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At least 289 records · Page 16

Plant‐mediated methane transport in emergent and floating‐leaved species of a temperate freshwater mineral‐soil wetland

Abstract Methane flux from freshwater mineral‐soil (FWMS) wetlands and its variability among sites is largely modulated by plant‐mediated transport. However, plant‐mediated transport processes are rarely resolved in land surface models and are poorly parametrized for plants commonly found in FWMS wetlands. Here, relationships between methane flux and CO 2 uptake, as well as plant conductance of methane were evaluated for three plant species and two characteristic functional types: emergent (narrow‐leaved cattail) and floating‐leaved (American lotus and water lily). We found significant but contrasting correlations between methane flux and CO 2 uptake in cattails ( r 2 = 0.51, slope = −0.16, during morning) and water lily ( r 2 = 0.32, slope = 0.064, after midday). This relationship was not significant in American lotus, showing that stomata regulation of methane fluxes is species‐specific and not generalizable across the floating‐leaved plant functional type. Conductance of methane per leaf area showed distinct seasonal dynamics across species. Conductance was similar among the floating‐leaved species (6.2 × 10 −3 m d −1 in lotus and 7.2 × 10 −3 m d −1 in water lily) and higher than conductance in the emergent species (2.7 × 10 −3 m d −1 ). Our results provide direct observations of plant conductance rates and identify the vegetation parameters (leaf area, stomatal conductance) that modify them. Our results further suggest that models of methane emissions from FWMS should parameterize plant‐mediated transport in different plant functional types, scaled by leaf area and with variable seasonal phenological dynamics, and consider possible species‐specific mechanisms that control methane transport through plants.

Villa, Jorge A.↗

Beryllium characterization in soils by selective extraction

In the present work, an analytical method has been developed for the determination of the amount of man-made beryllium metal and/or beryllium compounds in soil in addition to the amount of native beryllium that is present. The method is based on the premise that if high-fired beryllium oxide can be extracted efficiently, then beryllium metal and acid-soluble beryllium salts would also be extracted efficiently.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Geochemistry of 2-4-mm particles from Apollo 14 soil (14161) and implications regarding igneous components and soil-forming processes

The present paper describes the compositional systematics of 381 particles analyzed from 14161, which was taken near the lunar module as part of the bulk sample. Attention is given to the distribution of lithologies, based on petrographic examination and compositions determined by INAA, and to implications of the compositions of polymict particles regarding igneous precursors and soil-forming processes. It was found that the most abundant particles are the impact-melt lithologies and regolith and fragmental breccias. The mean composition of the entire suite of 2-4-mm particles differs from that of the associated less-than-1-mm fines by having higher concentrations of incompatible trace elements and Na2O, and a lower concentration of CaO. There is a subset of regolith breccia particles and agglutinates in the 2-4-mm particles that have nearly identical compositions and Is/FeO similar to those of the less-than-1-mm fines. It is suggested that these particles are constructional products formed from the local regolith rather than comminuted fragments of ancient regolith breccias.

Jolliff, B. L.↗

Possible petrogenetic associations among igneous components in North Massif soils: Evidence in 2-4 mm soil particles from 76503

Studies of Apollo 17 highland igneous rocks and clasts in breccias from the North and South Massifs have described magnesian troctolite, norite, anorthositic gabbro, dunite, spinel cataclasites, and granulitic lithologies that may have noritic anothosite or anorthositic norite/gabbro as igneous precursors, and have speculated on possible petrogenetic relationships among these rock types. Mineral compositions and relative proportions of plagioclase and plagioclase-olivine particles in samples 76503 indicate that the precursor lithology of those particles were troctolitic anorthosite, not troctolite. Mineral and chemical compositions of more pyroxene-rich, magnesian breccias and granulites in 76503 indicate that their precursor lithology was anorthositic norite/gabbro. The combination of mineral compositions and whole-rock trace-element compositional trends supports a genetic relationship among these two groups as would result from differentiation of a single pluton. Although highland igneous lithologies in Apollo 17 materials have been described previously, the proportions of different igneous lithologies present in the massifs, their frequency of association, and how they are related are not well known. We consider the proportions of, and associations among, the igneous lithologies found in a North Massif soil, which may represent those of the North Massif or a major part of it.

Jolliff, Bradley L.↗

Pigmenting agents in Martian soils: inferences from spectral, Mossbauer, and magnetic properties of nanophase and other iron oxides in Hawaiian palagonitic soil PN-9

We have examined a Hawaiian palagonitic tephra sample (PN-9) that has spectroscopic similarities to Martian bright regions using a number of analytical techniques, including Mossbauer and reflectance spectroscopy, X-ray diffraction, instrumental neutron activation analysis, electron probe microanalysis, transmission electron microscopy, and dithionite-citrate-bicarbonate extraction. Chemically, PN-9 has a Hawaiitic composition with alkali (and presumably silica) loss resulting from leaching by meteoric water during palagonitization; no Ce anomaly is present in the REE pattern. Mineralogically, our results show that nanophase ferric oxide (np-Ox) particles (either nanophase hematite (np-Hm) or a mixture of ferrihydrite and np-Hm) are responsible for the distinctive ferric doublet and visible-wavelength ferric absorption edge observed in Mossbauer and reflectivity spectra, respectively, for this and other spectrally similar palagonitic samples. The np-Ox particles appear to be imbedded in a hydrated aluminosilicate matrix material; no evidence was found for phyllosilicates. Other iron-bearing phases observed are titanomagnetite, which accounts for the magnetic nature of the sample; olivine; pyroxene; and glass. By analogy, np-Ox is likely the primary pigmenting agent of the bright soils and dust of Mars.

Minerals/analysis↗