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At least 289 records · Page 16

Spectral Indices to Monitor Nitrogen-Driven Carbon Uptake in Field Corn

Climate change is heavily impacted by changing vegetation cover and productivity with large scale monitoring of vegetation only possible with remote sensing techniques. The goal of this effort was to evaluate existing reflectance (R) spectroscopic methods for determining vegetation parameters related to photosynthetic function and carbon (C) dynamics in plants. Since nitrogen (N) is a key constituent of photosynthetic pigments and C fixing enzymes, biological C sequestration is regulated in part by N availability. Spectral R information was obtained from field corn grown at four N application rates (0, 70, 140, 280 kg N/ha). A hierarchy of spectral observations were obtained: leaf and canopy with a spectral radiometer; aircraft with the AISA sensor; and satellite with EO-1 Hyperion. A number of spectral R indices were calculated from these hyperspectral observations and compared to geo-located biophysical measures of plant growth and physiological condition. Top performing indices included the R derivative index D730/D705 and the normalized difference of R750 vs. R705 (ND705), both of which differentiated three of the four N fertilization rates at multiple observation levels and yielded high correlations to these carbon parameters: light use efficiency (LUE); C:N ratio; and crop grain yield. These results advocate the use of hyperspectral sensors for remotely monitoring carbon cycle dynamics in managed terrestrial ecosystems.

Corp, Lawrence A.↗

Highlights of NASA’s Orbital Debris Program Office In Situ and Laboratory Measurements

NASA’s Orbital Debris Program Office (ODPO) maintains various returned spacecraft materials, capabilities, and facilities used for in situ and laboratory measurements that directly support orbital debris environmental models. In situ measurements include the analysis of exposed and returned hardware surfaces. These surfaces serve as passive sensors for the small-sized micrometeoroid and orbital debris (MMOD) flux below the sensitivity of ground-based radar and optical sensors. Various instruments and techniques are used to determine the size and depth of selected impact features, and – if feasible – the composition of the projectile material. Analysis of the impactor residues enables the differentiation of MM and OD for debris below 1 mm to support modeling the OD environment. In addition, projectiles identified as OD can be further differentiated in low-, medium-, and high- density impactors based on chemical analyses. In addition to in situ measurements, the ODPO has also worked in collaboration with the U.S. Space Force Space Systems Command (formerly the U.S. Air Force Space and Missile Systems Center), the Aerospace Corporation, and the University of Florida on a laboratory-based hypervelocity impact test, DebriSat, conducted at the Air Force Arnold Engineering Development Complex in 2014. The resulting data from this impact test series are being analyzed to assess the fragments’ sizes/masses, materials/densities, shapes, and other parameters of interest. The DebriSat project provides the data needed to update NASA’s breakup models and size estimation models using the simulated orbital breakup of a modern, low Earth orbit spacecraft. Ultimately, over 200,000 fragments from this impact test will be stored at NASA Johnson Space Center (JSC) and further analyzed by the ODPO. This project will also use machine learning techniques to infer physical parameters of fragments embedded in the soft-catch foam used in the impact experiment. Applied to X-ray imagery of the foam panels, these techniques promise to minimize human-in-the-loop processes for fragment extraction and physical characterization. A brief overview of this project and data collected will be presented. Lastly, the ODPO provides various capabilities hosted at NASA JSC for optical inspections and measurements using a variety of techniques and scientific instrumentation to support both in situ and laboratory measurements. The ODPO’s Optical Measurement Center (OMC) is an advanced facility for photometric and spectroscopic laboratory measurements of targets, including fragments from the DebriSat project. The OMC simulates telescopic observations by using space-like illumination conditions and source-target-sensor orientation techniques. Additionally, the OMC is uniquely equipped to acquire pseudo-bidirectional reflectance distribution data for broadband photometric measurements, thus removing aspect angle dependencies that can affect target size estimates using the optical size estimation model. Narrow-band surface material characterization using spectroscopic instrumentation gives insight into how the albedo parameter – also important in the optical size estimation model – may vary depending on the state of the material. The OMC also performs simulations of photometric measurements using optical ray-tracing software to model the OMC optical throughput. In addition to the OMC, the ODPO houses a start-of-the-art Fragment Analysis Facility that uses multiple microscopic inspection instruments to support in situ measurements and material characterization. An overview of both facilities will be highlighted in this paper.

Orbital Debris↗

Highlights of NASA’s Orbital Debris Program Office In Situ and Laboratory Measurements

NASA’s Orbital Debris Program Office (ODPO) maintains various returned spacecraft materials, capabilities, and facilities used for in situ and laboratory measurements that directly support orbital debris environmental models. In situ measurements include the analysis of exposed and returned hardware surfaces. These surfaces serve as passive sensors for the small-sized micrometeoroid and orbital debris (MMOD) flux below the sensitivity of ground-based radar and optical sensors. Various instruments and techniques are used to determine the size and depth of selected impact features, and – if feasible – the composition of the projectile material. Analysis of the impactor residues enables the differentiation of MM and OD for debris below 1 mm to support modeling the OD environment. In addition, projectiles identified as OD can be further differentiated in low-, medium-, and high- density impactors based on chemical analyses. In addition to in situ measurements, the ODPO has also worked in collaboration with the U.S. Space Force Space Systems Command (formerly the U.S. Air Force Space and Missile Systems Center), the Aerospace Corporation, and the University of Florida on a laboratory-based hypervelocity impact test, DebriSat, conducted at the Air Force Arnold Engineering Development Complex in 2014. The resulting data from this impact test series are being analyzed to assess the fragments’ sizes/masses, materials/densities, shapes, and other parameters of interest. The DebriSat project provides the data needed to update NASA’s breakup models and size estimation models using the simulated orbital breakup of a modern, low Earth orbit spacecraft. Ultimately, over 200,000 fragments from this impact test will be stored at NASA Johnson Space Center (JSC) and further analyzed by the ODPO. This project will also use machine learning techniques to infer physical parameters of fragments embedded in the soft-catch foam used in the impact experiment. Applied to X-ray imagery of the foam panels, these techniques promise to minimize human-in-the-loop processes for fragment extraction and physical characterization. A brief overview of this project and data collected will be presented. Lastly, the ODPO provides various capabilities hosted at NASA JSC for optical inspections and measurements using a variety of techniques and scientific instrumentation to support both in situ and laboratory measurements. The ODPO’s Optical Measurement Center (OMC) is an advanced facility for photometric and spectroscopic laboratory measurements of targets, including fragments from the DebriSat project. The OMC simulates telescopic observations by using space-like illumination conditions and source-target-sensor orientation techniques. Additionally, the OMC is uniquely equipped to acquire pseudo-bidirectional reflectance distribution data for broadband photometric measurements, thus removing aspect angle dependencies that can affect target size estimates using the optical size estimation model. Narrow-band surface material characterization using spectroscopic instrumentation gives insight into how the albedo parameter – also important in the optical size estimation model – may vary depending on the state of the material. The OMC also performs simulations of photometric measurements using optical ray-tracing software to model the OMC optical throughput. In addition to the OMC, the ODPO houses a start-of-the-art Fragment Analysis Facility that uses multiple microscopic inspection instruments to support in situ measurements and material characterization. An overview of both facilities will be highlighted in this paper.

Orbital Debris↗

Equilibrium and nonequilibrium electron density measurements in transient shock-heated hydrogen-helium plasmas

In the NASA planetary program, atmospheric entry probe missions to Jupiter, Saturn, and Uranus are potential programs now being planned for the 1980's. The work reported in this paper is concerned with predicting the electron density, and resulting radiative emission from the shock layer which must be accommodated by the entry probe heatshield. Within the hydrogen-helium plasma surrounding the forward heatshield, there are regions of near thermochemical equilibrium whose properties are predictable - however, there are uncertainties in these electron density calculations necessitating further measurements by H-beta line broadening and holographic interferometer fringe shift as reported here. There is good agreement between the results obtained from the holographic measurements and the spectroscopic measurements which lends confidence to each of the two completely independent diagnostic techniques. The equilibrium electron density determined from the experimental measurements is somewhat higher than that predicted.

Livingston, F. R.↗

X-ray astronomical spectroscopy

The elementary spectral signatures of fundamental physical processes that might be operable in galactic and extragalactic X-ray sources are reviewed. Some of the instrument limitations of experimental techniques used in X-ray astronomical spectroscopy are described. X-ray spectroscopic measurements are examined for various types of X-ray-emitting objects, including degenerate and nondegenerate stellar systems, supernova remnants, clusters of galaxies, active galactic nuclei, and quasars.

Holt, S. S.↗

Preliminary orbital parallax catalog

The study is undertaken to calibrate the more reliable parallaxes derived from a comparison of visual and spectroscopic orbits and to encourage observational studies of other promising binaries. The methodological techniques used in computing orbital parallaxes are analyzed. Tables summarizing orbital data and derived system properties are then given. Also given is a series of detailed discussions of the 71 individual systems included in the tables. Data are listed for 57 other systems which are considered promising candidates for eventual orbital parallax determination.

Halliwell, M.↗

The Baade-Wesselink method applied to field RR Lyrae stars. II - SW Andromedae, SW Draconis, and SS Fornacis

The Baade-Wesselink method has been combined with previous photometry and radial velocities to yield distances of 520 + or - 50 pc, 840 + or - 50 pc, and 780 + or - 150 pc, and mean absolute magnitudes of 0.88 + or - 0.20, 0.86 + or - 0.20, and 0.73 + or - 0.50, for SW And, SW Dra, and SS For, respectively. The present technique is able to account for the problem of phase-lag between spectroscopically and photometrically determined radial displacements in SW Dra, the Blazhko effect in SW And, and both the phase-lag and Blazhko effects in SS For.

Cacciari, C.↗

Rotational Relaxation in Nonequilibrium Freejet Expansions of Heated Nitrogen

Rotational temperatures have been measured in rarefied, nonequilibrium, heated freejet expansions of nitrogen using the electron beam fluorescence technique at the University of California at Berkeley Low Density Wind Tunnel facility. Spectroscopic measurements of the (0,0) band of the first negative system of nitrogen reveal the nonequilibrium behavior in the flowfield upstream of, and through the Mach disk, which forms as the freejet expands into a region of finite back pressure. Results compare well with previous freejet expansion data and computations regarding location of the Mach disk and terminal rotational temperature in the expansion. Measurements are also presented for shock thickness based on the rotational temperature changes in the flow. Thickening shock layers, departures of rotational temperature from equilibrium in the expansion region, and downstream rotational temperature recovery much below that of an isentropic normal shock provide indications of the rarefied, nonequilibrium flow behavior. The data are analyzed to infer constant values of the rotational-relaxation collision number from 2.2 to 6.5 for the various flow conditions. Collision numbers are also calculated in a consistent manner for data from other investigations for which is seen a qualitative increase with increasing temperature. Rotational-relaxation collision numbers are seen as not fully descriptive of the rarefied freejet flows. This may be due to the high degree of nonequilibrium in the flowfields, and/or to the use of a temperature-insensitive rotational-relaxation collision number model in the data analyses.

Gochberg, Lawrence A.↗

Experimental and Theoretical Studies of Atmosphereic Inorganic Chlorine Chemistry

Over the last five years substantial progress has been made in defining the realm of new chlorine chemistry in the polar stratosphere. Application of existing experimental techniques to potentially important chlorine-containing compounds has yielded quantitative kinetic and spectroscopic data as well as qualitative mechanistic insights into the relevant reactions.

Atmosphere Chlorine Chemistry↗

Jet Fuel Thermal Stability Investigations Using Ellipsometry

Jet fuels are typically used for endothermic cooling in practical engines where their thermal stability is very important. In this work the thermal stability of Sasol IPK (a synthetic jet fuel) with varying levels of naphthalene has been studied on stainless steel substrates using spectroscopic ellipsometry in the temperature range 385-400 K. Ellipsometry is an optical technique that measures the changes in a light beam’s polarization and intensity after it reflects off of a thin film to determine the film’s thickness and optical properties. All of the tubes used were rated as thermally unstable by the color standard portion of the Jet Fuel Thermal Oxidation Test, and this was confirmed by the deposit thicknesses observed using ellipsometry. A new amorphous model on a stainless steel substrate was used to model the data and obtain the results. It was observed that, as would be expected, increasing the temperature of the tube increased the overall deposit amount for a constant concentration of naphthalene. The repeatability of these measurements was assessed using multiple trials of the same fuel at 385 K. Lastly, the effect of increasing the naphthalene concentration in the fuel at a constant temperature was found to increase the deposit thickness.In conclusion, ellipsometry was used to investigate the thermal stability of jet fuels on stainless steel substrate. The effects of increasing temperature and addition of naphthalene on stainless steel tubes with Sasol IPK fuel were investigated. It was found, as expected, that increasing temperature lead to an increase in deposit thickness. It wasAmerican Institute of Aeronautics and Astronautics6also found that increasing amounts of naphthalene increased the maximum deposit thickness. The repeatability of these measurements was investigated using multiple tests at the same conditions. The present work provides as a better quantitative tool compared to the widely used JFTOT technique. Future work will expand on the fuel types, temperature, and substrate materials.

thermal stability↗

Spectroscopic comparison of effects of electron radiation on mechanical properties of two polyimides

The differences in the radiation durabilities of two polyimide materials, Du Pont Kapton and General Electric Ultem, are compared. An explanation of the basic mechanisms which occur during exposure to electron radiation from analyses of infrared (IR) and electron paramagnetic resonance (EPR) spectroscopic data for each material is provided. The molecular model for Kapton was, in part, established from earlier modeling for Ultem (pp. 1293-1298 of IEEE Transactions on Nuclear Science, December 1984). Techniques for understanding the durability of one complex polymer based on the understanding of a different and equally complex polymer are demonstrated. The spectroscopic data showed that the primary radiation-generated change in the tensile properties of Ultem (a large reduction in tensile elongation) was due to crosslinking, which followed the capture by phenyl radicals of hydrogen atoms removed from gem-dimethyl groups. In contrast, the tensile properties of Kapton remained unchanged because radical-radical recombination, a self-mending process, took place.

Long, Edward R., Jr.↗

Chemical and spectroscopic characterization of a suite of Mars soil analogs

The National Aeronautics and Space Administration has begun preparations for the flight of the Mars Observer Mission in the early 1990s. An advanced ground-based study is being conducted on a usefully limited suite of Mars Soil Analog Materials (MarSAM) intended to simulate the aeolian material covering the surface of Mars. A series of variably proportioned iron/calcium smectite clays were prepared from a typical montmorillonite clay using the Banin method. The effect of increasing iron on a diverse set of chemical and spectroscopic properties of the suite of clays is discussed. In order to chemically characterize the MarSAM and compare them with the Martian soil studied by Viking, the clays were analyzed for their major and minor elemental compositions by X-ray fluorescence and ion-coupled plasma techniques. It was concluded that the surface iron has a complex and hitherto uninvestigated impact on the catalytic and spectroscopic properties of clays and on the ability of these material to store energy.

Coyne, L. M.↗

The Maturing of High Contrast Imaging and Starlight Suppression Techniques for Future NASA Exoplanet Characterization Missions

Over 3000 exoplanets and hundreds of exoplanetary systems have been detected to date and we are now rapidly moving toward an era where the focus is shifting from detection to direct imaging and spectroscopic characterization of these new worlds and their atmospheres. NASA is currently studying several exoplanet characterization mission concepts for the 2020 Decadal Survey ranging from probe class to flagships. Detailed and comprehensive exoplanet characterization, particularly of exo-Earths, leading to assessment of habitability, or indeed detection of life, will require significant advances beyond the current state-of-the-art in high contrast imaging and starlight suppression techniques which utilize specially shaped precision optical elements to block the light from the parent star while controlling scattering and diffraction thus revealing and enabling spectroscopic study of the orbiting exoplanets in reflected light. In this paper we describe the two primary high contrast starlight suppression techniques currently being pursued by NASA: 1) coronagraphs (including several design variations) and 2) free-flying starshades. These techniques are rapidly moving from the technology development phase to the design and engineering phase and we discuss the prospects and projected performance for future exoplanet characterization missions utilizing these techniques coupled with large aperture telescopes in space.

high contrast↗

The effects of electron and gamma radiation on epoxy-based materials

Specimens of graphite/epoxy composites and epoxy resins were exposed to electron and gamma radiation, followed by mechanical property and fundamental measurements. Measurement techniques included: scanning electron microscopy, X-ray diffraction analysis, and electron spin resonance spectroscopic analysis. Results indicate little or no change in flexural properties of miniature specimens of a graphite/epoxy composite and no change in failure mode at the fiber-resin interface and in the crystallinity of the fiber and the resin. Some doubt in the observation of stable flexural properties is cast by electron paramagnetic resonance spectra of a relatively large number of radiation-generated radicals. These generally lead to a change in cross-linking and in chain-scissioning which should alter mechanical properties.

Fornes, R. E.↗

Planar double delay-line readout technique for microchannel plate detectors

A two-dimensional position-sensitive electrical readout system for microchannel plate detectors in spectroscopic applications has been devised. Two adjacent parallel coplanar delay lines are used. The difference in time of arrival of the electron event signal between the ends of the delay lines gives one coordinate of the centroid of each event pulse. The ratio of the event amplitudes on the two delay lines gives the orthogonal coordinate by means of charge partitioning. The performance characteristics of operational double delay lines for systems of this type are presented.

Lampton, M.↗

An innovative approach to the development of a portable unit for analytical flame characterization in a microgravity environment

The availability of manned laboratory facilities in space offers wonderful opportunities and challenges in microgravity combustion science and technology. In turn, the fundamentals of microgravity combustion science can be studied via spectroscopic characterization of free radicals generated in flames. The laser-induced fluorescence (LIF) technique is a noninvasive method of considerable utility in combustion physics and chemistry suitable for monitoring not only specific species and their kinetics, but it is also important for imaging of flames. This makes LIF one of the most important tools for microgravity combustion science. Flame characterization under microgravity conditions using LIF is expected to be more informative than other methods aimed at searching for effects like pumping phenomenon that can be modeled via ground level experiments. A primary goal of our work consisted in working out an innovative approach to devising an LIF-based analytical unit suitable for in-space flame characterization. It was decided to follow two approaches in tandem: (1) use the existing laboratory (non-portable) equipment and determine the optimal set of parameters for flames that can be used as analytical criteria for flame characterization under microgravity conditions; and (2) use state-of-the-art developments in laser technology and concentrate some effort in devising a layout for the portable analytical equipment. This paper presents an up-to-date summary of the results of our experiments aimed at the creation of the portable device for combustion studies in a microgravity environment, which is based on a portable UV tunable solid-state laser for excitation of free radicals normally present in flames in detectable amounts. A systematic approach has allowed us to make a convenient choice of species under investigation, as well as the proper tunable laser system, and also enabled us to carry out LIF experiments on free radicals using a solid-state laser tunable in the UV.

Dubinskiy, Mark A.↗

Microwave, Millimeter, Submillimeter, and Far Infrared Spectral Databases

The spectrum of most known astrophysical molecules is derived from transitions between a few hundred to a few hundred thousand energy levels populated at room temperature. In the microwave and millimeter wave regions. spectroscopy is almost always performed with traditional microwave techniques. In the submillimeter and far infrared microwave technique becomes progressively more technologically challenging and infrared techniques become more widely employed as the wavelength gets shorter. Infrared techniques are typically one to two orders of magnitude less precise but they do generate all the strong features in the spectrum. With microwave technique, it is generally impossible and rarely necessary to measure every single transition of a molecular species, so careful fitting of quantum mechanical Hamiltonians to the transitions measured are required to produce the complete spectral picture of the molecule required by astronomers. The fitting process produces the most precise data possible and is required in the interpret heterodyne observations. The drawback of traditional microwave technique is that precise knowledge of the band origins of low lying excited states is rarely gained. The fitting of data interpolates well for the range of quantum numbers where there is laboratory data, but extrapolation is almost never precise. The majority of high resolution spectroscopic data is millimeter or longer in wavelength and a very limited number of molecules have ever been studied with microwave techniques at wavelengths shorter than 0.3 millimeters. The situation with infrared technique is similarly dire in the submillimeter and far infrared because the black body sources used are competing with a very significant thermal background making the signal to noise poor. Regardless of the technique used the data must be archived in a way useful for the interpretation of observations.

Pearson, J. C.↗