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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 289 records · Page 16
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Mineral Scale Prevention on Electrically Conducting Membrane Distillation Membranes Using Induced Electrophoretic Mixing

The growth of mineral crystals on surfaces is a challenge across multiple industrial processes. Membrane-based desalination processes, in particular, are plagued by crystal growth (known as scaling), which restricts the flow of water through the membrane, can cause membrane wetting in membrane distillation, and can lead to the physical destruction of the membrane material. Scaling occurs when supersaturated conditions develop along the membrane surface due to the passage of water through the membrane, a process known as concentration polarization. To reduce scaling, concentration polarization is minimized by encouraging turbulent conditions and by reducing the amount of water recovered from the saline feed. In addition, antiscaling chemicals can be used to reduce the availability of cations. Here, we report on an energy-efficient electrophoretic mixing method capable of nearly eliminating CaSO4 and silicate scaling on electrically conducting membrane distillation (ECMD) membranes. The ECMD membrane material is composed of a percolating layer of carbon nanotubes deposited on porous polypropylene support and cross-linked by poly(vinyl alcohol). The application of low alternating potentials (2 Vpp,1Hz) had a dramatic impact on scale formation, with the impact highly dependent on the frequency of the applied signal, and in the case of silicate, on the pH of the solution.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

Additively-manufactured Al-0.3Zr-0.2Ce-0.2Cu alloy with high creep resistance and electrical conductivity

Here, a new, solute-lean Al-0.3Zr-0.2Ce-0.2Cu (wt.%) alloy is developed for additive manufacturing that overcomes the classical tradeoff between conductivity and creep resistance. The rapid-cooling-enabled supersaturation of Zr, and its uniform distribution in α-Al matrix, along with formation of submicron (Ce,Cu)-rich intermetallic particles on solidification lead to unusually high creep resistance at 200 °C. Near-zero secondary creep rates are achieved up to the alloy yield stress (YS) of 65 MPa at 200 °C in as-fabricated state. The Zr-solute-induced dislocation-climb suppression mechanism underlying this improvement also restricts dynamic recovery above YS, as noted from appreciable primary creep and its transitioning to near-zero secondary creep rates. A combination of relatively coarse, epitaxially-grown α-Al grains, low Zr concentration in α-Al, and the impurity-scavenging effect of Ce to purify α-Al matrix produces high electrical conductivity of ∼48 %IACS. Aging precipitation of L1 2 -Al 3 Zr nanoprecipitates doubles the YS (to ∼150 MPa) at room temperature and increases alloy conductivity to ∼58 %IACS, but loss of solid-solution Zr out of α-Al matrix leads to activation of dislocation climb, degrading the creep properties as compared to the supersaturated Al-Zr solid solution in the as-fabricated state. Compared to L1 2 -Al 3 Zr nanoprecipitates, submicron (Ce,Cu)-rich particles formed on solidification are more effective at impeding dislocation climb, producing a threshold stress for dislocation creep of ∼ 50 MPa at 200 °C. The new alloy design concepts, especially solute-induced dislocation-climb suppression for creep resistance, explored here may pave way for the design of new metallic alloys for thermal/electrical conductors and other high-temperature applications.

Additive Manufacturing↗
NASA NTRS1994

Magnetospheric and ionospheric signals in magnetic observatory monthly means: Electrical conductivity of the deep mantle

First differences of magnetic observatory monthly means for 1963-1982 were analyzed using techniques of spherical harmonics analysis and power spectral analysis. The external source signal is shown to be primarily zonal in geomagnetic coordinates. Prominent peaks are present in the power spectrum at frequencies of 1.0 cycle/yr and 2.0 cycles/yr. The annual signal is largest on the degree 2 external zonal spherical harmonic, while the semiannual signal is largest on the degree 1 and degree 3 external zonal spherical harmonics. The presence of the semiannual signal on odd-degree spherical harmonics and of the annual signal on even-degree spherical harmonics was predicted from symmetry considerations and the annual cycle of solar inclination. These signals are all modulated by the sunspot frequency and its harmonics. The degree 1 term is believed to be due mainly to magnetopause and ring currents while the degree 2 and degree 3 terms are believed to be due mainly to ionospheric currents. The degree 1 external zonal harmonic has a continuous spectrum in addition to the semiannual spectral peak. A corresponding degree 1 internal term is due to electromagnetic induction. The degree 1 continuous spectrum is useful for study of the electrical conductivity of the deep mantle. A global geomagnetic response function consistent with a mantle conductivity of about 10 S/m at the core-mantle boundary has been derived.

Mcleod, Malcolm G.↗
DOE OSTI2023

Overview of Electrically Conductive and Active Shielding for Wireless Power Transfer with a Polyphase Wireless Electric Vehicle Charging Study

The development and deployment of wireless power transfer (WPT) is increasing across industries including applications in healthcare, sensing and telecommunications, and electric vehicle charging due to its increased mobility and convenience. An important aspect of wireless power transfer is shielding to limit the intensity of electromagnetic fields (EMF) within external regions to protect users and nearby technology. Within this paper, the classifications and recent developments in shielding technologies are reviewed with discussion on potential benefits and drawbacks towards application for wireless charging of electric vehicles (EV). Additionally, a design study is proposed and simulated in 3D FEA for a novel active shield to substantially reduce magnetic field emissions of a high-power, high-frequency rotating-field 3-phase electromagnetic coupler for quickly charging electric vehicles. The active shield, designed to reduce Z-axis emissions, was found to be highly effective, reducing maximum EMF emissions by 83% in aligned static operation and by 50% with lateral misalignment. Active shielding was also found to strongly mitigate the impact of lateral misalignment at each studied partial alignment.

Lewis, Donovin D.↗
DOE OSTI2021

Understanding Electrical Conduction and Nanopore Formation During Controlled Breakdown

Controlled breakdown has recently emerged as a highly appealing technique to fabricate solid-state nanopores for a wide range of biosensing applications. This technique relies on applying an electric field of approximately 0.4–1 V nm –1 across the membrane to induce a current, and eventually, breakdown of the dielectric. Although previous studies have performed controlled breakdown under a range of different conditions, the mechanism of conduction and breakdown has not been fully explored. Here, electrical conduction and nanopore formation in SiN x membranes during controlled breakdown is studied. It is demonstrated that for Si-rich SiN x , oxidation reactions that occur at the membrane-electrolyte interface limit conduction across the dielectric. However, for stoichiometric Si 3 N 4 the effect of oxidation reactions becomes relatively small and conduction is predominately limited by charge transport across the dielectric. Several important implications resulting from understanding this process are provided which will aid in further developing controlled breakdown in the coming years, particularly for extending this technique to integrate nanopores with on-chip nanostructures.

36 MATERIALS SCIENCE↗
NASA NTRS1988

Nonlinear dynamics in cardiac conduction

Electrical conduction in the heart shows many phenomena familiar from nonlinear dynamics. Among these phenomena are multiple basins of attraction, phase locking, and perhaps period-doubling bifurcations and chaos. We describe a simple cellular-automation model of electrical conduction which simulates normal conduction patterns in the heart as well as a wide range of disturbances of heart rhythm. In addition, we review the application of percolation theory to the analysis of the development of complex, self-sustaining conduction patterns.

NASA Discipline Cardiopulmonary↗
DOE OSTI2021

dc electrical conductivity in strongly magnetized plasmas

A generalized Ohm's law is derived to treat strongly magnetized plasmas in which the electron gyrofrequency significantly exceeds the electron plasma frequency. Here, strong magnetization of electrons causes the frictional drag between electrons and ions due to Coulomb collisions to shift, producing an additional transverse resistivity term in the generalized Ohm's law that is perpendicular to both the current ($J$) and the Hall ($JxB$) direction. In the limit of very strong magnetization the parallel resistivity is found to increase by a factor of 3/2, and the perpendicular resistivity by a factor of $\frac{3}{4} \ln (m_i/m_e)$, where $m_i$ and $m_e$ are the ion and electron masses. These results suggest that strong magnetization significantly changes the magnetohydrodynamic evolution of a plasma.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2021

Removal of As(III) by Electrically Conducting Ultrafiltration Membranes

As(III) species are the predominant form of arsenic found in groundwater. However, nanofiltration (NF) and reverse osmosis (RO) membranes are often unable to effectively reject As(III). In this study, we fabricate highly conducting ultrafiltration (UF) membranes for effective As(III) rejection. Here, these membranes consist of a hydrophilic nickel-carbon nanotubes layer deposited on a UF support, and used as cathodes. Applying cathodic potentials significantly increased As(III) rejection in synthetic/real tap water, a result of locally elevated pH that is brought upon through water electrolysis at the membrane/water interface. The elevated pH conditions convert H 3 ASO 3 to H 2 AsO 3 – /HAsO 3 2– that are rejected by the negatively charged membranes. In addition, it was found that Mg(OH) 2 that precipitates on the membrane can further trap arsenic. Importantly, almost all As(III) passing through the membranes is oxidized to As(V) by hydrogen peroxide produced on the cathode, which significantly decreased its overall toxicity and mobility. Although the high pH along the membrane surface led to mineral scaling, this scale could be partially removed by backwashing the membrane. To the best of our knowledge, this is the first report of effective As(III) removal using low-pressure membranes, with As(III) rejection higher than that achieved by NF and RO, and high water permeance.

42 ENGINEERING↗
DOE OSTI2020

Investigation of Failure Modes, Mechanisms and Driving Forces for Electrically Conductive Adhesives as Interconnects in PV Modules

In this work we describe our current progress into investigating the reliability of ECA interconnects for PV modules. Preliminary thermal cycling experiments demonstrated that both cohesive and adhesive failure of the ECA joint are relevant failure modes that result in an increase of the joints electrical resistance. A thorough viscoelastic characterization of the candidate ECA was conducted to enable accurate numerical modeling of the joint’s response to thermal cycling. Combined with critical and subcritical fracture measurements, the numerical model elucidates that an additional fatigue mechanism exists which can result in fracture well below subcritical debonding threshold values. It is also demonstrated that fracture of the ECA is more sensitive to humidity than temperature and subcritical debonding mechanisms do exist which are again more sensitive to humidity.

41 EE - Solar Energy Technologies Office (EE-4S)↗
NASA NTRS1982

Electrochemical intercalation and electrical conductivity of graphite fibers

Lamellar compounds of graphite fibers were prepared by electrochemical intercalation. The dependence of the electrical resistance on the intercalate concentration was determined by a quasi simultaneous method. A factor 30 decrease of the relative fiber resistance was obtained with fluorosulfuric acid.

Besenhard, J. O.↗