatment Mission (HTWTM) through technology development. Our focus is on addressing technology needs that address risks, enhance efficiency, ensure worker safety, and uphold environmental standards. This Roadmap identifies key technology initiatives essential for the successful completion of the Hanford Site tank waste cleanup. Updated annually, it incorporates insights from the U.S. Department of Energy (DOE), the Integrated Tank Disposition Contractor (ITDC) H2C, recognized national lab experts, and fieldwork specialists. The Roadmap includes approximately 100 technology elements, each detailed in Technology Element Description Summaries (TEDS) and summarized in catalog sheets. These elements are crucial for aligning technology development activities with mission objectives across the HTWTM. With the initiation of the Direct-Feed Low-Activity Waste (DFLAW) program and the operation of the Tank Side Cesium Removal (TSCR) system, our focus now shifts to the support of scaled up production in East Area; applying similar and exploring new treatment alternatives to West Area Tank Waste; and advancing retrieval, delivery and treatment technologies for waste managed as high-level waste (HLW) across the Hanford tank farms. This transition is reflected in the technology and maturation (TM&E) charts, which highlight the evolving technology priorities. This document serves as a guide for navigating the challenges and opportunities in technology development at the Hanford Site.

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Off-line Tests of the DM1200 Thermal Catalytic Oxidation (TCO) Unit (Final Report)

The River Protection Project-Waste Treatment Plant (RPP-WTP) Low-Activity Waste (LAW) and High-Level Waste (HLW) feed streams are listed for a variety of hazardous organic compounds. The permitting basis for the WTP systems may necessitate the demonstration of minimum Destruction/Removal Efficiencies (DREs) of such species from any released emissions of up to 99.99%. Results from a previous study on the fate of hazardous organics in the melter itself indicated, not only that DREs for selected test compounds approached 99.99% only at extreme melter conditions, but also that organic compounds not originally present in the feed were actually produced in the melter, In order to ensure that the required DREs for hazardous organics are met, Thermal Catalytic Oxidation (TCO) units were therefore added to both the HLW and LAW off-gas treatment systems, The extent to which these species can be destroyed or removed in the TCO units is therefore an important issue in the design and permitting of the LAW and HLW off-gas treatment systems. A further consideration is that it would be desirable, if possible, to be able to achieve all of the required DRE across the TCO alone. If that is not the case, the DRE would be distributed across several unit operations, which may then become subject to additional operational constraints that may reduce process flexibility. Compliance with the DRE requirements on the basis of the TCO unit alone is also an approach that lends itself to periodic confirmation during operations, since the TCO is located at the back-end of the off-gas treatment system where radioactivity levels are lowest.

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Inspection Tools for Hanford Tanks and Waste Transport Systems - 20444

Recent integrity issues in the double-shell tanks (DST) at Hanford have motivated the need for developing innovative tools that can provide information regarding the health of the tanks. These issues include the primary linear failure of AY-102 and recent concerns of thinning in the DST secondary liners. Other concerns include erosion or corrosion on transfer lines and processing pipes. In recent years, Florida International University (FIU) has supported DOE-EM by developing tools that can assist in understanding the health of tanks and waste transport system at Hanford. More specifically, FIU has developed a miniature rover that can be deployed through small risers and gain access to refractory slots in the Hanford DSTs. It traverses through the slots on the primary liner upside down via magnets to avoid debris in the slots. Recent modifications include a spring loaded magnetic arm that allows the unit to traverse over large weld seams but does not reduce the overall functionality of the system. The system has also incorporated a control capsule that will sit within the annulus of the tank and improves on issues related to signal and voltage loss over long tether lines. Lastly, the unit is also being augmented with a second module that will include a means to prep the tank surface and obtain a thickness measurement using a dual element ultrasonic sensor. FIU has also developed a 6-inch peristaltic pipe crawler that operates similar to the previous pipe crawlers developed at FIU. This crawler is a marsupial type crawler that will navigate through the 6-inch drain lines, and deploy a small rover at the entrance of the drain slots. This rover will also traverse upside down on the secondary liner and provide information regarding the health of the liner. An initial prototype for the crawler unit has been developed, assembled and tested. The system is pneumatic and consists of three modules - two grippers and one extender. The validation tests are conducted in a mockup of the drain lines and demonstrate the system's ability to navigate through long pipe lengths and elbows. In this paper, a general overview of each of the aforementioned systems is presented along with results from testing and demonstrations that shows the applicability of each system. (authors)

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Evaluation of FTWC Vent System

A monitored exhaust system has been designed for use in venting the Flanged Tritium Waste Containers (FTWCs) at LANL. This system will provide controlled exhaust and emissions monitoring for the FTWCs, and also provide general area exhaust around the venting operations to measure any emissions which may bypass the primary vent system. A full description of the process and need for the system is described in the Pre-Construction Application for this project. This document describes the commissioning testing performed on the FTWC vent system to prepare it for use. The system has been tested and shown to meet ANSI standard requirements and is fully suitable for use.

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Operations and Recent Upgrades to a Tritium Recycling Facility - 20375

Nuclear Sources and Services Inc. (NSSI) is a waste handling treatment company that has been operating since 1971. In 2000, NSSI began building a 1,000 m{sup 2} (∼10,000 sqft) tritium recycling facility on the Houston, Texas premises to address a growing need in the waste disposal market. Over the years, the capability of the facility grew to address many different waste streams with the goal of recycling > 99.9% of all tritium activity back into the fusion community. This is achieved by maintaining an effluent stack release well below the 150 GBq/year (C Ci/year) operating limit and maintaining all liquid and solid waste disposal below the low-level radioactive release limit of 0.C MBq/kg (10 μCi/kg). The unique processing systems in the facility attracts many challenging contracts. Within the past two years, NSSI has engaged with customers to treat; organic mixed wastes that simultaneously contain tritium and carbon-14, safely extract tritium from large quantities of exit sign lights, and remove tritium from uncharacterised legacy depleted uranium beds from a superfund site. This paper will outline the initial testing, the system upgrades to treat these varied streams, and the progress in processing the feedstocks provided by these projects. (authors)

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Regulatory Decision-Making Process Using 'Weight of Evidence: An Evidence Integration Approach' by the State of Washington at the Hanford Site - 20163

Performance Assessment and Environmental Impact Statement Modeling, Human and Ecological Risk Assessments are the tools used by the Washington State Department of Ecology (Ecology) to make regulatory decisions for permitting and cleanup. These efforts all inherently have large amounts of uncertainty no matter how many alternative approaches are attempted. Professional feedback from tribal governments, stakeholders, federal and state regulators, the public and independent peer review groups are taken into account in this process of informed decision making. The process also includes full evaluation of the comments and the associated reviews made by the various peer review groups such as the Low -Level Waste Disposal Facility Federal Review Group (DOE order 435.1) and the Nuclear Regulatory Commission (NRC). The evolution of technology has produced quicker and more efficient fate and transport modeling tools with related quantification of uncertainties and their significance. Groundwater and vadose zone models have been expanded across the entire Hanford site. Many of the technical approaches identified in the Washington State Regulations are updated using current knowledge to better understand the complexities of the Hanford Site using the latest state of the art tools for risk assessment and modeling. More emphasis and time are directed on defining uncertainty and then managing the uncertainty. One added tool is to run sensitivity cases based on informed decision making. The weight of evidence approach considers all relevant information in an integrative assessment that takes into account the kinds of evidence available, the quality and quantity, the uncertainty and error associated with each type, and how they fit together. Evidence of integration involves looking at systematic reviews and evaluating their strengths and weaknesses. In conclusion, Ecology, Washington State's lead regulatory agency at the Hanford site, has had to modify its site closure approach compared to the rest of the state. A more holistic approach dealing with the Hanford site as an integrated system has evolved leading to a defensible informed approach for regulatory closure decisions. (authors)

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