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At least 289 records · Page 16

Heterogeneous Activation, Local Structure, and Softness in Supercooled Colloidal Liquids

We experimentally characterize heterogeneous nonexponential relaxation in bidisperse supercooled colloidal liquids utilizing a recent concept called “softness”. Particle trajectory and structure data enable classification of particles into subgroups with different local environments and propensities to hop. We determine residence times t R between particle hops and show that t R derived from particles in the same softness subgroup are exponentially distributed. Using the mean residence time t¯ R for each softness subgroup, and a Kramers’ reaction rate model, we estimate the activation energy barriers E b for particle hops, and show that both t¯ R and E b are monotonic functions of softness. Lastly, we derive information about the combinations of large and small particle neighbors that determine particle softness, and we explicitly show that multiple exponential relaxation channels in the supercooled liquid give rise to its nonexponential behavior.

36 MATERIALS SCIENCE↗

Designing and Evaluating Redundancy-Based Soft-Error Masking on a Continuum of Energy versus Robustness

Near-threshold computing is an effective strategy to reduce the power dissipation of deeply-scaled CMOS logic circuits. However, near-threshold strategies exacerbate the impact of delay variations on device performance and increase the susceptibility to soft errors due to narrow voltage margins. The objective of this work is to develop and assess design approaches that leverage tradeoffs between performance and the resilience of fault masking coverage for various soft-error mitigation techniques. The primary insight from this work is identification of redundancy-based hardening techniques that can deliver increased benefits in terms of the fault coverage energy ratio (FCER) for the leveraged tradeoffs within iso-energy constraints at near-threshold voltage (NTV). Simulation results demonstrate that temporal redundancy approaches offer favorable tradeoffs in terms of FCER. They exhibit reduced impact on performance variations and achieve extensive soft fault masking, therefore improving the system robustness within acceptable delay constraints. Meanwhile, it is shown that a hybrid redundancy approach can be used to protect a low-power system to maintain throughput while tolerating soft errors. We demonstrate how the FCER metric can be used as an optimization parameter to guide circuit synthesis to meet performance and robustness goals. Lastly, the impact of design diversity on spatial and hybrid redundancy at NTV is assessed in terms of FCER and delay variation to form overall recommendations regarding soft-error mitigation at NTV.

97 MATHEMATICS AND COMPUTING↗

Integration of Soft Data Into Geostatistical Simulation of Categorical Variables

Uncertain or indirect “soft” data, such as geologic interpretation, driller’s logs, geophysical logs or imaging, offer potential constraints or “soft conditioning” to stochastic models of discrete categorical subsurface variables in hydrogeology such as hydrofacies. Previous bivariate geostatistical simulation algorithms have not fully addressed the impact of data uncertainty in formulation of the (co) kriging equations and the objective function in simulated annealing (or quenching). This paper introduces the geostatistical simulation code tsim-s, which accounts for categorical data uncertainty through a data “hardness” parameter. In generating geostatistical realizations with tsim-s, the uncertainty inherent to soft conditioning is factored into both 1) the data declustering and spatial correlation functions in cokriging and 2) the acceptance probability for change of category in simulated quenching. The degree or sensitivity to which soft data conditions a realization as a function of hardness can be quantified by mapping category probabilities derived from multiple realizations. In addition to point or borehole data, arrays of data (e.g., as derived from a depth-dependency function, probability map, or “prior realization”) can be used as soft conditioning. The tsim-s algorithm provides a theoretically sound and general framework for integrating datasets of variable location, resolution, and uncertainty into geostatistical simulation of categorical variables. A practical example shows how tsim-s is capable of generating a large-scale three-dimensional simulation including curvilinear features.

54 ENVIRONMENTAL SCIENCES↗

Embedded Fluidic Sensing and Control with Soft Open‐Cell Foams

Abstract The synthesis of soft matter intelligence with circuit‐driven logic has enabled a new class of robots that perform complex tasks or conform to specialized form factors in unique ways that cannot be realized through conventional designs. Translating this hybrid approach to fluidic systems, the present work addresses the need for sheet‐based circuit materials by leveraging the innate porosity of foam—a soft material—to develop pneumatic components that support digital logic, mixed‐signal control, and analog force sensing in wearables and soft robots. Analytical tools and experimental techniques developed in this work serve to elucidate compressible gas flow through porous sheets, and to inform the design of centimeter‐sized foam resistors with fluidic resistances on the order of 10 9 Pa s m −3 . When embedded inside soft robots and wearables, these resistors facilitate diverse functionalities spanning both sensing and control domains, including digital logic using textile logic gates, digital‐to‐analog signal conversion using ladder networks, and analog sensing of forces up to 40 N via compression‐induced changes in resistance. By combining features of both circuit‐based and materials‐based approaches, foam‐enabled fluidic circuits serve as a useful paradigm for future hybrid robotic architectures that fully embody the sensing and computing capabilities of soft fluidic materials.

Rajappan, Anoop↗

Conformally soft photons and gravitons

The four-dimensional S-matrix is reconsidered as a correlator on the celestial sphere at null infinity. Asymptotic particle states can be characterized by the point at which they enter or exit the celestial sphere as well as their SL(2, C) Lorentz quantum numbers: namely their conformal scaling dimension and spin h±h¯ instead of the energy and momentum. This characterization precludes the notion of a soft particle whose energy is taken to zero. We propose it should be replaced by the notion of a conformally soft particle with h = 0 or h¯ = 0. For photons we explicitly construct conformally soft SL(2, C) try on the celestial sphere. For gravity the generator of celestial conformal symmetry is constructed from a (2, 0) SL(2, C) primary wavefunction. Interestingly, BMS supertranslations are generated by a spin-one weight (3/2, 1/2) operator, which nevertheless shares holomorphic characteristics of a conformally soft operator. This is because the right hand side of its OPE with a weight (h, h¯) operator Oh,h¯ involves the shifted operator Oh+1/2,h¯+1/2. This OPE relation looks quite unusual from the celestial CFT 2 perspective but is equivalent to the leading soft graviton theorem and may usefully constrain celestial correlators in quantum gravity.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Three-loop soft function for heavy-to-light quark decays

We compute the 1-jettiness soft function for the decay of a heavy quark into a light quark jet plus colorless particles at three-loop order in soft-collinear effective theory. The 1-jettiness measurement fixes the total small light-cone momentum component of the soft radiation with respect to the jet direction. This soft function is a universal ingredient to the factorization of heavy-to-light quark decays in the limit of small 1-jettiness. Our three-loop result is required for resummation at the N 3 LL' level, e.g. near the endpoint in the photon energy spectrum of the B → X s γ decay. It is also a necessary ingredient for future calculations of fully-differential heavy-to-light quark decay rates at N 3 LO using the N -jettiness subtraction method, e.g. for semileptonic top decays. Using our result for the soft anomalous dimension we confirm predictions on the universal infrared structure of QCD scattering amplitudes with a massive external quark at three loops.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Geometric soft theorems

We derive a universal soft theorem for every scattering amplitude with at least one massless particle in an arbitrary theory of scalars. Our results follow from the geometry of field space and are valid for any choice of mass spectrum, potential terms, and higher-derivative interactions. For a vanishing potential, the soft limit of every amplitude is equal to the field-space covariant derivative of an amplitude with one fewer particle. Furthermore, the Adler zero and the dilaton soft theorem are special cases of our results. We also discuss more exotic scenarios in which the soft limit is non-trivial but still universal. Last but not least, we derive new theorems for multiple-soft limits which directly probe the field-space curvature, as well as on-shell recursion relations applicable to two-derivative scalar field theories exhibiting no symmetries whatsoever.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

The soft quark Sudakov

There has been recent interest in understanding the all loop structure of the subleading power soft and collinear limits, with the goal of achieving a systematic resummation of subleading power infrared logarithms. Most of this work has focused on subleading power corrections to soft gluon emission, whose form is strongly constrained by symmetries. In this paper we initiate a study of the all loop structure of soft fermion emission. In N = 1 QCD we perform an operator based factorization and resummation of the associated infrared logarithms using the formalism introduced in, and prove that they exponentiate into a Sudakov due to their relation to soft gluon emission. We verify this result through explicit calculation to O($α$ $^{3}_{s}$). We show that in QCD, this simple Sudakov exponentiation is violated by endpoint contributions proportional to (C A –C F ) n which contribute at leading logarithmic order. Combining our N = 1 result and our calculation of the endpoint contributions to O($α$ $^{3}_{s}$), we conjecture a result for the soft quark Sudakov in QCD, a new all orders function first appearing at subleading power, and give evidence for its universality. Our result, which is expressed in terms of combinations of cusp anomalous dimensions in different color representations, takes an intriguingly simple form and also exhibits interesting similarities to results for large-x logarithms in the off diagonal splitting functions.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Soft scalars in effective field theory

We derive a soft theorem for a massless scalar in an effective field theory with generic field content using the geometry of field space. This result extends the geometric soft theorem for scalar effective field theories by allowing the massless scalar to couple to other scalars, fermions, and gauge bosons. The soft theorem keeps its geometric form, but where the field-space geometry now involves the full field content of the theory. As a bonus, we also present novel double soft theorems with fermions, which mimic the geometric structure of the double soft theorem for scalars.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Matter couplings and equivalence principles for soft scalars

Scalar effective field theories with enhanced soft limits behave in many ways like gauge theories and gravity. In particular, symmetries fix the structure of interactions and the tree-level S-matrix in both types of theories. We explore how this analogy persists in the presence of matter by considering theories with additional fields coupled to the Dirac-Born-Infeld (DBI) scalar or the special galileon in a way that is consistent with their symmetries. Using purely on-shell arguments, we show that these theories obey analogues of the S-matrix equivalence principle whereby all matter fields must couple to the DBI scalar or the special galileon through a particular quartic vertex with a universal coupling. These equivalence principles imply the universality of the leading double soft theorems in these theories, which are scalar analogues of Weinberg’s gravitational soft theorem, and can be used to rule out interactions with massless higher-spin fields when combined with analogues of the generalized Weinberg-Witten theorem. We verify in several examples that amplitudes with external matter fields nontrivially exhibit enhanced single soft limits and we show that such amplitudes can be constructed using soft recursion relations when they have sufficiently many external DBI or special galileon legs, including amplitudes with massive higher-spin fields. As part of our analysis we construct a recently conjectured special galileon-vector effective field theory.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Celestial soft currents at one-loop and their OPEs

Conformally soft operators and their associated soft theorems on the celestial sphere encode the low energy behaviour of bulk scattering amplitudes. They lead to an infinite dimensional symmetry algebra of the celestial CFT at tree-level. In this paper, focusing our attention to Yang-Mills theory, we introduce new operators in the boundary celestial CFT in order to extend the definition of conformally soft currents to include one-loop effects. We then compute their OPEs with other operators in the theory. We also examine new subtleties that arise in defining OPEs of two conformally soft operators. We elucidate the connection between the new operators and loop corrected soft theorems in the bulk. Finally, we conclude by demonstrating how these operators fit into the framework of a logarithmic CFT.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Soft matrices downregulate FAK activity to promote growth of tumor-repopulating cells

Tumor-repopulating cells (TRCs) are a tumorigenic sub-population of cancer cells that drives tumorigenesis. We have recently reported that soft fibrin matrices maintain TRC growth by promoting histone 3 lysine 9 (H3K9) demethylation and Sox2 expression and that Cdc42 expression influences H3K9 methylation. However, the underlying mechanisms of how soft matrices induce H3K9 demethylation remain elusive. Here we find that TRCs exhibit lower focal adhesion kinase (FAK) and H3K9 methylation levels in soft fibrin matrices than control melanoma cells on 2D rigid substrates. Silencing FAK in control melanoma cells decreases H3K9 methylation, whereas overexpressing FAK in tumor-repopulating cells enhances H3K9 methylation. Overexpressing Cdc42 or RhoA in the presence of FAK knockdown restores H3K9 methylation levels. Importantly, silencing FAK, Cdc42, or RhoA promotes Sox2 expression and proliferation of control melanoma cells in stiff fibrin matrices, whereas overexpressing each gene suppresses Sox2 expression and reduces growth of TRCs in soft but not in stiff fibrin matrices. Our findings suggest that low FAK mediated by soft fibrin matrices downregulates H3K9 methylation through reduction of Cdc42 and RhoA and promotes TRC growth. - Highlights: • FAK activity, mRNA and protein are low in highly tumorigenic cells. • FAK is tightly associated with H3K9 methylation and negatively related to the growth of tumor-repopulating cells. • Low FAK promotes rather than blocks the growth of highly tumorigenic cells. • Matrix stiffness (rigidity) is a key player in regulating the response of the melanoma cells to FAK modulation.

60 APPLIED LIFE SCIENCES↗

Synthesis, microstructure and magnetic properties of Fe{sub 3}Si{sub 0.7}Al{sub 0.3}@SiO{sub 2} core–shell particles and Fe{sub 3}Si/Al{sub 2}O{sub 3} soft magnetic composite core

Fe{sub 3}Si{sub 0.7}Al{sub 0.3}@SiO{sub 2} core–shell particles and Fe{sub 3}Si/Al{sub 2}O{sub 3} soft magnetic composite core have been synthesized via a modified stöber method combined with following high temperature sintering process. Most of conductive Fe{sub 3}Si{sub 0.7}Al{sub 0.3} particles could be uniformly coated by insulating SiO{sub 2} using the modified stöber method. The Fe{sub 3}Si{sub 0.7}Al{sub 0.3}@SiO{sub 2} core–shell particles exhibited good soft magnetic properties with low coercivity and high saturation magnetization. The reaction 4Al+3SiO{sub 2}=2α-Al{sub 2}O{sub 3}+3Si took place during the sintering process. As a result the new Fe{sub 3}Si/Al{sub 2}O{sub 3} composite was formed. The Fe{sub 3}Si/Al{sub 2}O{sub 3} composite core displayed more excellent soft magnetic properties, better frequency stability at high frequencies, much higher electrical resistivity and lower core loss than the pure Fe{sub 3}Si{sub 0.7}Al{sub 0.3} core. The method of introducing insulating layers surrounding magnetic particles provides a promising route to develop new and high compact soft magnetic materials with good magnetic and electric properties. - Graphical abstract: In Fe{sub 3}Si/Al{sub 2}O{sub 3} composite, Fe{sub 3}Si phases are separated by Al{sub 2}O{sub 3} layers and the eddy currents are confined in Fe{sub 3}Si phases, thus increasing resistivity and reducing core loss. - Highlights: • Fe{sub 3}Si{sub 0.7}Al{sub 0.3}@SiO{sub 2} core–shell particles and Fe{sub 3}Si/Al{sub 2}O{sub 3} cores were prepared. • Fe{sub 3}Si{sub 0.7}Al{sub 0.3} particles could be uniformly coated by nano-sized SiO{sub 2} clusters. • Fe{sub 3}Si{sub 0.7}Al{sub 0.3}@SiO{sub 2} particles and Fe{sub 3}Si/Al{sub 2}O{sub 3} cores showed good soft magnetic properties. • Fe{sub 3}Si/Al{sub 2}O{sub 3} had lower core loss and better frequency stability than Fe{sub 3}Si{sub 0.7}Al{sub 0.3} cores.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Tensor-Train Split-Operator Fourier Transform (TT-SOFT) Method: Multidimensional Nonadiabatic Quantum Dynamics

We introduce the “tensor-train split-operator Fourier transform” (TT-SOFT) method for simulations of multidimensional nonadiabatic quantum dynamics. TT-SOFT is essentially the grid-based SOFT method implemented in dynamically adaptive tensor-train representations. In the same spirit of all matrix product states, the tensor-train format enables the representation, propagation, and computation of observables of multidimensional wave functions in terms of the grid-based wavepacket tensor components, bypassing the need of actually computing the wave function in its full-rank tensor product grid space. We demonstrate the accuracy and efficiency of the TT-SOFT method as applied to propagation of 24-dimensional wave packets, describing the S 1 / S 2 interconversion dynamics of pyrazine after UV photoexcitation to the S 2 state. Furthermore, our results show that the TT-SOFT method is a powerful computational approach for simulations of quantum dynamics of polyatomic systems since it avoids the exponential scaling problem of full-rank grid-based representations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Dynamic Equivalence between Soft Star Polymers and Hard Spheres

Understanding the dynamics of soft colloids, such as star polymers, dendrimers, and microgels, is of scientific and practical importance. It is known that the excluded volume effect plays a key role in colloidal dynamics. Here, we propose a condition of compressibility equivalence that provides a simple method to experimentally evaluate the excluded volume of soft colloids from a thermodynamic view. We apply this condition to survey the dynamics of a series of star polymer dispersions. It is found that, as the concentration increases, the slowing of the long-time self-diffusivity of the star polymer, normalized by the short-time self-diffusivity, can be mapped onto the hard-sphere behavior. This phenomenon reveals the dynamic equivalence between soft colloids and hard spheres, despite the apparent complexity of the interparticle interaction of the soft colloids. The methods for measuring the osmotic compressibility and the self-diffusivities of soft colloidal dispersions are also presented.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Mechanics of an Asymmetric Hard-Soft Lamellar Nanomaterial

Nanolayered lamellae are common structures in nanoscience and nanotechnology, but most are nearly symmetric in layer thickness. Here, we report on the structure and mechanics of highly asymmetric and thermodynamically stable soft–hard lamellar structures self-assembled from optimally designed PS 1 -(PI-b-PS 2 ) 3 miktoarm star block copolymers. The remarkable mechanical properties of these strong and ductile PS (polystyrene)-based nanomaterials can be tuned over a broad range by varying the hard layer thickness while maintaining the soft layer thickness constant at 13 nm. Upon deformation, thin PS lamellae (<100 nm) exhibited kinks and predamaged/damaged grains, as well as cavitation in the soft layers. In contrast, deformation of thick lamellae (>100 nm) manifests cavitation in both soft and hard nanolayers. In situ tensile-SAXS experiments revealed the evolution of cavities during deformation and confirmed that the damage in such systems reflects both plastic deformation by shear and residual cavities. The aspects of the mechanics should point to universal deformation behavior in broader classes of asymmetric hard–soft lamellar materials, whose properties are just being revealed for versatile applications.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

A Case for Soft Error Detection and Correction in Computational Chemistry

High performance computing platforms are expected to deliver 10(18) floating operations per second by the year 2022 through the deployment of millions of cores. Even if every core is highly reliable the sheer number of the them will mean that the mean time between failures will become so short that most applications runs will suffer at least one fault. In particular soft errors caused by intermittent incorrect behavior of the hardware are a concern as they lead to silent data corruption. In this paper we investigate the impact of soft errors on optimization algorithms using Hartree-Fock as a particular example. Optimization algorithms iteratively reduce the error in the initial guess to reach the intended solution. Therefore they may intuitively appear to be resilient to soft errors. Our results show that this is true for soft errors of small magnitudes but not for large errors. We suggest error detection and correction mechanisms for different classes of data structures. The results obtained with these mechanisms indicate that we can correct more than 95% of the soft errors at moderate increases in the computational cost.

Computational chemistry↗

Soft mobile robots driven by foldable dielectric elastomer actuators

A cantilever beam with elastic hinge pulled antagonistically by two dielectric elastomer (DE) membranes in tension forms a foldable actuator if one DE membrane is subject to a voltage and releases part of tension. Simply placing parallel rigid bars on the prestressed DE membranes results in enhanced actuators working in a pure shear state. We report design, analysis, fabrication, and experiment of soft mobile robots that are moved by such foldable DE actuators. We describe systematic measurement of the foldable actuators and perform theoretical analysis of such actuators based on minimization of total energy, and a good agreement is achieved between model prediction and measurement. We develop two versions of prototypes of soft mobile robots driven either by two sets of DE membranes or one DE membrane and elastic springs. We demonstrate locomotion of these soft mobile robots and highlight several key design parameters that influence locomotion of the robots. A 45 g soft robot driven by a cyclic triangle voltage with amplitude 7.4 kV demonstrates maximal stroke 160 mm or maximal rolling velocity 42 mm/s. The underlying mechanics and physics of foldable DE actuators can be leveraged to develop other soft machines for various applications.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗