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At least 289 records · Page 16

Numerical Simulation of Flow Field Within Parallel Plate Plastometer

Parallel Plate Plastometer (PPP) is a device commonly used for measuring the viscosity of high polymers at low rates of shear in the range 10 4 to 10 9 poises. This device is being validated for use in measuring the viscosity of liquid glasses at high temperatures having similar ranges for the viscosity values. PPP instrument consists of two similar parallel plates, both in the range of 1 inch in diameter with the upper plate being movable while the lower one is kept stationary. Load is applied to the upper plate by means of a beam connected to shaft attached to the upper plate. The viscosity of the fluid is deduced from measuring the variation of the plate separation, h, as a function of time when a specified fixed load is applied on the beam. Operating plate speeds measured with the PPP is usually in the range of 10 -3 cm/s or lower. The flow field within the PPP can be simulated using the equations of motion of fluid flow for this configuration. With flow speeds in the range quoted above the flow field between the two plates is certainly incompressible and laminar. Such flows can be easily simulated using numerical modeling with computational fluid dynamics (CFD) codes. We present below the mathematical model used to simulate this flow field and also the solutions obtained for the flow using a commercially available finite element CFD code.

Basil N. Antar↗

Mixing-length, shears, and differential rotation

Three aspects of convection in the solar envelope, the mixing length, the shears, and the differential rotation, are considered. Numerical experiments show that the mixing length is scaled by the pressure scale height rather than by the density scale height. Results indicate that the effective viscosity of convective turbulence on large scale shears may be approximated as 1/3 the product of the rms vertical velocity and the pressure scale height. It is suggested that the differential rotation of the solar convection zone may be viewed as an unstable axisymmetric mode which produces slower rotation at the surface.

Chan, K. L.↗

Study on Emulsification/Demulsification Behavior and Mechanism of Produced Liquid from Polymer Flooding on Alaska North Slope

Heavy oil reservoirs on Alaska North Slope (ANS) are unconsolidated and contain abundant clay minerals, where the first-ever field pilot is currently implemented to validate the use of polymer floods for heavy oil enhanced oil recovery (EOR). The polymer molecules and/or fine clay particles carried with the produced liquid could potentially affect the oil/water separation, which is one of the major concerns for field operators. This dissertation aims to investigate the emulsification behavior of produced liquid, understand the emulsifying mechanism, and seek an adaptive and cost-effective method to treat the produced liquid from polymer flooding. Emulsions were prepared by mechanically mixing the actual heavy oil and the produced water from the pilot site, of which the stability was investigated by bottle test method or multiple light scattering method. Drop size distribution and interfacial properties were measured via microscope and pendant drop technique to probe the stability mechanism further. Results showed that oil-continuous or water-continuous emulsion could be generated depending on the water cut, clay types, clay concentration, and polymer concentration. In the crude oil/water system, the increasing water cut triggered the phase inversion of oil-continuous emulsion to water-continuous emulsion, resulting in faster separation and lower emulsion stability. Whereas, clay particles, no matter added to the oil or water phase, resulted in an unfavorable phase inversion from the loose water-continuous emulsion to the tight oil-continuous emulsion as clay concentration increased. For all four types of clay except Ca-montmorillonite, clay particles added to water led to an earlier phase inversion and higher emulsion stability than that added to the oil. The dual function of polymer on emulsion stability was observed. On the one hand, both sheared and unsheared polymer tended to convert the oil-continuous emulsion formed in either crude oil/water system or complex crude oil/water/clay particle system to the water-continuous emulsion, acting as a weak demulsifier to accelerate the oil/water separation. On the other hand, the addition of polymer to the water-continuous emulsion could result in enhanced emulsion stability, which is primarily attributed to the increased viscosity of the continuous phase and the decreased drop size of the dispersed oil phase. Particularly, the sheared polymer had a weaker ability to stabilize the o/w emulsion than the unsheared polymer due to the lower viscosity of the sheared polymer solution resulting from the breakdown of the polymer macromolecules. As for the chemical demulsification tests, the performance of demulsifiers showed a complex dependency upon the water cut, the shearing intensity, demulsifier type and dosage, and the polymer concentration. A compound emulsion breaker, E12+E18, exhibited the most satisfactory demulsification performance despite the varied test conditions. For severe water-continuous emulsions that might require a multi-fold dosage of demulsifier, a less expensive electrolyte, KCl, was proposed to be used in combination with demulsifier E12+E18 to improve the demulsification performance. In the proposed demulsifier formula, the effectiveness of the commercial demulsifier relied on its destructive effect on the interfacial film, while the efficacy of KCl was mainly dependent on its viscosity reduction effect on the continuous phase. This dissertation illustrates that intermediate layer elimination and water clarification are the major challenges for produced liquid treatment from polymer flooding. It also provides practical and theoretical guidance in advance for the demulsification strategy of the produced liquid from the ongoing first-ever polymer flooding pilot on ANS.

Chang, Hongli↗

Pressure-viscosity measurements for several lubricants to 5.5 x 10 to the 8th power Newtons per square meter (8 x 10 to the 4th psi) and 149 C (300 F)

A capillary viscometer was used to measure viscosity as a function of pressure, temperature, and shear stress for a number of lubricants. The conditions under which the measurements were made are specified. The results obtained for each material are analyzed. It was determined that all pressure-viscosity coefficients decreased with increasing temperature. Data from other techniques such as optical elastohydrodynamics, oscillating crystal, and low shear capillary viscometry were compared with the results obtained.

Jones, W. R.↗

Effect of cold-cap-bottom shear stress on primary foam stability

Here, we analyze the heat transfer between the melt pool and the layer of reacting materials called cold cap, which is the determining factor for the glass production rate in Joule-heated air-bubbled nuclear waste glass melters. We consider the effects of bubbling rate, melt viscosity, melt thermal conductivity, conversion kinetics, and shear rate at the cold-cap bottom, and develop simple relationships for the cold-cap bottom temperature and glass production rate. We show that the melt convection enhances the heat transfer to the cold cap by suppressing the thermal boundary layer and primary foam, while the conversion kinetics opposes these effects. Additionally, we mention how dissolving silica particles affects the primary foam stability and discuss the limitations of the presented approach for vigorously foaming feeds.

36 MATERIALS SCIENCE↗

Odd-viscosity-induced passivation of Moffatt vortices

Odd viscosity is associated with a number of striking physical phenomena: a disk rotating in a viscous liquid experiences a normal compressive or tensile stress depending on its sense of rotation; chiral active matter interfacial deformations level off in a manner akin to surface tension; and unstable thermocapillary films become stabilized. In this article we show that odd viscosity decreases the size and intensity of Moffatt vortices in a corner formed by a solid substrate and a free interface. The effect is present because odd viscosity creates a normal-stress-induced shear stress at the liquid–gas interface. The new shear stress is out of phase and oppositely directed with respect to the interfacial liquid velocity. It squeezes the vortices and damps their rotation. As a consequence, Moffatt vortices can now be observed with greater facility in an experiment. Odd viscosity also increases the range of corner angles over which Moffatt vortices can be observed, and, in general, it shows a tendency to moderate singular behaviour.

Mechanics↗

Recovery of postconsumer mechanically recycled polymers

Mechanical recycling plays a key role in reducing landfill bound plastics that pollute our environment. This process converts plastic waste into marketable pellets by sorting, cleaning, grinding into flakes, compounding in the molten state, and ultimately pelletizing. A primary restriction for the widescale usage of mechanical recycling is the highly variable quality and mechanical properties of the plastic waste feedstock. Degradation can occur during the plastic life cycle with the consumer, during the mechanical processing itself, or during the complex sorting process required to produce the feedstock. This study explores how rheological characterization can mitigate the batch-to-batch variability and identify a potential application for each batch. Shear and extensional rheology of “application-specific” virgin high-density polyethylene (HDPE) and virgin polypropylene (PP) was used as the control for this categorization process. Recycled HDPE and PP from three different streams were then measured and compared to the results from the control study. Rheological measurements proved to be very effective at providing sufficient differentiation to categorize the recycled polymer as suitable for different applications such as injection molding, blow molding, or thermoforming. Finally, the usage of an additional step to sort the recycled polymers by their initial use application was found to achieve a remarkably consistent recovery of application-specific material properties. Furthermore, this secondary sorting could provide significant added value for mechanically recycled polymers.

Differential scanning calorimetry↗

Theory of the tertiary instability and the Dimits shift from reduced drift-wave models

Tertiary modes in electrostatic drift-wave turbulence are localized near extrema of the zonal velocity $U(x)$ with respect to the radial coordinate $x$. We argue that these modes can be described as quantum harmonic oscillators with complex frequencies, so their spectrum can be readily calculated. The corresponding growth rate $\gamma_{\rm TI}$ is derived within the modified Hasegawa--Wakatani model. We show that $\gamma_{\rm TI}$ equals the primary-instability growth rate plus a term that depends on the local $U''$; hence, the instability threshold is shifted compared to that in homogeneous turbulence. This provides a generic explanation of the well-known yet elusive Dimits shift, which we find explicitly in the Terry--Horton limit. Linearly unstable tertiary modes either saturate due to the evolution of the zonal density or generate radially propagating structures when the shear $|U'|$ is sufficiently weakened by viscosity. The Dimits regime ends when such structures are generated continuously.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

A normal shock-wave turbulent boundary-layer interaction at transonic speeds

Experimental results, including surveys of the mean and fluctuating flow, and measurements of surface pressure, skin friction, and separation length, are compared with solutions to the Navier-Stokes equations utilizing various algebraic eddy viscosity models to describe the Reynolds shear stresses. The experimental data, obtained at a free-stream Mach number of 1.5 and Reynolds numbers between 10 million and 80 million, show that a separated zone forms near the foot of the shock and that its length is proportional to the initial boundary-layer thickness; that a supersonic region forms downstream of the shock; and that the shear stress increases significantly through the interaction and subsequently decays downstream. The computations adequately represent the qualitative features of the flow field throughout the interaction but quantitatively underpredict the extent of separation and the downstream level of skin friction.

Mateer, G. G.↗

A possible explanation of the mechanism of formation of the equatorial jet on the surface of Jupiter

Formation of the equatorial jet of the Jovian surface was explained as a consequence of the Taylor-Proudman theorem. The asymptotic theory of motion of low viscosity fluids in a rotating spherical shear layer was included. The model shows the straited structure of the Jovian surface as the outflow of convective cells having the shape of axisymmetric rolls extended along the axis of rotation in the meridional direction. Depth of the layer was found to be of the order of 1000 kilometers.

Yavorskaya, I. M.↗

Effect of wall temperature on a supersonic turbulent boundary layer

Measurement of mean flow profiles in a fully developed Mach 3 turbulent boundary layer with negligible pressure gradient is reported. Data were acquired at several streamwise locations for wall-to-total temperature ratios of 0.94, 0.71, and 0.54. The results demonstrate that the velocity defect formulation of the law-of-the-wake, which successfully correlates compressible, adiabatic boundary layers, is also valid for nonadiabatic flows. It is also shown that for adiabatic walls, the linear Crocco relation between total temperature and velocity does not provide a valid test of the nature of the boundary-layer flow for practical cases where the Prandtl number departs from unity. Finally, the turbulent shear stress, mixing length, and eddy viscosity were extracted from the 'time-averaged' conservation equations using the measured mean flow profiles and found to be insensitive to wall temperature. In particular, the latter properties are in good agreement with earlier compressible, adiabatic correlations of turbulent transport properties.

Laderman, A. J.↗

Discrete-vortex simulation of pulsating flow on a turbulent leading-edge separation bubble

Studies are made of the turbulent separation bubble in a two-dimensional semi-infinite blunt plate aligned to a uniform free stream with a pulsating component. The discrete-vortex method is applied to simulate this flow situation because this approach is effective for representing the unsteady motions of the turbulent shear layer and the effect of viscosity near the solid surface. The numerical simulation provides reasonable predictions when compared with the experimental results. A particular frequency with a minimum reattachment is related to the drag reduction. The most effective frequency is dependent on the amplified shedding frequency. The turbulent flow structure is scrutinized. This includes the time-mean and fluctuations of the velocity and the surface pressure, together with correlations between the fluctuating components. A comparison between the pulsating flow and the non-pulsating flow at the particular frequency of the minimum reattachment length of the separation bubble suggests that the large-scale vortical structure is associated with the shedding frequency and the flow instabilities.

Sung, Hyung Jin↗

The effect of solid film lubricants on the stability of rolling element bearings

A technique has been developed for modeling solid films in rolling element bearings. For a given bearing geometry an effective viscosity can be calculated for a solid film as a function of the film shear modulus and ball-race friction coefficient. The calculated effective viscosity can subsequently be used as an input to a numerical model of cage motion and stability. Results from a sample calculation of effective viscosity and prediction of cage stability for a turbopump bearing are presented for films of molybdenum disulfide (MoS2) and polytetrafluoroethylene ()PTFE).

Kannel, J. W.↗

Development of high viscosity coatings for advanced Space Shuttle applications

Laboratory studies for increasing the thermal resistance of high viscosity coatings for silica reusable surface insulation are presented. The coatings are intended for the reentry temperature associated with advanced Space Shuttle applications which will involve aerodynamic shear forces during entry from earth orbits. Coating viscosity was increased by (1) reduction in the concentration of the low viscosity additive B2O3; (2) reduction in the particle size of the constituent powders in coatings; and (3) addition of a high viscosity glass former (GeO2). A coating system was produced by combining the three methods which showed apparent higher viscosity than the current coating, while satisfying all the current Shuttle Orbiter coating requirements.

Garofalini, S. H.↗

In-situ X-ray scattering study of isotactic polypropylene/graphene nanocomposites under shear during fused deposition modeling 3D printing

Complementary techniques were applied to characterize the structure property relationships of FDM printed isotactic polypropylene/graphene nanocomposites. Raman spectroscopy indicated that graphene was mostly exfoliated during the nozzle extrusion process. Rheological measurements of the viscosity indicated that the presence of graphene induced shear thinning during extrusion. Azimuthal scans of wide angle x-ray scattering indicate correlated thermal fluctuations of the graphene platelets which stops abruptly at the onset of transcrystallization, or templating of the iPP chains on the graphene. X-ray microbeam SAXS analysis show the formation of ‘shish-kebab’ structures at the core of the unfilled filaments, where the ‘kebab’ component vanishes at the fiber-fiber interface enabling interdiffusion. Weak lamellar structure, and a corresponding decrease in the storage modulus are observed with the addition of 5% graphene. The lamellar structure disappears entirely with the addition of 10% graphene, while the storage modulus is decreased by nearly 50%. Thermal imaging of heat flux dissipation across molded and printed samples shows no orientational effects in pure iPP despite differences in crystal structure. Thermal conductivity increases dramatically in the samples with 10% graphene, and strong orientational effects are observed where the thermal coefficients differ by 180% between samples printed parallel or perpendicular to the heat flux.

36 MATERIALS SCIENCE↗

Applying colloidal silica suspensions injection and sequential gelation to block vertical water flow in well annulus: laboratory testing on rheology, gelation, and injection

We evaluated the application of silica suspension injection and sequential gelation to block vertical water flow in the annuli of long-screened wells. First, we studied the viscosity, rheological behavior, and gelation performance of colloidal silica suspensions in batch tests. Then, we tested the injection of silica suspensions and the water flow blocking efficiency of the later formed silica gel in column and bench-scale sandbox experiments. Micron-sized fumed powder silica suspensions and nanosized silica suspensions recovered from geothermal fluids were tested in this work. Fumed silica suspensions showed shear thinning, while nanosized silica suspensions exhibited Newtonian flow behavior. During the gelation process, the nanosized silica suspension changed from a Newtonian fluid to a shear thinning fluid while increasing its overall viscosity. At comparable concentrations, the nanosized silica suspensions have much lower viscosity than that of the fumed silica suspensions. Increases in the Na + concentration and silica particle concentration in these suspensions shortened the gelation time. Silica suspension gelation in sand columns completely blocked the water flow and sustained the injection pressure up to 50 psig (344.7 kPa). A silica suspension was successfully injected into the target zone in the annulus of a bench-scale sandbox mimicking long-screened wells in the field. The silica gel formed in the annulus effectively blocked chemical transport through the gelled zone. Our research reveals that a process using silica suspension injection and sequential gelation technology is promising for blocking the vertical water flow and chemical transport through the filter pack in targeted zones within the annulus of long-screened well systems.

54 ENVIRONMENTAL SCIENCES↗