Insights into Operational Parameters Affecting CO2 Storage in Saline Aquifers
Insights into Operational Parameters Affecting CO2 Storage in Saline Aquifers
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Insights into Operational Parameters Affecting CO2 Storage in Saline Aquifers
A concept is described for passive microwave sensing of soil moisture and ocean salinity from space. The Inflatable Radiometric Imaging System (IRIS) makes use of a large-diameter, offset-fed, parabolic-torus antenna with multiple feeds, in a conical pushbroom configuration.
The application of time-series radar measurements to accurately invert the thickness of saline ice is presented in this study. We describe briefly some experimental observations from the CRRELEX 93 campaign of sea ice.
Ocean salinity measurements using the Passive Active L/S-band instrument flying on the NCAR C-130 aircraft were made in July 2002 near Monterey, CA.
The development of a compact, lightweight, dual-frequency antenna feed for future soil moisture and sea surface salinity (SSS) missions is described.
Sea surface salinity is a key parameter for the study of ocean circulation, global water cycle and hence climate changes.
A concept has been studied for remote sensing of sea surface salinity and soil moistute from space using a large deployable mesh antenna system.
The development of a compact, lightweight, dual-frequency antenna feed for future soil moistur and sea surface salinity missions is described.
The development of a compact, lightweight, dual frequency antenna feed for future soil moisture and sea surface salinity (SSS) missions is described. The design is based on the microstrip stacked-patch array (MSPA) to be used to feed a large lightweight deployable rotating mesh antenna for spaceborne L-band (approx. 1 GHz) passive and active sensing systems. The design features will also enable applications to airborne sensors operating on small aircrafts. This paper describes the design of stacked patch elements, 16-element array configuration and power-divider beam forming network The test results from the fabrication of stacked patches and power divider were also described.
A numerical reconstruction of the brightness temperature is examined as a potential way to improve the retrieval of salinity from Aquarius measurements closer to landwater boundaries. A test case using simulated ocean-land scenes suggest promise for the technique.
A concept has been studied for remote sensing of sea surface salinity form space using a large deployable mesh antenna system.
A Passive Active L/S-band microwave aircraft instrument to measure ocean salinity has been built and tested.
A set of geophysical error sources for the microwave remote sensing of ocean surface salinity have been examined.
A set of geophysical error sources for the microwave remote sensing of ocean surface salinity have been examined.
Argo profiling floats and L-band passive microwave remote sensing have significantly improved the global sampling of sea surface salinity (SSS) in the past 15 years, allowing the study of the range of SSS seasonal variability using concurrent satellite and in situ platforms. Here, harmonic analysis was applied to four 0.25° satellite products and two 1° in situ products between 2016 and 2018 to determine seasonal harmonic patterns. The 0.25° World Ocean Atlas (WOA) version 2018 was referenced to help assess the harmonic patterns from a long-term perspective based on the 3-year period. The results show that annual harmonic is the most characteristic signal of the seasonal cycle, and semiannual harmonic is important in regions influenced by monsoon and major rivers. The percentage of the observed variance that can be explained by harmonic modes varies with products, with values ranging between 50% and 72% for annual harmonic and between 15% and 19% for semiannual harmonic. The large spread in the explained variance by the annual harmonic reflects the large disparity in nonseasonal variance (or noise) in the different products. Satellite products are capable of capturing sharp SSS features on meso- and frontal scales and the patterns agree well with the WOA 2018. These products are, however, subject to the impacts of radiometric noises and are algorithm dependent. The coarser-resolution in situ products may underrepresent the full range of high-frequency small scale SSS variability when data record is short, which may have enlarged the explained SSS variance by the annual harmonic.
Coastal upwelling regions are one of the most dynamic areas of the world’s oceans. The California and Baja California Coasts are impacted by both coastal upwelling and the California Current, leading to frontal activity that is captured by gradients in both Sea Surface Temperature (SST) and Sea Surface Salinity (SSS). Satellite data are a great source of spatial data to study fronts. However, biases near coastal areas and coarse resolutions can impair its usefulness in upwelling areas. In this work gradients in SST from NASA Multi-Scale Ultra-High Resolution (MUR) and in two SSS products derived from the Soil Moisture Active Passive (SMAP) NASA mission are compared directly with gradients derived from the Saildrone uncrewed vehicles to validate the gradients as well as to assess their ability to detect known frontal features. The three remotely sensed data sets (MURSST/JPL, SMAP SSS/RSS, SMAP SSS) were co-located with the Saildrone data prior to the calculation of the gradients. Wavelet analysis is used to determine how well the satellite derived SST and SSS products are reproducing the Saildrone derived gradients. Overall results indicate the remote sensing products are reproducing features of known areas of coastal upwelling. Differences between the SST and SSS gradients are mainly associated with the limitations of the microwave derived SSS coverage near land and its reduced spatial resolution. The results are promising for using remote sensing data sets to monitor frontal structure along the California Coast and the application to long term changes in coastal upwelling and dynamics.
Classical electric double layer (EDL) models have been widely used to describe ion distributions at charged solid-water interfaces in dilute electrolytes. However, the chemistry of EDLs remains poorly constrained at high ionic strength where ion-ion correlations control non-classical behavior such as overcharging, i. e., the accumulation of counter-ions in amounts exceeding the substrate's surface charge. Here, we provide direct experimental observations of correlated cation and anion distributions adsorbed at the muscovite (001)-aqueous electrolyte interface as a function of dissolved RbBr concentration ([RbBr]=0.01–5.8 M) using resonant anomalous X-ray reflectivity. Our results show alternating cation-anion layers in the EDL when [RbBr]≳100 mM, whose spatial extension (i. e., ~20 Å from the surface) far exceeds the dimension of the classical Stern layer. Comparison to RbCl and RbI electrolytes indicates that these behaviors are sensitive to the choice of co-ion. This new in-depth molecular-scale understanding of the EDL structure during transition from classical to non-classical regimes supports the development of realistic EDL models for technologies operating at high salinity such as water purification applications or modern electrochemical storage.
This review analyses the fundamental thermodynamic theory of the crude oil-brine-rock (COBR) interface and the underlying rock-brine and oil-brine interactions. Next, the available data are reviewed to outline potential mechanisms responsible for increased oil recovery from low salinity waterflooding (LSWF). We propose an approach to studying LSWF and identify the key missing links that are needed to explain observations at multiple length scales. The synergistic effect of LSWFon other chemical enhanced oil recovery methods such as surfactant, alkaline, nanoparticle and polymer flooding are also outlined. We specifically highlight key uncertainties that must be overcome to fully implement the technique in the field.