Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “vertical”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 289 records · Page 16
All sourcesNASA NTRSDOE OSTI
DOE OSTI2026

Examining Aerosol Vertical Transport and Removal during Deep Convective Events

Atmospheric aerosols affect the global energy budget by scattering and absorbing sunlight (direct effects) and by changing the microphysical structure, lifetime, and coverage of clouds (indirect effects). Globally, the free troposphere is a major source of nucleation- and Aitken-mode aerosols due to the enhanced new particle formation rates at high altitudes. Recent studies have shown deep convective systems are capable of transporting these small aerosols from the free troposphere to the boundary layer by strong convective downdrafts and weaker downward motions in the stratiform regions. These vertically transported aerosols can grow into cloud condensation nuclei (CCN) and play a significant role in the global climate. During the deep convective processes, existing accumulation-mode aerosols that act as coagulation sinks of smaller particles are also removed by wet scavenging. Compared to the vertical transport of these particles by entrainment mixing, which is slower but more prevalent, the deep convective downdraft processes may be more rapid and efficient in the vertical transport of aerosols. However, most of the current climate models do not include this mechanism as a source of CCN, mainly because the frequency of deep convective events varies significantly with geographic location and thus their contributions to CCN are unpredictable. We target this critical gap in understanding the vertical transport and removal of aerosols by deep convections. We proposed to analyze a multi-year, multi-site measurement record available from the U.S. Department of Energy (DOE) ARM program, including the observations from the 2014/15 Observations and Modeling of the Green Ocean Amazon (GoAmazon) field campaign, the 2017/18 Aerosol and Cloud Experiments in the Eastern North Atlantic (ACE-ENA) field campaign, the 2018/19 Cloud, Aerosol, and Complex Terrain Interactions (CACTI) field campaign, the 2021/22 Tracking Aerosol Convection Interactions Experiment (TRACER) field campaign, and the long-term measurements collected at the Southern Great Plains (SGP) atmospheric observatory, where deep convective clouds were frequently observed. This project is aimed at the following three objectives: (1) Gaining a detailed and quantitative understanding of the aerosols transported by a convective downdraft and their evolution in the atmosphere; (2) Examining the wet scavenging mechanisms and efficiencies of aerosols at altitudes of deep convective systems based on ground and aircraft measurements; (3) Evaluating the contribution of deep convective systems to CCN as both a source and a sink of atmospheric aerosols and its seasonal variabilities.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2022

An “Eddy β-Spiral” mechanism for vertical velocity dipole patterns of isolated oceanic mesoscale eddies

Oceanic eddies accompanied by a significant vertical velocity ( w ) are known to be of great importance for the vertical transport of various climatically, biologically or biogeochemically relevant properties. Using quasi-geostrophic w -thinking to extend the classic “ β -spiral” w -theory for gyre circulations to isolated and nearly symmetric oceanic mesoscale eddies, we propose that their w motion will be dominated by a strong east-west dipole pattern with deep ocean penetrations. Contrasting numerical simulations of idealized isolated eddies together with w -equation diagnostics confirm that the w -dipole is indeed dominated by the “eddy β -spiral” mechanism in the β -plane simulation, whereas this w -dipole expectedly disappears in the f -plane simulation. Analyses of relatively isolated warm and cold eddy examples show good agreement with the proposed mechanism. Our studies further clarify eddy vertical motions, have implications for ocean mixing and vertical transport, and inspire further studies.

58 GEOSCIENCES↗
DOE OSTI2019

Enhancing Absorption Bandwidth through Vertically Oriented Metamaterials

Metamaterials research has developed perfect absorbers from microwave to optical frequencies, mainly featuring planar metamaterials, also referred to as metasurfaces. In this study, we investigated vertically oriented metamaterials, which make use of the entire three-dimensional space, as a new avenue to widen the spectral absorption band in the infrared regime between 20 and 40 THz. Vertically oriented metamaterials, such as those simulated in this work, can be experimentally realized through membrane projection lithography, which allows a single unit cell to be decorated with multiple resonators by exploiting the vertical dimension. In particular, we analyzed the cases of a unit cell containing a single vertical split-ring resonator (VSRR), a single planar split-ring resonator (PSRR), and both a VSRR and PSRR to explore intra-cell coupling between resonators. We show that the additional degrees of freedom enabled by placing multiple resonators in a unit cell lead to novel ways of achieving omnidirectional super absorption. Our results provide an innovative approach for controlling and designing engineered nanostructures.

36 MATERIALS SCIENCE↗
DOE OSTI2014

Comparing the Cloud Vertical Structure Derived from Several Methods Based on Radiosonde Profiles and Ground-based Remote Sensing Measurements

The cloud vertical distribution and especially the cloud base height, which is linked to cloud type, is an important characteristic in order to describe the impact of clouds in a changing climate. In this work several methods to estimate the cloud vertical structure (CVS) based on atmospheric sounding profiles are compared, considering number and position of cloud layers, with a ground based system which is taken as a reference: the Active Remote Sensing of Clouds (ARSCL). All methods establish some conditions on the relative humidity, and differ on the use of other variables, the thresholds applied, or the vertical resolution of the profile. In this study these methods are applied to 125 radiosonde profiles acquired at the ARM Southern Great Plains site during all seasons of year 2009 and endorsed by GOES images, to confirm that the cloudiness conditions are homogeneous enough across their trajectory. The overall agreement for the methods ranges between 44-88%; four methods produce total agreements around 85%. Further tests and improvements are applied on one of these methods. In addition, we attempt to make this method suitable for low resolution vertical profiles, which could be useful in atmospheric modeling. The total agreement, even when using low resolution profiles, can be improved up to 91% if the thresholds for a moist layer to become a cloud layer are modified to minimize false negatives with the current data set, thus improving overall agreement.

atmospheric↗
NASA NTRS2022

Vertical Climb Testing of the Model 699 Proprotor on the Tiltrotor Test Rig

The Tiltrotor Test Rig (TTR) is a new NASA asset for testing full-scale proprotors. The first test campaign in the National Full-Scale Aerodynamics Facility (NFAC) concluded in November 2018. The wind-tunnel test included vertical climb conditions simulated by axial flow at low airspeeds (true hover is not possible in the NFAC). The rotor tested was the Bell Model 699, an AW609 rotor modified specifically for wind-tunnel testing. The rotor was tested under a variety of NFAC configurations, some unprecedented and unique to vertical climb. This paper presents results for all test configurations applicable to vertical climb, including assessments of data quality. Comparisons with earlier tests of a similar rotor, the 0.656-scale Joint Vertical Experimental (JVX) rotor, are included to provide additional insights into rotor and wind tunnel behavior.

Vertical Climb↗
DOE OSTI2015

Effect of dry large‐scale vertical motions on initial MJO convective onset

Abstract Anomalies of eastward propagating large‐scale vertical motion with ~30 day variability at Addu City, Maldives, move into the Indian Ocean from the west and are implicated in Madden‐Julian Oscillation (MJO) convective onset. Using ground‐based radar and large‐scale forcing data derived from a sounding array, typical profiles of environmental heating, moisture sink, vertical motion, moisture advection, and Eulerian moisture tendency are computed for periods prior to those during which deep convection is prevalent and those during which moderately deep cumulonimbi do not form into deep clouds. Convection with 3–7 km tops is ubiquitous but present in greater numbers when tropospheric moistening occurs below 600 hPa. Vertical eddy convergence of moisture in shallow to moderately deep clouds is likely responsible for moistening during a 3–7 day long transition period between suppressed and active MJO conditions, although moistening via evaporation of cloud condensate detrained into the environment of such clouds may also be important. Reduction in large‐scale subsidence, associated with a vertical velocity structure that travels with a dry eastward propagating zonal wavenumbers 1–1.5 structure in zonal wind, drives a steepening of the lapse rate below 700 hPa, which supports an increase in moderately deep moist convection. As the moderately deep cumulonimbi moisten the lower troposphere, more deep convection develops, which itself moistens the upper troposphere. Reduction in large‐scale subsidence associated with the eastward propagating feature reinforces the upper tropospheric moistening, helping to then rapidly make the environment conducive to formation of large stratiform precipitation regions, whose heating is critical for MJO maintenance.

Powell, Scott W.↗
DOE OSTI2015

Roles of Wind Shear at Different Vertical Levels, Part I: Cloud System Organization and Properties

Understanding of critical processes that contribute to the organization of mesoscale convective systems is important for accurate weather forecast and climate prediction. In this study, we investigate the effects of wind shear at different vertical levels on the organization and properties of cloud systems using the Weather Research & Forecasting (WRF) model with a spectral-bin microphysical scheme. The sensitivity experiments are performed by increasing wind shear at the lower (0-5 km), middle (5-10 km), upper (> 10 km) and the entire troposphere, respectively, based on a control run for a mesoscale convective system (MCS) with weak wind shear. We find that increasing wind shear at the both lower and middle vertical levels reduces the domain-accumulated precipitation and the occurrence of heavy rain, while increasing wind shear at the upper levels changes little on precipitation. Although increasing wind shear at the lower-levels is favorable for a more organized quasi-line system which leads to enlarged updraft core area, and enhanced updraft velocities and vertical mass fluxes, the precipitation is still reduced by 18.6% compared with the control run due to stronger rain evaporation induced by the low-level wind shear. Strong wind shear in the middle levels only produces a strong super-cell over a narrow area, leading to 67.3% reduction of precipitation over the domain. By increasing wind shear at the upper levels only, the organization of the convection is not changed much, but the increased cloudiness at the upper-levels leads to stronger surface cooling and then stabilizes the atmosphere and weakens the convection. When strong wind shear exists over the entire vertical profile, a deep dry layer (2-9 km) is produced and convection is severely suppressed. There are fewer very-high (cloud top height (CTH) > 15 km) and very-deep (cloud thickness > 15 km) clouds, and the precipitation is only about 11.8% of the control run. The changes in cloud microphysical properties further explain the reduction of surface rain by strong wind shear especially at the lower- and middle-levels. The insights obtained from this study help us better understand the cloud system organization and provide foundation for better parameterizing organized MCS.

cloud system organization↗
DOE OSTI2023

Face‐on Orientation Matches Vertical Organic Electrochemical Transistors for High Transconductance and Superior Non‐Volatility

Abstract The recently developed vertical structure of organic electrochemical transistors (OECTs) can integrate volatile and non‐volatile functions into one reconfigurable device, making it highly promising. However, comparing with the conventional planar OECT (c‐OECT), the understanding of vertical OECT (v‐OECT) working principles and device engineering strategies is still lacking, impeding rational optimization. Since a major difference between c‐ and v‐OECTs is their charge transport directionality, which is highly influenced by crystallite orientations, the orientation–device structure match thus becomes an important yet outstanding topic for OECTs. Herein, using ann‐type small molecule IDIC‐MEG, investigate how much impact such match can have on OECT performance. The IDIC‐MEG c‐OECT fails to work due to the seriously hindered in‐plane electron transport by face‐on orientation. Surprisingly, simply changing the device structure from planar to vertical allows the resultant v‐OECT to exhibit the highest reported transconductance (46.3 mS) among all small‐molecule OECTs, thanks to the match between face‐on orientation and the vertical structure. Such match also leads to excellent non‐volatility, including highly predictable programmability and good operational stability. This work, for the first time, explicitly demonstrates the significance of orientation–device structure match for OECT optimization, establishing new guidelines for achieving high‐performance volatile and non‐volatile OECTs.

Chemistry↗
DOE OSTI2019

Competing Interface and Bulk Effect–Driven Magnetoelectric Coupling in Vertically Aligned Nanocomposites

Abstract Room‐temperature magnetoelectric (ME) coupling is developed in artificial multilayers and nanocomposites composed of magnetostrictive and electrostrictive materials. While the coupling mechanisms and strengths in multilayers are widely studied, they are largely unexplored in vertically aligned nanocomposites (VANs), even though theory has predicted that VANs exhibit much larger ME coupling coefficients than multilayer structures. Here, strong transverse and longitudinal ME coupling in epitaxial BaTiO 3 :CoFe 2 O 4 VANs measured by both optical second harmonic generation and piezoresponse force microscopy under magnetic fields is reported. Phase field simulations have shown that the ME coupling strength strongly depends on the vertical interfacial area which is ultimately controlled by pillar size. The ME coupling in VANs is determined by the competition between the vertical interface coupling effect and the bulk volume conservation effect. The revealed mechanisms shed light on the physical insights of vertical interface coupling in VANs in general, which can be applied to a variety of nanocomposites with different functionalities beyond the studied ME coupling effect.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Improving vertical detail in simulated temperature and humidity data using machine learning

Atmospheric models used for weather forecasting and climate predictions discretise the atmosphere onto a vertical grid. There are however atmospheric phenomena that occur on scales smaller than the thickness of those model layers. The formation of low-level clouds due to temperature inversions is an example. This leads to atmospheric models underestimating, or even missing, these clouds and their radiative effects. Using radiosonde observations as training data, a machine learning model is used to improve the vertical detail of modelled profiles of temperature and specific humidity. In addition, a physics-informed machine learning model is developed and compared to the traditional approach; showing improvements in the cloud fraction profiles calculated from its predictions. The vertically enhanced profiles also improve the representation of layers of convective inhibition and anomalous refractivity gradients. This work facilitates targeted improvements to the representation of certain atmospheric processes without the burden of increased memory and computational cost from increasing vertical resolution throughout the whole model.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Little vertical and circumferential variations in stem xylem water Δ 2 H and Δ 18 O in three tree species

Vertical and circumferential patterns of xylem water isotope signatures in large trees are rarely characterized but may influence interpretation of water source investigations and soil/xylem water isotope offsets. Furthermore, to examine vertical and circumferential variation in xylem water δ 2 H and δ 18 O, we collected xylem tissue at 5 heights (0, 1, 4, 7 and 10 m) from three replicate trees of three species with contrasting xylem anatomy, two angiosperms (Liquidambar styraciflua and Quercus nigra) and one gymnosperm (Pinus taeda). Concurrently, we also determined δ 2 H and δ 18 O of groundwater, soil water, and recent precipitation. On a different day, we collected circumferential samples at 1 m from the same trees to test for sectorality effects. Water from stem and soil samples were cryogenically extracted and analyzed for δ 2 H and δ 18 O. Mean xylem water δ 2 H and δ 18 O were significantly different between species, both vertically and circumferentially. We did not find significant (p = 0.05) systematic variation in δ 2 H or δ 18 O with height. We found no significant evidence for sectorality effects on δ 2 H, δ 18 O. Variances of vertical synoptic xylem water δ 2 H or δ 18 O were similar between species, 7.2–10.4‰ for δ 2 H and 0.58–0.81‰ for δ 18 O. Circumferential variances were also similar between species, 4.0–6.0 for δ 2 H and 0.37–0.44 for δ 18 O. A mixing model showed that sweetgum, water oak and loblolly pine, were drawing most of their water from deep soil from 45 to 190 cm (84.7, 68.4 and 53.2%, respectively) however, soil water-excess values indicate δ 2 H fractionation effects on these estimates. Dual isotope mixing model evaluation with single and multiple sample configurations showed that source water estimates were not affected by within tree variability of xylem water signatures. Xylem water δ 2 H and δ 18 O variability with height or circumference, was 3.2 and 2.7 times less than between tree variation because of transient temporal and spatial processes and is, therefore, not likely to affect interpretations of water sourcing in these three species.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2020

Multilayered microstructures with shape memory effects for vertical deployment

This paper presents a fabrication and characterization of multilayered microstructures with shape memory effects enabling large vertical deployment under electro-thermal actuation. Our previous research demonstrated vertical deployment of such microstructures by the effect of thermal mismatch. Development of equiatomic NiTi layers in the multilayered microstructure is investigated further for shape memory effects. Multilayered microstructures are built by sputtered NiTi layers and a lift-off process. Negative photoresist ma-N1420 enables clean lift-off of 500 nm thick NiTi layers by forming a significant undercut profile after development. The parametric study on co-sputter powers for Ti and Ni 50 Ti 50 targets suggests that 100 W RF on Ti target and 200 W DC on Ni 50 Ti 50 target can deposit Ni 49.62 Ti 50.38 layers. X-Ray Diffraction (XRD) and Atomic Force Microscopy (AFM) were used to study the crystal structures and surface topography of NiTi layers. XRD results of post-annealed Ni 49.62 Ti 50.38 layers show coexistence of austenite and martensitic phases at room temperature, suggesting that the transformation temperature of such NiTi layers should be approximate 20 °C. The surface topography of Ni 49.62 Ti 50.38 layers reveals substantial increase of surface roughness at ambient conditions after the annealing. Experimental verification of the multilayered microstructure for vertical deployment was carried out by Signatone Probe Station and Dual Scanning Electron Microscope/Focused Ion Beam (SEM/FIB) system. Finally, a vertical deployment of the two-dimensional (2D) multilayered microstructures for three-dimensional (3D) can be detected by applying a constant voltage of 0.04 V, and the expected 3D deployment displacement is enlarged from 2 μm to 10 μm by introducing the shape memory effect.

42 ENGINEERING↗
DOE OSTI2015

CVD growth of graphene under exfoliated hexagonal boron nitride for vertical hybrid structures

Graphical abstract: We have demonstrated a novel yet simple method for fabricating graphene-based vertical hybrid structures by performing the CVD growth of graphene at an h-BN/Cu interface. Our systematic Raman measurements combined with plasma etching process indicate that a graphene film is grown under exfoliated h-BN rather than on its top surface, and that an h-BN/graphene vertical hybrid structure has been fabricated. Electrical transport measurements of this h-BN/graphene, transferred on SiO2, show the carrier mobility up to approximately 2250 cm{sup 2} V{sup −1} s{sup −1}. The developed method would enable the exploration of the possibility of novel hybrid structure integration with two-dimensional material systems. - Abstract: We have demonstrated a novel yet simple method for fabricating graphene-based vertical hybrid structures by performing the CVD growth of graphene at an h-BN/Cu interface. Our systematic Raman measurements combined with plasma etching process indicate that a graphene film is grown under exfoliated h-BN rather than on its top surface, and that an h-BN/graphene vertical hybrid structure has been fabricated. Electrical transport measurements of this h-BN/graphene, transferred on SiO{sub 2}, show the carrier mobility up to approximately 2250 cm{sup 2} V{sup −1} s{sup −1}. The developed method would enable the exploration of the possibility of novel hybrid structure integration with two-dimensional material systems.

36 MATERIALS SCIENCE↗
DOE OSTI2016

Vertical Phase Segregation Induced by Dipolar Interactions in Planar Polymer Brushes

In this paper, we present a generalized theory for studying structural properties of a planar dipolar polymer brush immersed in a polar solvent. We show that an explicit treatment of the dipolar interactions yields a macroscopic concentration dependent effective “chi” (the Flory–Huggins-like interaction) parameter. Furthermore, it is shown that the concentration dependent chi parameter promotes phase segregation in polymer solutions and brushes so that the polymer-poor phase consists of a finite/nonzero polymer concentration. Such a destabilization of the homogeneous phase by the dipolar interactions appears as vertical phase segregation in a planar polymer brush. In a vertically phase segregated polymer brush, the polymer-rich phase near the grafting surface coexists with the polymer-poor phase at the other end. Predictions of the theory are directly compared with prior reported experimental results for dipolar polymers in polar solvents. Excellent agreements with the experimental results are found, hinting that the dipolar interactions play a significant role in vertical phase segregation of planar polymer brushes. We also compare our field theoretical approach with the two-state and other models invoking ad hoc concentration dependence of the chi parameter. Interplay between the short-ranged excluded volume interactions and long-ranged dipolar interactions is shown to play an important role in affecting the vertical phase separation. Finally, effects of mismatch between the dipole moments of the polymer segments and the solvent molecules are investigated in detail.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Assembling Vertical Block Copolymer Nanopores via Solvent Vapor Annealing on Homopolymer-Functionalized Substrates

Utilizing the self-assembly of block copolymers with large Flory–Huggins interaction parameters (χ) for nanofabrication is a formidable challenge due to the attendant large surface energy differences between the blocks. This work reports a robust protocol for the fabrication of thin films with highly ordered cylindrical nanopore arrays via the self-assembly of an asymmetric poly(styrene-block-4-vinylpyridine) (PS-b-P4VP) diblock copolymer blended with a P4VP homopolymer. The desired vertical domain orientation is achieved at the air–polymer interface by controlled solvent vapor annealing (SVA) using acetone, a solvent with weak selectivity for PS over P4VP, and at the substrate interface by functionalization using a hydroxy-terminated poly(2-vinylpyridine) (P2VP-OH) homopolymer brush. In contrast, the vertical cylinder orientation is unstable during acetone SVA on substrates functionalized using hydroxy-terminated poly(methyl methacrylate) (PMMA-OH). Although PMMA exhibits more balanced interfacial energies between PS and P4VP than P2VP in the dry state, it is also swollen more selectively by acetone. We hypothesize that the nearly balanced solvent swelling of the three polymers (P2VP, P4VP, and PS) stabilizes the vertical cylinder orientation, while unbalanced swelling (PMMA > P4VP and PS) does not. Here we further characterize pore formation by addition of a P4VP homopolymer and its postassembly extraction using ethanol, revealing a narrow window of pore size tunability. Notably, minimal differences in nanopore morphologies are observed for P4VP volume fractions as high as 0.1, regardless of the P4VP molar mass. However, further increasing the P4VP volume fraction results in domain reorientation or macrophase separation when its molar mass is less than or greater than the P4VP block molar mass, respectively. Using a P4VP homopolymer that is nearly equal in length to the P4VP block enables the fabrication of well-ordered arrays of vertical, through-film nanopores with high aspect ratios (>10), small periods (<23 nm), and diameters less than 10 nm.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2022

Atomic-Scale Insights into the Lateral and Vertical Epitaxial Growth in Two-Dimensional Pd 2 Se 3 –MoS 2 Heterostructures

Two-dimensional (2D) materials form heterostructures in both the lateral and vertical directions when two different materials are interfaced, but with totally different bonding mechanisms of covalent in-plane to van der Waal’s layered interactions. Understanding how the competition between lateral and vertical forces influences the epitaxial growth is important for future materials development of complex mixed layered heterostructures. In this study, we use atomic-resolution annular dark-field scanning transmission electron microscopy to study the detailed atomic arrangements at mixed 2D heterostructure interfaces composed of two semiconductors with distinctly different crystal symmetry and elemental composition, Pd 2 Se 3 :MoS 2 , in order to understand the role of different chemical bonds on the resultant epitaxy. Pd 2 Se 3 is grown off the step edge in bilayer MoS 2 , and the vertical and lateral epitaxial relationships of the Pd 2 Se 3 –MoS 2 heterostructures are investigated. We find that the similarity of geometry at the interface with one metal (Pd or Mo) atoms bonded with two chalcogens (S or Se) are the crucial factors to make the atomically stitched lateral junction of 2D heterostructures. In addition, the vertical van der Waal interactions that are normally dominant in layered materials can be overcome by in-plane forces if the interfacial atomic stitching is high in quality and low in defect density. This knowledge should help guide the approaches for improving the epitaxy in mixed 2D heterostructures and seamless stitching of in-plane 2D heterostructures with various complex monolayer structures.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Vertical Variations of Cloud Microphysical Relationships in Marine Stratocumulus Clouds Observed During the ACE‐ENA Campaign

Abstract This study examines the vertical variations of cloud microphysical relationships and their implications to cloud microphysical processes in marine stratocumulus clouds using in‐situ aircraft observations during the Aerosol and Cloud Experiments in Eastern North Atlantic (ACE‐ENA) field campaign. A new diagram with a coordinate system based on cloud droplet liquid water content (L c ) and phase relaxation time scale is proposed to investigate mixing mechanisms. This new diagram analysis shows that the inhomogeneous mixing trait is dominant near the cloud top, but homogeneous mixing trait is stronger at lower altitudes. The relevant scale parameters (i.e., transition length scale and transition scale number) also indicate a high likelihood of inhomogeneous mixing. The relationship between L c and standard deviation of droplet radius (σ R ) clearly shows the vertical transition: the correlation between L c and σ R is positive at lower cloud altitudes, but it becomes negative as altitude increases. Such a vertical transition is consistent with the vertical circulation mixing, modulating the cloud microphysical relationships to suggest homogeneous mixing at a significant depth from the cloud top.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Vertical organic electrochemical transistors for complementary circuits

Abstract Organic electrochemical transistors (OECTs) and OECT-based circuitry offer great potential in bioelectronics, wearable electronics and artificial neuromorphic electronics because of their exceptionally low driving voltages (<1 V), low power consumption (<1 µW), high transconductances (>10 mS) and biocompatibility 1–5 . However, the successful realization of critical complementary logic OECTs is currently limited by temporal and/or operational instability, slow redox processes and/or switching, incompatibility with high-density monolithic integration and inferior n-type OECT performance 6–8 . Here we demonstrate p- and n-type vertical OECTs with balanced and ultra-high performance by blending redox-active semiconducting polymers with a redox-inactive photocurable and/or photopatternable polymer to form an ion-permeable semiconducting channel, implemented in a simple, scalable vertical architecture that has a dense, impermeable top contact. Footprint current densities exceeding 1 kA cm −2 at less than ±0.7 V, transconductances of 0.2–0.4 S, short transient times of less than 1 ms and ultra-stable switching (>50,000 cycles) are achieved in, to our knowledge, the first vertically stacked complementary vertical OECT logic circuits. This architecture opens many possibilities for fundamental studies of organic semiconductor redox chemistry and physics in nanoscopically confined spaces, without macroscopic electrolyte contact, as well as wearable and implantable device applications.

Science & Technology - Other Topics↗