Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “condensed phase systems”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 289 records · Page 16

Mass spectrometer use in a large chamber

The early satellites were somewhat insensitive to contamination produced during the construction and testing phases. The On-Orbit lifetime was such that contamination effects went either unnoticed or unrecognized. With today's On-Orbit lifetimes approaching 10+ years, contamination has become a paramount concern. The scientific payloads have increased in complexity and sensitivity. The ability to clean a contaminated sensor has greatly diminished. This requires better pumping systems and methods for improved monitoring. The conversion from diffusion pumped thermal vacuum chambers to cryo pumped chambers with the use of Misner traps and selective cold traps has reduced contamination. Witness samples supply a record of the condensates that remain after a testing cycle, but impart no knowledge of the contaminant migration during the cycle that may be a month in duration. Due to a customer's request that mass spectrometry be used during the testing of their spacecraft, a consultant was contracted to install a mass spectrometer to determine the feasibility of the instrument. The equipment and methodology described will start with the original system and its evolution to GE's present system.

Chuvala, Tom↗

A new interpretation of luminous blue stars

A major revision of current theoretical ideas about the brightest blue stars must be made if Carson's (1976) radiative opacities are adopted in stellar models. Unlike earlier opacities, these exhibit a large 'bump' due to CNO ionization, which leads to very strong central condensation, convective instability, and pulsational instability in hot diffuse stellar envelopes. Despite a number of theoretical uncertainties, the new picture of the structure of very luminous stars is reasonably successful in accounting for a variety of previously unexplained observations. The stellar models for the phase of core hydrogen burning predict large radii and rather cool effective temperatures for O stars and a spreading out of the main-sequence band in the H-R diagram toward luminous cool supergiants for masses higher than about 20 solar masses. In massive X-ray binary systems, circular orbits and supergiant-like visual companions are expected to be quite common. Long-period variability is predicted to exist for massive blue supergiants of luminosity class Ia. The models for helium stars predict large radii and rather cool effective temperatures for Wolf-Rayet stars, as well as multimodal pulsational instability and, possibly, surface turbulence for these stars.

Stothers, R.↗

Lunar Sulfur Capture System

The Lunar Sulfur Capture System (LSCS) protects in situ resource utilization (ISRU) hardware from corrosion, and reduces contaminant levels in water condensed for electrolysis. The LSCS uses a lunar soil sorbent to trap over 98 percent of sulfur gases and about two-thirds of halide gases evolved during hydrogen reduction of lunar soils. LSCS soil sorbent is based on lunar minerals containing iron and calcium compounds that trap sulfur and halide gas contaminants in a fixed-bed reactor held at temperatures between 250 and 400 C, allowing moisture produced during reduction to pass through in vapor phase. Small amounts of Earth-based polishing sorbents consisting of zinc oxide and sodium aluminate are used to reduce contaminant concentrations to one ppm or less. The preferred LSCS configuration employs lunar soil beneficiation to boost concentrations of reactive sorbent minerals. Lunar soils contain sulfur in concentrations of about 0.1 percent, and halogen compounds including chlorine and fluorine in concentrations of about 0.01 percent. These contaminants are released as gases such as H2S, COS, CS2,HCl, and HF during thermal ISRU processing with hydrogen or other reducing gases. Removal of contaminant gases is required during ISRU processing to prevent hardware corrosion, electrolyzer damage, and catalyst poisoning. The use of Earth-supplied, single-use consumables to entirely remove contaminants at the levels existing in lunar soils would make many ISRU processes unattractive due to the large mass of consumables relative to the mass of oxygen produced. The LSCS concept of using a primary sorbent prepared from lunar soil was identified as a method by which the majority of contaminants could be removed from process gas streams, thereby substantially reducing the required mass of Earth-supplied consumables. The LSCS takes advantage of minerals containing iron and calcium compounds that are present in lunar soil to trap sulfur and halide gases in a fixedbed reactor downstream of an in-ISRU process such as hydrogen reduction. The lunar-soil-sorbent trap is held at a temperature significantly lower than the operating temperature of the hydrogen reduction or other ISRU process in order to maximize capture of contaminants, but is held at a high enough temperature to allow moisture to pass through without condensing. The lunar soil benefits from physical beneficiation to remove ultrafine particles (to reduce pressure drop through a fixed bed reactor) and to upgrade concentrations of iron and/or calcium compounds (to improve reactivity with gaseous contaminants).

Berggren, Mark↗

Reaction Mechanisms and Particle Interaction in Burning Two-Phase Systems

The main objective of this research is to understand the mechanisms by which particle interactions affect ignition and combustion in the two-phase systems. Combustion of metal aerosols representing the two-phase systems is carried out in the microgravity environment enabling one to avoid the buoyant flows that mask the particle motion due to the particle-particle interaction effects. In addition, relatively large, e.g., 100 micron diameter particles can be used, that remain aerosolized (i.e., do not fall down as they would at normal gravity) so that their behavior ahead, behind, and within the propagating flame can be resolved optically. An experimental apparatus exploiting this approach has been designed for the 2.2-s drop tower microgravity experiments. A typical experiment includes fluidizing metal particles under microgravity in an acoustic field, turning off the acoustic exciter, and igniting the created aerosol at a constant pressure using a hot wire igniter. The flame propagation and details of the individual particle combustion and particle interactions are studied using high-speed movie and video cameras coupled with microscope lenses to resolve individual particles. Recorded flame images are digitized and various image processing techniques including flame position tracking, color separation, and pixel by pixel image comparisons are employed to understand the processes occurring in the burning aerosols. Condensed combustion products are collected after each experiment for the phase, composition, and morphology analyses. New experiments described in this paper address combustion of Ti and Al particle clouds in air and combustion of Mg particle clouds in CO2. In addition, microgravity combustion experiments have been conducted with the particles of the newly produced Al-Mg mechanical alloys aerosolized in air.

Dreizin, Edward L.↗

Heat Transfer and Fluid Mechanics Institute, Meeting, 26th, Washington State University, Pullman, Wash., June 26-28, 1978, Proceedings

Papers are presented on the heat transfer and fluid mechanics in energy systems including diesel combustion analysis using rapid sampling and the numerical simulation of thermal response of architectural structures. Experiments associated with hypersonic boundary layers, the prediction of nozzle-wall pressure distribution, and the effects of nozzle geometry on an axisymmetric thrust augmentor are outlined. Predictions are made of film thickness on a roll-metering device and the thermal characteristics of multiple-surface submerged condenser modules are described. Numerical studies are made of the interaction between natural and forced convection in a complex geometry and of pressure drop and holdup in two-phase stratified flow. A numerical solution is given for viscous flows at high Reynolds numbers and for compressible boundary layer flows near separation or reattachment. The structure and transport properties in turbulent shear flows are reviewed along with the spectra of Reynolds stresses in a developing pipe flow.

Crowe, C. T.↗

A model of active prominences

A one-dimensional numerical model of active loop prominences is investigated. The model includes the effects of gravity, the geometry of the magnetic field, and conduction losses to the chromosphere. Calculations indicate that, as originally proposed by Goldsmith, the thermal instability mechanism is, by itself, sufficient to account for the appearance of bright H-alpha knots in postflare loops. Under certain conditions, initial perturbations in the loop temperature and density profiles of small, but finite, amplitude (approximately 5%) and large size scale (greater than or approximately equal to 10 to the 9th cm) can grow into condensations with temperature and density differences of over an order of magnitude and size scales of less than 10 to the 8th cm. In agreement with observations, the conditions that must be satisfied are such that loop prominence systems are likely to occur only in large flares and such that knots preferentially form at the tops of loops. The velocities, densities, and lifetimes calculated for the loop material are also in agreement with observations. It is concluded that in order for H-alpha knots to occur, heating of some form must continue into the late cooling phase of a flare loop, and that this heating is more intense near the loop base than near the apex.

Antiochos, S. K.↗

Origin and chemistry of comets

Long-period and short-period comets are all derived from a steady flux of 'new' comets coming straight from the margin of a sphere whose radius is 50,000 AU (the Oort's cloud). No empirical evidence requires that the Oort's cloud be older than a few million years, but all satisfactory theories have so far linked its formation to the origin of the solar system. 'New' comets have a size distribution consistent with the accretion of planetesimals, in contrast with older comets that are consistent with a fragmentation distribution. The H, C, N, O elemental ratios to Si suggest the comets are more primitive than the most primitive meteorites, namely the C I chondrites. Their chemistry is poorly known, but observational data suggest a protosolar ratio of C/O at least as large as 0.66, and a drastic depletion of hydrogen in the solar nebula. This could for instance imply that the T Tauri phase of the sun happened prior to the condensation of comets. An alternate explanation is possible: the interstellar grains were relatively unprocessed during their contraction in the solar nebula, and their mantles, barely modified, would have followed suit in the accretion of comets.

Delsemme, A. H.↗

Vapor phase pyrolysis

The vapor phase pyrolysis process is designed exclusively for the lunar production of oxygen. In this concept, granulated raw material (soil) that consists almost entirely of metal oxides is vaporized and the vapor is raised to a temperature where it dissociates into suboxides and free oxygen. Rapid cooling of the dissociated vapor to a discrete temperature causes condensation of the suboxides, while the oxygen remains essentially intact and can be collected downstream. The gas flow path and flow rate are maintained at an optimum level by control of the pressure differential between the vaporization region and the oxygen collection system with the aid of the environmental vacuum.

Steurer, Wolfgang↗

CFD Modeling of Helium Pressurant Effects on Cryogenic Tank Pressure Rise Rates in Normal Gravity

A recently developed computational fluid dynamics modeling capability for cryogenic tanks is used to simulate both self-pressurization from external heating and also depressurization from thermodynamic vent operation. Axisymmetric models using a modified version of the commercially available FLOW-3D software are used to simulate actual physical tests. The models assume an incompressible liquid phase with density that is a function of temperature only. A fully compressible formulation is used for the ullage gas mixture that contains both condensable vapor and a noncondensable gas component. The tests, conducted at the NASA Marshall Space Flight Center, include both liquid hydrogen and nitrogen in tanks with ullage gas mixtures of each liquid's vapor and helium. Pressure and temperature predictions from the model are compared to sensor measurements from the tests and a good agreement is achieved. This further establishes the accuracy of the developed FLOW-3D based modeling approach for cryogenic systems.

Grayson, Gary↗

One-Dimensional, Two-Phase Flow Modeling Toward Interpreting Motor Slag Expulsion Phenomena

Aluminum oxide slag accumulation and expulsion was previously shown to be a player in various solid rocket motor phenomena, including the Space Shuttle's Reusable Solid Rocket Motor (RSRM) pressure perturbation, or "blip," and phantom moment. In the latter case, such un ]commanded side accelerations near the end of burn have also been identified in several other motor systems. However, efforts to estimate the mass expelled during a given event have come up short. Either bulk calculations are performed without enough physics present, or multiphase, multidimensional Computational Fluid Dynamic analyses are performed that give a snapshot in time and space but do not always aid in grasping the general principle. One ]dimensional, two ]phase compressible flow calculations yield an analytical result for nozzle flow under certain assumptions. This can be carried further to relate the bulk motor parameters of pressure, thrust, and mass flow rate under the different exhaust conditions driven by the addition of condensed phase mass flow. An unknown parameter is correlated to airflow testing with water injection where mass flow rates and pressure are known. Comparison is also made to full ]scale static test motor data where thrust and pressure changes are known and similar behavior is shown. The end goal is to be able to include the accumulation and flow of slag in internal ballistics predictions. This will allow better prediction of the tailoff when much slag is ejected and of mass retained versus time, believed to be a contributor to the widely-observed "flight knockdown" parameter.

Kibbey, Timothy P.↗

Total Water Content Measurements with an Isokinetic Sampling Probe

The NASA Glenn Research Center has developed a Total Water Content (TWC) Isokinetic Sampling Probe. Since it is not sensitive to cloud water particle phase nor size, it is particularly attractive to support super-cooled large droplet and high ice water content aircraft icing studies. The instrument is comprised of the Sampling Probe, Sample Flow Control, and Water Vapor Measurement subsystems. Analysis and testing have been conducted on the subsystems to ensure their proper function and accuracy. End-to-end bench testing has also been conducted to ensure the reliability of the entire instrument system. A Stokes Number based collection efficiency correction was developed to correct for probe thickness effects. The authors further discuss the need to ensure that no condensation occurs within the instrument plumbing. Instrument measurements compared to facility calibrations from testing in the NASA Glenn Icing Research Tunnel are presented and discussed. There appears to be liquid water content and droplet size effects in the differences between the two measurement techniques.

Reehorst, Andrew L.↗

2019 NASA Division of Space Life and Physical Sciences Research and Applications Fluid Physics Workshop Report

On October 16 and 17, 2019, NASA’s Space Life and Physical Sciences Research and Applications (SLPSRA) Division held the 2019 NASA SLPSRA Fluid Physics Workshop at the Glenn Research Center in Cleveland, Ohio. Researchers from academia, industry, and Government agencies gathered to provide recommendations to NASA on exploration-related microgravity challenges in multiphase systems and thermal transport processes. The goal of the workshop was to identify overarching future research themes relevant to NASA’s exploration goals in three key areas: (1) boiling and condensation; (2) water recovery; and (3) heat pipes.

microgravity↗

Evolution of Ca-Al-rich bodies in the earliest solar system Growth by incorporation

Thirty different Allende Ca-Al-rich inclusions (CAIs), 11 of type A and 19 of type B, were examined for spinel palisades and framboids, and the possible origins of these structures are discussed. Possible mechanisms for in situ formation of palisades are assessed, all of them either being rejected outright or considered highly implausible. The evidence for external formation and incorporation of palisade bodies is then assessed, and possible mechanisms are considered. It is proposed that type B CAIs are residues from the heating and incomplete evaporation of interstellar dust during the accretion of the protosolar nebula, and that type A CAIs are later condensates from completely evaporated dust whose exotic O-16-rich component became more diluted in the gas phase.

Wark, D. A.↗

Modeling of zero gravity venting: Studies of two-phase heat transfer under reduced gravity

The objective is to predict the pressure response of a saturated liquid-vapor system when undergoing a venting or depressurization process in zero gravity at low vent rates. An experimental investigation of the venting of cylindrical containers partially filled with initially saturated liquids was previously conducted under zero-gravity conditions and compared with an analytical model which incorporated the effect of interfacial mass transfer on the ullage pressure response during venting. A new model is presented to improve the estimation of the interfacial mass transfer. Duhammel's superposition integral is incorporated to approximate the transient temperature response of the interface, treating the liquid as a semi-infinite solid with conduction heat transfer. Account is also taken of the condensation taking place within the bulk of a saturated vapor as isentropic expansion takes place. Computational results are presented for the venting of R-11 from a given vessel and initial state for five different venting rates over a period of three seconds, and compared to prior NASA experiments. An improvement in the prediction of the final pressure takes place, but is still considerably below the measurements.

Merte, H., Jr.↗

Development of a Battery-Free Solar Refrigerator

Recent technology developments and a systems engineering design approach have led to the development of a practical battery-free solar refrigerator as a spin-off of NASA's aerospace refrigeration research. Off-grid refrigeration is a good application of solar photovoltaic (PV) power if thermal storage is incorporated and a direct connection is made between the cooling system and the PV panel. This was accomplished by integrating water as a phase-change material into a well insulated refrigerator cabinet and by developing a microprocessor based control system that allows direct connection of a PV panel to a variable speed compressor. This second innovation also allowed peak power-point tracking from the PV panel and elimination of batteries from the system. First a laboratory unit was developed to prove the concept and then a commercial unit was produced and deployed in a field test. The laboratory unit was used to test many different configurations including thermoelectric, Stirling and vapor compression cooling systems. The final configuration used a vapor compression cooling cycle, vacuum insulation, a passive condenser, an integral evaporator/ thermal storage tank, two 77 watt PV panels and the novel controller mentioned above. The system's only moving part was the variable speed BD35 compressor made by Danfoss. The 365 liter cabinet stayed cold with as little as 274 watt-hours per day average PV power. Battery-free testing was conducted for several months with very good results. The amount of thermal storage, size of compressor and power of PV panels connected can all be adjusted to optimize the design for a given application and climate. In the commercial unit, the high cost of the vacuum insulated refrigerator cabinet and the stainless steel thermal storage tank were addressed in an effort to make the technology commercially viable. This unit started with a 142 liter, mass-produced chest freezer cabinet that had the evaporator integrated into its inner walls. Its compressor was replaced with a Danfoss DC compressor slightly larger than the one used in the laboratory unit. The control system was integrated onto a single electronics card and packaged with its starting capacitors. The water for thermal storage was placed behind a liner that was made to fit inside the original factory liner. The original condenser was also augmented with additional surface area to improve performance. PV panels with a total rated power of 180 watts were used. The unit was tested with very successful results in an outside ambient environment, demonstrating its potential for widespread use in many off-grid applications for solar refrigeration.

Ewert, Michael K.↗

A Coordinated Mineralogical and Oxygen Isotopic Study of Refractory Ca-Al-Rich Inclusions

Refractory Ca-Al-rich inclusions (CAIs) in primitive chondritic meteorites represent the oldest solids that formed in our Solar System. Coordinated analyses using multiple ion and electron-beam techniques are vital to fully understand complex nebular and asteroidal processes that CAIs may have experienced in the context of the formation and early evolution of our Solar System. We report the results of a coordinated mineralogical and oxygen isotopic study of unique grossite bearing CAIs from reduced CV (Vigarano type) carbonaceous chondrites using transmission electron microscopy and secondary ion mass spectrometry. Grossite (CaAl 4 O 7 ) occurs in cores of nodules in fine grained CAIs that likely represent aggregates of nebular condensates. In many occurrences, grossite has been partially replaced by hercynite [(Fe,Mg,Zn)Al 2 O 4 ], which displays complex microstructures and compositions, and magnetite nanoparticles. This grossite alteration likely occurred via crystallographically controlled metasomatic reactions with Zn, Fe-rich aqueous fluids on the parent asteroid. The constituent phases of grossite bearing CAIs show heterogeneous oxygen isotopic compositions . That is, grossite and perovskite are 16 O poor and melilite is variably 16 O-depleted in contrast to solar like, 16 O-rich hibonite and spinel. The observed oxygen isotopic distribution is interpreted as a result of mineralogically controlled oxygen isotopic exchange with an 16 O-poor fluid on the parent asteroid. Collectively, we conclude that the presence of limited fluids played an important role in preferential alteration of grossite to hercynite and magnetite and various degrees of 16 O depletion in grossite, perovskite, and melilite during thermal metamorphism on the CV chondrite parent asteroid.

Jangmi Han↗

Aerosol-Cloud Interactions during Tropical Deep Convection: Evidence for the Importance of Free Tropospheric Aerosols

NASA's 2002 CRYSTAL-FACE field experiment focused on the formation and evolution of tropical cirrus cloud systems in southern Florida. Multiple aircraft extensively sampled cumulonimbus dynamical and microphysical properties, as well as characterizing ambient aerosol populations both inside and outside the full depth of the convective column. On July 18, unique measurements were taken when a powerful updraft was traversed directly by aircraft, providing a window into the primary source region of cumulonimbus anvil crystals. Observations of the updraft, entered at approximately l0 km altitude and -34 C, indicated more than 200 cloud particles per mL at vertical velocities exceeding 20 m/s and the presence of significant condensation nuclei and liquid water within the core. In this work, aerosol and cloud phase observations are integrated by simulating the updraft conditions using a large-eddy resolving model with 3 explicit multiphase microphysics, including treatment of size-resolved aerosol fields, aerosol activation and freezing, and evaporation of cloud particles back to the aerosol phase. Simulations were initialized with observed thermodynamic and aerosol size distributions profiles and convection was driven by surface fluxes assimilated from the ARPS forecast model. Model results are consistent with the conclusions that most crystals are homogeneously frozen droplets and that entrained free tropospheric aerosols may contribute a significant fraction of the crystals. Thus most anvil crystals appear to be formed aloft in updraft cores, well above cloud base. These conclusions are supported by observations of hydrometeor size distribution made while traversing the dore, as well as aerosol and cloud particle size distributions generally observed by aircraft below 4km and crystal properties generally observed by aircraft above 12km.

Ackerman, A.↗

Chemical condensation in the outflowing matter from the proto-sun and its application to meteorites

A novel model for solar nebula is proposed which is based on the observations of nebular disks around young solar-type stars in their T Tauri phase and the evidence that these disks formed from the material condensed from the outflowing gases from these stars. The model makes it possible to calculate the mass and the angular momentum. From these, parameters and the known photospheric temperature of T Tauri stars, the characteristic features of the nebula (such as radial extent, thickness, and temperature and pressure profiles) can be calculated. The model accounts very well for meteoritic mineralogy. It is suggested that chemical condensation took place in the outflowing matter from the protosun and that the solar nebula formed from this condensed material. The model also accounts for the formation of ices in the outer solar system and for planetary composition.

Trivedi, B. M. P.↗