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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 289 records · Page 16

Advancing insulation retrofits from flexible inexpensive lucid materials (AIR FILMs) for single-pane windows

This project focused on Advancing Insulation Retrofits from Flexible Inexpensive Lucid Materials (AIR FILMs) for Single-Pane Windows. The team developed innovative porous materials that can improve the energy efficiency of existing single-pane windows in commercial and residential buildings in two technical product categories: (1) retrofits that can be applied onto existing windowpanes and (2) manufactured windowpanes that can be installed into the existing window sash.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Demonstration and Evaluation of Lightweight High Performance Secondary Windows

Eight secondary windows (single-pane and double-pane) were installed at Building 53 of the Denver Federal Center in Colorado as part of a demonstration project to assess their thermal performance, life cycle costs, and deployment potential for use in conjunction with existing, older single-pane windows. The U.S. Department of Energy's National Renewable Energy Laboratory performed several different evaluations to assess the viability of the secondary windows for GSA applications. Some assessments were performed with models, while others required onsite evaluations including time series measurements.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Extending Analysis of Asay Windows to High Areal Mass Range [Slides]

The accretion layer addition to Asay window analysis results in new equations of motion that depend on the location of collisions within the layer. Asay window equations of motion can be represented in terms of experiment observables. Balance of linear momentum for variable mass systems provides a framework for developing equations of motion for Asay window diagnostics under a variety of operating assumptions. The growth in the accretion layer thickness during an experiment substantially influences mass and density measurements when high accumulation of areal mass is present.

97 MATHEMATICS AND COMPUTING↗

Extending the Asay window measurement model to high areal mass ranges [Slides]

The accretion layer addition to Asay window analysis results in new equations of motion that depend on the location of collisions within the layer. Asay window equations of motion can be represented in terms of experiment observables. Balance of linear momentum for variable mass systems provides a framework for developing equations of motion for Asay window diagnostics under a variety of operating assumptions. The growth in the accretion layer thickness during an experiment substantially influences mass and density measurements when high accumulation of areal mass is present.

97 MATHEMATICS AND COMPUTING↗

10% Loss of Incident Power through Solar Reactor Window: Myth or Good Rule of Thumb?

It is known that a solar beam crossing a window losses 10% of its incident power. Yet, this affirmation is not supported by many published scientific evidences. In this work, a heat flux mapping method was used to determine the heat flux distributions at the focal spot of a solar concentrating device without and with a window on the incident beams' trajectory. The presence of a window on the beams' trajectory induces a 12% loss of the total power and a 11% decrease of the peak heat flux density.

14 SOLAR ENERGY↗

Characterization of an explosively bonded aluminum proton beam window for the Spallation Neutron Source

An effort is underway at the Spallation Neutron Source (SNS) to change the design of the 1st Generation high-nickel alloy proton beam window (PBW) to one that utilizes aluminum for the window material. One of the key challenges to implementation of an aluminum PBW at the SNS was selection of an appropriate joining method to bond an aluminum window to the stainless steel bulk shielding of the PBW assembly. An explosively formed bond was selected as the most promising joining method for the aluminum PBW design. A testing campaign was conducted to evaluate the strength and efficacy of explosively formed bonds that were produced using two different interlayer materials: niobium and titanium. The characterization methods reported here include tensile testing, thermal-shock leak testing, optical microscopy, and advanced scanning electron microscopy. All tensile specimens examined failed in the aluminum interlayer and measured tensile strengths were all slightly greater than the native properties of the aluminum interlayer, while elongation values were all slightly lower. A leak developed in the test vessel with a niobium interlayer joint after repeated thermal-shock cycles, and was attributed to an extensive crack network that formed in a layer of niobium-rich intermetallics located on the bond interfaces of the niobium interlayer; the test vessel with a titanium interlayer did not develop a leak under the conditions tested. Due to the experience gained from these characterizations, the explosively formed bond with a titanium interlayer was selected for the aluminum PBW design at the SNS.

316L Stainless Steel↗

Assessment of Environmentally Friendly Refrigerants for Window Air Conditioners

This paper presents technical assessment of environmentally friendly refrigerants for window air conditioners that currently use refrigerant R410A for residential and commercial applications. The alternative refrigerants that are studied for its replacement include R32, R600a, R290, R1234yf, R1234ze and a mixture of R32 (90% molar concentration) and R125 (10% molar concentration). Baseline experiments were performed on a window unit charged with R410A. The ORNL Heat Pump Design Model was calibrated with the baseline data and was used to assess the comparative performance of the WAC with alternative refrigerants. The paper discusses the advantages and disadvantages of each refrigerants and their suitability for window air conditioners.

Alternative refrigerants↗

Evaluation of Low-E Storm Windows in the PNNL Lab Homes

This study examines the performance of exterior and interior low-e storm panels with a controlled whole home experimental design using PNNL's Lab Homes. Summing the estimated annual average heating and cooling savings, the installation of low-e storm panels resulted in approximately 10% annual energy savings. The results of the experiment will be used to determine and validate performance of low-e storm windows over double pane clear glass windows in a whole home setting.

energy savings↗

Side-Chain Nanophase Separation Broadens the Double-Gyroid Stability Window in PS–PODMA Diblock Copolymers

Expanding access to bicontinuous network phases in block copolymers remains an important challenge because the double gyroid (DG) phase is usually stable only within a narrow composition window in conventional diblock copolymers. Here, we show that poly(styrene-block-octadecyl methacrylate) (PS-b-PODMA) exhibits an unusually broad DG window. Small-angle X-ray scattering measurements across a wide composition range reveal lamellar and hexagonally packed cylindrical phases at higher polystyrene fractions. In contrast, the DG phase appears over 0.22 ≤ fPS ≤ 0.35, with DG/BCC and DG/HEX coexistence near fPS = 0.18 and 0.40, respectively. This broad DG window is much wider than those reported for neat diblock copolymers and is not readily explained by conformational asymmetry alone. Wide-angle X-ray scattering detects a characteristic signature of nanophase separation within the PODMA-rich domains, indicating that side-chain ordering introduces an additional internal length scale. These results suggest that hierarchical side-chain nanophase separation modifies packing frustration and curvature selection, thereby broadening DG stability and providing a new molecular design strategy for stabilizing complex network morphologies.

Seko, Tamio↗

One-Dimensional Metallo-Superconductor Photonic Crystals as a Smart Window

A new structure to control the electromagnetic waves has been successfully designed for smart windows applications. The present photonic crystals (PCs) smart window is designed from a unit cell of two different materials such as A (metal) and B (superconductor) of thicknesses that repeated for N periods. The numerical results are investigated based on the characteristic matrix method. It was found that the angle of incidence has a significant effect on the transmission values. At 10{sup o} angle of incidence, we found more than 80% of the visible light and a near IR is transmitted whereas at 60{sup o} angle of incidence, the photonic band gap (PBG) begins to appear at wavelengths greater than 800 nm and the visible light transmittance remains more than 80%. Also, the dependence of the transmittance values on the periodicity and thickness of the proposed design was investigated. The proposed structure could be of potential use as a smart window in low-temperature applications and space industry.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Efficacy of Gadolinium Gallium Garnet (GGG) as a High-Impedance Optical Window for Shock Wave Experiments

We conducted a series of plate impact experiments to examine the efficacy of < 111>-oriented gadolinium gallium garnet (GGG) single crystals as high-impedance optical window for Photonic Doppler velocimetry (PDV) under shock and double-shock loading. At ~ 123 GPa, shocked GGG remains fully transparent to 1550 nm light for at least 250 ns without any signal degradation. Above 135 GPa, PDV data measured through GGG exhibit a gradual loss of fringe contrast following shock entrance, which eventually leads to transparency loss. The duration for which shocked GGG remains transparent decreases with increasing pressure, and at ~ 148 GPa, it becomes opaque within ~ 20–30 ns. This limits the use of GGG as an interferometry window between ~ 110–140 GPa under single shock loading. Within this pressure range, the refractive index of GGG increases linearly with density: n = 1.552 + 0.054ρ. In contrast to single shock loading, where GGG becomes opaque rapidly above ~ 140 GPa, double-shocked GGG remains optically transparent for over 100 ns when it is first shocked to ~ 123 GPa and then reshocked to significantly higher pressures (215–233 GPa). Our findings raise the exciting possibility of GGG being used as a high-impedance optical window in multi-shock and shock-ramp loading experiments.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Selective excitation of window and buffer layers in chalcopyrite devices and modules

Window and buffer layers in chalcopyrite devices are well known to affect junctions, conduction, and photo-absorption properties of the device. Some of these layers, particularly 'buffers,' which are deposited directly on top of the absorber, exhibit metastable effects upon exposure to light. Thus, to understand device performance and/or metastability, it is sometimes desirable to selectively excite different layers in the device stack. Absorption characteristics of various window and buffer layers used in chalcopyrite devices are measured. These characteristics are compared with emission spectra of common and available light sources that might be used to optically excite such layers. Effects of the window and buffer absorption on device quantum efficiency and metastability are discussed. For the case of bath-deposited Zn(O,S) buffers, we conclude that this layer is not optically excited in research devices or modules. Furthermore, this provides a complimentary mechanism to the chemical differences that may cause long time constants (compared to devices with CdS buffers) associated with reaching a stable 'light-soaked' state.

14 SOLAR ENERGY↗

Electrochemical Window of the Li-Ion Solid Electrolyte Li 7 La 3 Zr 2 O 12

The recent discovery of fast ion-conducting solid electrolytes could enable solid-state and other advanced battery chemistries with higher energy densities and enhanced safety. In addition to high ionic conductivity, a viable electrolyte should also exhibit an electrochemical window that is wide enough to suppress undesirable electronic transport (i.e., self-discharge and/or short circuiting) arising from charge injection or extraction from the electrodes. Here, direct current chronoamperometry, alternating current electrochemical impedance spectroscopy, and optical absorption band gap measurements are combined with first-principles calculations to systematically characterize the electrochemical window of the promising superionic conductor Li 7 La 3 Zr 2 O 12 (LLZO). Negligible electronic current was measured within LLZO for a wide range of voltages relevant for high-voltage cathodes. This auspicious behavior is consistent with both the large band gap (~6 eV) predicted for LLZO and the absolute positions of its band edges. These features imply that a wide electrochemical window is an intrinsic property of LLZO, facilitating its use in next-generation batteries.

Thompson, Travis↗

A More Transparent Infrared Window

The infrared window region (780–1,250 cm –1 , 12.8 to 8.0 μm) is of great importance to Earth's climate due to its high transparency and thermal energy. We present here a new investigation of the transparency of this spectral region based on observations by interferometers of downwelling surface radiance at two DOE Atmospheric Radiation Measurement program sites. We focus on the dominant source of absorption in this region, the water vapor continuum, and derive updated values of spectral absorption coefficients for both the self and foreign continua. Our results show that the self continuum is too strong in the previous version of Mlawer-Tobin_Clough-Kneizys-Davies (MT_CKD) water vapor continuum model, a result that is consistent with other recent analyses, while the foreign continuum is too weak in MT_CKD. In general, the weaker self continuum derived in this study results in an overall increase in atmospheric transparency in the window, although in atmospheres with low amounts of water vapor the transparency may slightly decrease due to the increase in foreign continuum absorption. These continuum changes lead to a significant decrease in downwelling longwave flux at the surface for moist atmospheres and a modest increase in outgoing longwave radiation. The increased fraction of surface-leaving radiation that escapes to space leads to a notable increase (~5–10%) in climate feedback, implying that climate simulations that use the new infrared window continuum will show somewhat less warming than before. This study also points out the possibly important role that aerosol absorption may play in the longwave radiative budget.

58 GEOSCIENCES↗

Nanostructured electrochromic smart windows: traditional materials and NIR-selective plasmonic nanocrystals

Electrochromic devices, which dynamically change colour under applied potential, are widely studied for use in energy-efficient smart windows. To improve the viability of smart windows, many researchers are utilizing nanomaterials, which can provide electrochromic devices with improved colouration efficiencies, faster switching times, longer cycle lives, and potentially reduced costs. In an effort to demonstrate a new type of electrochromic device that goes beyond the capabilities of commonly used electrochromic materials, researchers have turned to plasmonic transparent conductive oxide (TCO) nanocrystals. Electrochemical injection of electrons into plasmonic TCO nanocrystal films induces a shift in the plasmon frequency and gives rise to the new functionality of selective optical modulation in the near-infrared region of the solar spectrum. These nanocrystals can be used as building blocks to enable creation of advanced electrochromic devices containing mesoporous electrodes or nanocrystal-in-glass composites. Such devices have been important in advancing the field towards achieving the ideal smart window with independent control over visible and NIR transmittance.

Runnerstrom, EL↗

A method for eliminating Faraday rotation in cryostat windows in longitudinal magneto-optical Kerr effect measurements

A solution to the problem of disturbing effect of the background Faraday rotation in the cryostat windows on longitudinal magneto-optical Kerr effect (LMOKE) measured under vacuum conditions and/or at low temperatures is proposed. The method for eliminating the influence of Faraday rotation in cryostat windows is based on special arrangement of additional mirrors placed on sample holder. In this arrangement, the orientation of the cryostat window is perpendicular to the light beam direction and parallel to an external magnetic field generated by the H-frame electromagnet. The operation of the LMOKE magnetometer with the special sample holder based on polarization modulation technique with a photo-elastic modulator is theoretically analyzed with the use of Jones matrices, and formulas for evaluating of the actual Kerr rotation and ellipticity of the sample are derived. The feasibility of the method and good performance of the magnetometer is experimentally demonstrated for the LMOKE effect measured in Fe/Au multilayer structures. The influence of imperfect alignment of the magnetometer setup on the Kerr angles, as derived theoretically through the analytic model and verified experimentally, is examined and discussed.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

The effects of high temperature processing on the structural and optical properties of oxygenated CdS window layers in CdTe solar cells

High efficiency CdTe solar cells typically use oxygenated CdS (CdS:O) window layers. We synthesize CdS:O window layers at room temperature (RT) and 270 °C using reactive sputtering. The band gaps of CdS:O layers deposited at RT increase when O{sub 2}/(O{sub 2} + Ar) ratios in the deposition chamber increase. On the other hand, the band gaps of CdS:O layers deposited at 270 °C decrease as the O{sub 2}/(O{sub 2} + Ar) ratios increase. Interestingly, however, our high temperature closed-space sublimation (CSS) processed CdTe solar cells using CdS:O window layers deposited at RT and 270 °C exhibit very similar cell performance, including similar short-circuit current densities. To understand the underlying reasons, CdS:O thin films deposited at RT and 270 °C are annealed at temperatures that simulate the CSS process of CdTe deposition. X-ray diffraction, atomic force microscopy, and UV-visible light absorption spectroscopy characterization of the annealed films reveals that the CdS:O films deposited at RT undergo grain regrowth and/or crystallization and exhibit reduced band gaps after the annealing. Our results suggest that CdS:O thin films deposited at RT and 270 °C should exhibit similar optical properties after the deposition of CdTe layers, explaining the similar cell performance.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

The suppression effect of external magnetic field on the high-power microwave window multipactor phenomenon

To suppress the surface multipactor phenomenon and improve the transmitting power of the high-power microwave window, the application of external magnetic fields is theoretically analyzed and simulated. A Monte Carlo algorithm is used to track the secondary electron trajectories and study the multipactor scenario on the surface of a cylinder window. It is confirmed that over-resonant magnetic fields (an external magnetic field whose magnitude is slightly greater than that of a resonant magnetic field) will generate a compensating trajectory and collision, which can suppress the secondary electron avalanche. The optimal value of this external magnetic field that will avoid the multipactor phenomenon on cylinder windows is discussed.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗