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At least 289 records · Page 16
All sourcesNASA NTRSDOE OSTI
NASA NTRS2019

Near-Infrared Reflectance Spectroscopy of Venus-Analog Rocks at Venus Surface Temperatures

Venus’ surface can be viewed in emission through the relatively opaque atmosphere via a few spectral ‘windows’ in the near-infrared (NIR, most near 1 μm). Venus’ surface appears to show emissivities that correlate with surface geology, and these emissivity variations are interpreted as differences in surface rock type (mafic vs. silicic) and/or extent of weathering (Fe(2+) silicates vs. Fe(3+)-oxide-coated). To understand and quantify the observed variations in NIR emissivity, laboratories are measuring high-T NIR emissivity directly. For example, the measured emissivities of basalts in the wavelength range 0.85 – 1.2 μm are ~0.9. This value can be tested by measurement of reflectance, because Kirchoff’s Law holds that emissivity (e) = 1 – reflectance (r). The r of basalt in the NIR is ~0.1 so its e should be ~0.9. However, high-T NIR e’s of silicic igneous rocks (granitic, rhyolite) are reported to be 0.8-0.9, which is inconsistent with r values of 0.3-0.7 of such rocks at room-T. For both datasets to be correct, the r values of silicic igneous rock would have to decrease precipitously between room and Venus surface temperatures. This seems unlikely.

Treiman, A. H.↗
NASA NTRS2020

Cerium Stable Isotope Analysis of Synthetic and Terrestrial Rock Reference Materials by MC-ICPMS

Cerium is the most abundant rare earth element (REE) in the solar photosphere, CI chondrites, and the Earth. It has four main stable isotopes (masses: 136,138,140, and 142), with 138Ce being the most studied species, used in geochronology and petrogenesis. In addition, more abundant 140Ce and 142Ce are suggested to be potentially applicable in geochemical investigations. In this work, we developed a modified four-step ion chromatography procedure for Ce chemical separation. Using a MC-ICPMS, we designed a cup configuration to measure 142Ce/140Ce ratio of the samples with an optimized Nd correction equation. A 0.03‰ (2SD) reproducibility was obtained for Ce Ames metal standard. We analyzed ten different igneous and one sedimentary geochemical reference materials. Mean δ142Ce range from −0.07 to 0.32‰. Most of the samples show a heavier Ce isotopic composition than the Ce Ames standard. The majority of rocks have a homogenous δ142Ce. The δ142Ce does not show any correlation with rock chemical composition including their Ce content or rock types. A carbonatite (SARM 40) has a mean δ142Ce of −0.07 ± 0.13‰ (2SD), lower than the other rocks, suggesting the possibility of a pronounced isotopic fractionation. Our work demonstrates the applicability of the developed methodology and the potential of Ce stable isotopes for future geochemical studies. Production of a larger database of δ142Ce values is required to obtain a clearer view on the similarities and differences between different geological material and explaining Ce stable isotope dynamics.

Cerium↗
NASA NTRS2004

Intensity-based rock detection for acquiring onboard rover science

Missions to Mars already under study call for very long autonomous traverses (on the order of hundreds of meters per sol) during which there will be limited contact with Earth. The onboard Autonomous Science Investigation System (OASIS) is a technology for increasing science return during rover traverses by prioritizing science opportunities. By prioritizing data for downlink onboard, it is expected that the set of images selected for downlink by OASIS will have a consistently higher scientific interest then any set of equal number of images of the same traverse obtained using random or periodic sampling. Thus, OASIS can be used to increase the science returned from a long traverse. OASIS prioritizes data and identifies science opportunities by extracting information from image data and then using this information to prioritize the data and identify potential new science opportunities. Currently, the information extracted from the images is the location of the rocks in the image and several properties of these rocks such as size, albedo, texture and shape, In this paper we give an overview of the role of rock detection in the OASIS system and describe the functionality of the rock detector. We then present results on representative images

Judd, Michele↗
NASA NTRSDate not supplied

Comparing the Volatile Contents of Basaltic Rocks Through the Inner Solar System

Volatiles in planetary interiors play important roles in magma genesis, crust formation, eruption style, and even habitability of planetary surfaces. Allan Treiman’s career has touched on volatiles in the Moon, Mars, HED-parent body, the Earth, Venus, and other planetary bodies through studies of igneous rocks, volatile-bearing igneous minerals within these rocks, and the secondary alteration products produced from these rocks and minerals. His seminal work in many of these fields has inspired our careers and many others in our field. Here, we will build on and summarize what we know of the volatile content of basaltic rocks in the inner solar system. Specifically, this talk will focus on using volatile-bearing minerals (amphibole and apatite) along with bulk compositions to constrain the pre-eruptive, and potentially predegassed, volatile content of the magma and their source regions. We will then use these estimates to compare the volatile content of the Earth, Moon, Mars, Venus, and Mercury and what open questions there are for each planetary body.

Justin Filiberto↗
NASA NTRSDate not supplied

Impact of Stress-Activated Positive Holes on the Redox Timing in Organisms Living at the Surface of Rocks: Unlocking Nature's Secrets

Squeezing and deforming igneous and/or high-grade metamorphic rocks activates electronic charge carriers known as positive holes, h•, that are defect electrons in the O2– sublattice. Similar to h• in semiconductors the h• in rocks affect electrical and thermal properties. They produce electrochemical reactions, localized electrical signals, and currents. In this study, we explore the effects of positive holes on the electron flow in the electron transport chain (ETC) of organisms living at the surface of rocks such as gabbro or granite. We found that positive holes, h•, disrupt the temporal coordination in vivo governed by oscillating reduction-oxidation reactions, known as the redox cycle. Positive holes affect the timing of the redox cycle by interacting with molecules in vivo, leading to the formation of superoxide anions and hydroxyl radicals. Thus, we observed that positive holes significantly impede the growth of yeast Saccharomyces cerevisiae (i.e., colony size) and delay the sprouting of broccoli and chia seeds. Additionally, positive holes were found to exert discernible impacts on plant development such as stem length and leaf size. Our findings highlight the intricate interplay between positive holes, redox timing, and biological processes, shedding light on the potentially significant role of positive holes in influencing the growth and development of organisms in tectonically stressed rock environments. Understanding these effects has implications for a broader understanding of redox biology and of how environmental factors can influence cellular development in natural settings.

Redox Timing in Organisms↗
NASA NTRS1972

Planetary rock corer and drill concepts

Several planetary rock corers and drill design concepts have been developed for obtaining subsurface rock samples in future planetary explorations. Tools are designed for unmanned space vehicles. Two devices are rotary impact multiple chisel trepan rock corer and hole drilling tool.

Imus, R. E.↗
NASA NTRS1972

Experimental petrology and origin of Fra Mauro rocks and soil

Melting experiments over the pressure range 0 to 20 kilobars were conducted on Apollo 14 igneous rocks 14310 and 14072 and on comprehensive fines 14259. The mineralogy and textures of rocks 14310 and 14072 are presumed to be the result of near-surface crystallization. The chemical compositions of the samples show special relationships to multiply-saturated liquids in the system: anorthite-forsterite-fayalite-silica at low pressure. Partial melting of a lunar crust consisting largely of plagioclase, low calcium pyroxene, and olivine, followed by crystal fractionation at the lunar surface is proposed as a mechanism for the production of the igneous rocks and soil glasses sampled by Apollo 14.

Walker, D.↗
NASA NTRS1971

Remote sensing of some sedimentary rocks.

Sedimentary rocks including varying sized clastics and carbonates were overflown by aircraft between 1966 and 1971 producing data in the ultraviolet to microwave regions of the electromagnetic spectrum. This paper reports that multispectral analysis increases the ease and rapidity of discrimination of rock types having subtle differences in physical characteristics, but fails to enhance and may degrade distinctions where physical characteristics are significantly different. Brief resumes of color and color IR photographic data are presented. Thermal infrared is found to be useful in the mapping of rock units, but limitations such as moisture variation, soil cover, and vegetation may exceed in one formation the distinction between differing lithologies. A brief review of previously published SLAR data is included for completeness. Remote sensing techniques should reduce field geological effort by as much as 50%.

Brennan, P. A.↗
NASA NTRS1971

Fungal leaching of titanium from rock.

Penicillium simplicissimum is found to solubilize up to 80% of the titanium in granitic rocks but less than 2% of the titanium in basaltic rocks. These findings were made in investigating the interactions of microorganisms with rocks and minerals of the biosphere in studies aimed at developing experiments for the detection of extraterrestrial life.

Silverman, M. P.↗
NASA NTRS1971

Impact breccias in carbonate rocks, Sierra Madera, Texas.

Two main types of deformational breccia occur in the Sierra Madera cryptoexplosion structure: monolithologic breccias composed of shattered rock of a single lithology and mixed breccias composed of rocks of several lithologies. Monolithologic breccias generally show no mineralogic signs of shock deformation, but a few samples are shatter-coned in a manner suggesting simultaneous formation of breccias and shatter cones. Mixed breccias, forming irregular, cross-cutting bodies, consistently contain moderately to highly shocked material, with mineralogic evidence of shock pressures of 50 kb to more than 200 kb, which, with evidence from the structural geometry of Sierra Madera and orientation of shatter cones, indicate an impact origin of the breccias. The mode of occurrence of the breccias, petrographic characteristics, and association with shock features are shared by breccias in many other cryptoexplosion structures in both carbonate and crystalline rock terranes, suggesting that such breccias have a common origin.

Wilshire, H. G.↗
NASA NTRS1972

Major and trace element abundances in volcanic rocks of orogenic areas.

The composition of recent island-arc volcanic rocks in relation to their geographic and stratigraphic relations is discussed. The differences in composition between volcanic rocks and those in continental margins are pointed out. Trace elements and major elements are shown to suggest a continuous gradational sequence from tholeiites through calc-alkaline rocks to shoshonites.

Jakes, P.↗
NASA NTRS1972

Rare gas studies of the galactic cosmic ray irradiation history of lunar rocks.

Average irradiation depths and exposure ages of Tranquillity Base rocks are computed on the basis of eight analyses of the five noble gases in whole rock samples and lunar separates from lunar rocks, in conjunction with available literature data. Correlated variations in He-3/Ne-21 and Ar-38/Ne-21 reflect shielding differences. This correlation cannot be explained by diffusion losses, even though evidence for gas loss is obtained from mineral separate data. A qualitative shielding sequence is constructed which agrees reasonably well with the sequence based on Gd isotopic data.

Huneke, J. C.↗
NASA NTRS1972

Chromian spinels from Apollo 14 rocks.

Results of electron microprobe analysis of 13 pink, isotropic, high-relief grains from Apollo 14 elastic rock 14063,14 and a lithic fragment from the 1 to 2 mm fines, 14002,7, identifying them as spinel minerals dominated by the spinel component MgAl2O4 associated with a moderate content of chromite and hercynite. The spinel is thought to have crystallized from a magma high in aluminum and low in iron, with possible crystal separation, followed by incorporation in clastic rocks by impacts. Many bulk compositions of the elastic fragments fall near the field of primary spinel in the model system An-Fo-SiO2. Experimental syntheses of Apollo 14 rocks are needed to test the suggested primary origin.

Steele, I. M.↗
NASA NTRS1972

Spectral compositional imaging of silicate rocks.

A technique is presented for the broad-scale mapping of gross compositional differences in silicate rocks from three medium-width (2 to 3 microns) spectral channels of thermal infrared scanner data. Ratios of radiances in two of the channels as measured by a two-element Hg:Cd:Te detector from an altitude of 1000 meters are calculated for 25 silicate rocks. The ratios are shown to be nearly linearly correlated with the position of the centers of gravity of the reststrahlen spectral emissivity features, as measured in the laboratory. Further, the ratios are shown to be generally correlated with SiO2 content of silicate rocks. A third channel is proposed for correction of temperature variations across the scene.

Vincent, R. K.↗
NASA NTRS1973

Distinguishing major lithologic types in rocks of precambrian age in central Wyoming using multilevel sensing, with a chapter on possible economic significance of iron formation discovered by use of aircraft images in the Granite Mountains of Wyoming

The author has identified the following significant results. Information obtained by remote sensing from three altitude levels: ERTS-1 (565 miles), U-2 (60,000 feet), and C-130 aircraft (15,000 feet) illustrates the possible application of multilevel sensing in mineral exploration. Distinction can be made between rocks of greenstone belts and rocks of granite-granite gneiss areas by using ERTS-1 imagery in portions of the Precambrian of central Wyoming. Study of low altitude color and color infrared photographs of the mafic terrain revealed the presence of metasedimentary rocks with distinct layers that were interpreted as amphibolite by photogeologic techniques. Some of the amphibolite layers were found to be iron formation when examined in the field. To our knowledge this occurrence of iron formation has not been previously reported in the literature.

Houston, R. S.↗
NASA NTRS1972

Elastic properties of Apollo 14 and 15 rocks.

Ultrasonic P- and S-wave velocities of lunar samples 14310,72 and 15418,43 and P-wave velocities of sample 15015,18 were measured at room temperature to 5 kb confining pressure. The velocities of both igneous and breccia samples increased sharply over this pressure range. At low confining pressures, the shape of velocity-pressure curves of rocks is determined by the distribution function of crack aspect ratios. We suggest that analogue studies on terrestrial rocks having a wide assortment of crack parameters may be used to infer the nature of cracks in lunar rocks.

Todd, T.↗
NASA NTRS1973

Effects of atmospheric moisture on rock resistivity.

This study examines the changes in resistivity of rock samples as induced by atmospheric moisture. Experiments were performed on samples of hematitic sandstone, pyrite, and galena. The sandstone underwent a change in resistivity of four orders of magnitude when it was measured in a vacuum of 500 ntorr and in air of 37% relative humidity. Pyrite and galena showed no variations in resistivity when they were measured under the same conditions. These results, plus others obtained elsewhere, indicate that rocks of the resistive type are affected in their electrical properties by atmospheric moisture, whereas rocks of the conductive type are not. The experimental evidence obtained is difficult to reconcile with a model of aqueous electrolytic conduction on the sample surface. It is instead suggested that adsorbed water molecules alter the surface resistivity in a manner similar to that observed in semiconductors and insulators.

Alvarez, R.↗
NASA NTRS1973

Elasticity of water-saturated rocks as a function of temperature and pressure.

Compressional and shear wave velocities of water-saturated rocks were measured as a function of both pressure and temperature near the melting point of ice to confining pressure of 2 kb. The pore pressure was kept at about 1 bar before the water froze. The presence of a liquid phase (rather than ice) in microcracks of about 0.3% porosity affected the compressional wave velocity by about 5% and the shear wave velocity by about 10%. The calculated effective bulk modulus of the rocks changes rapidly over a narrow range of temperature near the melting point of ice, but the effective shear modulus changes gradually over a wider range of temperature. This phenomenon, termed elastic anomaly, is attributed to the existence of liquid on the boundary between rock and ice due to local stresses and anomalous melting of ice under pressure.

Takeuchi, S.↗