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The present invention concerns a new organometallic polymer material containing in part a vanadium-siloxane linkage (V-0-Si), which has excellent resistance to heat and oxidation and a high residue ratio after high temperature treatment in a non-oxidizing atmosphere, for example, nitrogen, argon, helium, ammonia, or hydrogen.
One hypothesis of the origin of pre-modern forms of life is that the original replicating molecules were specific polypeptides which acted as templates for the assembly of poly-Schiff bases complementary to the template, and that these polymers were then oxidized to peptide linkages, probably by photo-produced oxidants. A double cycle of such anti-parallel complementary replication would yield the original peptide polymer. If this model were valid, the Schiff base between an N-acyl alpha mino aldehyde and an amino acid should yield a dipeptide in aqueous solution in the presence of an appropriate oxidant. In the present study it is shown that the substituted dipeptide, N-acetyl-tyrosyl-tyrosine, is produced in high yield in aqueous solution at pH 9 through the action of H2O2 on the Schiff-base complex between N-acetyl-tyrosinal and tyrosine and that a great variety of N-acyl amino acids are formed from amino acids and aliphatic aldehydes under similar conditions.
A new method of screech tone reduction in underexpanded supersonic jets is utilized to determine if the amplitude of screech is related to the level of shock-associated broadband noise. Acoustic measurements show that as the screech tone is reduced, the broadband shock-associated noise may be increased by up to 4dB at some locations. Several experiments were conducted with disturbances put into the flow upstream of the final contraction. Results from these tests support the concept of linkage between the broadband shock noise and screech tones. Some interesting preliminary results were obtained with a disturbance of the flow at several locations downstream of the nozzle. These results are also discussed.
The roles of absolute and relative oxygen uptake (VO2 and percent of muscle group specific VO2-max) as determinants of the cardiovascular and ventilatory responses to exercise over a wide range of active muscle mass are investigated. Experiments were conducted using four types of dynamic exercise: one-arm curl, one-arm cranking, and one and two-leg cycling at four different relative work loads (25, 50, 75, and 100 percent of VO2-max) for the corresponding muscle group. Results show that VO2 during maximal one-arm curl, one-arm cranking, and one-leg cycling averaged 20, 50, and 75 percent, respectively, of that for maximal two-leg cycling. Cardiac output was determined to be linearly related to VO2 with a similar slope and intercept for each type of exercise, and the heart rate at a given percent VO2-max was higher with larger active muscle mass. It is concluded that the cardiovascular responses to exercise was determined to a large extent by the active muscle mass and the absolute oxygen uptake, with the principal feature appearing to be the tight linkage between systematic oxygen transport and utilization.
Hardware, software, and performance features of the Digital Instrumentation and Navigation System (DIANS) designed for NASA research to collect flight data as a strap-down system are detailed. The support software for the system has a cross compiler, a linkage editor, and cross assembler, extended communication capabilities, postflight processing applications, and compilers for PASCAL, FORTRAN, CBASIC and MT. The DIANS microcomputer has a 1 Mbyte RAM module, a fast floating point processor board, a 68000 monoboard computer with 64 RAM, a 128 Kbyte bubble memory card, and a navigation radio. The system also carries a battery for full system operation for over an hour. The support software is also stored on a host mainframe computer, which has a CP/M operating system. Pitch, roll, and heading data are gathered from the on-board system, and communication is possible between the airborne and ground-based computer.
The objective of this contract was to investigate the mechanisms operative in thermal and thermal oxidative degradation of Fomblin Z and hexafluoropropene oxide derived fluids and the effect of alloys and additives upon these processes. The nature of arrangements responsible for the inherent thermal oxidative instability of the Fomblin Z fluids has not been established. It was determined that this behavior was not associated with hydrogen end-groups or peroxy linkages. The degradation rate of these fluids at elevated temperatures in oxidizing atmospheres was found to be dependent on the surface/volume ratio. Once a limiting ratio was reached, a steady rate appeared to be attained. Based on elemental analysis and oxygen consumption data, -CF2OCF2CF2O-, not -CF2CF2O-, is one of the major arrangements present. The action of the M-50 and Ti(4 Al, 4 Mn) alloys was found to be much more drastic in the case of Fomblin Z fluids than that observed for the hexalfuoropropane oxide derived materials. The effectiveness of antioxidation/anticorrosion additives, P-3 and phospha-s-triazine, in the presence of metal alloys was very limited at 316 C; at 288 C the additives arrested almost completely the fluid degradation. The phospha-s-triazine appeared to be at least twice as effective as the P-3 compound; it also protected the coupon better. The Ti(4 Al, 4 Mn) alloy degraded the fluid mainly by chain scission processes; this took place to a much lesser degree with M-50.
A very low-power, low-interference Stirling cryocooler is being developed based on principles and techniques described in several previous publications over the last four years. It differs in several important details from those built previously. It uses a tapered displacer based upon an analytical optimization procedure. The displacer is driven by an auxiliary piston and cylinder (rather than by mechanical linkage) using some of the working fluid itself to provide the driving force. This provides smooth, vibration-free motion, and, more importantly, allows complete mechanical and spatial separation of the cryostat from the pressure-wave generator. Either of two different pressure-wave generators can be used. One is a non-contaminating, unlubricated ceramic piston and cylinder. The other is a compressed-air-operated rubber diaphragm with motor-driven valves to cycle the pressure between appropriate limits.
The success of the Real Time Multiprocessor Operating System (RTMPOS) in the development and evaluation of experimental hardware and software systems for real time interactive simulation of air breathing propulsion systems was evaluated. The Real Time Multiprocessor Operating System (RTMPOS) provides the user with a versatile, interactive means for loading, running, debugging and obtaining results from a multiprocessor based simulator. A front end processor (FEP) serves as the simulator controller and interface between the user and the simulator. These functions are facilitated by the RTMPOS which resides on the FEP. The RTMPOS acts in conjunction with the FEP's manufacturer supplied disk operating system that provides typical utilities like an assembler, linkage editor, text editor, file handling services, etc. Once a simulation is formulated, the RTMPOS provides for engineering level, run time operations such as loading, modifying and specifying computation flow of programs, simulator mode control, data handling and run time monitoring. Run time monitoring is a powerful feature of RTMPOS that allows the user to record all actions taken during a simulation session and to receive advisories from the simulator via the FEP. The RTMPOS is programmed mainly in PASCAL along with some assembly language routines. The RTMPOS software is easily modified to be applicable to hardware from different manufacturers.
An electromechanical ac-powered rotary actuated four-bar linkage system for rotating the Shuttle/Centaur deployment adapter is described. The essential features of the deployment adapter rotation system (DARS) are increased reliability for mission success and maximum practical hazard control for safety. The requirements, concept development, hardware configuration, quality assurance provisions, and techniques used to meet two-fault tolerance requirements are highlighted. The rationale used to achieve a degree of safety equivalent of that of two-failure tolerance is presented. Conditions that make this approach acceptable, including single failure point components with regard to redundancy versus credibility of failure modes, are also discussed.
The present investigation is concerned with experimental results related, in one case, to the chirality of nucleotides, and, in another case, to the possibility of a link between the chirality of nucleic acids, and that of peptides. It has been found that aminoacylation of the 'internal' hydroxyl group of a dinucleoside monophosphate can occur stereoselectively. However, this reaction has not yet been made a part of a working peptide synthesis scheme. The formation and cleavage of oligonucleotides is considered. In the event of the formation of a helical complex between the oligonucleotide and the polymer, 1-prime,5-prime-bonds in the oligomer are found to become more resistant towards cleavage. The conditions required for peptide bond formation are examined, taking into account the known structures of RNA and possible mechanisms for prebiotic peptide bond formation. The possibility is considered that the 2-prime,5-prime-internucleotide linkage could have played an important part in the early days of biological peptide synthesis.
In connection with the increase in air traffic, IFR (Instrument Flight Rules) flight in the air traffic control system has become very demanding. It has, therefore, become imperative to optimize the pilot's skills in his management of the various aircraft systems. The present investigation is concerned with the human factors aspects of the use of sidesticks in direct mechanical linkage (reversible) control systems in a production General Aviation (G.A.) aircraft. A total of 140 fifteen to twenty minute flight tasks were flown on the NASA Langley G.A. motion base simulator. The study involved a comparison of three locations of the sidestick, left side, center, and right side, and the standard yoke. It was found that the sidestick is preferable to the standard yoke. However, some of the design and installation features of the sidestick are critical for pilot acceptance.
Attention is given to observations made in connection with the First GARP (Global Atmospheric Research Program) Global Experiment (FGGE), taking into account the average 200 mb zonal wind for two periods during the First Special Observing Period of FGGE, and the 200 mb velocity potential. The meridional linkages implied in the observations involve sources south of 15 deg N, and the most active extratropical patterns are collocated with regions of tropical easterlies. The possibility is investigated that the theory of reduced Rossby wave propagation through easterlies is not sufficiently general to cover the considered observations, taking into account a shallow water model. It is found that the meridional interactions cannot be associated with Rossby waves because these waves connot be generated in the regions of zero absolute vorticity gradient within which the forcing is embedded.
Time is an important parameter for space-acquired measurements, in virtue of the basing of instrument analysis on a sampled sensor time series. In addition, time provides the most efficient linkage between instrument data and externally generated ancillary parameters. Attention is presently given to the rationale and form of the standard timecode structure developed by NASA, with emphasis on the important class of binary unsegmented codes. The structure provides a mechanism for the self-documentation of timecodes, so that data users can interpret time measurement in an unambiguous manner. The binary unsegmented codes are modular and easily machine-readable; they also feature expendable resolution and ambiguity periods.
New method for synthesizing metal phthalocyanine tetracarboxylic acids (MPTCA's) yields high purity end product. In addition, high-purity metal phthalocyanine sheet polymers synthesized from compounds. Monomer formed into sheet polymer by heating. Units of polymer linked in manner similar to phenyl-group linkages in biphenyl: Conjugation extends throughout macromolecule, thereby increasing delocalization of TT-electrons. Increases conductivity and thermal stability of polymer.
Joint with four-bar-linkage geometry has following attributes: Springs to fully extended fully folded positions. Automatically locks in its extended position. Joint combines zero backlash, positive locking, and centerline pivoting. Used in folding tool handles, portable antenna booms, and many other deployable structures.
Latch for three-member telescoping column developed for deployment of antenna 122 meters in diameter. Deployable column along axis of antenna open lattice structure with three longerons as principal loadbearing members. Column divided into telescoping sections that deploy, one section at time. Latch automatically locks sections into position during deployment and unlocks them when antenna restowed. Latch is four-bar linkage using over-center principle for locking, with Belleville spring washers to absorb deflections.
Progress has been made on the design fabrication and installation of a tension carry-through linkage between the aft parts of the port and starboard wings to resist forward bending deflection on the RP-2 sailplane. In addition, towhook/release mechanisms, landing gear and wheel brake assembly, compound curved sandwich composite fuselage shells and an enclosed trailer to house and transport the complete disassembled aircraft, have all undergone various stages of design, fabrication, installation and testing.
The introduction of ceramics to those parts suffering high thermal loading was successfully demonstrated, and there is no question that the 100 kw (134 hp) naturally aspirated engine of the future will be developed to produce up to 300 kw (402 hp) by the application of turbocharging or its equivalent. However, at the 60 - 80 kw (80 - 107 hp) size needed for the economic automotive engine, scaling down the 300 kw (402 hp) is beset by the laws of scale. The conventional four stroke diesel was not shown to be successful at the small high speed engine size. The opposed piston two stroke engine does not suffer the same laws of scale and engines in the low power range have already been marketed successfully. The half liter/cylinder Armstrong Whitworth Swing Beam Engine is the latest to be designed with the automotive market in mind. Its low noise structure and balanced linkage system coupled with advantages for easy start and potential use of low grade fuels, derived from its variable compression ratio and slow piston motion, qualifies it for the application.