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At least 289 records · Page 16
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Impact of undoped substrates on high performance silicon solar cells

Today's highest-efficiency silicon solar cells typically operate near the threshold between low-level and high-level injection. It is not well understood if pushing further into a regime in which the cell operating point is solidly in high-level injection at all times of the day has further benefits for the solar cell performance. From a reliability perspective, cells fabricated on lower doped silicon have a larger breakdown voltage. This advantage can affect the design of modules allowing higher voltages and a relaxation of the number of bypass diodes needed. In this project, we present a comprehensive assessment, both experimental and using simulation, of how bulk resistivity, light intensity, and operation temperature impact the performance of the silicon solar cell. This work incorporates a comprehensive device physics analysis assisted by numerical simulation. The source code is now available under General Public License (GPL3), and to further leverage the findings of this project and outreach people outside of the scientific community, we are working with www.pveducation.org (which receives >1 million visitors a year) to create interactive content using our simulation results. The simulation results indicate that high bulk resistivity wafers (>>10 Ωcm) require bulk Shockley-Read-Hall (SRH) lifetimes in the millisecond range to outperform wafers with standard bulk resistivities (<10 Ωcm). Additionally, above bulk resistivities of 10 Ωcm (the exact value depends on the bulk characteristics of the wafer), the cell efficiency is weakly dependent on the bulk resistivity. As a result, ingot manufactures may have an opportunity to further reduce wafer cost by growing higher resistivity ingots that are more tolerant to resistivity variations. This project is particularly relevant today, as solar cell architectures with improved surface passivation and milliseconds lifetimes wafers are commercially available, leveraging potential benefits of using higher bulk resistivities. Outside of interdigitated back contact (IBC) cell, reported studies on high resistivity silicon (>100 Ωcm) are very limited. To the best of our knowledge, this project provides for the first-time experimental insight on solar cells fabricated on wafers with bulk resistivities up to several thousand Ωcm, delivering a comprehensive vision of their performance under real-world temperature and light intensity operation conditions. We manufactured and characterized solar cells with bulk resistivities in the range of 1 Ωcm to >15k Ωcm. Under standard testing conditions (STC), we measured solar cells efficiencies over 20% over the entire range of bulk resistivities, using our baseline cell processing. To evaluate the cell performance in real-world operation conditions, the solar cells were measured at different temperatures (25-80°C) and at different light intensities (0.1-1 suns). The measurements show that the bulk resistivity does not impact the solar cell response to temperature and light intensity. Similar thermal coefficients (TC) were measured for standard and high bulk resistivities, and they are comparable with the TC values reported in the literature for standard bulk resistivities <10 Ωcm. After light soaking, the solar cell didn’t show signs of light-induced degradation (LID). This result was expected since n-type float zone (FZ) wafers were used in this work, i.e. low traces of boron and low concentration of oxygen (oxygen is typically found in the seed end of Czochralski (CZ) ingots). We measured for high bulk resistivities (>10 Ωcm) extremely high breakdown voltages (>1000V). In conclusion, the insight provided by this project can positively impact the levelized cost of energy (LCOE) of the photovoltaic systems through its effect on cell and ingot manufacturing yield, silicon cell power output, and module reliability.

14 SOLAR ENERGY↗
DOE OSTI2023

Elimination of QCD Renormalization Scale and Scheme Ambiguities

The setting of the renormalization scale (μ r ) in the perturbative QCD (pQCD) is one of the crucial problems for achieving precise fixed-order pQCD predictions. The conventional prescription is to take its value as the typical momentum transfer Q in a given process, and theoretical uncertainties are then evaluated by varying it over an arbitrary range. The conventional scale-setting procedure introduces arbitrary scheme-and-scale ambiguities in fixed-order pQCD predictions. The principle of maximum conformality (PMC) provides a systematic way to eliminate the renormalization scheme-and-scale ambiguities. The PMC method has rigorous theoretical foundations; it satisfies the renormalization group invariance (RGI) and all of the self-consistency conditions derived from the renormalization group. The PMC has now been successfully applied to many physical processes. In this paper, we summarize recent PMC applications, including event shape observables and heavy quark pair production near the threshold region in e + e – annihilation and top-quark decay at hadronic colliders. In addition, estimating the contributions related to the uncalculated higher-order terms is also summarized. These results show that the major theoretical uncertainties caused by different choices of μ r are eliminated, and the improved pQCD predictions are thus obtained, demonstrating the generality and applicability of the PMC.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
NASA NTRS1966

Theory and Practical Design of Phase-locked Receivers, Volume I

This is Volume I of a two-volume work on the theory, of phase-locked receivers, with pertinent reference material on practical receiver design. Volume I is primarily devoted to the performance of carrier-tracking loops, including a rigorous treatment of narrow-band systems having IF limiters. The bulk of the work is based on a theoretical linear model, but a nonlinear method is also presented to predict behavior near the threshold. The emphasis throughout the work is toward completeness, simplicity, and internal consistency of the material assembled. Part I of this Volume is an exposition of the theory, the resulting equations, and the design philosophy that have enabled the phase-lock concept to evolve into the basic principle underlying the most sensitive receivers il, the world today. Part II is a condensed version of Part I, intended as a quick reference to formulas, definitions, and salient design considerations.

RECEIVER↗
NASA NTRS1970

Photoionization mass spectrometer

Photoionization source with a vacuum UV monochromator is used in ion reaction kinetics. Monochromator passes only the photon energies near the threshold of the selected ionization process. Absence of electron impact alleviates creation of different type ions that result in ion fragmentation.

Warneck, P.↗
NASA NTRS1973

A working list of meteor streams

The list is restricted to meteor streams that do exist; included are six streams with activity near the threshold of detection by photography not related to any known comet and not shown to be active for as long as a decade.

Cook, A. F.↗
NASA NTRS1975

Detection of the isotopes of heavy cosmic ray nuclei

A counter telescope designed to detect and resolve the isotopic composition of cosmic ray nuclei heavier than neon is being prepared. The telescope consists of a rather conventional charge measuring array using two scintillator elements and two solid Cerenkov radiators of differing refractive index. The mass measurement is obtained by combining the velocity information from one or both of the Cerenkov radiators operating near their threshold with residual range measured in a block of nuclear emulsion. Path length corrections and particle location in the emulsions is provided by a spark chamber fired in coincidence with potentially suitable particles. The telescope has a geometry factor of 530 sq cm sr roughly. It should be able to resolve the isotopes of iron over the energy range of 300 to 720 Mev/n and those of neon over 300 to 400 MeV/n. The expected response and characteristics of the telescope are described in detail and the sensitivity to rare isotopes discussed.

Gilman, C. M.↗
NASA NTRS1985

Cone formation as a result of whisker growth on ion bombarded metal surfaces

It is shown experimentally that the seed metals which can cause cone development on ion bombarded metal targets need not to have a lower sputtering yield as widely believed but rather a higher melting point. By lowering the bombarding ion energy to near sputtering threshold values (less than 100 eV) the growth of genuine single crystal whiskers which point in all directions not related to the direction of ion incidence is observed. It is concluded that (intentional or unintentional) seed cones are the result of an interplay among whisker growth, surface movement of atoms, and the effects of sputtering.

Wehner, G. K.↗
NASA NTRS1986

The production of CO(+) (B2Sigma +) from dissociative photoionization excitation of CO2

The dissociative photoionization excitation process in CO2 is studied. In contrast to previous studies, attention is focused on the vibrational and rotational levels produced in fragment ions, partial cross-section measurements for producing such fragment ions in a specific quantum state, and the mechanisms that govern the dissociative ionization excitation processes. The partial fluorescence cross section for the production of CO(+) (B2Sigma +) from CO2 over a wide wavelength range was measured. It is concluded that the production of the CO(+) (B2Sigma +) fragment near the threshold is through a direct dissociative photoionization process.

Wu, C. Y. R.↗
NASA NTRS1987

Fixed lag smoothers for carrier phase and frequency tracking

The application of fixed lag smoothing algorithms are presented for the problem of estimation of the phase and frequency of a sinusoidal carrier received in the presence of process noise and additive observation noise. A suboptimal structure consists of a phase-locked loop (PLL) followed by a post loop correction to the phase and frequency estimates. When the PLL is operating under a high signal-to-noise ratio, the phase detector is approximately linear, and the smoother equations then correspond to the optimal linear equations for an equivalent linear signal model. The performance of such a smoother can be predicted by the linear filtering theory. However, if the PLL is operating near the threshold region of the signal to noise ratio, the phase detector cannot be assumed to be linear. Then the actual performance of the smoother can significantly differ from that predicted by linear filtering theory. Both the theoretical and simulated performance of such smoothers derived on the basis of various models for the phase of frequency processes are presented.

Kumar, R.↗
NASA NTRS1987

Measurement of electron-impact excitation in boronlike carbon

The cross section for the electron-impact excitation of C(+) (2s2 2p 2P0)-(2s2p2 2D) is measured in a colliding-beams apparatus for several collision energies near the threshold for the process. A cross section of (1.1 + or - 0.3) x 10 to the -16th sq cm at threshold is found. Reasonable agreement is found with close-coupling calculations.

Lafyatis, G. P.↗
NASA NTRS1987

Optimum filters and smoothers design for carrier phase and frequency tracking

The report presents the application of fixed lag smoothing algorithms to the problem of estimation of the phase and frequency of a sinusoidal carrier received in the presence of process noise and additive observation noise. A suboptimal structure consists of a phase-locked loop (PLL) followed by post-loop correction to the phase and frequency estimates. When the PLL is operating under high signal-to-noise ratio, the phase detector is approximately linear, and the smoother equations then correspond to the optimal linear equations for an equivalent linear signal model. The performance of such a smoother can be predicted by linear filtering theory. However, if the PLL is operating near the threshold region of the signal-to-noise ratio, the phase detector cannot be assumed to be linear. Then the actual performance of the smoother can significantly differ from that predicted by linear theory. In this report we present both the theoretical and simulated performance of such smoothers derived on the basis of various models for the phase and frequency processes.

Kumar, Rajendra↗
NASA NTRS1987

Intracavity absorption with a continuous wave dye laser - Quantification for a narrowband absorber

An experimental investigation of the dependence of intracavity absorption on factors including transition strength, concentration, absorber path length, and pump power is presented for a CW dye laser with a narrow-band absorber (NO2). A Beer-Lambert type relationship is found over a small but useful range of these parameters. Quantitative measurement of intracavity absorption from the dye laser spectral profiles showed enhancements up to 12,000 (for pump powers near lasing threshold) when compared to extracavity measurements. The definition of an intracavity absorption coefficient allowed the determination of accurate transition strength ratios, demonstrating the reliability of the method.

Brobst, William D.↗
NASA NTRS1991

Modeling of life limiting phenomena in the discharge chamber of an electron bombardment ion thruster

An experimental facility to study the low energy sputtering of metal surfaces with ions produced by an ion gun is described. The energy of the ions ranged from 10 to 500 eV. Cesium ions with energies from 100 to 500 eV were used initially to characterize the operation of the ion gun. Next, argon and xenon ions were used to measure the sputtering yields of cobalt (Co), Cadmium (Cd), and Chromium (Cr) at an operating temperature of 2x10(exp -5) Torr. The ion current ranged from 0.0135 micro-A at 500 eV. The targets were electroplated on a copper substrate. The surface density of the electroplated material was approx. 50 micro-g/sq cm. The sputtered atoms were collected on an aluminum foil surrounding the target. Radioactive tracers were used to measure the sputtering yields. The sputtering yields of Cr were found to be much higher than those of Co and Cd. The yields of Co and Cd were comparable, with Co providing the higher yields. Co and Cd targets were observed to sputter at energies as low as 10 eV for both argon and xenon ions. The Cr yields could not be measured below 20 eV for argon ions and 15 eV for xenon ions. On a linear scale the yield energy curves near the threshold energies exhibit a concave nature.

Handoo, Arvind K.↗
NASA NTRS1992

A simple correction for the Born approximation for electron impact excitation of hydrogenic ions

An analytic procedure is developed for obtaining the electron impact excitation cross sections for hydrogenic ions. A simple modification of the Born approximation, in order to include Coulomb focusing of the continuum wave functions, produces the correct energy dependence of the cross section near excitation threshold. This procedure is used to compute the 1s yields 2s and 1s yields 2p excitation cross sections for hydrogenic ions (Z approaches infinity), and compare these modified-Born cross sections with numerical Colomb-Born calculations. The modified-Born cross sections agree well with the Coulomb-Born cross sections and thus provide a reliable generalized analytic expression for electron impact excitation of hydrogenic ions. By treating effective charges, the results in this work can be extended to nonhydrogenic target systems.

Jung, Young-Dae↗
NASA NTRS1992

Indentation flaw formation and strength response of silicon nitride ceramics at low indentation loads

The configuration and the strength response of indentation flaws in silicon nitrides are described as a function of indentation loads primarily near the threshold level. Test materials under consideration include 30 vol percent SiC whisker-reinforced composite silicon nitride and similar monolithic silicon nitride. The results of strength testing show that, at indentation loads less than or equal to 1.96, a number of the specimens fail from the intrinsic flaws of the materials rather than from the indent sites, causing a distinct trend to reach a plateau, at a level corresponding to the as-received strength of the material. The ratio of the mirror constant to the fracture toughness for the composite and monolithic materials is found to be 1.44 and 1.51, respectively.

Choi, Sung R.↗
NASA NTRS1994

A visual detection model for DCT coefficient quantization

The discrete cosine transform (DCT) is widely used in image compression and is part of the JPEG and MPEG compression standards. The degree of compression and the amount of distortion in the decompressed image are controlled by the quantization of the transform coefficients. The standards do not specify how the DCT coefficients should be quantized. One approach is to set the quantization level for each coefficient so that the quantization error is near the threshold of visibility. Results from previous work are combined to form the current best detection model for DCT coefficient quantization noise. This model predicts sensitivity as a function of display parameters, enabling quantization matrices to be designed for display situations varying in luminance, veiling light, and spatial frequency related conditions (pixel size, viewing distance, and aspect ratio). It also allows arbitrary color space directions for the representation of color. A model-based method of optimizing the quantization matrix for an individual image was developed. The model described above provides visual thresholds for each DCT frequency. These thresholds are adjusted within each block for visual light adaptation and contrast masking. For given quantization matrix, the DCT quantization errors are scaled by the adjusted thresholds to yield perceptual errors. These errors are pooled nonlinearly over the image to yield total perceptual error. With this model one may estimate the quantization matrix for a particular image that yields minimum bit rate for a given total perceptual error, or minimum perceptual error for a given bit rate. Custom matrices for a number of images show clear improvement over image-independent matrices. Custom matrices are compatible with the JPEG standard, which requires transmission of the quantization matrix.

Ahumada, Albert J., Jr.↗
NASA NTRS1994

W134: A new pre-main-sequence double-lined spectroscopic binary

We report the discovery that the pre-main-sequence star Walker 134 in the young cluster NGC 2264 is a double-lined spectroscopic binary. Both components are G stars with strong Li I 6708 A absorption lines. Twenty radial velocity measurements have been used to determined the orbital elements of this system. The orbit has a period of 6.3532 +/- 0.0012 days and is circular within the limits of our velocity resolution; e less than 0.01. The total system mass is stellar mass sin(exp 3) i = 3.16 solar mass with a mass ratio of 1.04. Estimates for the orbit inclination angle and stellar radii place the system near the threshold for eclipse observability; howerver, no decrease in brightness was seen during two attempts at photometric monitoring. The circular orbit of W 134 fills an important gap in the period distribution of pre-main-sequence binaries and thereby constrains the effectiveness of tidal orbital circularization during the pre-main sequence.

Padgett, Deborah L.↗
NASA NTRS1994

What we have learned about Mars from SNC meteorites

The SNC meteorites are thought to be igneous martian rocks, based on their young crystallization ages and a close match between the composition of gases implanted in them during shock and the atmosphere of Mars. A related meteorite, ALH84001, may be older and thus may represent ancient martian crust. These petrologically diverse basalts and ultramafic rocks are mostly cumulates, but their parent magmas share geochemical and radiogenic isotopic characteristics that suggest they may have formed by remelting the same mantle source region at different times. Information and inferences about martian geology drawn from these samples include the following: Planetary differentiation occured early at approximately 4.5 GA, probably concurrently with accretion. The martian mantle contains different abundances of moderately volatile and siderophile elements and is more Fe-rich than that of the Earth, which has implications for its mineralogy, density, and origin. The estimated core composition has a S abundance near the threshold value for inner core solidification. The former presence of a core dynamo may be suggested by remanent magnetization in Shergottite-Nakhlite-Chassignite (SNC) meteorites, although these rocks may have been magnetized during shock. The mineralogy of martian surface units, inferred from reflectance spectra, matches that of basaltic shergottites, but SNC lithologies thought to have crystallized in the subsurface are not presently recognized. The rheological properties of martian magmas are more accurately derived form these metorites than from observations of martian flow morphology, although the sampled range of magma compositions islimited. Estimates of planetary water abundance and the amount of outgassed water based on these meteorites are contridictory but overlap estimates based on geological observations and atmospheric measurements. Stable isotope measurements indicate that the martian hydrosphere experienced only limited exchange with the lithosphere, but it is in isotopic equilibrium with the atmosphere and has been since 1.3 Ga. The isotopically heavy atmosphere/hydrosphere composition deduced from these rocks reflects a loss process more severe than current atmospheric evolution models, and the occurence of carbonates in SNC meteorites suggest that they, rather than scapolite or hydrous carbonates, are the major crustal sink for CO2. Weathering products in SNC meteorites support the idea of limited alteration of the lithosphere by small volumes of saline, CO2-bearing water. Atmospheric composition and evolution are further constrained by noble gases in these meteorites, although Xe and Kr isotopes suggest different origins for the atmosphere. Planetary ejection of these rocks has promoted an advance in the understanding of impact physics, which has been accomplished by a model involving spallation during large cratering events. Ejection of all the SNC meteorites (except ALH84001) in one or two events may provide a plausible solution to most constraints imposed by chronology, geochemistry, and cosmic ray exposure, although problems remain with this scenario; ALH84001 may represent older martian crust sampled during a separate impact.

Mcsween, Harry Y., Jr.↗