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At least 289 records · Page 16

Accretion of the earliest inner Solar System planetesimals beyond the water snowline

How and where the first generation of inner Solar System planetesimals formed remains poorly understood. Potential formation regions are the silicate condensation line and water snowline of the solar protoplanetary disk. Whether the chemical compositions of these planetesimals align with accretion at the silicate condensation line (water-free and reduced) or water snowline (water-bearing and oxidized) is, however, unknown. Here we use the Fe/Ni and Fe/Co ratios of magmatic iron meteorites to quantify the oxidation states of the earliest planetesimals associated with non-carbonaceous (NC) and carbonaceous (CC) reservoirs, representing the inner and outer Solar System, respectively. Our results show that the earliest NC planetesimals contained substantial amounts of oxidized Fe in their mantles (3–19 wt% FeO). In turn, we argue that this required the accretion of water-bearing materials into these NC planetesimals. The presence of substantial quantities of moderately and highly volatile elements in their parent cores is also inconsistent with their accretion at the silicate condensation line and favours, instead, their formation at or beyond the water snowline. Similar oxidation states in the early formed parent bodies of NC iron meteorites and those of NC achondrites and chondrites with diverse accretion ages suggest that the formation of oxidized planetesimals from water-bearing materials was widespread in the early history of the inner Solar System.

Damanveer S. Grewal↗

Protracted core formation and impact disruptions shaped the earliest outer Solar System planetesimals

The distinct compositions of metallic cores from noncarbonaceous (NC) and carbonaceous (CC) iron meteorite parent bodies (IMPBs) reflect differences in accretion and differentiation histories of earliest inner and outer Solar System planetesimals. Compared to NC IMPBs, CC IMPBs have smaller, sulfur (S)–poor, highly siderophile element (HSE)–enriched cores and younger core formation ages. However, the origins of these differences remain debated. Using equilibrium partitioning models between the S-poor solid and the S-rich liquid metal, we argue that HSE enrichment in IID, IIF, IIIF, and IVB cores resulted from a multistage evolutionary sequence: (i) segregation of S-rich, HSE-depleted protocores during initial planetesimal heating; (ii) collisional disruption before S-poor metal segregation; (iii) reaccretion of mantle fragments into daughter planetesimals; and (iv) further 26 Al-driven heating producing HSE-enriched, S-poor cores. We suggest that iron meteorites from these CC IMPBs originate from such second-generation cores. Accounting for “missing” S-rich protocores helps reconcile several NC-CC IMPB differences and highlights the role of early collisional processing in shaping planetesimal chemical evolution.

Geosciences↗

Lunar and Planetary Science Conference, 13th, Houston, TX, March 15-19, 1982, Proceedings. Part 1

The present conference on planetary and lunar science considers theoretical models for the composition of the Venus crust, the lunar crust, the prediction of phase relationships in planetary mantles, the volumetric analysis of complex lunar craters, grazing impacts on Mars, the determination of lunar structure by means of electrical conductivity and seismic experiments, results of studies on the Apollo 16 site rocks, as well as Apollo 14, 15 and 17 lunar glasses and regoliths, and carbon components and isotopic compositions of chondritic meteorites. Also discussed are iron meteorites, interplanetary dust and tektites, and such theoretical and experimental issues as refractory condensates and chondrules from solar furnace experiments, molecular synthesis through the irradiation of silicates, and the adsorption of excess fission Xe.

Boynton, W. V.↗

Asteroid 1986 DA: Radar evidence for a metallic composition

Radar observations of the near-Earth asteroid 1986 DA were carried out at the Arecibo Observatory in April 1986, two months after its discovery. Radar results are consistent with the hypothesis that 1986 HA is a piece of NiFe metal derived from the interior of a much larger object that melted, differentiated, cooled and subsequently was disrupted in a catastrophic collision. This 2-km asteroid might be (or have been part of) the parent body of some iron meteorites. Or 1986 DA might share the parentage and/or part of the dynamical history of some meteorites without ever having contributed any of its own ejecta to our meteorite sample. Analysis of the samples returned from 1986 DA might ultimately involve economic considerations. Meteoritic metal is mostly iron with about 8 percent nickel, but also contains substantial concentrations of precious and strategic metals, including approx. 1 ppm of gold and approx. 10 ppm of platinum group elements. If these abundances apply to 1986 DA, it contains some 10(exp 16) g of iron, 10 (exp 15) g of nickel, 10(exp 11) g of platinum group metals, and 10(exp 10) g of gold.

Ostro, Steven J.↗

A Classification Table for Achondrites

Classifying chondrites is relatively easy and the criteria are well documented. It is based on mineral compositions, textural characteristics and more recently, magnetic susceptibility. It can be more difficult to classify achondrites, especially those that are very similar to terrestrial igneous rocks, because mineralogical, textural and compositional properties can be quite variable. Achondrites contain essentially olivine, pyroxenes, plagioclases, oxides, sulphides and accessory minerals. Their origin is attributed to differentiated parents bodies: large asteroids (Vesta); planets (Mars); a satellite (the Moon); and numerous asteroids of unknown size. In most cases, achondrites are not eye witnessed falls and some do not have fusion crust. Because of the mineralogical and magnetic susceptibility similarity with terrestrial igneous rocks for some achondrites, it can be difficult for classifiers to confirm their extra-terrestrial origin. We -as classifiers of meteorites- are confronted with this problem with every suspected achondrite we receive for identification. We are developing a "grid" of classification to provide an easier approach for initial classification. We use simple but reproducible criteria based on mineralogical, petrological and geochemical studies. We presented the classes: acapulcoites, lodranites, winonaites and Martian meteorites (shergottite, chassignites, nakhlites). In this work we are completing the classification table by including the groups: angrites, aubrites, brachinites, ureilites, HED (howardites, eucrites, and diogenites), lunar meteorites, pallasites and mesosiderites. Iron meteorites are not presented in this abstract.

Chennaoui-Aoudjehane, H.↗

Olivine-Orthopyroxene Equilibrium in Metal-rich Systems: Applications to Achondrites and Equilibrated Chondrites

Olivine and orthopyroxene are major minerals in every type of stony meteorite. The majority of achondritic meteorites and silicate-bearing iron meteorites have experienced high temperatures. If these temperatures persisted for an extended period of time then the iron contents of olivine and orthopyroxene should be in equilibrium. In their study of ungrouped clasts and chondritic meteorites, suggested that the equilibrium compositions of olivine and orthopyroxene should fall on a mixing line between LL chondrites and aubrites. Here we show that this is not necessarily the case and that a range of FeO contents in olivine and orthopyroxene can be in equilibrium with each other. The key parameters that determine the equilibrium Fe content in these minerals are temperature, oxygen fugacity (fO2), and silica activity (aSiO2).

Lauretta, D. S.↗

IMPACTS ON THE EARTH AND MOON

Brief consideration of the iron meteorites which strike the earth concluding that the near asteroids are primarily of iron content

IRON METEORITE↗

Superconductivity found in meteorites

Meteorites can contain a wide range of material phases due to the extreme environments found in space and are ideal candidates to search for natural superconductivity. However, meteorites are chemically inhomogeneous, and superconducting phases in them could potentially be minute, rendering detection of these phases difficult. To alleviate this difficulty, we have studied meteorite samples with the ultrasensitive magnetic field modulated microwave spectroscopy (MFMMS) technique [J. G. Ramírez, A. C. Basaran, J. de la Venta, J. Pereiro, I. K. Schuller, Rep. Prog. Phys. 77, 093902 (2014)]. Here, we report the identification of superconducting phases in two meteorites, Mundrabilla, a group IAB iron meteorite [R. Wilson, A. Cooney, Nature 213, 274–275 (1967)] and GRA 95205, a ureilite [J. N. Grossman, Meteorit. Planet. Sci. 33, A221–A239 (1998)]. MFMMS measurements detected superconducting transitions in samples from each, above 5 K. By subdividing and remeasuring individual samples, grains containing the largest superconducting fraction were isolated. The superconducting grains were then characterized with a series of complementary techniques, including vibrating-sample magnetometry (VSM), energy-dispersive X-ray spectroscopy (EDX), and numerical methods. Finally, these measurements and analysis identified the likely phases as alloys of lead, indium, and tin.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Reflectance spectra of 'featureless' materials and the surface mineralogies of M- and E-class asteroids

In a search for diagnostic spectral parameters which can be used to distinguish different materials on the surface of asteroids and to provide information on the detection limits for mafic silicates, the 0.3- to 2.6-micron reflectance spectra of meteoritic enstatite (nearly pure MgSiO3), iron meteorite metal, magnetite, and amorphous carbon as well as various mixtures of these materials with mafic silicates were examined. Results are presented on the dependence of the spectral detectability of mafic silicates associated with metal, carbon, and magnetite on the particle sizes of the phases, their chemistries, crystal structures, and abundances. It is shown that the observational data for a representative M-class asteroid, (16) Psyche, are largely consistent with a fine-grained metal-rich surface assemblage, whereas data for the E-class asteroid (44) Nysa indicate that its surface is composed of fine-grained material similar to enstatite achondrites, with a small amount of material comparable to the chondritic inclusions found in the Cumberland Falls aubrite.

Cloutis, Edward A.↗

Percolative Sulfide Core Formation in Oxidized Meteorite Parent Bodies

Most models of planetary differentiation involve the formation of metallic cores during or after extensive silicate melting, but some volatile-rich reservoirs in the protoplanetary disk did not accrete substantial amounts of Fe,Ni-metal. Instead, their potential core-forming assemblages were dominated by Fe,Ni-sulfides and oxides due to high ƒ O 2 and ƒ S 2 . Derivative melts from these assemblages may have been capable of percolative migration leading to core formation prior to silicate melting. However, no direct evidence for this process has been reported in meteoritic literature. Similarly, while many iron meteorites are thought to represent cores of their respective parent bodies, no direct evidence for Fe,Ni-sulfide/oxide cores have been reported to-date. The most promising potential for such evidence may be found in the anomalous noble metal trace element proportions of restitic oxidized primitive achondrites (i.e., brachinites, log ƒ O 2 ~IW-1), which are similar to those found in sulfides of Rumuruti-type chondrites (RCs) that contain only trace amounts of Fe,Ni-metal at log ƒ O 2 ≥ IW-1. This work addresses the following outstanding questions: (1) Are molten sulfides in oxidized meteorite assemblages capable of percolative melt migration? (2) How is this process recorded in the noble metal (i.e., siderophile/chalcophile) trace element geochemistry of relevant meteorites? (3) Did O,S-rich meteorite parent bodies form sulfide cores?

S. D. Crossley↗

An Atlas of extraterrestrial particles collected with NASA U-2 aircraft, 1974 - 1976

Extraterrestrial particles collected during U-2 flights in the stratosphere were divided into four groups: chondritic, iron-sulfur--nickel, mafic silicates, and others. The chondritic aggregates are typically composed of Fe, Mg, Si, C, S, Ca, and Ni. Detectable levels of He-4 implanted from the solar wind occur in some. Olivine, spinel, and possibly pyrrhotite and a hydrated layered-lattice silicate were identified. The chondritic ablation particles contain no sulfur and appear to have been melted. Magnetite, olivine, and pyroxene were identified. The iron-sulfur-nickel type particles resemble meteoritic iron sulfide with a small amount of nickel, and contain magnetite and troilite. The mafic silicate type particles are iron magnesium silicate grains with clumps of chondritic aggregate particles adhering to their surfaces. Olivine and possibly pyrrhotite and pyroxene were identified. Most of the iron-nickel type particles are spherules and include taenite and wustite. The other type particles include nickel-iron mounds on spheroidal glassy-like grains having chondritic-like elemental abundances.

Brownlee, D. E.↗

International Workshop on Antarctic Meteorites

Topics addressed include: meteorite concentration mechanisms; meteorites and the Antarctic ice sheet; iron meteorites; iodine overabundance in meteorites; entrainment, transport, and concentration of meteorites in polar ice sheets; weathering of stony meteorites; cosmic ray records; radiocarbon dating; element distribution and noble gas isotopic abundances in lunar meteorites; thermoanalytical characterization; trace elements; thermoluminescence; parent sources; and meteorite ablation and fusion spherules in Antarctic ice.

Annexstad, J. O.↗

The nature of dark-etching rims in meteoritic taenite.

Taenite fields when etched develop a cloudy brown rim with approximate compositional limits of 25 and 40% Ni. In iron meteorites this cloudy zone is only a few microns wide, with a sharp, high-Ni edge about 1 micron from the kamacite interface and a diffuse edge several microns from the central plessite. It is always present in irons unless the meteorite has been cosmically or terrestrially reheated. X-ray and electron diffraction of grains scratched from exceptionally larger areas of cloudy taenite in the mesosiderite Estherville show that this etching zone contains a fine exsolution of kamacite. Detailed electron-probe investigations of taenite in Estherville show that there is a step in the M-shaped Ni profile at the sharp, high-Ni edge of the cloudy region, the Ni dropping suddenly from approximately 45 to 42%. It is proposed that exsolution in the cloudy region effectively froze in the Ni profile at that temperature. On subsequent cooling only the clear outer taenite continued to equilibrate with the kamacite matrix, producing the kink in the M profile. Cloudy taenite is therefore a variety of plessite differing from the usual varieties in that it forms at lower temperatures in areas much richer in Ni, and the morphology is not crystallographically oriented. Its absence can provide a sensitive indication of reheating.

Scott, E. R. D.↗

A new Antarctic meteorite with chromite, orthopyroxene and metal with reference to a formation model of S asteroids

Mineralogy of a unique meteorite from Antarctica, EET84302 and the related primitive achondrites, was studied to gain better understanding on relationship between S asteroids and this meteorite group. EET84302 consists of metal-rich (M) region with metal filling interstices of silicate grains of orthopyroxene (Opx), olivine Fa8, plagioclase An24, and augite (Aug), chromite-rich (C) region with major chromite and Opx, and silicate-rich (S) region with mainly Opx. This is the first example of chromite-rich achondrite. Distribution of three areas (C, M, S) are in line with a proposed model of primitive achondrites and S asteroids. Since reflectance spectra of some members of primitive achondrites combined with those of iron meteorites, resemble those of the S asteroids, there is an expectation that S asteroids are modified products of chondrites. The trends of the variations in their mineral assemblages are in line with those of the S asteroids. Hiroi proposed a stony-iron model of S asteroids, which assumes that a few domains of various primitive achondrites are embedded in iron matrix. Polished thin sections (PTS) of EET84302,19 and ALH81187,16 were supplied from Meteorite Working Group (MWG). A previously studied PTS of EET84302 was similar in both texture and mineralogy to silicate inclusions in some iron meteorites. PTS EET84302,19 was studied by electron probe microanalyzer (EPMA) and scanning electron microscope (SEM). The reflectance spectra of EET84302 showed a weathering problem and was not used to match with those of S asteroids.

Takeda, Hiroshi↗

Internal constitution of Mars.

Models of the internal structure of Mars consistent with the mass, radius and moment of inertia of the planet are constructed. The models assume that the radius of the core is between 0.36 and 0.60 of the radius of the planet, that the zero-pressure density of the mantle is between 3.54 and 3.49 g/cu cm, and that the planet contains 25 to 28% iron. Meteorite models of Mars containing 25 wt % iron and 12 wt % core are also proposed. It is maintained that Mars in contrast to the earth is an incompletely differentiated planet with a core substantially richer in sulfur than the core of the earth. The absence of a magnetic field on Mars is possibly linked with lack of lunar precessional torque and the small size and high resistivity of the Martian core.

Anderson, D. L.↗