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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 289 records · Page 16

Chemomechanically Stable Ultrahigh-Ni Single-Crystalline Cathodes with Improved Oxygen Retention and Delayed Phase Degradations

The pressing demand in electrical vehicle (EV) markets for high-energy-density lithium-ion batteries (LIBs) requires further increasing the Ni content in high-Ni and low-Co cathodes. However, the commercialization of high-Ni cathodes is hindered by their intrinsic chemomechanical instabilities and fast capacity fade. The emerging single-crystalline strategy offers a promising solution, yet the operation and degradation mechanism of single-crystalline cathodes remain elusive, especially in the extremely challenging ultrahigh-Ni (Ni > 90%) regime whereby the phase transformation, oxygen loss, and mechanical instability are exacerbated with increased Ni content. Herein, we decipher the atomic-scale stabilization mechanism controlling the enhanced cycling performance of an ultrahigh-Ni single-crystalline cathode. We find that the charge/discharge inhomogeneity, the intergranular cracking, and oxygen-loss-related phase degradations that are prominent in ultrahigh-Ni polycrystalline cathodes are considerably suppressed in their single-crystalline counterparts, leading to improved chemomechanical and cycling stabilities of the single-crystalline cathodes. Furthermore, our work offers important guidance for designing next-generation single-crystalline cathodes for high-capacity, long-life LIBs.

25 ENERGY STORAGE↗

Large Polaron Screening Delays Mobility Roll-Off in Halide Perovskites under High Injection

The interplay between carrier density regimes and the various scattering processes is fundamental for understanding charge transport efficiency in high-performance semiconductors. Combining ultrafast time-resolved terahertz spectroscopy (TRTS) and transient microwave photoconductivity (TRMC), we measure carrier mobilities over 7 orders of magnitude (10 13 –10 20 carriers cm –3 ), reaching a regime where carrier–carrier scattering dominates and mobility begins to roll off. We find the Caughey–Thomas model can be effectively employed for transport modeling in 3D metal halide perovskites (MHPs), and the mobility roll-off near ∼10 19 cm –3 can be tuned by MHP composition. Carrier lifetime in MHPs starts decreasing at much lower carrier densities due to interband multi-carrier recombination, while intraband carrier mobility remains unchanged as carrier–carrier scattering is screened by the presence of polarons. The validated Caughey–Thomas model provides a practical input for device simulations, prevents overestimation of diffusion length under high injection, and suggests that MHPs are excellent candidates for unipolar device applications under high carrier densities.

14 SOLAR ENERGY↗

The Impact of Sudden Commencements on Ground Magnetic Field Variability: Immediate and Delayed Consequences

Abstract We examine how Sudden Commencements (SCs) and Storm Sudden Commencements (SSCs) influence the occurrence of high rates of change of the magnetic field ( R ) as a function of geomagnetic latitude. These rapid, high amplitude variations in the ground‐level geomagnetic field pose a significant risk to ground infrastructure, such as power networks, as the drivers of geomagnetically induced currents. We find that rates of change of ∼30 nT min −1 at near‐equatorial stations are up to 700 times more likely in an SC than in any random interval. This factor decreases with geomagnetic latitude such that rates of change around 30 nT min −1 are only up to 10 times more likely by 65°. At equatorial latitudes we find that 25% of all R in excess of 50 nT min −1 occurs during SCs. This percentage also decreases with geomagnetic latitude, reaching ≤1% by 55°. However, the time period from the SC to 3 days afterward accounts for ≥90% of geomagnetic field fluctuations over 50 nT min −1 , up to ∼60° latitude. Above 60°, other phenomena such as isolated substorms account for the majority of large R . Furthermore, the elevated rates of change observed during and after SCs are solely due to those classified as SSCs. These results show that SSCs are the predominant risk events for large R at mid and low latitudes, but that the risk from the SC itself decreases with latitude.

Smith, Andrew W.↗