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At least 289 records · Page 16

Low Level Calibration of Liquid Scintillation Counting

Liquid Scintillation Counting (LSC) is an analytical laboratory method that quantifies the concentrations of alpha and beta emitting isotopes. The LSC method can be utilized for the detection of tritium, both environmentally and at nuclear facilities. Most LSC samples are aqueous-based and prepared as a radioactive sample dissolved or suspended in a high efficiency scintillation cocktail that converts radioactive energy into light pulses. When placed in counting vials, the liquid scintillation cocktail allows for optical coupling in which energy is released from the samples radioactive decay, and transferred to the scintillator. That energy is then absorbed to produce excited electrons that fall back to their ground-state and emit a pulse of light that is detected by the liquid scintillation analyzers photomultiplier tubes. Quench is a signal attenuation due to physical, chemical, or color interferences. To compensate for quench, quench standards of a known concentration are implemented at increasing increments of quench per vial to create a quench curve. Quench standards can be purchased pre-made or customized from the manufacturer, however, there are several issues that arise from purchasing the pre-made quench standards. The main issues with ordering pre-made quench standards is that they use higher count values, between 30,000 and 250,000 disintegrations per minute (dpm) of tritium per vial and only come in glass vials. Using higher counting standards in glass vials makes it hard to see lower concentrations in plastic vials. Additionally, when using higher energy standards the accuracy of the calibration readings tend to be lower. On the other hand, making a set of quench standards in-house allows for the customization of the dpm concentration to roughly 1,500-3,000 and preparation in plastic vials. This allows for lower activity readings that results in closer precision of the samples' true concentration. Technical Objectives: Create a quench curve and calibrate the LSA for tritium. Verify the calibration of the quench curve prior to cross sample runs. Check calibration against Quality Control (QC) reference value. Conclusion: a tritium quench curve calibration was performed using a scintillation cocktail with ultima gold (AB and AB/F), acetone (only with AB), and water (only with AB/F). By performing the tritium quench curve calibration, the counting efficiency was correlated to various levels of quench. Calibration checks with quality control standards were also performed to verify that the calibration was correct. The observed results provided acceptable values that matched the quality control standard reference values with an acceptable uncertainty. The next step will be fine tuning and cross comparison checks with legacy instrumentation.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Gas sampling method for determining pollutant concentrations in the flame zone of two swirl-can combustor modules

A gas sampling probe and traversing mechanism were developed to obtain detailed measurements of gaseous pollutant concentrations in the primary and mixing regions of combustors in order to better understand how pollutants are formed. The gas sampling probe was actuated by a three-degree-of-freedom traversing mechanism and the samples obtained were analyzed by an on-line gas analysis system. The pollutants in the flame zone of two different swirl-can combustor modules were measured at an inlet-air temperature of 590 K, pressure of 6 atmospheres, and reference velocities of 23 and 30 meters per second at a fuel-air ratio of 0.02. Typical results show large spatial gradients in the gaseous pollutant concentration close to the swirl-can module. Average concentrations of unburned hydrocarbons and carbon monoxide decrease rapidly in the downstream wake regions of each module. By careful and detailed probing, the effect of various module design features on pollutant formation can be assessed. The techniques presently developed seem adequate to obtain the desired information.

Duerr, R. A.↗

Multidecadal Biological Monitoring and Abatement Program assessing human impacts on aquatic ecosystems within the Oak Ridge Reservation in eastern Tennessee, USA

Human activities can be powerful drivers of ecosystem change within catchments. While most long-term catchment studies have been conducted at pristine sites, such studies are less common from sites more impacted by human activity. The Oak Ridge National Laboratory's Biological Monitoring and Abatement Program (BMAP) was developed in the mid-1980s to (1) assess compliance with environmental regulations, (2) identify causes of adverse ecological impacts, (3) provide data for human and ecological risk assessments, and (4) evaluate the effectiveness of remedial actions taken to mitigate the impacts of contaminants in soils, groundwater, and surface water by documenting ecological recovery on the Oak Ridge Reservation (ORR), a federally owned 33,476-acre site in eastern Tennessee, USA, managed by the U.S. Department of Energy. The ORR is composed of multiple watersheds containing many small to mid-size streams. BMAP uses an integrated approach for determining stream health; its databases include long-term seasonal records of contaminant concentrations in water and biota, data from aquatic toxicity testing, and surveys of macroinvertebrate and fish assemblages from impacted and reference streams. These long-term data provide valuable records of degradation and recovery in catchment ecosystems. Our objective in this work is to describe our study system and data series in order to increase awareness of the availability of these long-term data to the catchment science community.

54 ENVIRONMENTAL SCIENCES↗

Relaxation dynamics of water in the vicinity of cellulose nanocrystals

Water molecules near cellulose nanocrystals (CNCs; produced via the sulfuric acid-catalyzed hydrolysis of wood pulp) are believed to relax slower than those in the bulk liquid, which may result in unique properties of CNC aqueous dispersions. Herein this study analyzed the polarization behavior of water molecules in CNC aqueous dispersions and other reference samples using a dielectric relaxation spectroscopy (DRS) technique in the microwave frequency range (0.2–20 GHz). As the CNC concentration increases, two slow relaxation components become prominent. The comparison with DRS data of aqueous dispersions of nanoporous silica, polyvinyl alcohol (PVA), and hairy CNC (HCNC) with amorphous chains protruding from both ends suggested that these slow relaxation modes of water near CNC surfaces cannot be attributed to direct hydrogen bonding interactions with the hydroxyl (OH) groups exposed and immobilized at the solid surface. Instead, they are similar to the water molecules interacting with OH groups attached to flexible polymer chains. Molecular dynamics (MD) simulations of the polarization behavior of water near the (110) facet of cellulose Iβ crystals confirmed that the interactions of water molecules with the cellulose crystal surface do not cause slower relaxations in the frequency range studied via the DRS. These results indicated that the CNC surface cannot be depicted with the crystallographic facets of cellulose Iβ; instead, it resembles a polymer-brush surface on which the short glucan residues or fragments of the strong acid-catalyzed hydrolysis process are swollen and extended into the aqueous phase.

59 BASIC BIOLOGICAL SCIENCES↗

Determining P, S, Br, and I content in uranium by triple quadrupole inductively coupled plasma mass spectrometry

The trace impurities of a uranium ore concentrate (UOC) can be examined to determine mine source, methods of production, and quality. This study presents a method to determine the concentration of halides and main group elements, specifically P, S, Br and I, utilizing triple quadrupole inductively coupled plasma–mass spectrometry. These analytes were measured in a uranium matrix to simulate a UOC sample. The concentrations determined with this method showed agreement with known values. Solutions with and without uranium were compared. A UOC certified reference material, CUP-2, was analyzed to further demonstrate the effectiveness of the method.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗

Thermodynamics, local structure, and transport of protons in triple-conducing oxide, BaCo 0.4 Fe 0.4 Zr 0.1 Y 0.1 O 3-δ (BCFZY4411)

Triple-conducting oxides (TCOs) are an emerging class of mixed ionic and electronically conducting materials that show great promise for oxygen reduction/oxygen evolution (ORR/OER) electrocatalysis—primarily in high-temperature ceramic electrochemical cells— but also in aqueous alkaline environments. Their high activity is attributed, at least in part, to their ability to incorporate and transport three mobile charge carriers: protons, oxygen vacancies, and electron-holes Despite their promise, fundamental studies of TCOs are challenging, as transport dynamics from three charge carriers cannot be fully disentangled via traditional electrical measurement techniques. Characterizing proton dynamics in TCOs is particularly difficult as protons are generally the minority carrier, and their conduction response is typically obscured by the oxygen vacancies and electron holes. Here, we demonstrate successful isolation of the proton behavior in an archetypal TCO, BaCo 0.4 Fe 0.4 Zr 0.1 Y 0.1 O 3-δ (BCFZY4411), using a combination of non-electrical techniques. We determine proton uptake and oxygen non-stoichiometry (δ) using thermogravimetric analysis (TGA). X-ray absorption near edge structure (XANES) and neutron diffraction (ND) are used to validate the oxidation state of Co and the δ values obtained through TGA. We apply 1H solid-state magic-angle-spinning (MAS) nuclear magnetic resonance (NMR) to provide insights into local structure, dynamics, and proton kinetics. Finally, the proton transport properties are further quantified using tracer isotope exchange with time-of-flight secondary ion mass spectrometry (ToF-SIMS). Despite the very low proton concentrations in BCFZY4411 (<0.2% under most conditions), our analysis suggests that the oxygen Manuscript File Click here to view linked References 2 reduction and evolution reactions are nevertheless limited by the oxygen ion kinetics (e.g., oxygen surface exchange) rather than the proton kinetics at the reduced operating temperatures (<500 °C) that are targeted for electrochemical cell applications. These findings provide a comprehensive understanding of proton behavior in BCFZY4411 and pave the way for advancing the fundamental study of TCOs.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Characterizing how size distribution and concentration affect echogenicity of ultrasound contrast agents

Here, we investigated the effects of UCA gas bubble size distribution and concentration on the generated ultrasound echogenicity signal. Gas bubble size characterization using Coulter Counter and cryogenic-SEM revealed the hollow structure and rare presence of microbubbles >10 µm in a commercial UCA product, Lumason™. Volume-weighed size and concentration were observed to be more sensitive to changes in UCA bubble stability than number-weighted size and concentration. Size distribution measurements showed that the force (e.g., shaking/agitation energy) used to redisperse the sample did not affect the size distribution, concentration, or echogenicity of the UCA sample. The ultrasound backscattering coefficient (BSC) of size fractionated and serial diluted microbubbles showed that the echogenicity signal correlates most with UCA bubble concentration, especially volume-weighted concentration. Findings from this study may be used to support demonstrating the equivalence of a generic UCA product to the reference listed drug.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Radial Segregation between Red Giant Populations in the Globular Cluster NGC 3201: Tentative Role of Varying Mass among the Progenitors

In the globular cluster NGC 3201, we study subpopulations (SPs) of red giants (RGs) distinguished by their characteristics. In its central part, we make use of multicolor Hubble Space Telescope (HST) photometry coupled with spectroscopy of RGs spread out over a larger cluster face. In the color index CI = (m{sub F275W}−m{sub F336W}) −(m{sub F336W}−m{sub F439W}), RGs commonly referred to as first generation, SPI, are separated from the counterparts of the second generation, SPII. The latter are more concentrated than the former at a confidence level of P = 93%, within the field covered by the HST photometry. Their minor portion (∼28%, SPIIm) located in the middle of the δCI range spanned across the split RG branch relative to the splitting edge is more centrally concentrated at a higher confidence level of 96%. We found, from the [Na/Fe]−δCI plot for RGs in common between the photometry and spectroscopy, that SPI and SPII are mostly overlapped within 0.0 < [Na/Fe] < 0.3. RGs with [Na/Fe] < 0.0 (mostly SPI) keep their lower concentration to the cluster center over larger radial distance as compared to SPII RGs with [Na/Fe] > 0.3 at a confidence level of P = 88%. It is increased up to 95% if a restriction on [O/Fe] is imposed. The obtained result, particularly in the central part, is a clue that SPIIm RGs are the descendants of more massive progenitors. Of these RGs approximately one-third probably originate from recent (within the past 1.5 Gyr) blue stragglers with M {sub BS} > 1.1M {sub ☉}, and the other two-thirds could be accounted for by older collision products of primordial MS stars.

47 OTHER INSTRUMENTATION↗

Satellite power systems (SPS) concept definition study. Volume 1: Executive summary

System definition studies resulted in a further definition of the reference system using gallium arsenide solar arrays, analysis of alternative subsystem options for the reference concept, preliminary solid state microwave concept studies, and an environmental analysis of laser transmission systems. The special emphasis studies concentrated on satellite construction, satellite construction base definition, satellite construction base construction, and rectenna construction. Major emphasis in the transportation studies was put on definition of a two stage parallel burn, vertical takeoff/horizontal landing concept. The electric orbit transfer vehicle was defined in greater detail. Program definition included cost analyses and schedule definition.

Hanley, G. M.↗

Catalyst durability evaluation for advanced gas turbine engines

Catalytic combustion has demonstrated the ability to provide low NO(x) emissions while maintaining high combustion efficiency. Recently, under joint NASA Lewis, EPA, and Acurex sponsorship, a catalytic reactor was tested for 1000 hours to demonstrate durability in combustion environments representative of advanced automotive gas turbine engines. At a 740K air preheat temperature and a propane fuel/air ratio of 0.028 by mass, the adiabatic flame temperature was held at about 1700K. The graded cell monolithic reactor measured 5 cm in diameter by 10.2 cm in length and was operated at a reference velocity of 13.4 m/s at 1 atmosphere pressure. Measured NO(x) levels remained below 5 ppm while unburned hydrocarbon concentrations registered near zero and carbon monoxide levels were nominally below 20 ppm. The durability test included several parametric turndown studies and ended with a series of on/off cycling tests to further characterize reactor performance.

Snow, G. C.↗

Limits on Venus' SO2 abundance profile from interferometric observations at 3.4 mm wavelength

The role of SO2 in the chemistry of the clouds of Venus has been investigated by deducing its mixing ratio profile in the atmosphere through millimeter wavelength interferometric measurements of the planet's limb darkening. The first zero crossing of the Venus visibility function was measured to be 0.6221 + or - 0.0007 at a wavelength of 3.4 mm, using a reference radius for Venus of 6100 km. This measurement constrains the amount of limb darkening and shows that the high concentrations of SO2 found in the lower atmosphere do not persist above an altitude of 42 km. Thus, a sink for SO2 exists below the level of the lowest cloud deck.

Good, J. C.↗

Atmospheric and spectroscopic research in the far infrared

The University of Oregon (UO) has been a major participant in the development of far infrared spectroscopic research of the stratosphere for the purpose of understanding the ozone layer processes. The UO has had a 15-year collaboration with the Italian group of B. Carli, and have participated in the 1978/79 Sub-millimeter Infrared Balloon Experiment (SIBEX), in the Balloon Intercomparison Campaign, (BIC), in the Infrared Balloon Experiment (IBEX), and in the recently concluded Far Infrared Experiment for UARS Correlative Measurements (FIREX). Both IBEX and FIREX programs were conducted in collaboration with NASA Langley, and were designed as validation flights in support of the Upper Atmosphere Research Satellite (UARS) Program. The technique of atmospheric far infrared spectroscopy offers two important advantages. First, many chemically important species can be measured simultaneously and co-spatially in the atmosphere. Second, far infrared atmospheric spectra can be obtained in thermal emission without reference to the sun's position, enabling full diurnal and global coverage. Recent improvements in instrumentation, field measurements, and molecular concentration retrieval techniques are now making the far infrared a mature measurement technology. This work to date has largely focused on balloon-based studies, but the future efforts will focus also on satellite-based experiments. A program of research in the following general areas was proposed: Laboratory Pressure broadening coefficient studies; specialized detector system assembly and testing; and consultation and assistance with instrument and field support. The proposal was approved and a three-year research grant titled 'Atmospheric and Spectroscopic Research in the Far Infrared' was awarded. A summary of technical accomplishments attained during the grant period are presented.

Park, Kwangjai↗

Directional Attenuation of Jet Noise With Eccentric Coannular Nozzle Investigated

Jet noise and flow field were measured to follow up on observations made by Professor D. Papamoschou of the University of California at Irvine (NASA Grant NAG3-2345). When a dual-stream coannular nozzle was arranged non-concentrically, noise was attenuated significantly on the side where the annulus was thicker. A similar observation was also made in reference 2. The practical significance is obvious. If the bypass flow of a jet exhaust in flight could be diverted to form a thicker layer underneath, then less noise would be heard by an observer on the ground. In view of the current emphasis on jet noise abatement, researchers felt that the effect deserved further attention. This prompted an experiment to confirm the phenomenon in a larger facility and to obtain flow-field data to advance understanding of the mechanism.

Zaman, Khairul B.↗

Selected Lessons Learned in Space Shuttle Orbiter Propulsion and Power Subsystems

Over its 30 years of space flight history, plus the nearly 10 years of design, development test and evaluation, the Space Shuttle Orbiter is full of lessons learned in all of its numerous and complex subsystems. In the current paper, only selected lessons learned in the areas of the Orbiter propulsion and power subsystems will be described. The particular Orbiter subsystems include: Auxiliary Power Unit (APU), Hydraulics and Water Spray Boiler (WSB), Mechanical Flight Controls, Main Propulsion System (MPS), Fuel Cells and Power Reactant and Storage Devices (PRSD), Orbital Maneuvering System (OMS), Reaction Control System (RCS), Electrical Power Distribution (EPDC), electrical wiring and pyrotechnics. Given the complexity and extensive history of each of these subsystems, and the limited scope of this paper, it is impossible to include most of the lessons learned; instead the attempt will be to present a selected few or key lessons, in the judgment of the authors. Each subsystem is presented separate, beginning with an overview of the hardware and their function, a short description of a few historical problems and their lessons, followed by a more comprehensive table listing of the major subsystem problems and lessons. These tables serve as a quick reference for lessons learned in each subsystem. In addition, this paper will establish common lessons across subsystems as well as concentrate on those lessons which are deemed to have the highest applicability to future space flight programs.

Hernandez, Francisco J.↗

Promoted Combustion Behavior of 316 Stainless Steel and 6061 Aluminum Alloys in Elevated Pressure Nitrox Environments

Promoted combustion testing (outlined in the ASTM G124 “Standard Test Method for Determining the Combustion Behavior of Metallic Materials in Oxygen Enriched Atmospheres”) refers to a useful testing method to evaluate how metallic materials will behave when combusted in environments with high oxygen concentrations, elevated pressure, or both. These tests yield data which is useful for engineers and scientists from a variety of industries who need and rely on oxygen systems. Oxygen Compatibility Assessments (OCA’s) are vital for ensuring that materials will be safe for use, and these assessments rely on data from OCA’s or interpolation if a desired pressure/concentration is outside of previously tested bounds. It was identified that these bounds leave out significant areas of data for materials which are tested at high pressures (above 1500 psi) and variable oxygen concentrations (with nitrogen as the diluent gas). For this reason, the authors posited that conducting promoted combustion testing on materials above 1500 psi and in various concentrations of oxygen would be incredibly useful in future analyses for oxygen compatibility with similar environments (such as breathing air) as well as for further understanding of how materials behave at very high pressures (such as 10000 psi). Two materials were selected which are commonly used in industry today - 316 stainless steel and 6061 aluminum – and they were tested and analyzed for the purposes of this study.

oxygen compatibility↗

Design of Nuclear Criticality Safety Framework for Hands-on Construction of Fast Systems Over Ranges of Multiplication

Since 1945, Los Alamos National Laboratory (LANL) has performed critical experiments, primarily at the Los Alamos Critical Experiments Facility (LACEF) at Technical Area 18 (TA-18). Since 2011, these experiments have been conducted by the National Criticality Experiments Research Center (NCERC), operated by LANL, at the Device Assembly Facility (DAF) in the Nevada National Security Site (NNSS). These experiments utilize various types of Special Nuclear Material (SNM). Some of these experiments utilize what is referred to as the Rocky Flat Shells, which are called such as they came from the Rocky Flats Plant. These concentric hemi-shells are made of Highly Enriched Uranium (HEU), which is 93 w/o 235U. Fig. 1. Subset of the Rocky Flat Shells LANL is designing a new subcritical hands-on experiment with the goal of achieving a neutron multiplication in the range of 50 to 200, which correlates to Keff values of 0.98 to 0.995. ANSI/ANS-1 is the standard for Conduct of Critical Experiments which governs critical operations at NCERC. Section 3.9 of ANSI/ANS-1 states that when manipulating a critical assembly by hand, the predicted k eff of a known configuration should not exceed 0.95 (a neutron multiplication of 20). This presents a challenge, as this system would have a higher multiplication than 20 and the assembly would have to remain subcritical in normal and credible accident scenarios. To ensure the safety of such an assembly, the different normal and abnormal conditions that could alter the criticality 1 MCNP® and Monte Carlo N-Particle® are registered trademarks owned by Triad National Security, LLC, manager and operator of Los Alamos National Laboratory. Any third party use of such registered marks should be properly of the system must be considered and analyzed. If such a condition is deemed to be credible, it will be further investigated using the Monte Carlo N-Particle (MCNP) transport code. If the results of these simulations show that a k eff larger than one could be possible, modifications to the assembly will be made until such an event is deemed no longer possible.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

COMPUTATIONAL MODELING OF IGNITION AND PREMIXED FLAME PROPAGATION INITIATED BY A PRE-CHAMBER TURBULENT JET

Addressing the pressing need for reduced carbon emissions, Turbulent Jet Ignition (TJI) emerges as a promising technology for ultra-lean combustion, offering enhanced thermal efficiencies and minimized cyclic variability in spark-ignited engines. To facilitate rapid testing and integration of this technology, a robust computational modeling framework is crucial. This study delves into the predictive capabilities of computational models for main-chamber ignition and premixed flame propagation using a single-cycle TJI rig measured by Biswas et al. (Applied Thermal Engineering, vol 106, 2016). Employing an open-source compressible flow simulation solver with Large Eddy Simulation (LES) for turbulence modeling, the investigation integrates the conventional Laminar Finite Rate Chemistry (LFRC) model alongside the transported Probability Density Method (PDF) for turbulence-chemistry interaction. A fully-consistent Eulerian Monte-Carlo Fields (EMCF) method is utilized to approximate the transported PDF, while Interaction by Exchange with Mean is employed to close micro-mixing terms in stochastic differential equations. A reduced chemical reaction mechanism with 21 species and 84 reactions (DRM-19) is used for solving chemical kinetics, and a double Gaussian energy deposition model is used to approximate the spark ignition in the pre-chamber. An unstructured O-grid mesh with 0.3 million cells in the prechamber and 1 million cells in the main chamber is employed. Results are divided into two phases: pre-chamber initialization and full TJI simulations. Validation of the predicted pre-chamber flame propagation and the lean ignition in the main-chamber is carried out by using available experimental data. Under quiescent conditions, both the LFRC and transported PDF methods largely underestimate the flame speed and subsequent pressure growth in the pre-chamber. A linear momentum forcing technique is applied to investigate the impact of initial turbulence in the pre-chamber, demonstrating a notable influence on flame propagation. Fine-tuning of the forcing coefficient reproduces the sudden pressure growth observed in the experiment. The experimentally validated pre-chamber simulation serves as the initial condition for the full TJI simulations. It is found that the LFRC model fails to predict lean-ignition in the main-chamber, resulting in a misfiring event. Incorporation of turbulence-chemistry interaction using the transported PDF method substantially improves the prediction of the ignition event in the main-chamber, achieving fair qualitative agreement and quantitative validation of combustion parameters within ±10% of the reported experimental data. The rich simulation results consisting of a full set of statistical description of the thermo-chemical states enable us to gain deep insights into the ignition mechanisms in the main chamber, which is limited when done experimentally. A novel dual ignition phenomenon is revealed in the TJI rig for the first time. Initially, a primary ignition kernel is formed at a downstream location which eventually detaches from the main jet. As the jet momentum decreases, a secondary ignition event follows, this time at a more upstream location which eventually combines with the primary ignition kernel to form a single connected flame front. Investigation of these ignition sequences in chemical composition space reveal distinct differences between the two. The primary ignition event in the main-chamber is followed by a large concentration of active radicals from the pre-chamber jet, accelerating the chain-branching steps, characterizing what has been referred to as flame ignition. In contrast, the secondary ignition occurs in the absence of active radicals in the pre-chamber jet, hence characterized as jet ignition. Further analysis of the effect of pre-chamber jet characteristics on lean ignition in the main-chamber is conducted by setting up cases with different initial pressure ratios (por) between the two chambers, a non-dimensional parameter, ranging from 1.2 to 3.2. As the initial pressure ratio increases, jet momentum increases, with dual ignition observed in cases above por= 2.2. Case with por= 3.2 lead to misfiring. The effect of ignition sequence on global combustion characteristics of TJI is analyzed. Dual ignition events lead to non-monotonicity in combustion characteristics such as global reaction progress variable, flame penetration, and global heat release rate. In dual ignition events, although the rate of fuel consumption and global heat release rate is initially lower, the secondary ignition leads to a sudden increase in flame surface area, resulting in a sudden jump and promoting the overall performance of the TJI system.

42 ENGINEERING↗