Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “reprocessing”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 289 records · Page 16

Assessment of SNPP VIIRS VIS NIR Radiometric Calibration Stability Using Aqua MODIS and Invariant Surface Targets

The first Visible Infrared Imaging Radiometer Suite (VIIRS) is onboard the Suomi National Polar-orbiting Partnership (SNPP) satellite. As a primary sensor, it collects imagery and radiometric measurements of the land, atmosphere, cryosphere, and oceans in the spectral regions from visible (VIS) to long-wave infrared. NASA's National Polar-orbiting Partnership (NPP) VIIRS Characterization Support Team has been actively involved in the VIIRS radiometric and geometric calibration to support its Science Team Principal Investigators for their independent quality assessment of VIIRS Environmental Data Records. This paper presents the performance assessment of the radiometric calibration stability of the VIIRS VIS and NIR spectral bands using measurements from SNPP VIIRS and Aqua MODIS simultaneous nadir overpasses and over the invariant surface targets at the Libya-4 desert and Antarctic Dome Concordia snow sites. The VIIRS sensor data records (SDRs) used in this paper are reprocessed by the NASA SNPP Land Product Evaluation and Analysis Tool Element. This paper shows that the reprocessed VIIRS SDRs have been consistently calibrated from the beginning of the mission, and the calibration stability is similar to or better than MODIS. Results from different approaches indicate that the calibrations of the VIIRS VIS and NIR spectral bands are maintained to be stable to within 1% over the first three-year mission. The absolute calibration differences between VIIRS and MODIS are within 2%, with an exception for the 0.865-m band, after correction of their spectral response differences.

Wu, Aisheng↗

Development of an Operational Land Water Mask for MODIS Collection 6, and Influence on Downstream Data Products

Data from the Moderate Resolution Imaging Spectro-radiometer (MODIS)on-board the Earth Observing System Terra and Aqua satellites are processed using a land water mask to determine when an algorithm no longer needs to be run or when an algorithm needs to follow a different pathway. Entering the fourth reprocessing (Collection 6 (C6)) the MODIS team replaced the 1 km water mask with a 500 m water mask for improved representation of the continental surfaces. The new water mask represents more small water bodies for an overall increase in water surface from 1 to 2 of the continental surface. While this is still a small fraction of the overall global surface area the increase is more dramatic in certain areas such as the Arctic and Boreal regions where there are dramatic increases in water surface area in the new mask. MODIS products generated by the on-going C6 reprocessing using the new land water mask show significant impact in areas with high concentrations of change in the land water mask. Here differences between the Collection 5 (C5) and C6 water masks and the impact of these differences on the MOD04 aerosol product and the MOD11 land surface temperature product are shown.

Carroll, M. L.↗

Kepler Data Release 25 Notes (Q0-Q17)

These Data Release Notes provide information specific to the current reprocessing and re-export of the Q0-Q17 data. The data products included in this data release include target pixel files, light curve files, FFIs,CBVs, ARP, Background, and Collateral files. This release marks the final processing of the Kepler Mission Data. See Tables 1 and 2 for a list of the reprocessed Kepler cadence data. See Table 3 for a list of the available FFIs. The Long Cadence Data, Short Cadence Data, and FFI data are documented in these data release notes. The ancillary files (i.e., cotrending basis vectors, artifact removal pixels, background, and collateral data) are described in the Archive Manual (Thompson et al., 2016).

Data Release Notes↗

Homogenizing and Estimating the Uncertainty in NOAA's Long-Term Vertical Ozone Profile Records Measured with the Electrochemical Concentration Cell Ozonesonde

NOAA's program of long-term monitoring of the vertical distribution of ozone with electrochemical concentration cell (ECC) ozonesondes has undergone a number of changes over the 50-year record. In order to produce a homogenous data set, these changes must be documented and, where necessary, appropriate corrections applied. This is the first comprehensive and consistent reprocessing of NOAA's ozonesonde data records that corrects for these changes using the rawest form of the data (cell current and pump temperature) in native resolution as well as a point-by-point uncertainty calculation that is unique to each sounding. The reprocessing is carried out uniformly at all eight ozonesonde sites in NOAA's network with differences in sensing solution and ozonesonde types accounted for in the same way at all sites. The corrections used to homogenize the NOAA ozonesonde data records greatly improve the ozonesonde measurements with an average one sigma uncertainty of +/- 4-6% in the stratosphere and +/- 5-20% in the troposphere. A comparison of the integrated column ozone from the ozonesonde profile with co-located Dobson spectrophotometers total column ozone measurements shows agreement within +/- 5% for >70% of the profiles. Very good agreement is also found in the stratosphere between ozonesonde profiles and profiles retrieved from the Solar Backscatter Ultraviolet (SBUV) instruments.

ozonesonde↗

NICER Observes the Effects of an X-Ray Burst on the Accretion Environment in Aql X-1

Accretion disks around neutron stars regularly undergo sudden strong irradiation by Type I X-raybursts powered by unstable thermonuclear burning on the stellar surface. We investigate the impacton the disk during one of the first X-ray burst observations with the Neutron Star Interior CompositionExplorer (NICER) on the International Space Station. The burst is seen from Aql X-1 during the hardspectral state. In addition to thermal emission from the neutron star, the burst spectrum exhibits anexcess of soft X-ray photons below 1 keV, where NICER's sensitivity peaks. We interpret the excessas a combination of reprocessing by the strongly photoionized disk and enhancement of the pre-burstpersistent flux, possibly due to Poynting Robertson drag or coronal reprocessing. This is the firstsuch detection for a short sub-Eddington burst. As these bursts are observed frequently, NICER willbe able to study how X-ray bursts affect the disk and corona for a range of accreting neutron starsystems and disk states.

Keek, L.↗

Evaluation of MODIS and VIIRS Cloud-Gap-Filled Snow-Cover Products for Production of an Earth Science Data Record

MODerate resolution Imaging Spectroradiometer (MODIS) cryosphere products have been available since 2000 – following the 1999 launch of the Terra MODIS and the 2002 launch of the Aqua MODIS – and include global snow-cover extent (SCE) (swath, daily, and 8 d composites) at 500 m and ∼5 km spatial resolutions. These products are used extensively in hydrological modeling and climate studies. Reprocessing of the complete snow-cover data record, from Collection 5 (C5) to Collection 6 (C6) and Collection 6.1 (C6.1), has provided improvements in the MODIS product suite. Suomi National Polar-orbiting Partnership (S-NPP) Visible Infrared Imaging Radiometer Suite (VIIRS) Collection 1 (C1) snow-cover products at a 375 m spatial resolution have been available since 2011 and are currently being reprocessed for Collection 2 (C2). Both the MODIS C6.1 and the VIIRS C2 products will be available for download from the National Snow and Ice Data Center beginning in early 2020 with the complete time series available in 2020. To address the need for a cloud-reduced or cloud-free daily SCE product for both MODIS and VIIRS, a daily cloud-gap-filled (CGF) snow-cover algorithm was developed for MODIS C6.1 and VIIRS C2 processing. MOD10A1F (Terra) and MYD10A1F (Aqua) are daily, 500 m resolution CGF SCE map products from MODIS. VNP10A1F is the daily, 375 m resolution CGF SCE map product from VIIRS. These CGF products include quality-assurance data such as cloud-persistence statistics showing the age of the observation in each pixel. The objective of this paper is to introduce the new MODIS and VIIRS standard CGF daily SCE products and to provide a preliminary evaluation of uncertainties in the gap-filling methodology so that the products can be used as the basis for a moderate-resolution Earth science data record (ESDR) of SCE. Time series of the MODIS and VIIRS CGF products have been developed and evaluated at selected study sites in the US and southern Canada. Observed differences, although small, are largely attributed to cloud masking and differences in the time of day of image acquisition. A nearly 3-month time-series comparison of Terra MODIS and S-NPP VIIRS CGF snow-cover maps for a large study area covering all or parts of 11 states in the western US and part of southwestern Canada reveals excellent correspondence between the Terra MODIS and S-NPP VIIRS products, with a mean difference of 11 070 sqkm, which is ∼0.45 % of the study area. According to our preliminary validation of the Terra and Aqua MODIS CGF SCE products in the western US study area, we found higher accuracy of the Terra product compared with the Aqua product. The MODIS CGF SCE data record beginning in 2000 has been extended into the VIIRS era, which should last at least through the early 2030s.

Hall, Dorothy K.↗

N20 VIIRS RSB Calibration Algorithms and Results: Collection 2.0

The NOAA-20 (N20) satellite, previously the Joint Polar Satellite System-1 satellite, was launched on November 18, 2017. One of the five major scientific instruments aboard the satellite is the Visible Infrared Imaging Radiometer Suite (VIIRS). VIIRS scans the Earth’s surface in 22 spectral bands, 14 of which are the reflective solar bands (RSBs) with band center wavelengths from 0.412 to 2.25μm. VIIRS regularly performs on-orbit radiometric calibration of its RSBs, primarily through the observations of the onboard solar diffuser (SD). The on-orbit change of the SD’s bidirectional reflectance distribution function, known as the H-factor, is determined by the onboard SD stability monitor (SDSM). Since the H-factor exhibits angular dependence, obtaining the H-factor along the SD to the telescope direction is a challenge for the NOAA-20 VIIRS. Recently, Collection 2.0 of the NASA Land Science Investigator-led Processing Systems (SIPS) products were released. As a part of this reprocessing effort, we made two major improvements in the N20 VIIRS RSB radiometric calibration. One is the improved SD and SDSM attenuation screen transmittance functions, obtained by using calibration data collected during both the yaw maneuver and a small portion of regular orbits, resulting in a higher quality H-factor for the SDSM view. Another is the use of the H-factor for the telescope view, derived from the H-factor for the SDSM view, by using the results for the SNPP VIIRS. In June 2019, we delivered a set of mission-long N20 VIIRS Collection 2.0 RSB radiometric calibration look-up-tables. These tables have been employed by the NASA Land SIPS group to reprocess the entire time series of the NOAA-20 VIIRS products. In this paper, we discuss the Collection 2.0 NOAA-20 VIIRS RSB calibration algorithms and results.

N20 VIIRS↗

Intensive disc-reverberation mapping of Fairall 9: first year of Swift and LCO monitoring

We present results of time-series analysis of the first year of the Fairall 9 intensive disc-reverberation campaign. We used Swift and the Las Cumbres Observatory global telescope network to continuously monitor Fairall 9 from X-rays to near-infrared at a daily to subdaily cadence. The cross-correlation function between bands provides evidence for a lag spectrum consistent with the τ ∝ λ^(4/3) scaling expected for an optically thick, geometrically thin blackbody accretion disc. Decomposing the flux into constant and variable components, the variable component’s spectral energy distribution is slightly steeper than the standard accretion disc prediction. We find evidence at the Balmer edge in both the lag and flux spectra for an additional bound-free continuum contribution that may arise from reprocessing in the broad-line region. The inferred driving light curve suggests two distinct components, a rapidly variable (<4 d) component arising from X-ray reprocessing, and a more slowly varying (>100 d) component with an opposite lag to the reverberation signal.

J V Hernández Santisteban↗

A Weakening Compton Hump and Soft X-ray Excess Detected in the Seyfert-1 Galaxy MCG –02–58–22

We have carried out an extensive X-ray spectral study of the bare Seyfert-1 galaxy MCG –02–58–22to ascertain the nature of the X-ray reprocessing media, using observations from Suzaku(2009) and simultaneous observations from XMM-Newton and NuSTAR(2016) . The most significant results of our investigation are: 1. The primary X-ray emission from the corona is constant in these observations, both in terms of the power law slope (Γ = 1.80) and luminosity (L2−10 keV= 2.55×1044erg s−1). 2.The soft excess flux decreased by a factor of two in 2016, the Compton hump weakened/vanished in2016, and the narrow FeKαemission line became marginally broad (σ= 0.35±0.08 keV) and its flux doubled in 2016. 3. From physical model fits we find that the normalization of the narrow component of the FeKαline does not change in the two epochs, although the Compton hump vanishes in the same time span. Since the primary X-ray continuum does not change, we presume that any changes in there processed emission must arise due to changes in the reprocessing media. Our primary conclusions are: A. The vanishing of the Compton hump in 2016 can probably be explained by a dynamic clumpytorus which is infalling/outflowing, or by a polar torus wind. B. The torus in this AGN possibly has two structures: an equatorial toroidal disk (producing the narrow FeKαemission) and a polar component(producing the variable Compton hump), C. The reduction of the soft-excess flux by half and increase in the FeKαflux by a factor of two in the same period cannot be adequately explained by ionized disk reflection model alone.

Sibasish Laha↗

Considerations For Waste-to-Base Future Research Paths

Developing innovative technologies to reprocess low value waste into high value base products will enable a new “Waste-to-Base” (WtB) capability that can spawn a new approach to mission design. Systems engineers and mission architects will work together under a new paradigm in logistics planning. Equipment, components, packaging, storage, and structures will be understood not only by functional requirements, but also in terms of useful lifetimes and materials of construction. The advent of a new technical discipline - reprocess engineering - will grow from the intersection between chemical, mechanical, and systems engineering, mission design, and logistics planning. A crowdsourcing approach was employed to gather low TRL concepts into workable solutions for issues in trash management, CO2 processing, foam re-processing, and fecal processing. The results of the crowdsourcing activities are summarized along with a roadmap for future technology development work.

Logistics reduction↗

An Update on the Hydrological Land Surface Data and Services at NASA GES DISC

"The NASA Goddard Earth Sciences Data and Information Services Center (GES DISC) is one of twelve NASA Earth Observing System data centers that document, process, archive and distribute data from Earth science missions and related projects. The GES DISC hosts many hydrological land surface data products including North American Land Data Assimilation System (NLDAS), Global Land Data Assimilation System (GLDAS), the Famine Early Warning Systems Network (FEWS NET) Land Data Assimilation System (FLDAS), and assimilated-Gravity Recovery and Climate Experiment (GRACE). The Land Surface Model (LSM) products contain model output, including heat fluxes, rain, snow, soil temperature, soil moisture and runoff; and observational forcing data, including surface pressure, temperature, precipitation, downward shortwave and longwave radiation, humidity, and wind. The temporal resolution of the hydrology data at the GES DISC ranges from hourly to monthly and the spatial resolution 0.1 degree to 1.0 degree. The variability of Earth’s water and energy cycles can be characterized with these spatially and temporally consistent, and quality controlled hydrological land surface data. These data could support ongoing modeling activities, and help improve our understanding of land-surface-atmosphere interactions and their impact on climate. Over the years, new data is added, and older data is reprocessed and updated. This presentation provides a summary table of the hydrological data and discusses recent updates to the data and data services at the GES DISC. New data products include (1) GRACE Global Version 3.0 drought indicators and (2) FLDAS monthly global and Central Asia daily data. Reprocessed and updated products include (1) NLDAS Version 2.0 and (2) GRACE United States Version 4.0 drought indicators. Lastly, this presentation will discuss the opportunities for accessing some of our hydrology data from the cloud. As the hydrology land surface data is moved to the cloud, users can expect faster service for longer time series, notably the hydrology data rods time series service."

Ashley Heath↗

The MPACT 2020 Milestone: Safeguards and Security by Design of Future Nuclear Fuel Cycle Facilities.

The Materials Protection, Accounting, and Control Technologies (MPACT) campaign, within the U.S. Department of Energy Office of Nuclear Energy, has developed a Virtual Facility Distributed Test Bed for safeguards and security design for future nuclear fuel cycle facilities. The purpose of the Virtual Test Bed is to bring together experimental and modeling capabilities across the U.S. national laboratory and university complex to provide a one-stop-shop for advanced Safeguards and Security by Design (SSBD). Experimental testing alone of safeguards and security technologies would be cost prohibitive, but testbeds and laboratory processing facilities with safeguards measurement opportunities, coupled with modeling and simulation, provide the ability to generate modern, efficient safeguards and security systems for new facilities. This Virtual Test Bed concept has been demonstrated using a generic electrochemical reprocessing facility as an example, but the concept can be extended to other facilities. While much of the recent work in the MPACT program has focused on electrochemical safeguards and security technologies, the laboratory capabilities have been applied to other facilities in the past (including aqueous reprocessing, fuel fabrication, and molten salt reactors as examples). This paper provides an overview of the Virtual Test Bed concept, a description of the design process, and a baseline safeguards and security design for the example facility. Parallel papers in this issue go into more detail on the various technologies, experimental testing, modeling capabilities, and performance testing.

98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL P↗

Safeguards Modeling for Advanced Nuclear Facility Design.

Future nuclear fuel cycle facilities will see a significant benefit from considering materials accountancy requirements early in the design process. The Material Protection, Accounting, and Control Technologies (MPACT) working group is demonstrating Safeguards and Security by Design (SSBD) for a notional electrochemical reprocessing facility as part of a 2020 Milestone. The idea behind SSBD is to consider regulatory requirements early in the design process to provide more optimized systems and avoid costly retrofits later in the design process. Safeguards modeling, using single analyst tools, allows the designer to efficiently consider materials accountancy approaches that meet regulatory requirements. However, safeguards modeling also allows the facility designer to go beyond current regulations and work toward accountancy designs with rapid response and lower thresholds for detection of anomalies. This type of modeling enables new safeguards approaches and may inform future regulatory changes. The Separation and Safeguards Performance Model (SSPM) has been used for materials accountancy system design and analysis. This paper steps through the process of designing a Material Control and Accountancy (MC&A) system, presents the baseline system design for an electrochemical reprocessing facility, and provides performance metrics from the modeling analysis. The most critical measurements in the electrochemical facility are the spent fuel input, electrorefiner salt, and U/TRU product output measurements. Finally, material loss scenario analysis found that measurement uncertainties (relative standard deviations) for Pu would need to be at 1% (random and systematic error components) or better in order to meet domestic detection goals or as high as 3% in order to meet international detection goals, based on a 100 metric ton per year plant size.

98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL P↗

Integration of Nuclear Material Accounting Data and Process Monitoring Data for Improvement on Detection Probability in Safeguarding Electrochemical Processing Facilities (Final Technical Report)

The KAERI advanced spent fuel conditioning process (ACP) process is a critical component of the US- South Korean nuclear cooperation and the following “123 Agreement.” Its development has received considerable attention in both countries. The ACP is an electrochemical processing (pyroprocessing) that recycles over 96% of the used nuclear fuel (UNF). It is also intrinsically proliferation-resistant in theory. In normal operation, the U/TRU product is very hot radiologically. In addition, the Cm provides a high level of spontaneous neutrons, making the product unsuitable for weapon use. However, as pointed in some study, “the need for safeguards to protect against the diversion and misuse of separated plutonium applies essentially equally to all grades of plutonium.” As pointed by many studies, the well-established traditional Nuclear Material Accounting (NMA) approach cannot be directly applied to electrochemical processing because of the lack of an input accountability tank, the non-continuous material flow, and the unsatisfactory level of confidence in sampling methods. Therefore, nuclear safeguards remain a grand challenge in the developing of commercial electrochemical separations facilities, especially around the heart of such facilities, the electrorefiner (ER) systems. In contrast to NMA data, process monitoring (PM) data is normally an indirect measurement of the SNM and is acquired much more frequently. In a broad sense, PM includes monitoring by various types of equipment, e.g. radiation detectors, cameras, voltage, current sensors. Because it is already being collected by the operator, the additional cost to safeguards is low. It has long been believed that PM data can supplement NMA data and help improve safeguards, although the benefits are hard to quantify. The U.S. DOE’s Material Protection, Accounting, and Control Technology (MPACT) campaign has made substantial investments into innovative PM sensor technology and predictive model development for real- or near real-time measurement and prediction of molten salt density and level, salt composition and actinide concentration especially Pu, the cell voltage, and the cell current to supplement traditional NMA. For aqueous-based reprocessing facilities, it is reported that PM, integrated with traditional NMA, have a high detection probability for specific diversions. For electrochemical reprocessing, preliminary studies have shown that PM data can support traditional NMA in various ways by providing a basis to estimate some of the in-processing nuclear material inventories. Despite early success, further studies on fusion of PM data and NMA data are still needed, which is the goal of this proposed work.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Radiolytic transformation of AHA under single-cycle conditions

Historically, the radiation robustness of extractant ligands and the impact of their radiolysis products have been used to evaluate the radiolytic feasibility of solvent system formulations for used nuclear fuel (UNF) reprocessing. However, other key additives (e.g., reducing and hold-back reagents) are employed by these solvent systems. These chemical species have typically been overlooked from a radiolytic perspective, and consequently little is known on how they impact process performance. Therefore, to holistically support the development of advanced, simplified, single-cycle flowsheets for UNF reprocessing, the radiation robustness of two key proposed additives – (i) the complexing reductant acetohydroxamic acid (AHA) and (ii) the hold-back reagent 1,2-cyclohexylenedinitrilotetraacetic acid (CDTA) – have been evaluated under envisioned process conditions using a combination of steady-state gamma and time-resolved pulsed electron irradiation techniques.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗

Enabling Recycling of Composites: Understanding the Impacts of Multiple Thermal Processing Cycles

When considering the utilization of recycled short carbon fiber feedstock materials for advanced manufacturing, understanding the material degradation behavior is essential in determining how many times a composite material can be effectively reprocessed and remanufactured. This study characterizes the degradation behavior of short carbon fiber acrylonitrile butadiene (CF-ABS) that has been reprocessed five times with twin screw extrusion. Parallel plate rheology was completed to observe the degradation in complex viscosity of the recycled feedstock materials. Gel permeation chromatography (GPC) was utilized to characterize the changes in molecular weight distribution of the recycled materials as a result of thermal and mechanical degradation during the re-processing steps. Rheological characterization, GPC, and twin-screw processing data help inform the process optimizations required to process the recycled feedstock material. Successful characterization of the degradation behavior of short fiber composite feedstock materials aids in increased understanding of the lifespan of high value carbon fiber composite materials and aids in process optimization of recycled composite materials.

Walker, Roo↗

Solids from Fuel Dissolution, Process Solutions, and Waste Evaporation

Irradiated light water reactor (LWR) fuel contains material which is insoluble in nitric acid, and process solutions are unstable with respect to precipitation of compounds insoluble in nitric acid. Accordingly, solids will be encountered during fuel reprocessing, and operations must be conducted in a way to minimize formation of additional solids and to prevent their interference with reprocessing operations.

Campbell, D. O.↗

Investigating the Impacts of Direct Dissolution Conditions on the Radiolytic Longevity of Butyramide Extractants

Removing the nitric acid (HNO3) dissolution step in used nuclear fuel (UNF) reprocessing would reduce the volume of radioactive waste streams generated, thereby, improving process efficiency. A promising strategy for this is the direct dissolution of UNF that has been pretreated by voloxidation into an organic solvent composed of specialized extractants and diluent. However, removal of the aqueous HNO3 phase from the envisioned reprocessing system has the potential to drastically change the suite of radiation-induced processes occurring, and thus, alter the longevity of proposed reagents. Furthermore, the impacts of fission product and transuranic metal ion complexation on the aforementioned radiation-induced processes is poorly understood, and yet can cause significant changes in radiolytic longevity. To bridge these knowledge gaps and support the continued development of direct dissolution strategies, we present an investigation into the impacts of direct dissolution conditions on the gamma radiation-induced degradation of N,N-di-(2-ethylhexyl) butyramide (DEHBA) and N,N-di-(2-ethylhexyl)isobutyramide (DEHiBA) ligands—candidate replacements for tributyl phosphate—in pre-equilibrated n-dodecane solvent in the presence and absence of envisioned loading amounts of uranium.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗