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At least 289 records · Page 16

Olivines in angrite LEW 87051: Phenos or xenos

Nyquist et al. recently reported the presence of live Mn-53 in angrite LEW 86010 when it crystallized. Hence, melting must have occurred within approx. 10 Ma of the accretion of the angrite parent body, and LEW 86010 is the oldest known differentiated meteorite. This discovery has made it even more desirable to understand teh petrogenesis of angrites, which presumably were all formed at a similar time. As part of the continuing work on angrite petrogenesis, crystallization experiments were conducted on LEW 87051, the other Antarctic angrite, to clarify its petrogenesis. Several aspects of the experimental work is reported. Although the details are not understood, it is clear that the Cr abundance in the experimental olivines must be controlled by spinel crystallization.

Mckay, G.↗

The distribution of olivine in the crater Copernicus

Multispectral imaging in the visible and near-IR at four wavelengths (0.73, 0.96, 1.45, and 1.99 micron) of Copernicus crater has been used to map the distribution of olivine-rich, pyroxene-poor material known previously to occur in the central peak complex. Three additional portions of the crater exhibit spectral characteristics similar to those of the central peaks, strongly suggesting the presence of material similar to that exposed in the central peaks. These areas are a scarp forming a portion of the northern rim of Copernicus, and two slump blocks in the north wall which may have been derived from the same portion of the ejecta now exposed in the rim scarp. These occurrences decrease the minimum allowable depth for this unusual material in the Copernicus target site though still represent some of the deepest material exposed by Copernicus.

Lucey, Paul G.↗

The effect of oxygen fugacity on the partitioning of nickel and cobalt between olivine, silicate melt, and metal

The effect of oxygen fugacity, f(O2), on the partitioning behavior of Ni and Co between olivine, silicate melt, and metal was investigated in the CaO-MgO-Al2O3-SiO2-FeO-Na2O system, an analogue of a chondrule composition from an ordinary chondrite. The conditions were 1350 C and 1 atm, with values of f(O2) varying between 10 exp -5.5 and 10 exp -12.6 atm (i.e., the f(O2) range relevant for crystal/liquid processes in terrestrial planets and meteorite parent bodies). Results of chemical analysis showed that the values of the Ni and Co partitioning coefficients begin to decrease at values of f(O2) that are about 3.9 log units below the nickel-nickel oxide and cobalt-cobalt oxide buffers, respectively, near the metal saturation for the chondrule analogue composition.

Ehlers, Karin↗

Chemical and isotopic constraints on the formation and crystallization of SA-1, a basaltic Allende plagioclase-olivine inclusion

Results are presented of a detailed petrologic, chemical, and Mg-isotope study of SA-1, a basaltic Allende plagioclase-olivine inclusion. The chemical and isotopic data were used to identify the signatures of nebular vs. planetary processes and to determine if SA-1 contains a component produced by planetary differentiation. It was found that the results of major-element and trace-element abundances in SA-1 are inconsistent with its formation as a mixture of nebular materials. It is suggested that SA-1 contains a chemically fractionated component produced by igneous differentiation.

Kennedy, Allen K.↗

On high-temperature formation of iron-rich olivine in the early solar system

A kinetic restriction on the formation of fayalite-rich olivine in equilibrium with the cooling solar-composition gas appears to exist at the low temperature of approximately 500 K. We offer a high-temperature formation mechanism (different from simple condensation) which operates at high hydrogen depletion (up to 300 times) relative to solar abundance. We show how the necessary depletion rate decreases with temperature (thermodynamical equilibrium is suggested). The consequences for planet formation are considered.

Dorofeyeva, V. A.↗

Experimental segregation of iron-nickel metal, iron-sulfide, and olivine in a thermal gradient: Preliminary results

Speculation about the possible mechanisms for core formation in small asteroids raises more questions than answers. Petrologic evidence from iron meteorites, pallasites, and astronomical observations of M asteroids suggests that many small bodies were capable of core formation. Recent work by Taylor reviews the geochemical evidence and examines the possible physical/mechanical constraints on segregation processes. Taylor's evaluation suggests that extensive silicate partial melting (preferably 50 vol. percent or greater) is required before metal can segregate from the surrounding silicate and form a metal core. The arguments for large degrees of silicate partial melting are two-fold: (1) elemental trends in iron meteorites require that the metal was at is liquidus; and (2) experimental observations of metal/sulfide inclusions in partially molten silicate meteorites show that the metal/sulfide tends to form spherules in the liquid silicate due to surface tension effects. Taylor points out that for these metal spherules to sink through a silicate mush, high degrees of silicate partial melting are required to lower the silicate yield strength. Although some qualitative experimental data exists, little is actually known about the behavior of metals and liquid sulfides dispersed in silicate systems. In addition, we have been impressed with the ability of cumulative olivine to expel trapped liquid when placed in a thermal gradient. Consequently, we undertook to accomplish the following: (1) experimentally evaluate the potential for metal/sulfide/silicate segregation in a thermal gradient; and (2) obtain quantitative data of the wetting parameters of metal-sulfide melts among silicate grains.

Jurewicz, Stephen R.↗

Water in Earth's mantle: Hydrogen analysis of mantle olivine, pyroxenes and garnet using the SIMS

Hydrogen (or water) in the Earth's interior plays a key role in the evolution and dynamics of the planet. However, the abundance and the existence form of the hydrogen have scarcely been clear in practice. Hydrogen in the mantle was incorporated in the interior during the formation of the Earth. The incorporated hydrogen was hardly possible to concentrate locally inside the Earth considering its high mobility and high reactivity. The hydrogen, preferably, could be distributed homogeneously over the mantle and the core by the subsequent physical and chemical processes. Therefore, hydrogen in the mantle could be present in the form of trace hydrogen in nominally anhydrous mantle minerals. The hydrogen and the other trace elements in mantle olivines, orthopyroxenes, clinopyroxenes, and garnets were determined using secondary ion mass spectrometry (SIMS) for elucidating (1) the exact hydrogen contents, (2) the correlation between the hydrogen and the other trace elements, (3) the dependence of the hydrogen contents on the depth, and (4) the dependence of the whole rock water contents on the depth.

Kurosawa, Masanori↗

Diffuse reflectance spectra of orthopyroxene, olivine, and plagioclase as a function of composition and structure

Although many similarities exist between meteorite spectra and 'primitive' asteroids, there are unexplained discrepancies. These discrepancies do not appear to arise from grain size effects. Assuming that primitive meteorites did in fact originate from the 'primitive' asteroids, we believe that there are two testable explanations for the observed spectral discrepancies: compositional or structural differences. We have begun to synthesize and collect reflectance and Mossbauer spectra of pertinent materials, beginning with olivine, pyroxene, and plagioclase (all found in primitive meteorites), and to assess the possible effects composition may have on spectral features. Our study focuses on the combination of composition and structural effects.

Zolensky, M. E.↗

Heterogeneity in small aliquots of Apolllo 15 olivine-normative basalt: Implications for breccia clast studies

Most of the recent advances in lunar petrology are the direct result of breccia pull-apart studies, which have identified a wide array of new highland and mare basalt rock types that occur only as clasts within the breccias. These rocks show that the lunar crust is far more complex than suspected previously, and that processes such as magma mixing and wall-rock assimilation were important in its petrogenesis. These studies are based on the implicit assumption that the breccia clasts, which range in size from a few mm to several cm across, are representative of the parent rock from which they were derived. In many cases, the aliquot allocated for analysis may be only a few grain diameters across. While this problem is most acute for coarse-grained highland rocks, it can also cause considerable uncertainty in the analysis of mare basalt clasts. Similar problems arise with small aliquots of individual hand samples. Our study of sample heterogeneity in 9 samples of Apollo 15 olivine normative basalt (ONB) which exhibit a range in average grain size from coarse to fine are reported. Seven of these samples have not been analyzed previously, one has been analyzed by INAA only, and one has been analyzed by XRF+INAA. Our goal is to assess the effects of small aliquot size on the bulk chemistry of large mare basalt samples, and to extend this assessment to analyses of small breccia clasts.

Lindstrom, Marilyn M.↗

Compositional variations of olivines and pyroxenes in chondritic interplanetary dust particles

It is commonly held that hydrated interplanetary dust particles (IDP's) experienced aqueous alteration on hydrous asteroids, while the anhydrous IDP's could be derived from the more primitive asteroids and comets. We wish to discover whether the anhydrous IDPs are actually from the same parent body, being related by aqueous alteration of one to produce the other. We report here analyses of olivines and pyroxenes, and petrofabrics of 27 chondritic IDP's, comparing those from anhydrous and hydrous types. Based on mineralogical evidence, we find that hydrous and anhydrous IDP's are, in general, not directly related.

Zolensky, Michael E.↗

Implications for the evolution of chondrules from Agglomeratic olivine chondrules

There is considerable evidence that chondrules formed by the melting of solid materials and, by default, the early solar nebula is the preferred location for chondrule formation. Agglomeratic olivine (AO) chondrules supply perhaps the most intriguing, direct evidence for chondrule formation from agglomeration of solids. We review the characteristics of AO chondrules and discuss their implications for understanding chondrule precursors and chondrule evolution.

Weisberg, M. K.↗

Forsteritic Olivine Grains in Unequilibrated Ordinary Chondrites: Additional Evidence for a Link Between Ordinary and Carbonaceous Chondrites

We report mineral-chemical and Secondary Ion Mass Spectrometry (SIMS) oxygen-isotopic studies of forsteritic olivine grains from various Unequilibrated Ordinary Chondrites (UOCs). Our studies provide additional evidence for a genetic link between ordinary and carbonaceous chondrites and between various lithologies in these meteorites.

Ruzicka, A.↗

A Parent Magma for the Nakhla Martian Meteorite: Reconciliation of Estimates from 1-Bar Experiments, Magmatic Inclusions in Olivine, and Magmatic Inclusions in Augite

The composition of the parent magma for the Nakhla (martian) meteorite has been estimated from mineral-melt partitioning and from magmatic inclusions in olivine and in augite. These independent lines of evidence have converged on small range of likely compositions. Additional information is contained in the original extended abstract.

Treiman, Allan H.↗