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At least 289 records · Page 16

Mission Configuration Tree for the James Webb Space Telescope (JWST)

The GSFC Mission Configuration web-based application is a means of documenting the structure of the many elements used in building each mission that NASA launches, as well as archiving the documents associated with each of these elements and keeping track of suppliers. This includes all available drawings, engineering orders, parts lists, block diagrams, and photos of each system, subsystem, and component. While the information for several of NASA's missions is being input into Mission Configuration, the ten weeks of this project focused on collecting information for the instrument systems of the James Webb Space Telescope. Documents were collected from a database called the Next Generation Integrated Network (NGIN) so that they can eventually be uploaded into the application. From these documents, including drawings and parts lists, a configuration tree was created in Microsoft Visio which showed the relationships between each system, subsystem, and component. When both these documents and the configuration tree are input into Mission Configuration, they will be place into a drill down tree structure, from which drawings and documents can be accessed directly. Mission Configuration also includes search functions that make all parts searchable by keywords such as vendor, part number, taxonomy, and alternate nomenclature. This application is an important resource for providing access to documents related to the components used on each mission. It has created a central repository for information which can be used to benefit Safety & Mission Assurance, but may also be useful across codes. The process of collecting the information and documents to put into Mission Configuration is also allowing for a concise breakdown of information from diverse formats, creating standardization which makes information more readily accessible, while retaining project-specific information that makes it more easily searchable.

Cain, Mary C.↗

Distributed Sensing Node Configuration

A vision and radar sensor integration strategy for surveillance of Advance Air Mobility Mission concept of airspace is contained in the CAD drawing in this publication developed as part of NASA's Transformational Tools and Technology project. High-density airspace operations with multiple aircraft type and potentially noncooperative aircraft require distributed sensor detection and tracking systems to monitor airspace for safe, autonomous flight operations for advanced air mobility, urban air mobility, and high density small uncrewed air systems (SUAS) flight concepts. Contained herein are drawings that are available in the stp and creo file formats of the distributed sensing nodes. Additional dovetail integration is included to enable rapid changing of embedded system. A day in the life node deployment is included in the 2023_last_flight_day.mp4. Please cite this publication if you use these drawings. This sensor configuration methodology is presented in detail in the publication reference below. Chester Dolph, Thomas Lombaerts, Corey A. Ippolito, Vahram Stepanyan, Evan Kawamura, Keerthana Kannan, George Szatkowski, Todd Ferante, Christopher Morris, Federica Vitiello, Flavia Causa, Roberto Opromolla and Giancarmine Fasano. "Distributed Sensor Fusion of Ground and Air Nodes using Vision and Radar Modalities for Tracking Multirotor Small Uncrewed Air Systems and Birds," AIAA 2024-1781. AIAA SCITECH 2024 Forum. January 2024.

Chester V Dolph↗

Development of Thermoacoustic Sensors for Sodium-cooled Fast Reactors

This Final Report refers to the project “Development of Thermoacoustic Sensors for Sodium-cooled Fast Reactor Systems”, which was led by Westinghouse Electric Company (Westinghouse) and carried out in collaboration with Argonne National Laboratory (ANL) and University of Pittsburgh. Thermo-acoustic Power Sensors (TAPS) are self-powered, wireless sensors envisioned for measuring key parameters, such as local temperature and neutron flux, in a nuclear reactor core. This project was intended to specifically investigate their applicability to Sodium-cooled Fast Reactors (SFR). TAPS are non-invasive (wireless) and passive (self-powered) devices. The passivity derives from their ability to use conditions that “naturally” exist in a nuclear reactor, such as gamma and neutron flux, as power sources. They generate oscillating pressure waves (i.e., sound waves) which, with a frequency and amplitude dependent upon these conditions, can travel through the core and associated structures, and reach the outside of the reactor vessel where a properly designed network of receivers can detect and interpret them. These receivers require a very small amount of power which, during loss of power events, can be provided for example by harvesting gamma radiation energy, thus resulting in a monitoring system that can function both during normal operation and during loss of power events. The project aimed at TAPS development through a series of tasks which are listed and briefly discussed as follows. TASK 1 – Sensor hardware design Subtask 1a: Assessment of sensor applications to SFRs Subtask 1b: Development of sensor functional requirements Subtask 1c: Definition of sensor hardware design specifications Task description: TAPS design was informed by considerations on their application (Subtask 1a), both the ultimate one in an SFR and the actual one in the ANL testing facilities that was intended to be used in support of the project. Considerations were made to identify optimum sensor design features that optimize the sensor size, materials, and output signal, for installation inside an SFR core. These considerations led to the development of Functional Requirements (Subtask 1b) and Design Requirements (Subtask 1c). TASK 2 – Sensor Hardware Manufacture Subtask 2a: Sensor hardware construction drawing development Subtask 2b: Sensor manufacture and assembly Task description: TAPS technical drawings were developed (Subtask 2a) using the Design Requirements established under Task 1. Subsequently, in spite of some problems which ultimately caused the program to be delayed, TAPS manufacturing was completed based on drawings (Subtask 2b). TASK 3 – Development of TAPS Signal Measurement System and TAPS Testing in Water Subtask 3a: Design, assembly and testing of signal measurement system, and TAPS testing in water Subtask 3b: Signal prediction-correction methodology development Task description: An assessment was performed on the techniques that can potentially be used to detect the signals emitted by the TAPS, e.g. a fiber-optic based acoustic signal measurement system, a laser vibrometer system, or an accelerometer-based system. The most suited technology, i.e. the accelerometer-based system, was developed further, and tested in water (Subtask 3a). Moreover, efforts were made to develop the methodology required to determine the actual system temperature and neutron flux distribution using differences between the measured and predicted TAPS responses (Subtask 3b). TASK 4 – Sensor System Testing in Sodium Subtask 4a: Test plan development Subtask 4b: Design, assembly and testing in small-scale sodium facility Subtask 4c: Design, assembly and testing in large-scale sodium and structures facility Task description: Upon proper test plan development (Subtask 4a), the fabricated TAPS was planned to be tested in sodium, by using two sodium facilities at ANL having different size and different purpose. The Under Sodium Viewing (USV) small-scale facility was intended to be used to investigate the effect of sodium on the sensor and its performance (Subtask 4b). The Mechanism Engineering Test Loop (METL) large-scale facility was instead intended to be used to assess the additional effect of prototypical SFR structures, such as fuel assembly mockup or parts of the core restrain structure, on sensor performance (Subtask 4c). As discussed in Section 3.2.2.7, unexpected issues during the TAPS manufacturing process resulted in some activities being delayed, with the TAPS and USV facility developed to the point to be ready for testing in sodium, however without the possibility to actually perform such testing (including the testing in METL) due to the end of the program’s performance period. Overall, through the development and testing (in water only) of two TAPS devices (a First-Generation TAPS followed by an optimized Second-Generation TAPS), the project confirmed the capability of this technology to generate acoustic signals proportional to temperature, which can be detected through a network of accelerometers identified as the best-suited type of receivers for acoustic signal detection. Moreover, the project also developed a computational model to predict the characteristics of the acoustic signals being generated, which combines thermal analysis of the TAPS with Finite Element Modeling (FEM)-aided acoustic characterization of the system. This model was benchmarked against experimental data collected during the project and, although general agreement was obtained, some limitations of the modeling methods were identified, which require additional development. Additional testing is needed in order to assess the effect, on TAPS operation and performance, of environmental changes resulting from the transition from water to liquid sodium. Such testing, which is suggested to be performed in the future, should look specifically at 1) both the effect resulting from the different thermoacoustic behavior of sodium (relative to water) and the effects of higher temperature on TAPS performance, and 2) the performance of the sensor-receiver system when multiple TAPS are used simultaneously and prototypical reactor structures are positioned in the testing environment. The latter testing is needed to assess the effects that potential signal attenuation/ distortion phenomena, as well as potential interference between signals emitted simultaneously, have on the performance of the technology for ultimate application in a nuclear reactor.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Detailed Laboratory Evaluation of Electric Demand Load Shifting Potential of Controlled Heat Pump Water Heaters

The demand profile management of electric end uses is vital research for utilities and policymakers planning greenhouse gas emission reductions. In this study, detailed laboratory research was conducted on the load shifting potential of 4 grid-connected HPWHs and one electric resistance water heaters (ERWH). The testing applied different CTA-2045 shed and critical peak command designs under three water draw profiles. Highly-controlled laboratory experiments were conducted in Florida. One of the four HPWHs was a prototype incorporating the new CTA-2045-B protocol feature allowing ‘advanced’ load-up above tank setpoint. A three-hour morning (6 – 9 AM) and four-hour evening curtailment (4 – 8 PM) were defined as the shed or critical peak periods reflecting high-value control periods for utility coincident load for system-wide electric demand reductions. Tests were performed under baseline conditions (no load shift) and under varied load-shifting schemes, including load up and advanced load up, ahead of shed and critical peak commands. Data were collected from December 2020 – February 2022 in the laboratory and compared with field experiments in Florida and the Pacific Northwest. Grid-connected HPWHs were found to reduce peak demand by up to 0.47 kW compared to uncontrolled HPWH units, depending on time of day, control scheme, draw profile, and temperature cluster. The load up strategy demonstrated the ability of all units to utilize heat pump mode for extended periods ahead of peak events. Demand reductions for the HPWHs were much larger when compared with the ERWH— up to 1.64 kW with large hot water draws in winter.

Fenaughty, Karen↗

Recovery and Recrystallization Behavior of Nb-Containing Fe-Cr-Al Alloys

Nuclear-grade wrought Fe-Cr-Al alloys are currently under development as promising accident-tolerant fuel cladding materials for light water reactors (LWRs) due to their superior oxidation and corrosion resistance in high temperature steam environments when compared with current commercial Zr-based alloys. Sufficient amounts of Cr and Al additions in Fe-Cr-Al alloys provide the improved surface protection effects at both the service temperature and elevated temperatures in the accident case scenario. Minor alloying additions (such as Nb in the current study) also promote the second-phase precipitates to strengthen the alloys; e.g. sub-micron size Fe{sub 2}Nb-type Laves phase precipitates are likely to disperse at both inter- and trans-granular in BCC-Fe matrix after applying proper heat treatments. In LWRs, a seamless tube product is required for the fuel cladding which typically has ∼ 4 m length with an outside diameter of ∼ 10 mm and a wall thickness of less than 0.5 mm, and it imposes considerable challenges for tube fabrication process (e.g. tube drawing) of Fe-Cr-Al alloys. Research has been performed to achieve a balance between high-temperature performance and tube fabricability in newly developed Fe-Cr-Al alloys. BCC-Fe materials with Cr and Al additions typically suffer from poor ductility because of relatively high ductile-brittle transition temperature. In this sense, the microstructural stability of refined grain or subgrain structure, even at high temperature, is critical to maintain the deformability of the alloys during tube fabrication process, as well as sufficient mechanical properties at service condition. In this study, the recovery and recrystallization behaviors of Nb-containing Fe-Cr-Al alloys are studied. A specific focus was to evaluate the stability of the subgrain structure of the deformed Fe-Cr-Al alloys, and seek optimized processing parameters for seamless tube fabrication. The present results clearly demonstrated that the Nb addition stabilizes the refined subgrain microstructures of Fe-Cr-Al alloys below 700 deg. C due to Laves phase precipitations along sub-boundaries when compared with the Nb-free alloys, while maintaining sufficient strengths needed for fuel cladding in LWRs. At the same time, the results also showed that Nb-containing alloys can be softened through suitable annealing to improve the processability of tube drawing process. Detailed characterization efforts of subgrains and Laves phase precipitates are currently in progress. Completion of this work will deepen the understanding of the recovery and recrystallized behavior of Nb-containing Fe-Cr-Al alloys and provide guidelines to tube drawing process in the alloys. (authors)

36 MATERIALS SCIENCE↗

Strain softening during tension in cold drawn Cu–Ag alloys

Experiments were conducted on Cu–0.1wt.%Ag alloys to evaluate the influence of producing procedures and annealing conditions on microstructure evolution and mechanical properties of Cu–Ag alloys. Optical microscopy (OM), electron back-scattered diffraction (EBSD), X-ray diffraction (XRD) and transmission electron microscopy (TEM) were used for microstructural evaluation and mechanical properties were characterized by tensile tests. The results indicated that hot-extruded Cu–Ag alloys had a typical dynamic recrystallized microstructure with equiaxed grains. Cold drawing at room temperature leaded to partial recrystallized microstructure with a mixture of coarse and fine grains. The dominate {001}<100 > cubic texture formed during hot extrusion was changed to be {112}<111 > copper texture by cold drawing. Strain softening occurred during room temperature tension of cold drawn Cu–Ag alloys with an average grain size of 13–19.7 μm. - Highlights: • Strain softening occurred during tension of Cu–Ag alloys with coarse grain size. • Work hardening was observed in hot-extruded and annealed Cu–0.1wt.%Ag alloys. • Strain softening was ascribed to dynamic recovery and dynamic recrystallization.

36 MATERIALS SCIENCE↗

Tailoring the magnetic properties of new Fe-Ni-Co-Al-(Ta,Nb)-B superelastic rapidly quenched microwires

Ferromagnetic Fe-Ni-Co-Al-(Ta,Nb)-B microwires with diameters from 170 μm to 50 μm, which possess both superelastic and good magnetic properties, have been prepared by rapid quenching from the melt using the in rotating water spinning technique followed by cold-drawing and ageing. The cold-drawing and annealing processes lead to the initialization of premartensitic phases as confirmed by the X-ray diffraction and scanning transmission electron microscopic investigations, more significantly in the 50 μm cold-drawn microwires. An increase in the coercive field and in the saturation magnetization has been obtained by annealing, more importantly in the case of Nb-containing alloy. Ageing by thermal or current annealing led to the initialization of the superelastic effect. High values of strain of up to 1.8%, very good repeatability under successive loading, and values of superelastic effect of up to 1.2% have been achieved. The structural analysis coupled with the stress-strain data suggests that these materials annealed at 800 °C have superelastic potential at reduced ageing times. The magnetic behavior was found to be easily tailored through both thermal and thermomagnetic treatments with changes in the magnetic parameters which can be contactless detected. The results are important for future applications where both mechanical and magnetic properties matter, i.e., sensing/actuating systems.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Experimental investigations of ablation stream interaction dynamics in tungsten wire arrays: Interpenetration, magnetic field advection, and ion deflection

Experiments have been carried out to investigate the collisional dynamics of ablation streams produced by cylindrical wire array z-pinches. A combination of laser interferometric imaging, Thomson scattering, and Faraday rotation imaging has been used to make a range of measurements of the temporal evolution of various plasma and flow parameters. This paper presents a summary of previously published data, drawing together a range of different measurements in order to give an overview of the key results. The paper focuses mainly on the results of experiments with tungsten wire arrays. Early interferometric imaging measurements are reviewed, then more recent Thomson scattering measurements are discussed; these measurements provided the first direct evidence of ablation stream interpenetration in a wire array experiment. Combining the data from these experiments gives a view of the temporal evolution of the tungsten stream collisional dynamics. In the final part of the paper, we present new experimental measurements made using an imaging Faraday rotation diagnostic. These experiments investigated the structure of magnetic fields near the array axis directly; the presence of a magnetic field has previously been inferred based on Thomson scattering measurements of ion deflection near the array axis. Although the Thomson and Faraday measurements are not in full quantitative agreement, the Faraday data do qualitatively supports the conjecture that the observed deflections are induced by a static toroidal magnetic field, which has been advected to the array axis by the ablation streams. It is likely that detailed modeling will be needed in order to fully understand the dynamics observed in the experiment.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Viability of thin wall tube forming of ATF FeCrAl

Fabrication of thin walled tubing of FeCrAl alloys is critical to its success as a candidate enhanced accident-tolerant fuel cladding material. Alloys that are being investigated are Generation I and Generation II FeCrAl alloys produced at ORNL and an ODS FeCrAl alloy, MA-956 produced by Special Metals. Gen I and Gen II FeCrAl alloys were provided by ORNL and MA-956 was provided by LANL (initially produced by Special Metals). Three tube development efforts were undertaken. ORNL led the FeCrAl Gen I and Gen II alloy development and tube processing studies through drawing tubes at Rhenium Corporation. LANL received alloys from ORNL and led tube processing studies through drawing tubes at Century Tubing. PNNL led the development of tube processing studies on MA-956 through pilger processing working with Sandvik Corporation. A summary of the recent progress on tube development is provided in the following report and a separate ORNL report: ORNL/TM-2015/478, “Development and Quality Assessments of Commercial Heat Production of ATF FeCrAl Tubes”.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Preparation of Waste Fingerprints for the Miscellaneous Beta Gamma Waste Feeds to the Box Encapsulation Plant at Sellafield - 16080

There are a number of legacy pond and silo storage facilities on Sellafield Site that contain a broad range of ILW arising from the early Windscale Pile and Magnox Fuel Reprocessing Programmes. The waste comprises of solid Miscellaneous Beta Gamma Waste (MBGW) from operations (including filters, containerised waste, thermocouple wire, support struts, pumps, soft wastes) and associated sludges that have arisen from the corrosion of the fuel, Magnox Swarf cladding and the MBGW. It is intended to retrieve and package this waste to meet the requirements of interim storage and final disposal in the Box Encapsulation Plant (BEP) at Sellafield. As part of this process each package must be assigned a realistic and justifiable radionuclide and material inventory. These inventories can either be assigned by radiometric measurements including the associated errors or developed by fundamental data underpinning these assessments and a 'chain of custody' approach of knowing where the waste has been and how it has evolved. The subject of this paper is concerned with the development of the waste fingerprints for these legacy waste streams. As the wastes have arisen over a ∼70 year period there have been an assortment of different working practices and developments in equipment design that have led to significant variations in the waste condition and its composition. During storage the waste items have become mixed, corroded and sludge deposits have arisen. Because of this, and that early consignment records are either incomplete or missing, the task of assigning material and radionuclide fingerprints has been very challenging. In addition, to comply with regulatory requirements the inventory assignment has to be sufficiently robust to meet the processing envelope of the encapsulation process i.e. to allow controls to be made on the amounts of reactive materials (e.g. aluminium, Magnox and uranium) that can be processed within each product and allow identification of excluded items from being consigned from the donor plants. Also, as the waste comprises actinides, fission and activation products it was noted that whilst the UK standard inventory code FISPIN10 predicts the actinides and fission products well, there was a significant discrepancy in the prediction of activation products when compared with those predicted by the specialised fusion code FISPACT. It should be noted that the use of FISPACT to predict actinides and fission products is not recommended. To address these issues, - position statements were produced for each of the waste streams that would be consigned to BEP; - gaps within the data were assessed and where possible inactive trial work was identified to address it; - material and radionuclide fingerprint justification documents were developed from the position statements based upon available data, the experimental work and justified assumptions; - where FISPIN runs were required, these were run with a modified activation data library based on the European Activation File 2010 (EAF2010) to model the activation products. This paper summarises the BEP process, discusses examples of how the material and radionuclide waste stream fingerprints have been justified by revisiting the sample data, original consignment records, engineering drawings and recent remotely operated vehicle (ROV) pond surveys and making reasoned assumptions based on operational practices and non-active experimental work. Incorporation of the EAF2010 library within the FISPIN code has offered significant benefits to BEP and indeed other plants processing mixed fission and activated wastes as it allows comparable predictions of activation products compared with that made by FISPACT and for the plant to maintain one data processing stream rather than two if it had to utilise both modelling codes. This work will underpin the inventory submission in support of the Interim Letter of Compliance (ILoC) to Radioactive Waste Management Limited (RWM). The process of examining the original records, plant operation schedules and engineering drawings has enabled removal of some of the pessimisms that have been made in previous assessments. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Transparent, High‐Charge Capacity Metal Mesh Electrode for Reversible Metal Electrodeposition Dynamic Windows with Dark‐State Transmission <0.1%

Abstract Dynamic windows allow user control over light and heat flow to save energy and maximize comfort. Reversible metal electrodeposition (RME) dynamic windows can uniquely tint to a color‐neutral privacy state (0.1% visible light transmission). The design parameters of transparent metal mesh counter electrodes for high‐contrast RME dynamic windows: high transparency, charge capacity and surface area with low haze, sheet resistance and cost are discussed, concluding that woven metal meshes meet these design parameters. Electroplated current is measured on an indium tin oxide electrode and two meshes with different wire spacings, showing the meshes’ cylindrical geometry enable them to draw more current per square area. The mesh material composition is analyzed to ensure cycling durability in a CuBi electrolyte by developing a transparent mesh with an inert core (stainless steel, SS), a thin Au coating, and a high charge‐capacity (1.5 C cm −2 ) CuBi outer coating. The study demonstrates that the films maintain a consistent Cu:Bi ratio and optical properties after 250 privacy cycles or 1500 cycles to 10% transmission, showing that the Cu and Bi coating is effective in keeping the films from becoming Cu rich with cycling. Finally, a 100 cm 2 device with excellent uniformity and color neutrality is demonstrated.

Yeang, Andrew L.↗

Enhancing CO 2 Transport Across a PEEK‐Ionene Membrane and Water‐Lean Solvent Interface

Abstract Efficient direct air capture (DAC) of CO 2 will require strategies to deal with the relatively low concentration in the atmosphere. One such strategy is to employ the combination of a CO 2 ‐selective membrane coupled with a CO 2 capture solvent acting as a draw solution. Here, the interactions between a leading water‐lean carbon‐capture solvent, a polyether ether ketone (PEEK)‐ionene membrane, CO 2 , and combinations were probed using advanced NMR techniques coupled with advanced simulations. We identify the speciation and dynamics of the solvent, membrane, and CO 2 , presenting spectroscopic evidence of CO 2 diffusion through benzylic regions within the PEEK‐ionene membrane, not spaces in the ionic lattice as expected. Our results demonstrate that water‐lean capture solvents provide a thermodynamic and kinetic funnel to draw CO 2 from the air through the membrane and into the bulk solvent, thus enhancing the performance of the membrane. The reaction between the carbon‐capture solvent and CO 2 produces carbamic acid, disrupting interactions between the imidazolium (Im + ) cations and the bistriflimide anions within the PEEK‐ionene membrane, thereby creating structural changes through which CO 2 can diffuse more readily. Consequently, this restructuring results in CO 2 diffusion at the interface that is faster than CO 2 diffusion in the bulk carbon‐capture solvent.

Walter, Eric D.↗

Sodium Peroxide Dihydrate or Sodium Superoxide: The Importance of the Cell Configuration for Sodium–Oxygen Batteries

In sodium–oxygen (Na–O 2 ) batteries, multiple discharge products have been observed by different research groups. Given the fact that different materials, gas supplies, and cell configurations are used by different groups, it is a great challenge to draw a clear conclusion on the formation of the different products. Here, two different cell setups are used to investigate the cell chemistries of Na–O 2 batteries. With the same materials and gas supplies, a peroxide‐based product is observed in a glass chamber cell and a superoxide‐based product is observed in a stainless‐steel cell. Ex situ high‐energy X‐ray diffraction (HEXRD) and Raman spectroscopy are performed to investigate the structure and composition of the product. In addition, in situ XRD is used to investigate the structure evolution of the peroxide‐based product. The findings highlight the importance of the cell design and emphasize the critical environment of the formation of the discharge products of Na–O 2 batteries.

Bi, Xuanxuan↗

Pore-Scale Simulation of Intragranular Diffusion: Effects of Incomplete Mixing on Macroscopic Manifestations

Diffusive mass transfer into and out of intragranular micropores ("intragranular diffusion") plays an important role in the large-scale transport of some groundwater contaminants. We are interested in understanding the combined effect of pore-scale advection and intragranular diffusion on solute transport at the effective porous medium scale. To study this problem, we have developed a three-dimensional pore-scale model of fluid flow and solute transport that incorporates diffusion into and out of intragranular pore spaces. Our model is based on the Smoothed Particle Hydrodynamics (SPH) simulation method, which represents fluid and solid phases by a mesh-free particle discretization. In the pore spaces, fluid flow is simulated by discretizing the Navier-Stokes equations using the SPH approach. Solute transport is represented by advection, diffusion within the fluid phase, and diffusion between the fluid and solid phases. Our model is implemented on large-scale parallel computing hardware, allowing us to simulate millions of computational particles and represent fully three-dimensional systems of pores and grains with arbitrarily complex physical geometry. We have used this model system to perform numerical experiments using various model porous media systems, which allows us to draw comparisons between macroscopic measures computed from the pore-scale simulations (such as breakthrough curves) and those predicted by macroscopic formulations that assume complete mixing over the representative volume. In this paper we present results of 3D simulations of pore-scale flow and transport, including cases with and without intragranular diffusion, in two model porous media, one with randomly-packed uniform spherical grains and a second with randomly-packed spheres drawn from a binary grain size distribution. Breakthrough curves were computed from the 3D simulations at various transport distances. Comparable breakthrough curves were computed using 1D macroscopic models with parameters determined independently to the degree possible. Based on comparisons of the pore-scale and macroscopic model results, we draw two primary conclusions. First, non-Fickian behavior is persistent and ubiquitous at the scales considered, and most cases are better represented by a multi-rate mass transfer model even when there is no distinct secondary porosity (i.e., no intragranular diffusion). This suggests that diffusive mass transfer processes between preferential flow paths and relatively immobile zones within the primary porosity may have significant impact on transport, particular in low-concentration tails. Second, the application of mass transfer rate parameters based on an assumption of well-mixed concentrations at the pore-scale tend to overestimate the amount of mass transfer that occurs in heterogeneous pore geometries in which preferential flow leads to incomplete pore-scale lateral mixing.

Environmental Molecular Sciences Laboratory↗

Looking for a bulk point

Here, we consider Lorentzian correlators of local operators. In perturbation theory, singularities occur when we can draw a position-space Landau diagram with null lines. In theories with gravity duals, we can also draw Landau diagrams in the bulk. We also argue that certain singularities can arise only from bulk diagrams, not from boundary diagrams. As has been previously observed, these singularities are a clear diagnostic of bulk locality. We analyze some properties of these perturbative singularities and discuss their relation to the OPE and the dimensions of double-trace operators. In the exact nonperturbative theory, we expect no singularity at these locations. Finally, we prove this statement in 1+1 dimensions by CFT methods.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

LHC SUSY and WIMP dark matter searches confront the string theory landscape

The string theory landscape of vacua solutions provides physicists with some understanding as to the magnitude of the cosmological constant. Similar reasoning can be applied to the magnitude of the soft SUSY breaking terms in supersymmetric models of particle physics: there appears to be a statistical draw towards large soft terms which is tempered by the anthropic requirement of the weak scale lying not too far from ~100 GeV. For a mild statistical draw of m softn with n = 1 (as expected from SUSY breaking due to a single F term) then the light Higgs mass is preferred at ~125 GeV while sparticles are all pulled beyond LHC bounds. We confront a variety of LHC and WIMP dark matter search limits with the statistical expectations from a fertile patch of string theory landscape. The end result is that LHC and WIMP dark matter detectors see exactly that which is expected from the landscape: a Standard Model-like Higgs boson of mass 125 GeV but as yet no sign of sparticles or WIMP dark matter. SUSY from the n = 1 landscape is most likely to emerge at LHC in the soft opposite-sign dilepton plus jet plus MET channel. Multi-ton noble liquid WIMP detectors should be able to completely explore the n = 1 landscape parameter space.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

A nonparametric method for producing isolines of bivariate exceedance probabilities

We present a method for drawing isolines indicating regions of equal joint exceedance probability for bivariate data. The method relies on bivariate regular variation, a dependence framework widely used for extremes. The method we utilize for characterizing dependence in the tail is largely nonparametric. The extremes framework enables drawing isolines corresponding to very low exceedance probabilities and may even lie beyond the range of the data; such cases would be problematic for standard nonparametric methods. Furthermore, we extend this method to the case of asymptotic independence and propose a procedure which smooths the transition from hidden regular variation in the interior to the first-order behavior on the axes. We propose a diagnostic plot for assessing the isoline estimate and choice of smoothing, and a bootstrap procedure to visually assess uncertainty.

97 MATHEMATICS AND COMPUTING↗