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At least 289 records · Page 16

MODELING AND SIMULATION OF SOLID FLUIDIZATION IN A RESIN COLUMN

The objective of the present work is to model the resin particles within the column during fluidization and sedimentation processes using computation fluid dynamics (CFD) approach. The calculated results will help interpret experimental results, and they will assist in providing guidance on specific details of testing design and establishing a basic understanding of particle’s hydraulic characteristics within the column. The model is benchmarked against the literature data and the test data (2003) conducted at Savannah River Site (SRS). The paper presents the benchmarking results and the modeling predictions of the SRS resin column using the improved literature correlations applicable for liquid-solid granular flow.

42 ENGINEERING↗

Apparatus, components and operating methods for circulating fluidized bed transport gasifiers and reactors

The improvements proposed in this invention provide a reliable apparatus and method to gasify low rank coals in a class of pressurized circulating fluidized bed reactors termed "transport gasifier." The embodiments overcome a number of operability and reliability problems with existing gasifiers. The systems and methods address issues related to distribution of gasification agent without the use of internals, management of heat release to avoid any agglomeration and clinker formation, specific design of bends to withstand the highly erosive environment due to high solid particles circulation rates, design of a standpipe cyclone to withstand high temperature gasification environment, compact design of seal-leg that can handle high mass solids flux, design of nozzles that eliminate plugging, uniform aeration of large diameter Standpipe, oxidant injection at the cyclone exits to effectively modulate gasifier exit temperature and reduction in overall height of the gasifier with a modified non-mechanical valve.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Fluidized bed and method and system for gas component capture

The present disclosure is directed to a process that allows dry sorbents to remove a target constituent, such as carbon dioxide (CO.sub.2), from a gas stream. A staged fluidized bed separator enables gas and sorbent to move in opposite directions. The sorbent is loaded with target constituent in the separator. It is then transferred to a regenerator where the target constituent is stripped. The temperature of the separator and regenerator are controlled. After it is removed from the regenerator, the sorbent is then transferred back to the separator.

20 FOSSIL-FUELED POWER PLANTS↗

Use of fluidized-bed electrode reactors for alane production

Fluidized-bed reactors for producing alane are provided herein. An exemplary process includes inducing an electrical potential difference in an electrolyte solution to produce an anolyte solution that includes an alane adduct, wherein an electrical potential difference is generated between anode aluminum particles and a cathode, the electrolyte solution including an alkali metal hydride dissolved in a solvent, the anode aluminum particles and cathode being separated by a diaphragm.

Crouch-Baker, Steven↗

Prediction of Performance of a Pilot-Scale Dual Fluidized Bed System for Chemical Looping with Oxygen Uncoupling

Chemical looping with oxygen uncoupling (CLOU) is a variant of chemical looping combustion that involves spontaneous release of gaseous oxygen in the fuel reactor, which enables efficient combustion of solid fuel char. The University of Utah has constructed a 200 kW pilot-scale chemical looping process development unit (PDU) consisting of two fluidized beds. The CLOU oxygen carrier uses copper as the active metal, cycling between cupric (CuO) and cuprous (Cu2O) oxides. As an aid for design, troubleshooting and evaluation of the pilot system, a CFD model has been developed using CPFD Software’s Barracuda VR software. The 3D model includes both reactors, as well as loop seals and cyclone separators. Mechanisms describing CLOU reaction kinetics for cuprous oxide oxidation in the air reactor and cupric oxide reduction in the fuel reactor were adapted from previously reported experimental work. Coal char kinetics were based on the carbon-hydrogen-nitrogen-oxygen-sulfur, CHNOS, method. Submodels for devolatilization, gasification, and homogenous gas-phase reactions used preexisting relationships in the literature. Three different simulations were performed, analyzing the influence of particle properties (a base carrier and an alternate carrier referred to as cariact) and coal feeding rate (100kW, 200kW). Increased coal feeding rate caused significant increase in cuprious oxide oxidation in the air reactor as well as higher temperature. The alternate carrier predicted CO2 capture below 90%, in contrast to the other cases.

Reinking, Zachary↗

Circulating fluidized bed connected to a desublimating heat exchanger

Condensable vapors such as carbon dioxide are separated from light gases in a process stream. The systems and methods employ a circulating fluidized particle bed cooled by an out-bed heat exchanger to desublimate the solid form of condensable vapors from the process stream. Gas and solids may be sorted in a separator, and the solids may then be subcooled in a heat exchanger. The condensable vapors may be condensed on the bed particles or in the heat exchanger while the light gases from the process stream, which are not condensed, form a separated light-gas stream.

Baxter, Larry↗

Prediction of Performance of a Pilot Scale Dual Fluidized Bed System for Chemical Looping with Oxygen Uncoupling

Chemical looping with oxygen uncoupling (CLOU) is a variant of chemical looping combustion that involves spontaneous release of gaseous oxygen in the fuel reactor, which enables efficient combustion of solid fuel char. The University of Utah has constructed a pilot-scale dual fluidized bed chemical looping process development unit (PDU) with a nominal thermal input of 200 kW. The CLOU oxygen carrier uses copper as the active metal, cycling between cupric (CuO) and cuprous (Cu2O) oxides. As an aid for design, troubleshooting and evaluation of the pilot system, a CFD model has been developed using CPFD Software’s Barracuda VR software. The 3D model includes both reactors, as well as loop seals and cyclone separators. Mechanisms describing CLOU reaction kinetics for cuprous oxide oxidation in the air reactor and cupric oxide reduction in the fuel reactor were adapted from previously done experimental work. Coal char kinetics were based on the carbon-hydrogen-nitrogen-oxygen-sulfur, CHNOS, method. Submodels for devolatilization, gasification, and homogenous gas-phase reactions used preexisting relationships in the literature. Results predict temperature profiles, concentration profiles, product gas composition, and CO¬2 capture efficiency. This paper presents results of a parametric study in which key operational variables were adjusted to determine the influence on simulated performance of the PDU. The adjusted variables include fuel feed rate, fuel particle size, total oxygen carrier inventory, oxygen carrier copper oxide loading, and oxygen carrier particle physical properties.

Reinking, Zachary↗

Maintaining Microstructure – The Path to Successful Technology Maturation in Fluidized Systems

Scaling circulating fluidized bed risers has been a point of contention for nearly a century. There have been numerous attempts to define various methodologies. These have all fallen short of providing a robust approach, primarily due to a lack of maintaining microstructure dynamics – a key factor in maintain interphase heat and mass transfer. Recent work by the author put forward an approach based up maintaining dynamic similarity at different scales by ensuring that the microstructure remained similar by maintaining statistical and chaotic parameters across the scale. That work relied on a dimensionless regime map in which the x-axis was defined by the ratio of the solids flux to the saturation carrying capacity. This latter property was only good within the range of the data and it became evident that extrapolation beyond the limits of the data could induce unrealistic conditions. Therefore, literature was reviewed to develop a better correlation for the saturation carrying capacity. In doing so, a critical diameter concept was developed and applied to the correlations for both Geldart Group A and B materials. The critical diameter for Geldart Group A and B materials is 0.2 m and 0.3 m, respectively. The paper then gives examples on how to use the scaling approach to maintain dynamic similarity across the scales.<br>

Breault, Ronald↗

Fluidized-bed heat exchanger for conversion of thermal energy to electricity

The present disclosure describes heat exchangers for converting thermal energy stored in solid particles to electricity. Electro-thermal energy storage converts off-peak electricity into heat for thermal energy storage, which may be converted back to electricity, for example during peak-hour power generation. The heat exchanger for converting thermal energy stored in solid particles to electricity enables the conversion of thermal energy into electrical energy for redistribution to the grid. In some embodiments, pressurized fluidized-bed heat exchangers may achieve efficient conversion of thermal energy to electricity by providing direct contact of the solid particles with a gas stream.

Ma, Zhiwen↗

Effects of Low-temperature Pre-oxidation on the Titanomagnetite Ore Structure and Reduction Behaviors in a Fluidized Bed

With respect to high efficient utilization of low-grade iron ore resource, the behavior of low-temperature “973 K to 1123 K (700 °C to 850 °C)” oxidation, on the phase transition of SA TTM ore (South African titanomagnetite), and its effect on subsequent reduction was investigated. The results showed that hematite and rutile are the oxidation product below 1048 K (775 °C), while pseudobrookite is the stable phase above 1073 K (800 °C). With the increase in temperature and oxidation time, there is a competitive relationship between the amount of hematite and pseudobrookite generated. The reduction efficiency of SA TTM was significantly improved by oxidation pretreatment, primarily due to the dissociation of titania-ferrous oxides to more easily reducible hematite. But the generation of pseudobrookite phase decreases the amount of free hematite available for reduction, which weakens the improvement effect of pre-oxidation. The equilibrium relationship between the metallization degree and the gas reduction potential for TTM ore with pre-oxidation treatment has been built. Finally, the reduction metallization degree for the first and second step can be improved averagely by 16.67 and 3.45 pct, respectively, for sample pre-oxidized at 1098 K (825 °C) for 15 and 90 minutes, while 26.96 and 7.4 pct, improvement is achieved for sample pre-oxidized at a lower temperature of 1048 K (775 °C) for 120 minutes.

36 MATERIALS SCIENCE↗