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At least 289 records · Page 16

Laser Ablation for Low-Cost Multijunction III-V Solar Cell Mesa Isolations

Eliminating photolithography from solar cell processing is a significant opportunity for cost reduction for III-V solar cells. In this work, we test femtosecond laser ablation and scribing as an alternative to contact photolithography and wet chemical etching for mesa isolation, when processing multijunction cells. We demonstrate that upright multijunction solar cells isolated by using the laser as a scribe to cleave through the substrate had virtually no performance loss when compared to a baseline cell processed with photolithography. By contrast, cells isolated by laser ablating through the active layers have performance losses that cannot be fully eliminated with post-processing etches. This demonstration of photolithography-free mesa isolation with no performance losses is promising for less expensive III-V manufacturing.

14 SOLAR ENERGY↗

An extended Vlasov–Fokker–Planck approach for kinetic simulations of laser plasmas

Vlasov–Fokker–Planck simulation codes occupy an important niche in modeling laser-produced plasmas, since they are well suited to studying the effect of collisions on electron kinetic phenomena, especially energy transport. One of the most important elements of energy transport is the absorption of laser light by the plasma; however, simulating this in detail requires resolving oscillations of the laser light, whose characteristic timescale is orders of magnitude shorter than the simulation time needed to study transport physics. For this reason, most Vlasov–Fokker–Planck codes used to study electron transport in laser plasmas rely on simplified models of the laser–plasma coupling. Their underlying assumptions nominally preclude their use for modeling laser light having short-scale structure in space or time, such as broadband lasers. In this work, we derive a more general computational framework suitable for arbitrarily structured laser fields. Furthermore, our approach is based on an extended set of Vlasov–Fokker–Planck equations that separately solve for the low- and high-frequency plasma response. We implement these extended Vlasov–Fokker–Planck equations in the spherical harmonic code K2 and demonstrate the performance of the method on several laser absorption test problems, with particular attention to the judicious selection of time steps, time integrators, and spherical harmonic truncation, according to the intensity and spectrum of the laser light under consideration. Comparison with the widely used Langdon absorption operator shows the Langdon operator performs remarkably well for predicting laser heating in the simple cases considered here, even in situations that would seem to violate its underlying assumptions.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Radiating electron source generation in ultraintense laser-foil interactions

A radiating electron source is shown to be created by a laser pulse (with intensity of 10{sup 23 }W/cm{sup 2} and duration equal to 30 fs) interacting with a near-critical density plasma. It is shown that the back radiation reaction resulting from high energy synchrotron radiation tends to counteract the action of the ponderomotive force. This enhances the collective dynamics of the radiating electrons in the highest field areas, resulting in the production of a compact radiation source (containing 80% of the synchrotron radiation emission), with an energy on the order of tens of MeV over the laser pulse duration. These phenomena are investigated using a QED-particle-in-cell code, and compared with a kinetic model accounting for the radiation reaction force in the electron distribution function. The results shed new light on electron-photon sources at ultra-high laser intensities and could be tested on future laser facilities.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Investigation of UV, ns-laser damage resistance of hafnia films produced by electron beam evaporation and ion beam sputtering deposition methods

Laser-induced damage in coating materials with a high index of refraction, such as hafnia, limits the performance of high power and high energy laser systems. Understanding the underlying physics responsible for laser damage holds the key for developing damage-resistant optical films. Previous studies have reported a substantial difference in laser damage onset for hafnia films produced by different deposition methods, yet the underlying mechanisms for the observed difference remain elusive. We combined laser damage testing with analytical characterizations and theoretical simulations to investigate the response of hafnia films produced by electron (e-) beam evaporation vs ion beam sputtering (IBS) methods upon UV ns-laser exposure. We found that e-beam produced hafnia films were overall more damage resistant; in addition, we observed a polarization anisotropy associated with the onset of damage in the e-beam films, while this effect was absent in the latter films. The observed differences can be attributed to the stark contrast in the pressure inside the pores inherent in both films. The high pressure inside the IBS-induced nanobubbles has been shown to reduce the threshold for laser-induced plasma breakdown leading to film damage. The polarization effects in the e-beam coatings can be related to the asymmetric electric field intensification induced by the columnar void structure. Our findings provide a fundamental basis for developing strategies to produce laser damage-resistant coatings for UV pulsed laser applications.

36 MATERIALS SCIENCE↗

Laser damage comparisons of broad-bandwidth, high-reflection optical coatings containing TiO 2 , Nb 2 O 5 , or Ta 2 O 5 high-index layers

Broad bandwidth coatings allow angle of incidence flexibility and accommodate spectral shifts due to aging and water absorption. Higher refractive index materials in optical coatings, such as TiO 2 , Nb 2 O 5 , and Ta 2 O 5 , can be used to achieve broader bandwidths compared to coatings that contain HfO 2 high index layers. We have identified the deposition settings that lead to the highest index, lowest absorption layers of TiO 2 , Nb 2 O 5 , and Ta 2 O 5 , via e-beam evaporation using ion-assisted deposition. We paired these high index materials with SiO 2 as the low index material to create broad bandwidth high reflection coatings centered at 1054 nm for 45 deg angle of incidence and P polarization. Furthermore, high reflection bandwidths as large as 231 nm were realized. Laser damage tests of these coatings using the ISO 11254 and NIF-MEL protocols are presented, which revealed that the Ta 2 O 5 /SiO 2 coating exhibits the highest resistance to laser damage, at the expense of lower bandwidth compared to the TiO 2 /SiO 2 and Nb 2 O 5 /SiO 2 coatings.

36 MATERIALS SCIENCE↗

Design and characterization of “flow-cell” integrated-flow active cooling for high-average-power ceramic optics

We used COMSOL Multiphysics to design a prototype actively cooled “flow-cell” substrate targeted at high-average-power applications, fabricated the prototype from cordierite ceramic, and tested the substrate under load in our thermal loading test stand. Sub-aperture testing revealed average-power handling up to 3.88-W/cm 2 absorbed power density, in excellent agreement with model predictions. Gratings fabricated on 2-in.-diam cordierite coupons were subjected to laser-damage testing and showed a damage threshold of 250 mJ/cm 2 .

47 OTHER INSTRUMENTATION↗

Solid propellant combustion response to oscillatory radiant heat flux

A progress report is given on a research project to use the microwave Doppler velocimeter technique to measure the combustion response to an oscillating thermal radiation source (CO2 laser). The test technique and supporting analyses are described, and the results are presented for an initial test series on the nonmetallized, composite propellant, Naval Weapons Center formulation A-13. It is concluded that in-depth transmission of radiant heat flux is not a factor at the CO2 laser wave length.

Strand, L. D.↗

Preliminary Results of Solid Gas Generator Micropropulsion

A decomposing solid thruster concept, which creates a more benign thermal and chemical environment than solid propellant combustion, while maintaining, performance similar to solid combustion, is described. A Micro-Electro-Mechanical (MEMS) thruster concept with diode laser and fiber-optic initiation is proposed, and thruster components fabricated with MEMS technology are presented. A high nitrogen content solid gas generator compound is evaluated and tested in a conventional axisymmetric thrust chamber with nozzle throat area ratio of 100. Results show incomplete decomposition of this compound in both low pressure (1 kPa) and high pressure (1 MPa) environments, with decomposition of up to 80% of the original mass. Chamber pressures of 1.1 MPa were obtained, with maximum calculated thrust of approximately 2.7 N. Resistively heated wires and resistively heated walls were used to initiate decomposition. Initiation tests using available lasers were unsuccessful, but infrared spectra of the compound show that the laser initiation tests used inappropriate wavelengths for optimal propellant absorption. Optimal wavelengths for laser ignition were identified. Data presented are from tests currently in progress. Alternative solid gas generator compounds are being evaluated for future tests.

deGroot, Wilhelmus A.↗

Laser Techniques in Photovoltaic Research

High-power laser pulses were used to replace the conventional high temperature furnace processing for the p-n junction formation step in high speed, low cost solar cell fabrication. Three different approaches to junction formation were tested: (1) laser annealing of ion-implanted Si in which laser radiation is used to remove the radiation damage and to recover the electrical activity in the implanted layer; (2) a process in which a thin film of dopant is first deposited on the substrate and then incorporated into the near-surface region by laser-induced diffusion; and (3) a process in which a heavily doped amorphous silicon layer is deposited on the Si substrate and epitaxially regrown from the melted substrate layer by laser radiation. All three methods were found to provide suitable candidates for high efficiency Si solar cells.

Young, R. T.↗

Variation in Ion Acceleration Characteristics of the HERMeS Hall Thruster During Magnetic Optimization

To reduce design risks for future magnetically shielded Hall thrusters, a test was performed on the HERMeS to obtain data for optimizing the effect of magnetic shielding. As a part of this test, laser-induced fluorescence velocimetry was used to characterize the variations in the ion acceleration with different magnetic configurations. Four magnetic configurations representing varying amounts of magnetic shielding between the high-energy discharge plasma and the discharge channel walls were tested. The ion velocity data points to the possibility that different plasma-wall interaction physics applies to a magnetically shielded thruster than a non-shielded thruster. The transition point is very prominent and can potentially be used to test whether a thruster is fully magnetically shielded.

Hall thrusters↗

Variation in Ion Acceleration Characteristics of the HERMeS Hall Thruster During Magnetic Optimization

To reduce design risks for future magnetically shielded Hall thrusters, a test was performed on the HERMeS to obtain data for optimizing the effect of magnetic shielding. As a part of this test, laser-induced fluorescence velocimetry was used to characterize the variations in the ion acceleration with different magnetic configurations. Four magnetic configurations representing varying amounts of magnetic shielding between the high-energy discharge plasma and the discharge channel walls were tested. The ion velocity data points to the possibility that different plasma-wall interaction physics applies to a magnetically shielded thruster than a non-shielded thruster. The transition point is very prominent and can potentially be used to test whether a thruster is fully magnetically shielded.

HERMeS↗

Development of the Mars Observer Laser Altimeter (MOLA)

The Mars Observer (MO) spacecraft payload scientific mission is to gather data on Martian global topography, gravity, weather, magnetic field and its interaction with the solar flux, surface chemistry, and mineralogy over one Mars year. In mid-1988 the need for a replacement altimeter as part of the payload complement arose. The Mars Observer Laser Altimeter (MOLA) was proposed by GSFC as an in-house effort and shortly afterward was 'conditionally' accepted. Constraints on funding, schedule, power, and mass were imposed with periodic reviews during the instrument development to authorize continuation. MOLA was designed, tested, and delivered in less than 36 months and integrated with the spacecraft. During spacecraft payload testing, the laser failed due to contamination in the laser cavity. In only 6 months, the laser was removed, rebuilt from spare parts, retested, and the instrument reassembled, realigned, requalified, and again delivered for spacecraft integration. Other aspects of the development of the MOLA are presented.

Johnson, Bertrand L., Jr↗

Development of a subsurface LIBS sensor for in situ groundwater quality monitoring with applications in CO 2 leak sensing in carbon sequestration

Sub-surface activity such as geologic carbon sequestration (GCS) has the potential to contaminate groundwater sources with dissolved metals originating from sub-surface brines or leaching of formation rock. Therefore, a Laser Induced Breakdown Spectroscopy (LIBS) based sensor is developed for sub-surface water quality monitoring. The sensor head is built using a low cost passively Q-switched (PQSW) laser and is fiber coupled to a pump laser and a gated spectrometer. The prototype sensor head was constructed using off the shelf components and a custom monolithic, PQSW laser and testing has verified that the fiber coupled design performs as desired. The system shows good calibration linearity for tested elements (Ca, Sr, and K), quick data collection times, and Limits of Detection (LODs) that are comparable to or better than those of table top, actively Q-switched systems. The fiber coupled design gives the ability to separate the PQSW LIBS excitation laser from the pump source and spectrometer, allowing these expensive and fragile components to remain at the surface while only the low-cost, all optical sensor head needs to be exposed to the hostile downhole environment.

58 GEOSCIENCES↗

Determination of ultra-short laser induced damage threshold of KH{sub 2}PO{sub 4} crystal: Numerical calculation and experimental verification

Rapid growth and ultra-precision machining of large-size KDP (KH{sub 2}PO{sub 4}) crystals with high laser damage resistance are tough challenges in the development of large laser systems. It is of high interest and practical significance to have theoretical models for scientists and manufacturers to determine the laser-induced damage threshold (LIDT) of actually prepared KDP optics. Here, we numerically and experimentally investigate the laser-induced damage on KDP crystals in ultra-short pulse laser regime. On basis of the rate equation for free electron generation, a model dedicated to predicting the LIDT is developed by considering the synergistic effect of photoionization, impact ionization and decay of electrons. Laser damage tests are performed to measure the single-pulse LIDT with several testing protocols. The testing results combined with previously reported experimental data agree well with those calculated by the model. By taking the light intensification into consideration, the model is successfully applied to quantitatively evaluate the effect of surface flaws inevitably introduced in the preparation processes on the laser damage resistance of KDP crystals. This work can not only contribute to further understanding of the laser damage mechanisms of optical materials, but also provide available models for evaluating the laser damage resistance of exquisitely prepared optical components used in high power laser systems.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

High Throughput, High Precision Hot Testing Tool for HBLED Wafer Level Testing

The Socrates research effort developed an in depth understanding and demonstrated in a prototype tool new precise methods for teh characterization of color characteristics and flux from individual LEDs for the production of uniform quality lighting. This effort was focused on improving the color quality and consistency of solid state lighting and potentially reducing characterization costs for all LED product types. The patented laser hot testing method was demonstrated to be far more accurate than all current state of the art color and flux characterization methods in use by the solid state lighting industry today. A seperately patented LED grouping method (statistical binning) was demonstrated to be a useful approach to improving utilization of entire lots of large color and flux distributions of manufactured LEDs for high quality color solid-state lighting. At the conclusion of the research in late 2015 the solid-state lighting industry was however generally satisfied with its existing production methods for high quality color products for the small segment of customers that demand it, albeit with added costs.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Improving the laser performance of ion beam sputtered dielectric thin films through the suppression of nanoscale defects by employing a xenon sputtering gas

Laser damage-prone precursors in high index materials such as hafnia are believed to be the primary limiter in the performance of dielectric multilayer films to advance ultra-high power and energy laser applications. Removing or suppressing these precursors is the key to fabricating laser damage resistant thin films for the enabling technologies. Early work has revealed that nanobubbles formed by entrapped argon (Ar) working gas in ion beam sputtering (IBS) produced hafnia films are primarily responsible for the onset of laser damage upon exposure to UV, ns-laser pulses. In this study, we demonstrate that the UV ns-laser damage onset of IBS produced hafnia films can be improved to 3.1 +/- 0.2 J/cm 2 by substituting the conventional Ar working gas with xenon (Xe), a nearly 1 J/cm 2 increase from that of the Ar produced hafnia films. In addition to the suppression of the overall point-defect density of the hafnia films, the reduction of the Xe entrapment eliminates the nanobubbles and the generation of plasmas that initiates the laser damage. The defect suppression and its correlation to the increase in laser damage threshold is revealed by the combined analysis of Rutherford backscattering spectroscopy, electron paramagnetic resonance spectroscopy, transmission electron microscopy, and laser damage testing. Monte Carlo simulations suggest a much smaller entrapment of Xe gas by comparison to Ar, which is attributed to the significant difference in the energy of the reflected neutrals (3X) which are likely to be implanted. These results provide an effective process route with a fundamental understanding for producing high laser damage resistant dielectric films for high power and high energy laser applications.

36 MATERIALS SCIENCE↗