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At least 289 records · Page 16
All sourcesNASA NTRSDOE OSTI
DOE OSTI2019

Physical and Chemical Morphology of Passively Sampled Environmental Films

Environmental surface films are important mediators in the fate and transport of persistent organic pollutants (POP) via largely uncharacterized mechanisms. This work presents the first analysis of the physical and chemical morphology of passively sampled environmental films. The films are developed in urban, sub-urban, and metropolitan locations for timescales ranging from 1 to 52 weeks by exposing polished silicon wafers to collect passively deposited tropospheric particulate matter. The time-dependent spatial morphology of the films is analyzed by bright-field, scanning electron, and atomic force microscopies. Time-of-flight secondary ion mass spectrometry (ToF-SIMS) imaging data are analyzed to report the film’s chemical morphology and speciation. We find that the film matrix presents an extremely complex physical and chemical system. Deposited PM sizes span six orders of magnitude (millimeter to nanometer regimes), and surface coverages range from ca. 5 % for one week films and ca. 98 % for 52 week films. We observe significant amounts of mineral dust, biogenic organics, and occasional indications of flora growth (i.e., spores). The films exhibit nanoscale surface features indicative of small particulate depositions as well as films of (semi)volatile molecules. SIMS imaging reveals diverse and sometimes segregated chemical domains of hydrocarbons, inorganics, metals, and proteinaceous macromolecules. This work presents the first spatially resolved physical and chemical surface characterization of native environmental films, beginning a study of mechanisms by which these films form, persist, and mature in the environment.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Advancing Aerosol Chemical Characterization and Vertical Profiling over the Southern Great Plains Using Uncrewed Aerial Sampling and Offline Aerosol Mass Spectrometry

Recent advancements in uncrewed aerial systems (UASs) and particulate matter (PM) analytical techniques have provided opportunities for atmospheric research. In this study, we deployed the Department of Energy’s fixed-wing ArcticShark UAS to examine PM 2.5 composition at varying altitudes─within and above the planetary boundary layer (PBL)─over the Southern Great Plains atmospheric observatory (SGP). A total of 22 flights were conducted across March, June, and August 2023. Composite filter samples were collected during each flight and analyzed with offline aerosol mass spectrometry (AMS), complemented by on-board real-time sensors and ground-based instrumentation, to provide a comprehensive view of regional aerosol characteristics. Results show clear vertical and seasonal differences in the aerosol composition. Relative to ground-level measurements, aloft samples exhibited shifts in the distribution of organic and inorganic PM, with the organic composition varying distinctly across seasons. Particulate organic nitrogen (ON) was elevated, with bulk compositions similar in March and June but strongly altered in August, likely driven by biomass burning and enhanced photochemical activity. Combined AMS and chemical ionization mass spectrometry analyses detected amines, amides, and amino acids. PM above the planetary boundary layer was enriched in oxidized organic aerosols, while ground-level PM contained higher nitrate and sulfate. Seasonal differences in aqueous-phase processing were also observed, which were strongest in March during persistent cloud cover and weaker in the drier August period, suggesting a shift from aqueous- to gas-phase SOA formation. In conclusion, these findings highlight the value of UAS in advancing PM measurements and vertical profiling of aerosol composition.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2014

Sample-Averaged Biexciton Quantum Yield Measured by Solution-Phase Photon Correlation

The brightness of nanoscale optical materials such as semiconductor nanocrystals is currently limited in high excitation flux applications by inefficient multiexciton fluorescence. We have devised a solution-phase photon correlation measurement that can conveniently and reliably measure the average biexciton-to-exciton quantum yield ratio of an entire sample without user selection bias. This technique can be used to investigate the multiexciton recombination dynamics of a broad scope of synthetically underdeveloped materials, including those with low exciton quantum yields and poor fluorescence stability. Here in this study, we have applied this method to measure weak biexciton fluorescence in samples of visible-emitting InP/ZnS and InAs/ZnS core/shell nanocrystals, and to demonstrate that a rapid CdS shell growth procedure can markedly increase the biexciton fluorescence of CdSe nanocrystals.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Midlatitude Oceanic Cloud and Precipitation Properties as Sampled By the ARM Eastern North Atlantic Observatory

Marine low clouds are critical to the climate system because of their extensive coverage and associated controls on boundary layer dynamics and radiative energy balance. The primary foci for this study are marine low cloud observations over a heavily instrumented site on the Azores archipelago in the eastern North Atlantic (ENA) and their associated raindrop size distribution (DSD) properties, relative low-cloud contributions to the precipitation, and additional sampling (instrument, environmental) considerations. The contribution from low clouds (e.g., cloud top < 4 km) to the overall precipitation over midlatitude oceans is poorly understood, in part because of the lack of coupled, high-quality measurements of precipitation and low-cloud properties. Cloud regime and precipitation breakdowns performed for a multi-year record emphasize the diurnal precipitation cycle and DSD characteristics for both low and deeper clouds. Results demonstrate that marine low clouds over this ENA location account for a significant (45%) contribution to the total rainfall and exhibit a diurnal cycle in cloud (thickness, top, base) and precipitation characteristics similar to satellite records. Additional controls on observed surface rainfall characteristics of low clouds allowed by the extended ground-based facility datasets are also explored. From those analyses, it is suggested that the synoptic state exerts a significant control on low-cloud and surface precipitation properties.

Giangrande, Scott↗
DOE OSTI2014

9 T high magnetic field annealing effects on FeN bulk sample

α″-Fe{sub 16}N{sub 2} has been suggested as a promising candidate for future rare-earth-free magnets. In this paper, we report to use high magnetic field (9 T) assisted post-annealing process to enhance the Fe{sub 16}N{sub 2} phase formation in FeN bulk rod samples during the α′ → α″ phase transformation and thus improve its magnetic properties. It was found by X-ray Diffraction measurement that the volume ratio of Fe{sub 16}N{sub 2} phase was increased up to 22%, which corresponds to an increase in the amount of transformation from α′ → α″ up to 78%. Also, the saturation magnetization (M{sub s}) of the prepared FeN rod sample was increased to 227 emu/g with its coercivity up to 376 Oe at room temperature. A working mechanism for the high field assisted post-annealing process was presented.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2015

Fast temperature spectrometer for samples under extreme conditions

We have developed a multi-wavelength Fast Temperature Readout (FasTeR) spectrometer to capture a sample’s transient temperature fluctuations, and reduce uncertainties in melting temperature determination. Without sacrificing accuracy, FasTeR features a fast readout rate (about 100 Hz), high sensitivity, large dynamic range, and a well-constrained focus. Complimenting a charge-coupled device spectrometer, FasTeR consists of an array of photomultiplier tubes and optical dichroic filters. The temperatures determined by FasTeR outside of the vicinity of melting are, generally, in good agreement with results from the charge-coupled device spectrometer. Near melting, FasTeR is capable of capturing transient temperature fluctuations, at least on the order of 300 K/s. A software tool, SIMFaster, is described and has been developed to simulate FasTeR and assess design configurations. FasTeR is especially suitable for temperature determinations that utilize ultra-fast techniques under extreme conditions. Working in parallel with the laser-heated diamond-anvil cell, synchrotron Mössbauer spectroscopy, and X-ray diffraction, we have applied the FasTeR spectrometer to measure the melting temperature of {sup 57}Fe{sub 0.9}Ni{sub 0.1} at high pressure.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2015

THE SL2S GALAXY-SCALE LENS SAMPLE. V. DARK MATTER HALOS AND STELLAR IMF OF MASSIVE EARLY-TYPE GALAXIES OUT TO REDSHIFT 0.8

We investigate the cosmic evolution of the internal structure of massive early-type galaxies over half of the age of the universe. We perform a joint lensing and stellar dynamics analysis of a sample of 81 strong lenses from the Strong Lensing Legacy Survey and Sloan ACS Lens Survey and combine the results with a hierarchical Bayesian inference method to measure the distribution of dark matter mass and stellar initial mass function (IMF) across the population of massive early-type galaxies. Lensing selection effects are taken into account. We find that the dark matter mass projected within the inner 5 kpc increases for increasing redshift, decreases for increasing stellar mass density, but is roughly constant along the evolutionary tracks of early-type galaxies. The average dark matter slope is consistent with that of a Navarro-Frenk-White profile, but is not well constrained. The stellar IMF normalization is close to a Salpeter IMF at log M {sub *} = 11.5 and scales strongly with increasing stellar mass. No dependence of the IMF on redshift or stellar mass density is detected. The anti-correlation between dark matter mass and stellar mass density supports the idea of mergers being more frequent in more massive dark matter halos.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2017

Exploring cosmic homogeneity with the BOSS DR12 galaxy sample

In this study, we probe the transition to cosmic homogeneity in the Large Scale Structure (LSS) of the Universe using the CMASS galaxy sample of BOSS spectroscopic survey which covers the largest effective volume to date, 3 h -3 Gpc 3 at 0.43 ≤ z ≤ 0.7. We study the scaled counts-in-spheres, N( 2 (r), to assess the homogeneity scale of the universe using a Landy & Szalay inspired estimator. Defining the scale of transition to homogeneity as the scale at which D 2 (r) reaches 3 within 1%, i.e. D 2 (r)>2.97 for r>R H , we find R H = (63.3±0.7) h -1 Mpc, in agreement at the percentage level with the predictions of the ΛCDM model R H =62.0 h -1 Mpc. Thanks to the large cosmic depth of the survey, we investigate the redshift evolution of the transition to homogeneity scale and find agreement with the ΛCDM prediction. Finally, we find that D 2 is compatible with 3 at scales larger than 300 h -1 Mpc in all redshift bins. These results consolidate the Cosmological Principle and represent a precise consistency test of the ΛCDM model.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

A new paradigm for petascale Monte Carlo simulation: Replica exchange Wang-Landau sampling

We introduce a generic, parallel Wang-Landau method that is naturally suited to implementation on massively parallel, petaflop supercomputers. The approach introduces a replica-exchange framework in which densities of states for overlapping sub-windows in energy space are determined iteratively by traditional Wang-Landau sampling. The advantages and general applicability of the method are demonstrated for several distinct systems that possess discrete or continuous degrees of freedom, including those with complex free energy landscapes and topological constraints.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2018

Baryon content in a sample of 91 galaxy clusters selected by the South Pole Telescope at 0.2 <z < 1.25

We estimate total mass (M-500), intracluster medium (ICM) mass (M-ICM), and stellar mass (M-star) in a Sunyaev-Zel'dovich effect (SZE) selected sample of 91 galaxy clusters with masses M-500 greater than or similar to 2.5 x 10(14) M-circle dot and redshift 0.2 < z < 1.25 from the 2500 deg(2) South Pole Telescope SPT-SZ survey. The total masses M-500 are estimated from the SZE observable, the ICM masses M-ICM are obtained from the analysis of Chandra X-ray observations, and the stellar masses M-star are derived by fitting spectral energy distribution templates to Dark Energy Survey griz optical photometry and WISE or Spitzer near-infrared photometry. We study trends in the stellar mass, the ICM mass, the total baryonic mass, and the cold baryonic fraction with cluster halo mass and redshift. We find significant departures from self-similarity in the mass scaling for all quantities, while the redshift trends are all statistically consistent with zero, indicating that the baryon content of clusters at fixed mass has changed remarkably little over the past approximate to 9 Gyr. We compare our results to the mean baryon fraction (and the stellar mass fraction) in the field, finding that these values lie above (below) those in cluster virial regions in all but the most massive clusters at low redshift. Using a simple model of the matter assembly of clusters from infalling groups with lower masses and from infalling material from the low-density environment or field surrounding the parent haloes, we show that the measured mass trends without strong redshift trends in the stellar mass scaling relation could be explained by a mass and redshift dependent fractional contribution from field material. Similar analyses of the ICM and baryon mass scaling relations provide evidence for the so-called 'missing baryons' outside cluster virial regions.

galaxies: clusters: stellar masses: ICM masses: ba↗
DOE OSTI2013

Search for B → h ( * ) ν ν ¯ with the full Belle Υ ( 4 S ) data sample

This report is of a search for the rare decays B → h ( * ) ν ν ¯ , where h ( * ) stands for K + , K S 0 , K * + , K * 0 , π + , π 0 , ρ + , ρ 0 and Φ . The results are obtained from a 711 fb - 1 data sample that contains 772 × 10 6 B B ¯ pairs collected at the Υ ( 4 S ) resonance with the Belle detector at the KEKB e + e - collider. We search for signal candidates by fully reconstructing a hadronic decay of the accompanying B meson and requiring a single h ( * ) meson left on the signal side. No significant signal is observed and we set upper limits on the branching fractions at 90% confidence level. The measurements of B + → K * + ν ν ¯ , B + → π + ν ν ¯ , B 0 → π 0 ν ν ¯ and B 0 → ρ 0 ν ν ¯ provide the world’s currently most restrictive limits.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2013

Evidence for B - → τ - ν ¯ τ with a Hadronic Tagging Method Using the Full Data Sample of Belle

In this work, we measure the branching fraction of B - → τ - ν ¯ τ using the full Υ ( 4 S ) data sample containing 772 × 10 6 B B ¯ pairs collected with the Belle detector at the KEKB asymmetric-energy e + e - collider. Events with B B ¯ pairs are tagged by reconstructing one of the B mesons decaying into hadronic final states, and B - → τ - ν ¯ τ candidates are detected in the recoil. We discover evidence for B - → τ - ν ¯ τ with a significance of 3.0 standard deviations including systematic errors and measure a branching fraction B ( B - → τ - ν ¯ τ ) = [ 0.72 - 0.25 + 0.27 ( stat ) ± 0.11 ( syst ) ] × 10 - 4 .

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2015

Sample Results from the Interim Salt Disposition Program Macrobatch 8 Tank 21H Qualification Samples

Savannah River National Laboratory (SRNL) analyzed samples from Tank 21H in support of qualification of Macrobatch (Salt Batch) 8 for the Interim Salt Disposition Program (ISDP). An Actinide Removal Process (ARP) and several Extraction-Scrub- Strip (ESS) tests were also performed. This document reports characterization data on the samples of Tank 21H as well as simulated performance of ARP and the Modular Caustic Side Solvent Extraction (CSSX) Unit (MCU). No issues with the projected Salt Batch 8 strategy are identified. A demonstration of the monosodium titanate (MST) (0.2 g/L) removal of strontium and actinides provided acceptable average decontamination factors for plutonium of 2.62 (4 hour) and 2.90 (8 hour); and average strontium decontamination factors of 21.7 (4 hour) and 21.3 (8 hour). These values are consistent with results from previous salt batch ARP tests. The two ESS tests also showed acceptable performance with extraction distribution ratios (D(Cs)) values of 52.5 and 50.4 for the Next Generation Solvent (NGS) blend (from MCU) and NGS (lab prepared), respectively. These values are consistent with results from previous salt batch ESS tests. Even though the performance is acceptable, SRNL recommends that a model for predicting extraction behavior for cesium removal for the blended solvent and NGS be developed in order to improve our predictive capabilities for the ESS tests.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗
DOE OSTI2015

Sample results from the Interim Salt Disposition Program Macrobatch 8 Tank 21H qualification samples

Savannah River National Laboratory (SRNL) analyzed samples from Tank 21H in support of qualification of Macrobatch (Salt Batch) 8 for the Interim Salt Disposition Program (ISDP). An Actinide Removal Process (ARP) and several Extraction-Scrub-Strip (ESS) tests were also performed. This document reports characterization data on the samples of Tank 21H as well as simulated performance of ARP and the Modular Caustic Side Solvent Extraction (CSSX) Unit (MCU). No issues with the projected Salt Batch 8 strategy are identified. A demonstration of the monosodium titanate (MST) (0.2 g/L) removal of strontium and actinides provided acceptable average decontamination factors for plutonium of 2.62 (4 hour) and 2.90 (8 hour); and average strontium decontamination factors of 21.7 (4 hour) and 21.3 (8 hour). These values are consistent with results from previous salt batch ARP tests. The two ESS tests also showed acceptable performance with extraction distribution ratios (D (Cs) ) values of 52.5 and 50.4 for the Next Generation Solvent (NGS) blend (from MCU) and NGS (lab prepared), respectively. These values are consistent with results from previous salt batch ESS tests. Even though the performance is acceptable, SRNL recommends that a model for predicting extraction behavior for cesium removal for the blended solvent and NGS be developed in order to improve our predictive capabilities for the ESS tests.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗