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At least 289 records · Page 16

Radiological Monitoring Plan for the Oak Ridge Y-12 National Security Complex: Surface Water

DOE Order 458.1 requires that dose estimates consider contributions from all facilities. In the Y-12 Radiological Monitoring Plan (RMP), surface water is monitored at points that reflect individual facilities, as well as at points that reflect the combined contributions of all facilities. This monitoring plan does not consider other potential routes (i.e., airborne releases and food chains). Thus, a complete determination of total effective dose (TED) cannot be made based on this plan alone. The other routes from Y-12, and all routes from other DOE facilities on the Oak Ridge Reservation (e.g., Oak Ridge National Laboratory (ORNL) and The Heritage Center), must be considered in order to satisfy DOE Order 458.1 requirements. Determination of TED from all sites and pathways is done through the use of dose-assessment models and is documented in the Annual Site Environmental Report. This monitoring plan provides adequate monitoring goals for Y-12 surface water releases to provide input of sufficient sensitivity and accuracy to reliably determine the Y-12 surface water component of the TED. The routine radiological monitoring program is designed to monitor effluents at four types of locations: (1) treatment facilities, (2) other point and area source discharges, (3) instream locations, and (4) production building roof run-off. With this sampling and analysis program, data will be obtained on primary point sources as well as on locations that represent the composite of other potential sources. This plan will be reviewed periodically to determine necessary modifications to the sampling frequencies, parameters, and locations. Modifications, if any, will be based on the analysis of the previous data and its effectiveness in satisfying the objectives of this plan. Appendix A contains graphs of the sum of the DCS fractions for locations and frequencies contained in a previous version of this plan. The data was collected from January 2009 through December 2019. Each sample was analyzed, and each result was divided by the appropriate DCS to compute a DCS fraction. These fractions were summed for all isotopes. According to DOE –STD-1196-2011, the annual average of these sums should be below 1.

54 ENVIRONMENTAL SCIENCES↗

Annual Stormwater Report for the Y-12 National Security Complex Oak Ridge, Tennessee

This is the eighth annual stormwater report prepared in accordance with the modified National Pollutant Discharge Elimination System permit issued to the Y-12 National Security Complex (Y-12) on April 1, 2014. This modified permit removed the authorization to augment flow in East Fork Poplar Creek (EFPC) and thus removed the requirement to sample this effluent in conjunction with other major outfalls on EFPC. The general condition of the site continues to improve. The repair of Outfall 014 is complete and sampling was performed in 2020 from the new Outfall 014 structure. This repair marks a significant improvement in the storm drain network infrastructure. There are several construction and demolition activities currently in progress at Y-12. These include the construction of the Uranium Processing Facility, the Mercury Treatment Facility on EFPC, the site-wide power grid upgrade, and the demolition of the Biology Complex. Current stormwater protections have proven effective in 2020; however, moving forward, these projects will present challenges for the protection of stormwater. Therefore, oversight of these activities, and all other construction and demolition projects, will continue to be a priority in 2021. Y-12 will continue to implement appropriate best management practices and reduce outside material storage areas where possible.

54 ENVIRONMENTAL SCIENCES↗

Section 106 Recordation, Interpretation, and Documentation for the Demolition of Buildings 9201-5 and 9204-4, Y-12 National Security Complex, Oak Ridge, Tennessee

In 2019 and 2020, Cultural Resource Analysts, Inc. (CRA), began preparing recordation packages for 18 World War II and Cold War Era buildings slated for demolition at the request of Consolidated Nuclear Security, LLC (CNS), on behalf of the U.S. Department of Energy (DOE), National Nuclear Security Administration (NNSA). The recordations for these 18 buildings, which are located within what is now known as the Y-12 National Security Complex (Y-12) in Oak Ridge, Tennessee, were prepared and submitted in two separate packages. The first report (EC-NP-004) was prepared as a mitigation measure to address adverse effects that will result from the proposed demolition of 16 support and ancillary buildings. The current report is the second of the two packages and addresses the last two of the 18 buildings slated for demolition (9201-5 and 9204-4), which are two of the large process buildings located at Y-12. All 18 of these buildings have previously been determined eligible for listing in the National Register of Historic Places (NRHP). The two buildings, Building 9201-5 and Building 9204-4, are located south of Bear Creek Road and west of the main Y-12 entrance gate. Both buildings were constructed as uranium enrichment facilities in support of the Manhattan Project, a top-secret World War II mission to develop the world’s first nuclear weapons. Building 9201-5, completed in October 1944, is the Alpha-5 process facility and Building 9204-4, completed in Fall 1945, is the Beta-4 process facility. Over the years, these facilities were repurposed for a number of different functions.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Annual Stormwater Report for the Y-12 National Security Complex Oak Ridge, Tennessee

This is the ninth annual stormwater report prepared in accordance with the modified National Pollutant Discharge Elimination System permit issued to the Y-12 National Security Complex (Y-12) on April 1, 2014. This modified permit removed the authorization to augment flow in East Fork Poplar Creek (EFPC) and thus removed the requirement to sample this effluent in conjunction with other major outfalls on EFPC. There are several construction and demolition activities currently in progress at Y-12. These include the construction of the Uranium Processing Facility (UPF), the Mercury Treatment Facility (MTF) on EFPC, the site-wide power grid upgrade, construction of an Emergency Operations Center, construction of a new Fire Station, Security Improvement Revitalization Program (SIRP), West End Protection Area Reduction (WEPAR) Project, and the demolition of the Biology Complex. Current stormwater protections have proven effective in 2021. However, moving forward, challenges to protect stormwater will continue from these projects. Therefore, oversight of these activities, and all other construction and demolition projects, will continue to be a priority in 2022. Y-12 will continue to implement appropriate Best Management Practices and reduce outside material storage areas where possible.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Nuclear Material Process Modeling at the Y-12 National Security Complex

Dynamic simulation modeling is used at Y-12 to evaluate and forecast nuclear material inventories and production capacities to ensure that future supply can meet mission demand. Model outputs are analyzed by numerous Y-12 organizations and programs and coordinated with NNSA’s Office of Secondary Stage Production Modernization. Data-driven decisions for both short-term and long-term strategic planning for Y-12 mission execution are informed by the model. Dynamic simulation modeling capabilities for Y-12 nuclear material production continue to be expanded and refined.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Final Design for Thermal/Epithermal eXperiments (TEX) with Chloride Absorbers to Provide Validation Benchmarks for Y-12 Electrorefining Facility

Uranium electrorefining operations at Y-12 require validation for chlorine absorption and reflection. Plutonium chloride solution operations at Los Alamos National Laboratory require chlorine absorption validation. The growing need for chlorine validation is evident to the wider criticality safety community, with multiple attendees at the recent TEX 2.0 meeting at Lawrence Livermore National Laboratory (May 2023) requesting validation for chlorine (Idaho National Laboratory (INL), Institute de radioprotection et de surete nucleaire (IRSN), Savannah River Nuclear Site (SRNS), LANL, and Y-12). Los Alamos National Laboratory has recently performed, and benchmarked, an experiment titled Chlorine Worth Study (CWS) for the internal operations at the lab, but due to the difficulties in precisely characterizing the material compositions of the chlorine absorbers it is advantageous to perform a complimentary study with a different chlorine-based absorber material. Furthermore, having a uranium-based vs plutonium-based experiment provides a separate and important validation basis for criticality safety and nuclear data evaluation. The original final design report for the study of chlorine absorption using the TEX-HEU experimental base was presented in 2022, but used the same chlorine-bearing materials that were found to be difficult to characterize in the LANL benchmark. A complete redesign of the experiment has been performed looking at alternative absorber materials in various forms to produce an experiment that is fully characterizable. This report presents five novel chlorine experiments using the TEX-HEU test bed which provides direct comparison to the Y-12 and INL/Terrapower application needs, utilizing sodium chloride (NaCl) absorber plates. The absorber plates will consist of granulated NaCl (≥99.5% pure), which will be fully encapsulated in aluminum tins, providing a simple but effective chlorine-based absorber material that can be completely characterized. Of the five configurations presented in this report, it is expected that two or three configurations will be down selected for the actual experiment, with the other configurations being alternates. Three of the configurations are in the standard configuration, where the absorber is placed directly on the HEU fuel plates, and two in the sandwich configuration, where the absorber is surrounded by polyethylene moderators to force additional neutron thermalization prior to reaching the absorber. There are two thicknesses of NaCl absorber plates: 3/16” and 1/4” active thicknesses (i.e. not including the encapsulation). Both variations of the absorbers have an active absorber radius of 6” and a total radius of 7.5” to match the diameter of the HEU plates, with the outer 1.5” being aluminum encapsulation. The high-density polyethylene (HDPE) moderators are of the thicknesses: 27/16”, 7/4”, 1/8”, 11/16”, and 3/4”. The final configurations have six (one sandwich and one standard configuration), eight (one sandwich and one standard configuration), and 18 total fuel layers (standard configuration). The standard and sandwich configurations were designed such that the differences in moderator thicknesses are 1” HDPE, which were already procured for the original CED-2. The proposed configurations were precisely tuned to closely match the sensitivity profiles and neutron spectra of the Y-12 upset cases and were also compared to the INL/Terrapower upset cases. The assessment of experimental uncertainties of the non-absorber components was predicted to be 0.00114 Δk eff . The assessment of uncertainties resulting from the absorbers was predicted to be 0.00029 Δk eff . This results in a total uncertainty of 0.00118 Δk eff . Many of the largest uncertainties, namely the moderator densities, may be reduced with precision dimensional inspection of the components. The 1” HDPE moderators as well as the HDPE reflectors from the original CED-2 were incorporated in the final designs presented here. Additional HDPE moderator plates must be fabricated to complete the configurations. NaCl absorber plates will by fabricated at LLNL. The total additional cost is expected to be $\$$54,250 for the remaining components. Precise inspection, including dimensional, mass, density, and impurity, is recommended for all components. LLNL estimates that these costs are around $\$$12,000. It is expected, based on previous TEX-HEU experiments, that three weeks of experimental facility time is needed to complete the experiments.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

El Estudio de Resiliencia de la Red Electrica de Puerto Rico y Transiciones a Energia 100% Renovable (PR100): Informe Final [Puerto Rico Grid Resilience and Transitions to 100% Renewable Energy Study (PR100): Final Report]

El Estudio de Resiliencia de la Red de Puerto Rico y Transiciones a Energia 100% Renovable (PR100) es un analisis integral basado en amplios aportes de las partes interesadas sobre posibles caminos para que Puerto Rico alcance su meta de 100% de energía renovable para 2050. PR100 fue un esfuerzo integrado que se baso en experiencia y capacidades de los laboratorios nacionales contribuyentes que exploraron posibles caminos para que Puerto Rico logre su objetivo de 100% de energía renovable en el largo plazo (para 2050), aumente la confiabilidad y la resiliencia en el plazo inmediato (dentro de los proximos anos), y trabajar hacia la justicia energetica. El proposito del estudio es brindar apoyo a las decisiones e informar las decisiones de inversion para los implementadores de la transicion energetica de Puerto Rico. See NREL/TP-6A20-88384 for the English translation of this report.

100% renewable energy target↗

Theoretical Prediction of Thermal Expansion Anisotropy for Y 2 Si 2 O 7 Environmental Barrier Coatings Using a Deep Neural Network Potential and Comparison to Experiment

Environmental barrier coatings (EBCs) are an enabling technology for silicon carbide (SiC)-based ceramic matrix composites (CMCs) in extreme environments such as gas turbine engines. However, the development of new coating systems is hindered by the large design space and difficulty in predicting the properties for these materials. Density Functional Theory (DFT) has successfully been used to model and predict some thermodynamic and thermo-mechanical properties of high-temperature ceramics for EBCs, although these calculations are challenging due to their high computational costs. In this work, we use machine learning to train a deep neural network potential (DNP) for Y 2 Si 2 O 7 , which is then applied to calculate the thermodynamic and thermo-mechanical properties at near-DFT accuracy much faster and using less computational resources than DFT. We use this DNP to predict the phonon-based thermodynamic properties of Y 2 Si 2 O 7 with good agreement to DFT and experiments. We also utilize the DNP to calculate the anisotropic, lattice direction-dependent coefficients of thermal expansion (CTEs) for Y 2 Si 2 O 7 . Molecular dynamics trajectories using the DNP correctly demonstrate the accurate prediction of the anisotropy of the CTE in good agreement with the diffraction experiments. In the future, this DNP could be applied to accelerate additional property calculations for Y 2 Si 2 O 7 compared to DFT or experiments.

36 MATERIALS SCIENCE↗

IMF B(y) and day-night conductivity effects in the expanding polar cap convection model

During southward B(z) periods the open field line region in the ionosphere (polar cap) expands due to increased dayside merging. Ionospheric plasma flow patterns result which can be classified by the sign of the interplanetary magnetic field (IMF) B(y) component. In this paper, a time-dependent ionospheric convection model is constructed to simulate these flows. The model consists of a spiral boundary with a gap in it. The sign of the IMF B(y) component determines the geometry of the gap. A potential is applied across the gap and distributed around the boundary. A flow results which enters the polar cap through the gap and uniformly pushes the boundary outward. Results of the model show that B(y) effects are greatest near the gap and virtually unnoticeable on the nightside of the polar cap. Adding a day-night ionospheric conductivity gradient concentrates the polar cap electric field toward dawn. The resulting flow curvature gives a sunward component that is independent of B(y). These patterns are shown to be consistent with published observations.

Moses, J. J.↗

On the electron affinities of the Ca, Sc, Ti and Y atoms

For the Ca, Sc, Ti and Y atoms calculations are performed for the ground states of the neutrals and the ground and several low-lying excited states of the negative ions. Overall the computed electron affinities are in good accord with experiment. The calculations show the rapid stabilization of the 3d orbital relative to the 4p as the nuclear charge increases. The 3F(0) and 3D(0) terms are found to be close in energy in Sc(-) and in Y(-). This confirms earlier speculation that some of the peaks in the photodetachment spectra of Y(-) originate from the bound excited 3F(0) term of Y(-).

Bauschlicher, Charles W., Jr.↗

On the electron affinities of the Ca, Sc, Ti and Y atoms

For the Ca, Sc, Ti, and Y atoms calculations are performed for the ground states of the neutrals and the ground and several low-lying excited states of the negative ions. Overall, the computed electron affinities are in good accord with experiment. The calculations show the rapid stabilization of the 3d orbital relative to the 4p as the nuclear charge increases. The 3F0 and 3D0 terms are found to be close in energy in Sc(-) and in Y(-). This confirms earlier speculation that some of the peaks in the photodetachment spectra of Y(-) originate from the bound excited 3F0 term of Y(-).

Bauschlicher, Charles W., Jr.↗

Yttrium enrichment and improved magnetic properties in partially melted Y-Ba-Cu-O materials

The yttrium-rich compositions in the Y-Ba-Cu-O system were mapped out in a systematic manner to quantify their magnetic properties and to correlate them with the microstructure and phase composition as determined by scanning electron microscopy and X-ray diffraction analysis. It is found that the microstructure of Y-Ba-Cu-O compositions is a sensitive function of both their composition and processing conditions. Measurements of magnetic susceptibility and maximum (low-field) and remanent magnetization for the system Y:Ba:Cu = x:2:3 show highest values for x = 2. The corresponding structures involve numerous small crystals of Y2BaCuO5 (211) embedded in highly ordered assemblages of continous YBa2Cu3O(7-y) (123) layers.

Alterescu, Sidney↗

Vector performance analysis of three supercomputers - Cray-2, Cray Y-MP, and ETA10-Q

Results are presented of a series of experiments to study the single-processor performance of three supercomputers: Cray-2, Cray Y-MP, and ETA10-Q. The main object of this study is to determine the impact of certain architectural features on the performance of modern supercomputers. Features such as clock period, memory links, memory organization, multiple functional units, and chaining are considered. A simple performance model is used to examine the impact of these features on the performance of a set of basic operations. The results of implementing this set on these machines for three vector lengths and three memory strides are presented and compared. For unit stride operations, the Cray Y-MP outperformed the Cray-2 by as much as three times and the ETA10-Q by as much as four times for these operations. Moreover, unlike the Cray-2 and ETA10-Q, even-numbered strides do not cause a major performance degradation on the Cray Y-MP. Two numerical algorithms are also used for comparison. For three problem sizes of both algorithms, the Cray Y-MP outperformed the Cray-2 by 43 percent to 68 percent and the ETA10-Q by four to eight times.

Fatoohi, Rod A.↗

Experimental behavior of graphite-epoxy Y-stiffened specimens loaded in compression

An experimental investigation of the behavior of graphite-epoxy Y-stiffened specimens loaded in compression is presented. Experimental results are presented for element specimens with a single stiffener and for panel specimens with three stiffeners. Response and failure characteristics of the specimens are described. Effects of impact damage on structural response for both specimen configurations are also presented. Experimental results indicate that impact location may significantly affect the residual strength of the Y-stiffened specimens. The failure results indicate that the critical failure mode is buckling of the stiffener webs for Y-stiffened element specimens and buckling of the stiffener webs and other stiffener blades for the Y-stiffened panel specimens.

Sydow, P. Daniel↗

Experimental behavior of graphite-epoxy Y-stiffened specimens loaded in compression

An experimental investigation of the behavior of graphite-epoxy Y-stiffened specimens loaded in compression is presented. Experimental results are presented for element specimens with a single stiffener and for panel specimens with three stiffeners. Response and failure characteristics of the specimens are described. Effects of impact damage on structural response for both specimen configurations are also presented. Results indicate that impact location may significantly affect the residual strength of the Y-stiffened specimens. The failure results indicate that the critical failure mode is buckling of the stiffener webs for Y-stiffened element specimens and buckling of both stiffener web and stiffener blade for the Y-stiffened panel specimens.

Sydow, P. D.↗

Summertime tropospheric observations related to N(x)O(y) distributions and partitioning over Alaska - Arctic Boundary Layer Expedition 3A

Measurements of NO, NO2, PAN and NO(y) are presented for the summertime middle/lower troposphere over northern high latitudes. Chemical signatures from concurrent measurements of O3, CO, C2H2, C2H6, C3H8, C2Cl4, and H2O are used to characterize factors affecting the budget and distribution of N(x)O(y) in the Arctic and Sub-Arctic tropospheric air masses sampled over Alaska during the NASA Arctic Boundary Layer Expedition (ABLE 3A). The results implicate biomass burning in Siberia as the probable source of about one-third of the NO(y) abundance within the middle lower troposphere over Alaska and the downward transport of air from altitude in the vicinity of the tropopause as a major contributor to the abundance of NO(y) within the lower 6 km column over Alaska.

Sandholm, S. T.↗

Cusp/cleft auroral activity in relation to solar wind dynamic pressure, interplanetary magnetic field B(sub z) and B(sub y)

Continuous optical observations of cusp/cleft auroral activities within approximately equal to 09-15 MLT and 70-76 deg magnetic latitude are studied in relation to changes in solar wind dynamic pressure and interplanetary magnetic field (IMF) variability. The observed latitudinal movements of the cusp/cleft aurora in response to IMF B(sub z) changes may be explained as an effect of a variable magnetic field intensity in the outer dayside magnetosphere associated with the changing intensity of region 1 field-aligned currents and associated closure currents. Ground magnetic signatures related to such currents were observed in the present case (January 10, 1993). Strong, isolated enhancements in solar wind dynamic pressure (Delta p/p is greater than or equal to 0.5) gave rise to equatorward shifts of the cusp/cleft aurora, characteristic auroral transients, and distinct ground magnetic signatures of enhanced convection at cleft latitudes. A sequence of auroral events of approximately equal to 5-10 min recurrence time, moving eastward along the poleward boundary of the persistent cusp/cleft aurora in the approximately equal to 10-14 MLT sector, during negative IMF B(sub z) and B(sub y) conditions, were found to be correlated with brief pulses in solar wind dynamic pressure (0.1 is less than Delta p/p is less than 0.5). Simultaneous photometer observations from Ny Alesund, Svalbard, and Danmarkshavn, Greenland, show that the events often appeared on the prenoon side (approximately equal to 10-12 MLT), before moving into the postnoon sector in the case we study here, when IMF B(sub y) is less than 0. In other cases, similar auroral event sequences have been observed to move westward in the prenoon sector, during intervals of positive B(sub y). Thus a strong prenoon/postnoon asymmetry of event occurence and motion pattern related to the IMF B(sub y) polarity is observed. We find that this category of auroral event sequence is stimulated bursts of electron precipitation that originate from magnetosheath plasma that has accessed that dayside magnetosphere in the noon or near-noon sector, possibly at high latitudes, partly governed by the IMF orientation as well as by solar wind dynamic pressure pulses.

Sandholt, P. E.↗

High Temperature Superconductivity in Praseodymium Doped (0%, 2%, 4%) in Melt-Textured Y(1-x)Pr(x)Ba2Cu3O(7-delta) Systems

A study of the magnetic and structural properties of the alloy Y(1-x)Pr(x)Ba2Cu3O(7-delta) of 0%, 2%, and 4% doping of praseodymium is presented. The resulting oxides of the alloy series are a high-temperature superconductor Y-Ba-Cu-O, which has an orthorhombic superconducting crystal-lattice. Magnetic relaxation studies have been performed on the Y-Pr-Ba-CuO bulk samples for field orientation parallel to the c-axis, using a vibrating sample magnetometer. Relaxation was measured at several temperatures to obtain the irreversible magnetization curves used for the Bean model. Magnetization current densities were derived from the relaxation data. Field and temperature dependence of the logarithmic flux-creep relaxation was measured in critical state. The data indicates that the effective activation energy U(eff) increases with increasing T between 77 K and 86 K. Also, the data shows that U(eff)(T) and superconducting transition temperature, Tc, decreased as the lattice parameters increased with increasing Pr ion concentration, x, for the corresponding Y(1-x)Pr(x)Ba(x)Cu3O(7-delta) oxides. One contribution to Tc decrease in this sampling is suspected to be due to the larger ionic radius of the Pr(3+) ion. The upper critical field (H(sub c2)) was measured in the presence of magnetic field parallel to the c axis. A linear temperature dependence with H(sub c2) was obtained.

James, Claudell↗