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At least 289 records · Page 16

Developing a Coal to Products Technology Portfolio

At Ramaco Carbon we are working to bring into existence a new carbon economy with the mottos “coal is too valuable to burn” and “no molecule left behind.” Our research focus is using coal (carbon ore) as a feedstock for a variety of high-value carbon products. We have developed a process and manufacturing technology portfolio including carbon fiber, porous carbons, nano-structured carbons (bulk graphene), building products, monolayer graphene, and rare earth elements (REEs). A review of these product lines, the associated processes, and economics will provide insight into the value of carbon ore as a feedstock for high-value and specialty products. We will present our current progress in manufacturing and tailoring the properties of porous carbons and nano-structured carbon to enhance existing products and produce novel products. Included is a discussion of the properties of carbon fiber derived from direct liquefaction of sub-bituminous coal, and from pitches produced by pyrolysis and solvation by supercritical CO2. New processes for converting carbon ore into structural building materials and monolayer graphene and the evaluation of REE deposits in a Powder River Basin thermal coal reserve will also be described. The presentation will provide a review of our carbon ore to products technology portfolio and the economic advantages of using carbon ore as a feedstock for advanced carbon products and several associated end use applications.

01 COAL, LIGNITE, AND PEAT↗

Developing a Coal to Products Technology Portfolio

At Ramaco Carbon we are working to bring into existence a new carbon economy with the mottos “coal is too valuable to burn” and “no molecule left behind.” Our research focus is using coal (carbon ore) as a feedstock for a variety of high-value carbon products. We have developed a process and manufacturing technology portfolio including carbon fiber, porous carbons, nano-structured carbons (bulk graphene), building products, monolayer graphene, and rare earth elements (REEs). A review of these product lines, the associated processes, and economics will provide insight into the value of carbon ore as a feedstock for high-value and specialty products. We will present our current progress in manufacturing and tailoring the properties of porous carbons and nano-structured carbon to enhance existing products and produce novel products. Included is a discussion of the properties of carbon fiber derived from direct liquefaction of sub-bituminous coal, and from pitches produced by pyrolysis and solvation by supercritical CO2. New processes for converting carbon ore into structural building materials and monolayer graphene and the evaluation of REE deposits in a Powder River Basin thermal coal reserve will also be described. The presentation will provide a review of our carbon ore to products technology portfolio and the economic advantages of using carbon ore as a feedstock for advanced carbon products and several associated end use applications.

01 COAL, LIGNITE, AND PEAT↗

Developing mass spectrometric techniques for boundary layer measurement in hypersonic high enthalpy test facilities

Thermodynamic flow properties of gases in the boundary layer or the flowfield have been mainly deduced from pressures and temperatures measured on a model. However, further progress with respect to an understanding of these properties requires a more complete characterization of the layer including determination of the gas composition and chemistry. Most attempts to measure boundary layer chemistry involve the employment of a mass spectrometer and an associated gas sampling system. The three major limiting factors which must be addressed for species measurement in aerothermodynamic investigations on models at reentry stream velocities, are gas sampling effects, instrument limitations, and problems with data acquisition. The present investigation is concerned with a concentrated effort to quantitatively identify and correct for instrument and sampling system effects, and to develop a miniaturized high performance mass spectrometer for on-model real-time analysis of the boundary layer and its associated atmosphere.

Wood, G. M., Jr.↗

Silicates and variability in comets Okazaki-Levy-Rudenko (1989r) and Austin (1989c1)

Comet Okazaki-Levy-Rudenko (1989r) was studied over a wide range of wavelengths from the UV to the submillimeter. Using visual magnitude estimates from the IAU Circulars and reported submillimeter fluxes in conjunction with the thermal infrared spectroscopy and filter photometry, the nature of the grains and the behavior of the comet can be assessed and compared to other comets studied under this program. In addition, preliminary results from a collaborative infrared study of Comet Austin are presented which address the nature of the dust in that comet. Progress on a model for cometary properties and brightness behavior is discussed.

Russell, Ray W.↗

Planetary astronomy

The goal is to use a variety of observational techniques and instruments, and to reduce, interpret, and synthesize ground based astronomical data concerning small bodies in the solar system, especially the asteroids, in order to study the compositions, physical characteristics, population properties, and evolution of these bodies. Progress was made in the following areas: faint asteroid taxonomy survey; photometric geodesy of Main Belt asteroids; and Main Belt and Near Earth Asteroids synthesis studies.

Chapman, C. R.↗

Summary of ionizing radiation analysis on the Long Duration Exposure Facility

The ionizing radiation measurements flown on the Long Duration Exposure Facility (LDEF) were contained in 15 experiments which utilized passive detectors to pursue objectives in astrophysics and to measure the radiation environment and dosimetric quantities. The spacecraft structure became sufficiently radioactive to permit additional important studies. The induced activity allows extensive radiation mapping in the structure, and independent comparison with experiment dosimetric techniques, and significant studies of secondary effects. The long exposure time, attitude stability, and number and types of measurements produced a unique and critical set of data for low Earth orbit that will not be duplicated for more than a decade. The data allow an unprecedented test, and improvement if required, of models of the radiation environment and the radiation transport methods that are used to calculate the internal radiation and its effects in spacecraft. Results of measurements in the experiments, as well as from radioactivity in the structure, have clearly shown effects from the directional properties of the radiation environment, and progress was made in the dosimetric mapping of LDEF. These measurements have already influenced some Space Station Freedom design requirements. Preliminary results from experiments, reported at this symposium and in earlier papers, show that the 5.8 years exposure considerably enhanced the scientific return of the radiation measurements. The early results give confidence that the experiments will make significant advances in the knowledge of ultra heavy cosmic rays, anomalous cosmic rays, and heavy ions trapped in the radiation belts. Unexpected phenomena were observed, which require explanation. These include stopping iron group ions between the energy ranges anticipated for anomalous and galactic cosmic rays in the LDEF orbit. A surprising concentration of the Be-7 nuclide was discovered on the 'front' surface of LDEF, apparently transported up from the stratosphere with exceptional efficiency.

Parnell, T. A.↗

Development of silicon nitride rotors for the ATTAP program at Garrett Ceramic Components

The development and fabrication of reliable high temperature-high strength silicon nitride rotors by Garrett Ceramic Components (GCC) for the Advanced Turbine Technology Applications Project (ATTAP) is discussed. GCC's progress will be presented, including mechanical properties characterization, in-process monitoring development, and extensive NDE analysis. The current status of material, process, and part properties of the rotors being developed will be compared to properties required for implementation and successful operation of advanced gas turbine engines at 2500 F.

Busovne, B. J., Jr.↗

Electrostatic levitation technology for thermophysical properties of molten materials

Measurements of thermophysical properties of undercooled liquids often require some kind of levitator which isolates samples from container walls. We introduce in this presentation a high temperature/high vacuum electrostatic levitator (HTHVESL) which promises some unique capabilities for the studies of thermophysical properties of molten materials. Although substantial progress has been made in the past several months, this technology is still in the development stage, therefore, in this presentation we only focus on the present state of the HTHVESL(1) and point out other capabilities which might be realized in the near future.

Rhim, Won-Kyu↗

Processing of IN-718 Lattice Block Castings

Recently a low cost casting method known as lattice block casting has been developed by JAM Corporation, Wilmington, Massachusetts for engineering materials such as aluminum and stainless steels that has shown to provide very high stiffness and strength with only a fraction of density of the alloy. NASA Glenn Research Center has initiated research to investigate lattice block castings of high temperature Ni-base superalloys such as the model system Inconel-718 (IN-718) for lightweight nozzle applications. Although difficulties were encountered throughout the manufacturing process , a successful investment casting procedure was eventually developed. Wax formulation and pattern assembly, shell mold processing, and counter gravity casting techniques were developed. Ten IN-718 lattice block castings (each measuring 15-cm wide by 30-cm long by 1.2-cm thick) have been successfully produced by Hitchiner Gas Turbine Division, Milford, New Hampshire, using their patented counter gravity casting techniques. Details of the processing and resulting microstructures are discussed in this paper. Post casting processing and evaluation of system specific mechanical properties of these specimens are in progress.

Hebsur, Mohan G.↗

NASA Tech Briefs, December 2008

Topics covered include: Crew Activity Analyzer; Distributing Data to Hand-Held Devices in a Wireless Network; Reducing Surface Clutter in Cloud Profiling Radar Data; MODIS Atmospheric Data Handler; Multibeam Altimeter Navigation Update Using Faceted Shape Model; Spaceborne Hybrid-FPGA System for Processing FTIR Data; FPGA Coprocessor for Accelerated Classification of Images; SiC JFET Transistor Circuit Model for Extreme Temperature Range; TDR Using Autocorrelation and Varying-Duration Pulses; Update on Development of SiC Multi-Chip Power Modules; Radio Ranging System for Guidance of Approaching Spacecraft; Electromagnetically Clean Solar Arrays; Improved Short-Circuit Protection for Power Cells in Series; Electromagnetically Clean Solar Arrays; Logic Gates Made of N-Channel JFETs and Epitaxial Resistors; Improved Short-Circuit Protection for Power Cells in Series; Communication Limits Due to Photon-Detector Jitter; System for Removing Pollutants from Incinerator Exhaust; Sealing and External Sterilization of a Sample Container; Converting EOS Data from HDF-EOS to netCDF; HDF-EOS 2 and HDF-EOS 5 Compatibility Library; HDF-EOS Web Server; HDF-EOS 5 Validator; XML DTD and Schemas for HDF-EOS; Converting from XML to HDF-EOS; Simulating Attitudes and Trajectories of Multiple Spacecraft; Specialized Color Function for Display of Signed Data; Delivering Alert Messages to Members of a Work Force; Delivering Images for Mars Rover Science Planning; Oxide Fiber Cathode Materials for Rechargeable Lithium Cells; Electrocatalytic Reduction of Carbon Dioxide to Methane; Heterogeneous Superconducting Low-Noise Sensing Coils; Progress toward Making Epoxy/Carbon-Nanotube Composites; Predicting Properties of Unidirectional-Nanofiber Composites; Deployable Crew Quarters; Nonventing, Regenerable, Lightweight Heat Absorber; Miniature High-Force, Long-Stroke SMA Linear Actuators; "Bootstrap" Configuration for Multistage Pulse-Tube Coolers; Reducing Liquid Loss during Ullage Venting in Microgravity; Ka-Band Transponder for Deep-Space Radio Science; Replication of Space-Shuttle Computers in FPGAs and ASICs; Demisable Reaction-Wheel Assembly; Spatial and Temporal Low-Dimensional Models for Fluid Flow; Advanced Land Imager Assessment System; Range Imaging without Moving Parts.

Source record↗

Megawatt upgrade of NuMI target system

Fermilab operates the world’s highest power neutrino target system, called the Neutrinos at the Main Injector (NuMI) to provide intense neutrino flux to the NuMI Off-axis $\nu_{\mu}$ Appearance (NOvA) near and far neutrino detectors to reveal mysterious property of neutrinos. We report a progress of the NuMI beam power upgrade plan at Fermilab to transport a 1-Mega Watt (MW) proton beam to the high power neutrino target. The latest beam power record is 870 kW in Fall 2021.

Yonehara, Katsuya↗

Designing Secure and Resilient Cyber-Physical Systems Using Formal Models

This work-in-progress paper proposes a design methodology that addresses the complexity and heterogeneity of cyber-physical systems (CPS) while simultaneously proving resilient control logic and security properties. The design methodology involves a formal methods-based approach by translating the complex control logic and security properties of a water flow CPS into timed automata. Timed automata are a formal model that describes system behaviors and properties using mathematics-based logic languages with precision. Due to the semantics that are used in developing the formal models, verification techniques, such as theorem proving and model checking, are used to mathematically prove the specifications and security properties of the CPS. This work-in-progress paper aims to highlight the need for formalizing plant models by creating a timed automata of the physical portions of the water flow CPS. Extending the time automata with control logic, network security, and privacy control processes is investigated. The final model will be formally verified to prove the design specifications of the water flow CPS to ensure efficacy and security.

42 ENGINEERING↗

Controlling Nanoparticle Orientations in the Self-Assembly of ‘Patchy’ Quantum Dot-Gold Heterostructural Nanocrystals

Self-assembly of nanocrystals is a promising route for creating macroscale materials that derive function from the properties of their nanoscale building blocks. While much progress has been made assembling nanocrystals into different superlattices, controlling the relative orientations of nanocrystals in those lattices remains a challenge. Here, we combine experiments with computer simulations to study the self-assembly of patchy heterostructural nanocrystals (HNCs), consisting of near-spherical quantum dots decorated with regular arrangements of small gold satellites, into close-packed superlattices with pronounced orientational alignment of HNCs. Our simulations indicate that the orientational alignment is caused by van der Waals interactions between gold patches and is sensitive to the interparticle distance in the superlattice. We demonstrate experimentally that the degree and type of orientational alignment can be controlled by changing ligand populations on HNCs. This study provides guidance for the design and fabrication of nanocrystal superlattices with enhanced structural control.

ZHu, Hua↗

High Volume Fraction Carbon Nanotube Composites for Aerospace Applications

Reported mechanical properties of carbon nanotubes (CNTs) at the nanoscale suggest their potential to enable significantly lighter structures of interest for space applications. However, their utility depends on the retention of these properties in bulk material formats that permit practical fabrication of large structures. This presentation summarizes recent progress made to produce carbon nanotube composites with specific tensile properties that begin to rival those of carbon fiber reinforced polymer composites. CNT content in these nanocomposites was greater than 70% by weight. Tested nanocomposite specimens were fabricated from kilometers or tens of square meters of CNT, depending on the starting material format. Processing methods to yield these results, and characterization and testing to evaluate the performance of these composites will be discussed. The final objective is the demonstration of a CNT composite overwrapped pressure vessel to be flight tested in the Fall of 2016.

Siochi, E. J.↗

Pressure-Induced Bandgap Optimization in Lead-Based Perovskites with Prolonged Carrier Lifetime and Ambient Retainability

Bond length and bond angle exhibited by valence electrons is essential to the core of chemistry. Using lead-based organic–inorganic perovskite compounds as an exploratory platform, it is demonstrated that the modulation of valence electrons by compression can lead to discovery of new properties of known compounds. Yet, despite its unprecedented progress, further efficiency boost of lead-based organic–inorganic perovskite solar cells is hampered by their wider bandgap than the optimum value according to the Shockley–Queisser limit. By modulating the valence electron wavefunction with modest hydraulic pressure up to 2.1 GPa, the optimized bandgap for single-junction solar cells in lead-based perovskites, for the first time, is achieved by narrowing the bandgap of formamidinium lead triiodide (HC(NH 2 ) 2 PbI 3 ) from 1.489 to 1.337 eV. Strikingly, such bandgap narrowing is partially retained after the release of pressure to ambient, and the bandgap narrowing is also accompanied with double-prolonged carrier lifetime. With First-principles simulation, this work opens a new dimension in basic chemical understanding of structural photonics and electronics and paves an alternative pathway toward better photovoltaic materials-by-design.

14 SOLAR ENERGY↗

Nanoscale properties of lead halide perovskites by scanning tunneling microscopy

Since the introduction of lead halide perovskites, tremendous progress has been made regarding their stability, reproducibility and durability. However, one of the issues that remains is related to the interfacial atomic structure arrangement and structure-property relationship under optical and electrical stimuli. In this critical review, we highlight the recent progress using scanning tunneling microscopy (STM) to understand the nanoscale properties and dynamic processes occurring in these halide perovskite materials. STM is known to be a very challenging technique, which is reflected by the low number of relevant publications in the last years. These initial reports mirror the unique potential of STM to give Ångstrom-scale insight into the (opto)-electronic properties, morphology and underlying electronic structure and provide a path toward harnessing the full potential of these materials. However, care must be taken to understand the effects of the perturbations caused by STM and tailor the measurement conditions accordingly.

36 MATERIALS SCIENCE↗