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At least 289 records · Page 16

Demonstration of a multi-channel fluidized bed particle–supercritical carbon dioxide heat exchanger for concentrating solar applications

High-temperature thermal energy storage in oxide particles at temperatures above 600°C can couple concentrated solar energy with high-efficiency thermal power cycles to provide dispatchable solar-driven electricity. Challenges remain in developing cost-effective primary heat exchangers, which require expensive alloys, to extract the high-temperature thermal energy from the particles to power cycle fluids, such as supercritical CO 2 (sCO 2 ) in recuperated Brayton cycles. To explore one pathway for cost-effective, high-temperature particle heat exchangers, the current study demonstrates a shell-and-plate, particle–sCO 2 heat exchanger with narrow- channel fluidized beds coupled with micro-channel sCO 2 flows in the heat exchanger walls. This study evaluates the feasibility of multiple parallel, narrow-channel fluidized beds in shell-and-plate particle–sCO 2 HXs, to achieve high bed-wall heat fluxes at elevated temperatures. A reduced-order model simulates the narrow- channel, fluidized-bed particle–sCO 2 heat exchanger to design the fluidized bed geometry, in terms of depth, height, and number of channels,for a nominal 40-kWth heat exchanger at particle and sCO 2 inlet temperatures up to 600 °C and 400 °C respectively. The resulting shell-and-plate heat exchanger design operates with bubbling fluidization of the downward-flowing oxide particles to enhance bed-wall heat transfer. The heat exchanger core is fabricated with etched sCO 2 micro-channels in thin wall plates that are diffusion bonded to spacer frames to form the shell-and-plate structure with 12 parallel, fluidized bed channels, 10.4 mm deep. The heat exchanger is tested at the National Solar Thermal Test Facility at Sandia National Laboratories with CARBOBEAD HSP particles at design particle flow rates of 0.20 kg s –1 and inlet temperatures up to 525 °C. Results show that fluidization across multiple parallel channel beds can maintain uniform particle inventory with a common freeboard zone above the heat exchanger core. Bubbling fluidization improves particle–wall heat transfer coefficients but also increases axial dispersion of particle thermal energy, which lowers the log- mean temperature difference such that total heat transfer remains relatively constant to within ±10% over a broad range of fluidization gas velocities. The axial dispersion required particle and sCO 2 flow rates to be increased by 25% over model-designed conditions to achieve the targeted 40 kWth, which indicates the importance of incorporating axial dispersion into heat exchanger design models and of deploying bed structures to suppress it. Furthermore, this study demonstrates the feasibility and preferred fluidizing gas conditions for particle heat exchangers for releasing high-temperature thermal energy storage systems.

14 SOLAR ENERGY↗

THEORETICAL WAVELENGTHS OF Fe XVI L-SHELL TRANSITIONS AND COMPARISON WITH LABORATORY MEASUREMENTS AND CHANDRA OBSERVATIONS OF CAPELLA

We have used the relativistic multi-reference Moller-Plesset perturbation theory to calculate the energy levels of Fe XVI, including those of the autoionizing levels with a hole state in the L shell. Comparison of the resulting L-shell transition wavelengths with those from recent laboratory measurements shows remarkable agreement, i.e., agreement within the experimental uncertainties. Our calculation allows us to predict the wavelength of the second strongest 2p-3d Fe XVI line, which has not yet been directly observed in the laboratory, to be 15.266 A. This wavelength is within 0.0042 A of the strong Fe XVII line commonly labeled 3D. Relying on the high accuracy of our calculations, we have reassigned two previously identified lines and predict a different location than previously thought for the strongest Fe XVI magnetic quadrupole transition. Inspection of the spectra of Capella recorded with the transmission grating spectrometers on the Chandra X-ray Observatory yields features corresponding to the predicted location of the innershell excited Fe XVI lines. These features have not been identified before. Our analysis shows that these features are most likely from Fe XVI.

79 ASTRONOMY AND ASTROPHYSICS↗

Star dust

Recent infrared techniques have revealed that the dust which is a major constituent of the universe, is composed of refractory grains produced by certain classes of stars, condensed in their atmospheres and blown into interstellar space by the radiation pressure of these stars. In some cases stars are surrounded by dust shells which consist of carbon refractories in the case of a carbon-rich environment, and metallic silicates of the kind that produced terrestrial planets in the case of oxygen-rich environments. A few of these infrared stars (called cygnids) exhibit a unique morphology that suggests the formation of a planetary stage in the evolution of a planetary nebula. Comets which are bright in the infrared and believed to be the remnants of the most primitive material in the solar nebula, are found to inject the astrophysical dust into our solar system together with asteroidal debris. Certain novae are also found to condense grains which are blown out in their shells after the explosion.

Ney, E. P.↗

IUE spectra of the massive close binary V382 Cygni

The massive close binary, V382 Cyg, was observed with the low-dispersion spectrograph on the IUE satellite. The dereddened spectrum can be reasonably represented by a 40,000-K model atmosphere. The spectra show interstellar, photospheric, and shell absorption blends and one shell emission feature. From one of the shell absorptions, it is possible to calculate a limiting systemic mass loss rate of about 0.00004 solar mass/yr.

Koch, R. H.↗

Scientific management and implementation of the geophysical fluid flow cell for Spacelab missions

Scientific support for the spherical convection experiment to be flown on Spacelab 3 was developed. This experiment takes advantage of the zero gravity environment of the orbiting space laboratory to conduct fundamental fluid flow studies concerned with thermally driven motions inside a rotating spherical shell with radial gravity. Such a system is a laboratory analog of large scale atmospheric and solar circulations. The radial body force necessary to model gravity correctly is obtained by using dielectric polarization forces in a radially varying electric field to produce radial accelerations proportional to temperature. This experiment will answer fundamental questions concerned with establishing the preferred modes of large scale motion in planetary and stellar atmospheres.

Hart, J.↗

Suprathermal ions upstream from interplanetary shocks

Low energy (10 eV-30 keV) observations of suprathermal ions ahead of outward propagating interplanetary shock waves (ISQ) are reported. The data were taken with the fast plasma experiment on ISEE 1 and 2 during 17 events. Structure was more evident in the suprathermal ion distribution in the earth bow shock region than in the upstream region. Isotropic distributions were only observed ahead of ISW, although field alignment, kidney-bean distributions, ion shells in velocity space and bunches of gyrating ions were not. The data suggest that the solar wind ions are accelerated to suprathermal energies in the vicinity of the shocks, which feature low and subcritical Mach numbers at 1 AU.

Gosling, J. T.↗

Measurement of wavelengths and lamb shifts for inner-shell transitions in Fe XVIII-XXIV

The wavelengths of inner-shell 1s-2p transitions in the ions Fe XVIII-XXIV have been measured in solar flare spectra recorded by the Naval Research Laboratory crystal spectrometer (SOLFLEX) on the Air Force P78-1 spacecraft. The measurements are compared with previous measurements and with recently calculated wavelengths. It is found that the measured wavelengths are systematically larger than the wavelengths calculated using the Z-expansion method by up to 0.65 mA. For the more highly charged ions, these differences can be attributed to the QED contributions to the transition energies that are not included in the Z-expansion calculations.

Seely, J. F.↗

A model for the infrared emission from the bulge of our Galaxy

A quantitative model for the IR emission from the bulge of the Galaxy is constructed using a sequence of models for circumstellar dust shells around late-type stars. The luminosity function for asymptotic giant branch stars and the distribution function for the dust-shell optical depth are derived. The total bolometric luminosity of the bulge population is 170 million solar luminosities and the total mass loss rate is 0.0083 solar mass/yr. The 12 microns and most of the 25 microns flux from the inner part of M31 can be understood as emission from a bulge population similar to that in the Galaxy. A simple model for the IR emission from late-type stars in the disk of the Galaxy is also given.

Rowan-Robinson, M.↗

Cosmic ray modulation - Voyager 2 observations, 1987-1988

The intensity profile of cosmic rays above 70 MeV observed by Voyager 2 and its relation to the interplanetary magnetic field and plasma at the beginning of the new modulation cycle from day 190, 1987 to day 345, 1988 in the region from 23.3 AU to 27.8 AU is analyzed. The cosmic ray intensity profile was approximately a series of four plateaus separated by three steps in which the intensity dropped abruptly. Each step was associated with a region in which the magnetic field, density and temperature were higher than average. The plateaus were associated with regions in which the magnetic field was alternately strong and weak. The solar wind within 200 AU during this interval can be roughly pictured as consisting of three shells between which the flow was quasiperiodic with a 26 day periodicity. The latitudinal extent of the shells in the northern hemisphere was probably less than 33 deg, since no steps were observed by Voyager 1. Drift motions might play a role during the recovery phase, just prior to the onset of the new modulation cycle, in the plateau regions between the shells, within the shells where drifts in various directions might mimic diffusion, and close to 1 AU, where large regions of intense magnetic fields have not yet formed. However the principal decreases in the cosmic ray intensity in the outer heliosphere during 1987 and 1988 were associated with the passage of broad regions of intense magnetic fields, consistent with the diffusion/convection model.

Burlaga, L. F.↗

Luminescent solar concentrators and related methods of manufacturing

Luminescent solar concentrators in accordance with various embodiments of the invention can be designed to minimize photon thermalization losses and incomplete light trapping using various components and techniques. Cadmium selenide core, cadmium sulfide shell (CdSe/CdS) quantum dot (“QD”) technology can be implemented in such devices to allow for near-unity QDs and sufficiently large Stokes shifts. Many embodiments of the invention include a luminescent solar concentrator that incorporates CdSe/CdS quantum dot luminophores. In further embodiments, anisotropic luminophore emission can be implemented through metasurface/plasmonic antenna coupling. In several embodiments, red-shifted luminophores are implemented. Additionally, top and bottom spectrally-selective filters, such as but not limited to selectively-reflective metasurface mirrors and polymeric stack filters, can be implemented to enhance the photon collection efficiency. In some embodiments, luminescent solar concentrator component is optically connected in tandem with a planar Si subcell, forming a micro-optical tandem luminescent solar concentrator.

Needell, David R.↗

High-Fidelity and High-Performance Computational Simulations for Rapid Design Optimization of Sulfur Thermal Energy Storage

Industrial process heating (IPH) accounts for approximately 70% of US manufacturing energy use and is primarily produced by fossil fuel combustion. Approximately 1500 TWht (approximately 60%) of IPH demand is in the temperature range of 100-300. Industrial applications in this temperature range include drying, hydrothermal processing, thermal enhanced oil recovery, food and beverage, bioethanol production, etc. Cost-effective thermal energy storage (TES) that increases the utilization of waste and renewable heat (solar, geothermal, etc.) could provide significant energy savings and reliable heat sources, decrease emissions, and increase US manufacturing competitiveness through reductions in fuel consumption. TES development has historically been dominated by technologies suitable for deployment with concentrating solar power (CSP). State-of-the-art thermal storage deployed commercially with power tower CSP plants uses a 60%/40% NaNO3/KNO3 molten salt and operates between temperatures of approximately 280 degrees Celsius and 570 degrees Celsius using a two-tank configuration. However, these nitrate salts are unsuitable for operation outside of this temperature range due to a high freezing point of approximately 220 degrees Celsius, and limits on high-temperature salt stability and corrosion resistance of containment alloys. Other materials being investigated for TES include those based on: (1) sensible energy storage (various molten salt compositions, inert solid particles, rocks or pebble beds, sulfur, water, concrete, graphite, etc.), (2) latent energy storage in materials that undergo solid-liquid phase change at relevant temperatures (organic materials for low-temperature applications, inorganic salts and/or metals for high-temperature applications), or (3) thermochemical energy storage (hydrides, hydroxides, carbonates, metal oxides, etc.). The application temperature and challenges pertaining to storage material and/or containment cost, energy density, long-term thermal and cyclic stability, and charge/discharge heat transfer effectiveness drive material selection for a given IPH or electricity generation application. Sulfur is a cheap commodity at $80/ton compared to $1100 - 1300/ton for conventional salts. When using a metric of storage cost per kWh, sulfur costs around 2-3 $/kWh. Previous sulfur TES development focused on high temperature (>600 degrees) concentrated solar power applications with sulfur encapsulated in pipes and flow of gaseous HTF (air) in the shell side. However, for lower-temperature IPH applications in the range of approximately 100-300 degrees Celsius Element 16 adopted a compact and scalable TES design with molten sulfur in the shell and HTF pipes submerged in the molten sulfur bath. The low-cost molten sulfur TES for dispatchable IPH has deployment potential for broad applications. The spatial and temporal evolution of the HTF and sulfur temperature is critical to the TES system performance, and thus detailed modeling can improve understanding of the performance and facilitate design improvements. Using high performance computing and computational fluid dynamics (CFD) a low-cost molten sulfur thermal energy storage (TES) system for industrial process heating (IPH) applications was developed. The unique challenges in CFD modeling of sulfur TES are the sharp property changes of sulfur relevant to the working temperatures. Above 159, liquid sulfur undergoes polymerization, and the viscosity of sulfur rapidly increases by several orders of magnitude between 159 degrees Celsius and 188 degrees Celsius, followed by a decrease in viscosity beyond 188 degrees Celsius due to thermal bound dissociation. In addition, various concentrations of H2S impurities can also modify sulfur viscosity. This numerical challenge is especially relevant to transient simulation of the sulfur TES charging and discharging processes as the extreme property variations limit the applicability of traditional heat transfer correlations. Transient CFD simulations including the temperature-dependent sulfur properties and geometric complexity of the TES design were used to predict the effect of natural convection during charging and discharging on the heat transfer process, sulfur temperature uniformity, charge/discharge rates, and performance of the storage devices. The CFD model was validated with experimental results for a full charge and discharge cycle. The work will show 3D and 2D simulation comparisons aimed to facilitate rapid design iterations and a machine learning based design optimization approach.

CFD↗

Theoretical spectra of circumstellar dust shells around carbon-rich asymptotic giant branch stars

Realistic modeling of circumstellar dust shells around evolved stars has to include a physical treatment of the interaction among hydrodynamics, thermodynamics, radiative transfer, chemistry and dust formation and -growth. A self-consistent solution of this problem is presented in the case of stationary, spherical symmetric dust-driven winds. The resulting shell structure and the mass-loss rate are completely determined by the three fundamental stellar parameters stellar mass M(stellar), stellar luminosity L(stellar) and effective temperature T(sub eff) and by the element abundances epsilon(sub i). A detailed calculation of the transport coefficients of the dust component by means of the particle size distribution function and the solution of the non-grey radiative transfer problem provide realistic synthetic spectra of the dust shell models. We discuss the dependence of the resulting spectra on the stellar parameters in terms of infrared two color diagrams. Application of these model calculations to the prominent infrared object IRC +10216 yields best agreement with the observed spectrum and the visibility data at maximum light for the stellar parameters M(stellar) = 0.7 solar mass, L(stellar) = 2.4 x 10(exp 4) solar luminosity, T(stellar) = 2010K and a carbon to oxygen ratio of epsilon(sub c)/epsilon(sub o) = 1.40, which corresponds to a mass-loss rate of M-dot = 8 x 10(exp -5) solar mass/yr. In this model only amorphous carbon grains are considered as the main opacity source. From this model a distance to IRC +10216 of d = 170pc is deduced. The total mass contained in the circumstellar dust shell implies and initial main sequence mass of M(sub ZAMS) greater than or = 1.3 solar mass for IRC +10216.

Winters, J. M.↗

DYNAMO EFFECTS NEAR THE TRANSITION FROM SOLAR TO ANTI-SOLAR DIFFERENTIAL ROTATION

Numerical MHD simulations play an increasingly important role for understanding the mechanisms of stellar magnetism. We present simulations of convection and dynamos in density-stratified rotating spherical fluid shells. We employ a new 3D simulation code for obtaining the solution of a physically consistent anelastic model of the process with a minimum number of parameters. The reported dynamo simulations extend into a “buoyancy-dominated” regime where the buoyancy forcing is dominant while the Coriolis force is no longer balanced by pressure gradients, and strong anti-solar differential rotation develops as a result. We find that the self-generated magnetic fields, despite being relatively weak, are able to reverse the direction of differential rotation from anti-solar to solar-like. We also find that convection flows in this regime are significantly stronger in the polar regions than in the equatorial region, leading to non-oscillatory dipole-dominated dynamo solutions, and to a concentration of magnetic field in the polar regions. We observe that convection has a different morphology in the inner and the outer part of the convection zone simultaneously such that organized geostrophic convection columns are hidden below a near-surface layer of well-mixed highly chaotic convection. While we focus our attention on the buoyancy-dominated regime, we also demonstrate that conical differential rotation profiles and persistent regular dynamo oscillations can be obtained in the parameter space of the rotation-dominated regime even within this minimal model.

79 ASTRONOMY AND ASTROPHYSICS↗

Multiple circumstellar shells and radiation pressure on grains in the outflows from late-type giants

It is pointed out that mass loss from red giants and supergiants is sometimes as high as 0.0001 solar mass per year. This mass loss represents a major source of new interstellar matter. The present investigation is concerned with the phenomena involved in stellar mass loss, taking into account a comparison of currently available observations with plausible models. The case of the extended circumstellar envelope around IRC +10216 is considered. In observations about mass loss from circumstellar shells, it is sometimes found that the P Cygni profiles are split into two or more sharp, distinct components. The question is considered whether such narrow separate components can be understood in terms of the radiation pressure model. A grain growth model is discussed along with outflow velocity, radiation pressure, and mass loss rates. The models are compared with observations from Alpha Orionis, Mira, and IRC +10216. It is concluded that a hybrid model for the mass loss from some late-type stars seems appropriate. Under certain conditions, outflow speeds of 10 to 20 km/s can be understood.

Jura, M.↗

Electrochemical synthesis of p-Cu{sub 2}O/n-ZnO nanorods hetero-junction for photovoltaic application

Development of high performance visible light responsive solar cell materials has attracted wide interest due to their potential applications in the energy industries. In this work, ZnO nanorods films were successfully prepared on the ITO coated glass substrates via simple three electrode electrochemical deposition route. The Cu{sub 2}O nanoparticles were then electrodeposited on the surface of ZnO nanorods to form p-Cu{sub 2}O/n-ZnO core-shell hetero-structure. The synthesized ZnO, Cu{sub 2}O films and p-Cu{sub 2}O/n-ZnO hetero-structure were characterized by low angle x-ray diffraction, scanning electron microscopy, and UV-Visible spectrophotometer. Due to the hierarchical morphologies and core-shell structure, p-Cu{sub 2}O/n-ZnO hetero-structure shows a prominent visible-light-driven photocatalytic performance under the low intensity light irradiation. The obtained results suggest that it is possible to synthesize ZnO nanorods, Cu{sub 2}O films and p-Cu{sub 2}O/n-ZnO core-shell hetero-structure by a simple, cost effective and environment friendly electrodeposition process which can be useful for water splitting and solar cell device fabrication.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Monolithic III-V Nanowire Solar Cells on Graphene via Direct van der Waals Epitaxy

Novel solar cells, based on dense arrays of InGaAs nanowires, are grown directly on graphene. Furthermore, graphene serves as the conductive back contact and growth template for van der Waals epitaxial assembly of vertical nanowires. Although far from being the optimum material, core-shell p–n junction In0.25Ga0.75As nanowire arrays demonstrate a conversion efficiency of 2.51%, representing a new record for substrate-free, III-V nanowire-based solar cells.

36 MATERIALS SCIENCE↗

Ambient energy for buildings: Beyond energy efficiency

The following Key Messages comprise the salient findings of this study: 1. Ambient energy (from sun, air, ground, and sky) can heat and cool buildings; provide hot water, ventilation and daylighting; dry clothes; and cook food. These services account for about three-quarters of building energy consumption and a third of total US demand. Biophilic design (direct and indirect connections with nature) is an intrinsic adjunct to ambient energy systems, and improves wellness and human performance. 2. The current strategy of electrification and energy efficiency for buildings will not meet our climate goals, because the transition to an all-renewable electric grid is too slow. Widespread adoption of ambient energy is needed. Solar-heated buildings also flatten the seasonal demand for electricity compared to all-electric buildings, reducing required production capacity and long-term energy storage. In addition, ambient-conditioned buildings improve resilience by remaining livable during power outages. 3. National policies, incentives, and marketing should be enacted to promote ambient energy use. Federal administrative priorities should reflect the importance of ambient energy for buildings. Use of ambient energy should be encouraged through existing and new building codes and standards. 4. Ambient energy system design tools are needed for architects, engineers, builders, building scientists, realtors, appraisers, and consumers. PVWatts is used over 100 million times per year for photovoltaic system design. A similar, simple, and accessible tool for ambient design is crucial. 5. Training on ambient energy is needed throughout secondary, post-secondary, and continuing education for workforce development. Currently, only about 10% of colleges teach courses on passive heating and cooling systems. 6. Ambient-conditioned buildings should be demonstrated in all US climate zones. Performance should be monitored and reported, with quantitative case studies made widely available. 7. While current technology is sufficient to build high-performance ambient buildings now, research is needed to develop new technologies to harness ambient energy more effectively and more economically. Such advancements will facilitate adoption of ambient energy technologies in a wider range of buildings, including retrofits. Examples include windows with much lower thermal losses, use of the building shell as thermal storage, alternative light-weight thermal storage systems, sky radiation cooling systems, automated controls for solar gains and passive cooling, and ground coupling.

14 SOLAR ENERGY↗