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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 289 records · Page 16
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Axial vs equatorial: Capturing the intramolecular charge transfer state geometry in conformational polymorphic crystals of a donor–bridge–acceptor dyad in nanosecond-time-scale

Two conformational polymorphs of a donor–bridge–acceptor (D-B-A) dyad, p-(CH 3 ) 2 N-C 6 H 4 -(CH 2 ) 2 -(1-pyrenyl)/PyCHDMA, were studied, where the electron donor (D) moiety p-(CH 3 ) 2 N-C 6 H 4 /DMA is connected through a bridging group (B), –CH 2 –CH 2 –, to the electron acceptor (A) moiety pyrene. Though molecular dyads like PyCHDMA have the potential to change solar energy into electrical current through the process of photoinduced intramolecular charge transfer (ICT), the major challenge is the real-time investigation of the photoinduced ICT process in crystals, necessary to design solid-state optoelectronic materials. The time-correlated single photon counting (TCSPC) measurements with the single crystals showed that the ICT state lifetime of the thermodynamic form, PyCHDMA1 (pyrene and DMA: axial), is ~3 ns, whereas, for the kinetic form, PyCHDMA20 (pyrene and DMA: equatorial), it is ~7 ns, while photoexcited with 375 nm radiation. The polymorphic crystals were photo-excited and subsequently probed with a pink Laue x-ray beam in time-resolved x-ray diffraction (TRXRD) measurements. The TRXRD results suggest that in the ICT state, due to electron transfer from the tertiary N-atom in DMA moiety to the bridging group and pyrene moiety, a decreased repulsion between the lone-pair and the bond-pair at N-atom induces planarity in the C–N–(CH 3 ) 2 moiety, in both polymorphs. The Natural Bond Orbital calculations and partial atomic charge analysis by Hirshfeld partitioning also corroborated the same. Although the interfragment charge transfer (IFCT) analysis using the TDDFT results showed that for the charge transfer excitation in both conformers, the electrons were transferred from the DMA moiety to mostly the pyrene moiety, the bridging group has little role to play in that.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2013

Teleconnections, Midlatitude Cyclones and Aegean Sea Turbulent Heat Flux Variability on Daily Through Decadal Time Scales

We analyze daily wintertime cyclone variability in the central and eastern Mediterranean during 1958-2001, and identify four distinct cyclone states, corresponding to the presence or absence of cyclones in each basin. Each cyclone state is associated with wind flows that induce characteristic patterns of cooling via turbulent (sensible and latent) heat fluxes in the eastern Mediterranean basin and Aegean Sea. The relative frequency of occurrence of each state determines the heat loss from the Aegean Sea during that winter, with largest heat losses occurring when there is a storm in the eastern but not central Mediterranean (eNOTc), and the smallest occurring when there is a storm in the central but not eastern Mediterranean (cNOTe). Time series of daily cyclone states for each winter allow us to infer Aegean Sea cooling for winters prior to 1985, the earliest year for which we have daily heat flux observations. We show that cyclone states conducive to Aegean Sea convection occurred in 1991/1992 and 1992/1993, the winters during which deep water formation was observed in the Aegean Sea, and also during the mid-1970s and the winters of 1963/1964 and 1968/1969. We find that the eNOTc cyclone state is anticorrelated with the North Atlantic Oscillation (NAO) prior to 1977/1978. After 1977/1978, the cNOTe state is anticorrelated with both the NAO and the North Caspian Pattern (NCP), showing that the area of influence of large scale atmospheric teleconnections on regional cyclone activity shifted from the eastern to the central Mediterranean during the late 1970s. A trend toward more frequent occurrence of the positive phase of the NAO produced less frequent cNOTe states since the late 1970s, increasing the number of days with strong cooling of the Aegean Sea surface waters.

cyclones↗
NASA NTRS1998

Computational Modeling of Semiconductor Dynamics at Femtosecond Time Scales

The Interchange No. NCC2-5149 deals with the emerging technology of photonic (or optoelectronic) integrated circuits (PICs or OEICs). In PICs, optical and electronic components are grown together on the same chip. To build such devices and subsystems, one needs to model the entire chip. PICs are useful for building components for integrated optical transmitters, integrated optical receivers, optical data storage systems, optical interconnects, and optical computers. For example, the current commercial rate for optical data transmission is 2.5 gigabits per second, whereas the use of shorter pulses to improve optical transmission rates would yield an increase of 400 to 1000 times. The improved optical data transmitters would be used in telecommunications networks and computer local-area networks. Also, these components can be applied to activities in space, such as satellite to satellite communications, when the data transmissions are made at optical frequencies. The research project consisted of developing accurate computer modeling of electromagnetic wave propagation in semiconductors. Such modeling is necessary for the successful development of PICs. More specifically, these computer codes would enable the modeling of such devices, including their subsystems, such as semiconductor lasers and semiconductor amplifiers in which there is femtosecond pulse propagation. Presently, there are no computer codes that could provide this modeling. Current codes do not solve the full vector, nonlinear, Maxwell's equations, which are required for these short pulses and also current codes do not solve the semiconductor Bloch equations, which are required to accurately describe the material's interaction with femtosecond pulses. The research performed under NCC2-5149 solves the combined Maxwell's and Bloch's equations.

Agrawal, Govind P.↗
NASA NTRS2000

Rainfall Across the Globe: Precipitation. The Role of Landmass in Monsoon Development. The Relationship Between Precipitation and Sea Surface Temperature on Decadal Time Scales

The numerical simulation of precipitation helps scientists understand the complex mechanisms that determine how and why rainfall is distributed across the globe. Simulation aids in the development of forecastin,g efforts that inform policies regarding the management of water resources. Precipitation modeling also provides short-term warnings, for emergencies such as flash floods and mudslides. Just as precipitation modeling can warn of an impending abundance of rainfall, it can help anticipate the absence of rainfall in drought. What constitutes a drought? A meteorological drought simply means that an area is getting a significantly lower amount of rain than usual over a prolonged period of time and an agricultural drought is based on the level of soil moisture.

Chao, Winston↗
NASA NTRS1984

Radiative tearing - Magnetic reconnection on a fast thermal-instability time scale

Two energy modification mechanisms which are known to occur in sheared magnetic fields are the tearing and thermal instabilities. These processes can be studied separately with formalisms incorporating just the effective driving mechanism of interest (finite resistivity for the tearing mode and unstable radiation for the thermal mode). A model which includes both effects, and a temperature-dependent resistivity, indicates that modified forms of these two instabilities may coexist for identical physical conditions. When they are isolated computationally, one can show that their limiting growth rates are approximately those of the uncoupled instabilities. The spatial structure and energy content of these two new hybrid processes are then individually examined and are found to differ considerably from those obtained from separate treatments of the driving mechanisms. The faster radiative instability, which has a hydromagnetically scaled growth rate like the condensation mode of the thermal instability, is shown to involve a substantial amount of magnetic field reconnection. This can be partially explained by a large temperature drop (or resistivity rise) at the X-point. The island width of the Coulomb-coupled radiative mode is 30 percent of that produced by a comparable level of the slower tearing instability. In addition, the perturbed magnetic energy in the radiative instability is 5 times that of the perturbed thermal energy, indicating an appreciable modification of the initial magnetic structure.

Steinolfson, R. S.↗
DOE OSTI2014

Exploring the relationship between peatland net carbon balance and apparent carbon accumulation rate at century to millennial time scales

Each year, a peatland has an annual net carbon balance (NCB), which can be positive (net uptake), zero or negative. Over centuries to millennia, this NCB accumulates as a peat profile. Contemporary peatlands can be sampled (cored), and the past apparent carbon accumulation rate (aCAR) can be determined as the quantity of peat carbon in any particular dated interval down the core profile. Here, we use a process-based peatland carbon and water cycle model to compare peatland annual NCB during millennia of peat accumulation to the contemporary estimate of aCAR, resulting from this accumulation. Integrating over the entire profile, the accumulated NCB must equal the aCAR, but for shorter time intervals, these two quantities can diverge. A climate variation/perturbation that leads to persistent, slow carbon loss or negligible carbon gain through enhanced decomposition will necessarily reduce the aCAR for time periods before the climate variation/perturbation occurred. Finally, this can compromise peatland climate–carbon balance relationships inferred from joint analysis of peat cores and paleoclimate reconstructions.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS2004

A Time Scale for Major Events in Early Mars Crustal Evolution

The population of visible and buried impact basins > 200 km diameter revealed by high resolution gridded MOLA data and the cumulative frequency curves derived for these pvide a basis for a chronology of major events in early martian history. The relative chronology can be given in terms of N(200) crater retention ages; 'absolute ages' can be assigued using the Hartmann-Neukum (H&N) model chronology. In terms of billions of H&N years, the crustal dichotomy formed by large impact basins at 4.12 +/- 0.08 BYA (N(200) = 3.0-3.2) and the global magnetic field died at about or slightly before the same time (4.15 +/- 0.08 BYA (N(200) = 3.5). In this chronology, the buried lowlands are approx. 120 my younger than the buried highlands, approx. 160 my younger than the highlands overall and approx. 340 my younger than the oldest crater retention surface we see, defined by the largest impact basins.

Frey, Herbert V.↗
DOE OSTI2023

Hierarchical multi-time-scale predictive thermal management and fuel optimization for heavy-duty compression ignition engines

For heavy-duty diesel engines, NO X emissions reduction is strongly constrained by fuel efficiency. This paper presents a hierarchical model predictive controller (H-MPC) for coordinated control of tailpipe NO X emissions and fuel consumption. The H-MPC uses the separation of slow and fast dynamics that exist in the engine and its aftertreatment system. The controller is synthesized with an architecture in which a high-level MPC uses a longer prediction horizon compared to the low-level predictive controller which tracks the high-level controller command and manages the thermal dynamics of the aftertreatment system. Engine load preview enables the high-level controller to estimate the desired catalyst temperature ahead of time and addresses the selective catalytic reduction (SCR) slow thermal dynamics. Calculated by the high-level controller, the intake manifold pressure, and the start of injection (SOI) crank angle is used as reference trajectories in the low-level controller that regulates fast dynamical behaviors such as engine out NO X emissions. Hardware-in-the-loop (HIL) validation of this integrated H-MPC on a rapid prototype controller shows that when the SCR catalyst temperature is above light-off temperature (warmed-up condition), the engine operation is shifted to operate with the best fuel economy since the warmed-up SCR can efficiently reduce the engine-out NO X emissions. Results indicate that up to 0.8% benefit in cycle averaged BSFC along with a 13% reduction in tailpipe NO X compared to a stock engine calibration can be achieved with the coordinated engine and aftertreatment system through H-MPC.

Engineering↗
DOE OSTI2022

Beam steering at the nanosecond time scale with an atomically thin reflector

Techniques to mold the flow of light on subwavelength scales enable fundamentally new optical systems and device applications. The realization of programmable, active optical systems with fast, tunable components is among the outstanding challenges in the field. Here, we experimentally demonstrate a few-pixel beam steering device based on electrostatic gate control of excitons in an atomically thin semiconductor with strong light-matter interactions. By combining the high reflectivity of a MoSe 2 monolayer with a graphene split-gate geometry, we shape the wavefront phase profile to achieve continuously tunable beam deflection with a range of 10°, two-dimensional beam steering, and switching times down to 1.6 nanoseconds. Our approach opens the door for a new class of atomically thin optical systems, such as rapidly switchable beam arrays and quantum metasurfaces operating at their fundamental thickness limit.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2017

Thermalization time scales for WIMP capture by the Sun in effective theories

I study the process of dark matter capture by the Sun, under the assumption of a Weakly Interacting Massive Particle (WIMP), in the framework of non-relativistic effective field theory. Hypothetically, WIMPs from the galactic halo can scatter against atomic nuclei in the solar interior, settle to thermal equilibrium with the solar core and annihilate to produce an observable flux of neutrinos. In particular, I examine the thermalization process using Monte-Carlo integration of WIMP trajectories. I consider WIMPs in a mass range of 10–1000 GeV and WIMP-nucleon interaction operators with different dependence on spin and transferred momentum. I find that the density profiles of captured WIMPs are in accordance with a thermal profile described by the Sun's gravitational potential and core temperature. Depending on the operator that governs the interaction, the majority of the thermalization time is spent in either the solar interior or exterior. If normalizing the WIMP-nuclei interaction strength to a specific capture rate, I find that the thermalization time differs at most by 3 orders of magnitude between operators. In most cases of interest, the thermalization time is many orders of magnitude shorter than the age of the solar system.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1984

Time scales for the decay of induced large-scale magnetic fields in the Venus ionosphere

Observations made with the aid of a magnetometer on the Pioneer Venus Orbiter have shown large-scale horizontal magnetic fields in the dayside ionosphere of Venus. According to Cloutier and Daniell (1981), the observed magnetic structures may be quasi-steady features produced by an ionospheric current system driven by solar wind interaction. Russell et al. (1983) have suggested that the altitude profiles of the horizontal field on different orbits exhibit a pattern which can be interpreted as phases in the temporal evolution of an initial state in which the ionosphere was permeated with magnetosheath-like fields. The present investigation is concerned with the argument in favor of a temporal versus spatial explanation for some of the observed field structure. A calculation indicates that the diffusion time for ionospheric fields is long enough to justify attributing the observed fields to the 'memory' of the Venus ionosphere in certain regions.

Luhmann, J. G.↗
NASA NTRS2009

Relationships Between Tropical Deep Convection, Tropospheric Mean Temperature and Cloud-Induced Radiative Fluxes on Intraseasonal Time Scales

Intraseasonal variability of deep convection represents a fundamental mode of variability in the organization of tropical convection. While most studies of intraseasonal oscillations (ISOs) have focused on the spatial propagation and dynamics of convectively coupled circulations, we examine the projection of ISOs on the tropically-averaged temperature and energy budget. The area of interest is the global oceans between 20oN/S. Our analysis then focuses on these questions: (i) How is tropospheric temperature related to tropical deep convection and the associated ice cloud fractional amount (ICF) and ice water path (IWP)? (ii) What is the source of moisture sustaining the convection and what role does deep convection play in mediating the PBL - free atmospheric temperature equilibration? (iii) What affect do convectively generated upper-tropospheric clouds have on the TOA radiation budget? Our methodology is similar to that of Spencer et al., (2007) with some modifications and some additional diagnostics of both clouds and boundary layer thermodynamics. A composite ISO time series of cloud, precipitation and radiation quantities built from nearly 40 events during a six-year period is referenced to the atmospheric temperature signal. The increase of convective precipitation cannot be sustained by evaporation within the domain, implying strong moisture transports into the tropical ocean area. While there is a decrease in net TOA radiation that develops after the peak in deep convective rainfall, there seems little evidence that an "Infrared Iris"- like mechanism is dominant. Rather, the cloud-induced OLR increase seems largely produced by weakened convection with warmer cloud tops. Tropical ISO events offer an accessible target for studying ISOs not just in terms of propagation mechanisms, but on their global signals of heat, moisture and radiative flux feedback processes.

Ramey, Holly S.↗
NASA NTRS2010

Relationships Between Tropical Deep Convection, Tropospheric Mean Temperature and Cloud-Induced Radiative Fluxes on Intraseasonal Time Scales

Intraseasonal variability of deep convection represents a fundamental mode of variability in the organization of tropical convection. While most studies of intraseasonal oscillations (ISOs) have focused on the spatial propagation and dynamics of convectively coupled circulations, we examine the projection of ISOs on the tropically-averaged temperature and energy budget. The area of interest is the global oceans between 20degN/S. Our analysis then focuses on these questions: (i) How is tropospheric temperature related to tropical deep convection and the associated ice cloud fractional amount (ICF) and ice water path (IWP)? (ii) What is the source of moisture sustaining the convection and what role does deep convection play in mediating the PBL - free atmospheric temperature equilibration? (iii) What affect do convectively generated upper-tropospheric clouds have on the TOA radiation budget? Our methodology is similar to that of Spencer et al., (2007) with some modifications and some additional diagnostics of both clouds and boundary layer thermodynamics. A composite ISO time series of cloud, precipitation and radiation quantities built from nearly 40 events during a six-year period is referenced to the atmospheric temperature signal. The increase of convective precipitation cannot be sustained by evaporation within the domain, implying strong moisture transports into the tropical ocean area. While there is a decrease in net TOA radiation that develops after the peak in deep convective rainfall, there seems little evidence that an "Infrared Iris"- like mechanism is dominant. Rather, the cloud-induced OLR increase seems largely produced by weakened convection with warmer cloud tops. Tropical ISO events offer an accessible target for studying ISOs not just in terms of propagation mechanisms, but on their global signals of heat, moisture and radiative flux feedback processes.

Ramey, Holly S.↗
DOE OSTI2015

ITEAM - An international mechanistic approach to modeling glass behavior over geologic time scales - 15527

Vitrification is a common worldwide solution for radioactive waste immobilization. Although the excellent chemical durability of glass has been demonstrated in ancient man-made and natural analogues, the lack of an international consensus on a glass corrosion rate law limits the application of glass in high-level waste repository performance models. The contributions of physical and chemical processes controlling the long-term glass dissolution rate in geologic disposal remain uncertain resulting in this non-consensus. A thorough mechanistic understanding of waste form durability in geologic environments would improve public and regulator confidence. In addition, this understanding could lead to cost savings if it becomes possible to take credit for the true durability of the waste form itself in system evaluations rather than requiring expensive engineered barrier systems. To this end, five nations (US, UK, France, Japan, and Belgium) have joined together to formulate a joint plan for collaborative research into the mechanisms controlling the long-term corrosion of glass. Over the last five years, the coordinated research performed by these countries has produced a new level of understanding about the glass corrosion mechanisms, specifically as they apply to glasses similar in composition to the French R7T7 glass. Some recent results are presented as they relate to several mechanisms that are thought to control glass alteration at long time periods. It is important to understand the effects of each particular mechanism on the overall radionuclide release and the relative importance of each process model to the performance assessment calculation. In addition, a new series of experiments calls out potential sources of error due to the use of irregular shapes (such as crushed glass powder) in dissolution experiments. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
NASA NTRS1998

Computational Modeling of Semiconductor Dynamics at Femtosecond Time Scales

The main objective of the Joint-Research Interchange NCC2-5149 was to develop computer codes for accurate simulation of femtosecond pulse propagation in semiconductor lasers and semiconductor amplifiers [I]. The code should take into account all relevant processes such as the interband and intraband carrier relaxation mechanisms and the many-body effects arising from the Coulomb interaction among charge carriers [2]. This objective was fully accomplished. We made use of a previously developed algorithm developed at NASA Ames [3]-[5]. The new algorithm was tested on several problems of practical importance. One such problem was related to the amplification of femtosecond optical pulses in semiconductors. These results were presented in several international conferences over a period of three years. With the help of a postdoctoral fellow, we also investigated the origin of instabilities that can lead to the formation of femtosecond pulses in different kinds of lasers. We analyzed the occurrence of absolute instabilities in lasers that contain a dispersive host material with third-order nonlinearities. Starting from the Maxwell-Bloch equations, we derived general multimode equations to distinguish between convective and absolute instabilities. We find that both self-phase modulation and intensity-dependent absorption can dramatically affect the absolute stability of such lasers. In particular, the self-pulsing threshold (the so-called second laser threshold) can occur at few times the first laser threshold even in good-cavity lasers for which no self-pulsing occurs in the absence of intensity-dependent absorption. These results were presented in an international conference and published in the form of two papers.

Agrawal, Govind P.↗
DOE OSTI2016

Intermediate time scale response of atmospheric CO 2 following prescribed fire in a longleaf pine forest

Fire plays an essential role in maintaining the structure and function of longleaf pine ecosystems. While the effects of fire on carbon cycle have been measured in previous studies for short periods during a burn and for multiyear periods following the burn, information on how carbon cycle is influenced by such changes over the span of a few weeks to months has yet to be quantified. We have analyzed high-frequency measurements of CO 2 concentration and flux, as well as associated micrometeorological variables, at three levels of the tall Aiken AmeriFlux tower during and after a prescribed burn. Measurements of the CO 2 concentration and vertical fluxes were examined as well as calculated net ecosystem exchange (NEE) for periods prior to and after the burn. Large spikes in both CO 2 concentration and CO 2 flux during the fire and increases in atmospheric CO 2 concentration and reduced CO 2 flux were observed for several weeks following the burn, particularly below the forest canopy. Both CO 2 measurements and NEE were found to return to their preburn states within 60–90 days following the burn when no statistical significance was found between preburn and postburn NEE. Furthermore, this study examines the micrometeorological conditions during a low-intensity prescribed burn and its short-term effects on local CO 2 dynamics in a forested environment by identifying observable impacts on local measurements of atmospheric CO 2 concentration and fluxes.

54 ENVIRONMENTAL SCIENCES↗