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Physical properties of the particles composing the Martian dust storm of 1971-1972

Data obtained with the infrared interferometric spectrometer (IRIS) aboard Mariner 9 during the global Martian dust storm of 1971-1972 are analyzed to study the particle sizes in detail, estimate the dust particle size distribution, and determine the dust optical depth. Theoretical spectra of the emergent intensity from dust clouds with properties similar to those of the Martian cloud are generated, deficiencies of the approximation used are discussed, and the information content of the IR aerosol spectra is assessed. Analysis of IRIS spectra from a series of orbits spread through the early months of the Mariner 9 mission indicates that the dust could have been either igneous material with an SiO2 content similar to or higher than that of a typical terrestrial sediment or clay minerals similar to those on earth. In either case, the Martian dust was differentiated by geologic or weathering processes. The dust particle size distribution between 1 and 10 microns is found to have a slope similar to that of terrestrial dust size distributions far from source regions.

Toon, O. B.↗

The direct effects of strain on burning rates of composite solid propellants

A mathematical model is developed to predict burn rate augmentation due to strain in a composite solid propellant. The model assumes the effect is due to the ability of the flame to penetrate the small fissures and voids that form when a propellant is strained. The number and size of these fissures is obtained by applying a flaw propagation analysis to randomly distributed flaws that form when the binder-oxidizer particle bonds break under stress. A flame height is calculated with Summerfield's burn rate equation and is used to compute the burn rate augmentation based upon the additional burn area created when the flame penetrates the fissures. Comparisons are made with data obtained from published sources. The existence of threshold pressure and strains, above which augmentation occurs, is verified although the model predicts a lower threshold pressure and higher threshold strain than expected. Further results and applications of the model are discussed.

Langhenry, M. T.↗

Airborne particulate matter in spacecraft

Acceptability limits and sampling and monitoring strategies for airborne particles in spacecraft were considered. Based on instances of eye and respiratory tract irritation reported by Shuttle flight crews, the following acceptability limits for airborne particles were recommended: for flights of 1 week or less duration (1 mg/cu m for particles less than 10 microns in aerodynamic diameter (AD) plus 1 mg/cu m for particles 10 to 100 microns in AD); and for flights greater than 1 week and up to 6 months in duration (0.2 mg/cu m for particles less than 10 microns in AD plus 0.2 mg/cu m for particles 10 to 100 microns in AD. These numerical limits were recommended to aid in spacecraft atmosphere design which should aim at particulate levels that are a low as reasonably achievable. Sampling of spacecraft atmospheres for particles should include size-fractionated samples of 0 to 10, 10 to 100, and greater than 100 micron particles for mass concentration measurement and elementary chemical analysis by nondestructive analysis techniques. Morphological and chemical analyses of single particles should also be made to aid in identifying airborne particulate sources. Air cleaning systems based on inertial collection principles and fine particle collection devices based on electrostatic precipitation and filtration should be considered for incorporation into spacecraft air circulation systems. It was also recommended that research be carried out in space in the areas of health effects and particle characterization.

Source record↗

Numerically Modeling the Erosion of Lunar Soil by Rocket Exhaust Plumes

In preparation for the Apollo program, Leonard Roberts of the NASA Langley Research Center developed a remarkable analytical theory that predicts the blowing of lunar soil and dust beneath a rocket exhaust plume. Roberts assumed that the erosion rate was determined by the excess shear stress in the gas (the amount of shear stress greater than what causes grains to roll). The acceleration of particles to their final velocity in the gas consumes a portion of the shear stress. The erosion rate continues to increase until the excess shear stress is exactly consumed, thus determining the erosion rate. Roberts calculated the largest and smallest particles that could be eroded based on forces at the particle scale, but the erosion rate equation assumed that only one particle size existed in the soil. He assumed that particle ejection angles were determined entirely by the shape of the terrain, which acts like a ballistic ramp, with the particle aerodynamics being negligible. The predicted erosion rate and the upper limit of particle size appeared to be within an order of magnitude of small-scale terrestrial experiments but could not be tested more quantitatively at the time. The lower limit of particle size and the predictions of ejection angle were not tested. We observed in the Apollo landing videos that the ejection angles of particles streaming out from individual craters were time-varying and correlated to the Lunar Module thrust, thus implying that particle aerodynamics dominate. We modified Roberts theory in two ways. First, we used ad hoc the ejection angles measured in the Apollo landing videos, in lieu of developing a more sophisticated method. Second, we integrated Roberts equations over the lunar-particle size distribution and obtained a compact expression that could be implemented in a numerical code. We also added a material damage model that predicts the number and size of divots which the impinging particles will cause in hardware surrounding the landing rocket. Then, we performed a long-range ballistics analysis for the ejected particulates.

Source record↗

Instrument Would Detect and Collect Biological Aerosols

A proposed compact, portable instrument would sample micron-sized airborne particles, would discriminate between biological ones (e.g., bacteria) and nonbiological ones (e.g., dust particles), and would collect the detected biological particles for further analysis. The instrument is intended to satisfy a growing need for means of rapid, inexpensive collection of bioaerosols in a variety of indoor and outdoor settings. Purposes that could be served by such collection include detecting airborne pathogens inside buildings and their ventilation systems, measuring concentrations of airborne biological contaminants around municipal waste-processing facilities, monitoring airborne effluents from suspected biowarfare facilities, and warning of the presence of airborne biowarfare agents

Savoy, Steve↗

Laser anemometer signals - Visibility characteristics and application to particle sizing

Investigations have been conducted concerning the characteristics of the visibility function as determined by the parameters of the laser anemometer system and the electromagnetic scattering properties of the particles. Experiments have been performed to evaluate the backscatter visibility of signals from a symmetric, s polarization laser anemometer as a function of the particle diameter and a parameter ratio. The results have been compared with the predictions of an analysis based on Mie's scattering theory. The analysis has also been used to evaluate the effects of the collecting aperture's size and location.

Adrian, R. J.↗

Computationally Guided Development of Components for High Energy Density Solid-State Lithium-Sulfur Batteries

All electric vertical take-off and landing vehicles (eVTOL) for urban air mobility (UAM) concepts face numerous challenging technical barriers before their introduction into the consumer marketplace. The most challenging of these technical barriers to overcome is developing an energy storage system capable of meeting the rigorous aerospace safety and performance criteria1. The performance metrics for eVTOL craft, such as specific energy, specific power, and safety, exceed those of electric automobiles by a factor of two to four. Current state-of-the-art (SOA) lithium-ion batteries are incapable of meeting the key performance criteria of energy and safety for eVTOL. Therefore, next generation advanced chemistries and designs must be developed to meet required performance metrics for electric aviation2. Beyond lithium-ion chemistries, such as lithium-sulfur, show promise in their high energy, while limitations exist in their power and cyclability due to low electrical conductivity and high intermediate solubility in organic liquid electrolytes. Several strategies to overcome the low electrical conductivity involve the use of selenium as a dopant in the active sulfur material, along with the incorporation of 2-dimensional electron-conducting holey-graphene to improve the composite cathodes electronic conductivity. Furthermore, combining this chemistry with a solid-electrolyte avoids the components’ dissolution issues3. However, the development of composite solid-state cathodes is non-trivial as several components must be intimately mixed so that the active component has sufficient access to both electrons and lithium ions to undergo full electrochemical conversion. Mathematical modeling of battery components can assist experimental design through a robust and rigorous combination of computational modeling techniques covering multiple length scales. The objective is to leverage modern computational materials methods combined with battery multiphysics tools to develop radically advanced compatible cathode and electrolyte materials, build and test solid state lithium-sulfur cells and packs. A NASA-based cross-organizational team of high-powered experts combined integrated computational predictive modeling, fundamental chemistry analysis, advanced material science, and battery cell development to tackle this very challenging, multidisciplinary problem. This presentation will show a multiscale computational modeling approach that has produced a novel particle dynamics method called Solid Electrolyte Sphere Approximation Model (SESAM). SESAM modeling targets the 1-10 µm scale structures and provides electromechanical and grain interactions for predictive design guidelines for the manufacturing of solid-state components. Parameters such as particle size and volume fraction of the constituent materials were modeled and experimentally fabricated to optimize electrochemical performance through improved microstructure design. Experimental feedback was provided through ionic and electronic conductivity assessment and structural analysis of developed materials and cell components.

battery↗

Investigations of Clouds and Aerosols on Mars, Venus and Titan

This final report was included as part of a new proposal. This new proposal was selected for funding on 9 Nov. 1999. For Titan our interest during the past few years was to explain the observed asymmetry in the albedo. We suggested earlier, from one-dimensional modeling studies, that vertical transport rates were comparable to particle fall speeds. Since heating of the upper atmosphere, which drives dynamical motions, is largely due to the aerosols, a nonlinear interaction between dynamics, radiative heating and particle microphysics is possible. We pursued this interaction in a two-dimensional model. We showed that the observed variations in the albedo between the two hemispheres and over an orbital cycle, could be due to dynamical motions suspending particles so that particle sizes and optical depths vary across the planet. In the Cassini time frame, future studies of this interaction between dynamics, radiation and microphysics may be worthwhile using, the strong modeling base that others, and we have developed. In our recently approved proposal, however, we plan to extend our modeling to hydrocarbon clouds that lie at lower levels. We know very little about such clouds, and numerical models for their properties are non-existent. These clouds may be observed by the Huygen's Probe, and by the Cassini orbiter, so predictions of their properties should help in the analysis of Cassini data. We have also developed a sophisticated model for the lower, condensational, clouds on Venus. In this model we explored the water vapor budget on Venus, and the properties of the clouds such as particle size distribution. During the past few years we have applied our model of the water ice clouds on Mars to new data sets from Pathfinder, and Mars Global Surveyor. We have compared our predictions of cloud properties with those seen by Pathfinder, and found reasonable agreement.

Toon, Owen B.↗

Investigations of Clouds and Aerosols on Mars, Venus and Titan

For Titan our interest during the past few years was to explain the observed asymmetry in the albedo. We suggested earlier, from one-dimensional modeling studies, that vertical transport rates were comparable to particle fall speeds. Since heating of the upper atmosphere, which drives dynamical motions, is largely due to the aerosols, a non- linear interaction between dynamics, radiative heating and particle microphysics is possible. We pursued this interaction in a two-dimensional model. We showed that the observed variations in the albedo between the two hemispheres and over an orbital cycle, could be due to dynamical motions suspending particles so that particle sizes and optical depths vary across the planet. In the Cassini time frame, future studies of this interaction between dynamics, radiation and microphysics may be worthwhile using the strong modeling base that others, and we have developed. In our recently approved proposal, however, we plan to extend our modeling to hydrocarbon clouds that lie at lower levels. We know very little about such clouds, and numerical models for their properties are non-existent. These clouds may be observed by the Huygen's Probe, and by the Cassini orbiter, so predictions of their properties should help in the analysis of Cassini data. We have also developed a sophisticated model for the lower, condensational, clouds on Venus. In this model we explored the water vapor budget on Venus, and the properties of the clouds such as particle size distribution. Most researchers have investigated the upper clouds on Venus, which are essentially a photochemical aerosol with a long lifetime. The lower clouds, however, are similar to stratus clouds on Earth. These clouds have short lifetimes, and are tightly coupled to the dynamics at the base of the Venus cloud deck. We believe that the holes in these clouds seen at near infrared wavelengths by Galileo are related to some interaction between dynamics and cloud physics. One goal of our recently approved proposed work is to better understand this interaction, and to better understand how these clouds may vary if the climate of Venus were to vary. During the past few years we have applied our model of the water ice clouds on Mars to new data sets from Pathfinder, and Mars Global Surveyor. We have compared our predictions of cloud properties with those seen by Pathfinder, and found reasonable agreement. More recently we have improved our model by including a radiative transfer algorithm and a boundary layer transport scheme . The goal of this work is to understand the thermal inversions seen in Mars Global Surveyor data. We find that the inversions are created by clouds radiatively cooling the atmospheric layers in which the clouds form. We have also initiated laboratory work on the physics of carbon dioxide particle formation. In our recently approved work we propose to use these laboratory data, and to extend our modeling to carbon dioxide clouds in the Martian atmosphere.

Toon, Owen B.↗

Physical characteristics of cometary dust from dynamical studies - A review

Progress made in the determination of the physical characteristics of cometary dust particles from studies of dust tail dynamics is reviewed. Applications of the combined dynamical photometric approach of Finson and Probstein (1968) to studies of cometary tails exhibiting continuous light intensity variations are discussed, with attention given to determinations of the particle-size-related distribution function of the solar radiation pressure exerted on the particles, the contribution of comets to the interplanetary dust, calculations of dust ejection rates and a Monte Carlo approach to the analysis of dust tails. Investigations of dust streamers and striae, which are believed to be related to comet outbursts entailing brief but sharp enhancements of dust production, are then reviewed, with particular attention given to observations of Comet West 1976 VI. Finally, the question of cometary particle type is addressed, and it is pointed out that the presence of submicron absorbing particles in the striae of Comet West is not incompatible with the presence of micron-size dielectric particles in the inner coma.

Sekanina, Z.↗

Atmospheric Multiple Scattering Effects on GLAS Altimetry: Analysis of Expected Errors in Antarctic Altitude Measurements - Part 2

The altimetry bias in GLAS (Geoscience Laser Altimeter System) or other laser altimeters resulting from atmospheric multiple scattering is studied in relationship to current knowledge of cloud properties over the Antarctic Plateau. Estimates of seasonal and interannual changes in the bias are presented. Results show the bias in altitude from multiple scattering in clouds would be a significant error source without correction. The selective use of low optical depth clouds or cloudfree observations, as well as improved analysis of the return pulse such as by the Gaussian method used here, are necessary to minimize the surface altitude errors. The magnitude of the bias is affected by variations in cloud height, cloud effective particle size and optical depth. Interannual variations in these properties as well as in cloud cover fraction could lead to significant year-to-year variations in the altitude bias. Although cloud-free observations reduce biases in surface elevation measurements from space, over Antarctica these may often include near-surface blowing snow, also a source of scattering-induced delay. With careful selection and analysis of data, laser altimetry specifications can be met.

Mahesh, Ashwin↗

Laboratory Investigation of the Effect of Venusian Weathering on Mineral Spectra

Introduction: The recent selection of two missions to Venus has renewed the importance of deter-mining weathering reactions between minerals and the Venusian atmosphere, and the spectral signatures of minerals before, during, and after these reactions. The rate at which weathering reactions progress also constrain show long unstable minerals will be present on the surface (e.g., [1]), and enables the use of mineralogy as a constraint on surface age(e.g., [2-3]).In order to gain an understanding of how mineral compositions and spectra change with weathering, we have begun conducting experiments in a 1 atm experimental setup at Wesleyan University. This setup exposes minerals to the temperature and most abundant gases of the Venus atmosphere (CO2, SO2, N2).We conducted initial experiments using biotite, calcite, and montmorillonite in order to test our methodology with minerals that may be relevant to recording the history of water on Venus. Methods: Experiments were conducted in Thermo Fisher Scientific Lindberg/Blue M Mini-Mite horizontal tube furnaces at Wesleyan University. Experiments used natural mineral chips and powders, and were conducted at 1 atmosphere and 460 °C under pre-mixed gases provided by Air Gas(Table 1). The furnaces are set up in a flow through configuration so that solid samples are exposed to a fixed gas composition, and quartz glass process tubes were used in all experiments (1/4” diameter for experiment V4, ½” diameter for all others). These conditions were maintained for the du-rations listed in Table 1, at which point the furnace was turned off with gas flowing until the sample was cool enough to extract under N2and be placed in a desiccator for storage. Run products were carbon coated and examined using a Hitachi SU5000 Field Emission Gun Scanning Electron Microscope (SEM) equipped with an EDAX Octane Pro EDS detector located at Wesley-an University. Visible-Near Infrared Spectroscopy (VNIR) analysis was performed on powdered samples under a nitrogen atmosphere using an ASD Fieldspec Proover the 350-2500 nm range. Powdered mineral samples were milled to a particle size of < 45μm and were spiked with an internal standard (Al2O3, corundum) to obtain quantitative mineralogy. Samples were analyzed using a Panalytical X’Pert pro X-ray Diffractometer (XRD), with an X’Celerator high speed detector and Co Kα radiation, with data collected at a step size of 0.02 ̊/minute step counting rate from 2 to 80 degrees 2θ at 45 mA/40kV in the X-ray Diffraction Laboratory located at NASA Johnson Space Center. Materials Data Inc (MDI) software suite, JadeTMv9 was used for Rietveld refinement to determine phase abundances and mineral identification by comparing XRD patterns to International Center for Diffraction Data (ICDD) database patterns. Table 1: Experimental matrix. Experiment Name Duration (Days)Gas Com-position (trace gas)MineralsV487SO2/N2(1.4%)Montmorillonite, biotiteV519SO2/N2(1.4%)CalciteV619CO2/SO2/N2(1.4% SO2, 2.1% N2)Montmorillonite, biotiteV828SO2/N2(1.4%)Biotite, calcite Results: Calcite. In both experiments, calcite was exposed to the SO2/N2gas mixture, and in both experimental run products, XRD analysis detected anhydrite, which is consistent with EDS measurements conducted in the SEM. The XRD analyses show greater amounts of anhydrite present after 28 days than 19, suggesting the calcite reaction progressed further given longer duration. Grain surface morphology as seen in the SEM also shows secondary mineral growth (Fig. 1). VNIR spectra show no change, as expected since anhydrite lacks spectral features in this wavelength range. Montmorillonite. Montmorillonite was exposed to two different gas mixtures, the SO2/N2mix and CO2/SO2/N2mix over different durations (87 and 19 days, respectively). VNIR analyses of both run products show a reduction in the 1441and1910 nm water features as well as a shift of the 1411 and 2011 nm features to shorter wavelengths that may indicate re-structuring in the crystal lattice and the production of amorphous phases [4]. XRD results are consistent with this, showing a shift of the 001 peak from 15Åto 10Åin both run products. The amount of X-ray amorphous material in the montmorillonite run products was greater than that present in the unreacted clay, being the greatest in the 87 day V4 experiment. No other secondary phases were detected in the run products, however sulfur was present in EDS analyses of powder samples.

A R Santos↗

Using Remote Sensing Data to Evaluate Surface Soil Properties in Alabama Ultisols

Evaluation of surface soil properties via remote sensing could facilitate soil survey mapping, erosion prediction and allocation of agrochemicals for precision management. The objective of this study was to evaluate the relationship between soil spectral signature and surface soil properties in conventionally managed row crop systems. High-resolution RS data were acquired over bare fields in the Coastal Plain, Appalachian Plateau, and Ridge and Valley provinces of Alabama using the Airborne Terrestrial Applications Sensor multispectral scanner. Soils ranged from sandy Kandiudults to fine textured Rhodudults. Surface soil samples (0-1 cm) were collected from 163 sampling points for soil organic carbon, particle size distribution, and citrate dithionite extractable iron content. Surface roughness, soil water content, and crusting were also measured during sampling. Two methods of analysis were evaluated: 1) multiple linear regression using common spectral band ratios, and 2) partial least squares regression. Our data show that thermal infrared spectra are highly, linearly related to soil organic carbon, sand and clay content. Soil organic carbon content was the most difficult to quantify in these highly weathered systems, where soil organic carbon was generally less than 1.2%. Estimates of sand and clay content were best using partial least squares regression at the Valley site, explaining 42-59% of the variability. In the Coastal Plain, sandy surfaces prone to crusting limited estimates of sand and clay content via partial least squares and regression with common band ratios. Estimates of iron oxide content were a function of mineralogy and best accomplished using specific band ratios, with regression explaining 36-65% of the variability at the Valley and Coastal Plain sites, respectively.

Sullivan, Dana G.↗

Measurements of size and composition of particles in polar stratospheric clouds from infrared solar absorption spectra

Results are presented on polar stratospheric cloud (PSC) observations, based on IR measurements of solar extinction, made by the airborne JPL Mark IV interferometer during the Airborne Antarctic Ozone Expedition in 1987, together with the instrumentation and the theoretical aspects of data analysis. Thirty-three PSC cases were analyzed and categorized into two types, I and II, which were found to occur at different altitudes during September. Type I clouds, seen at altitudes above 15 km, contained particles with radii of about 0.5 micarons and nitric acid concentrations greater than 40 percent, while type II clouds, found usually below 15 km, contained particles with radii of 6 microns and larger, composed of water ice. In addition, particles of larger than the 15-micron-size detection limit were encounterd.

Kinne, S.↗

Preparation and analysis of particulate metal deposits

Small particles and clusters of palladium were grown by deposition from the vapor phase under ultrahigh vacuum conditions. Amorphous and crystalline support films of Al2O3 and ultrathin amorphous carbon films were used as substrate materials. The growth of the metal deposit was monitored in situ by scanning transmission diffraction of energy-filtered 100 kV electrons and high resolution transmission electron microscopy (TEM) analysis was performed in a separate instrument. It was established by in situ TEM, however, that the transfer of specimens in this case did not unduly affect the size and distribution of deposit particles. It was found that the cleanness, stoichiometry, crystallinity and structural perfection of the support surface play an essential role in determining the crystalline perfection and structure of the particles. The smallest palladium clusters reproducibly prepared contained not more than six atoms but size determinations below 1 nm average particle diameter are very problematic with conventional TEM. Palladium particles grown on carbon supports feature an impurity-stabilized mosaic structure.

Poppa, H.↗

Martian B Storm Genesis and Evolution: Initial Analysis of Thermal Datasets.

Introduction: Dust lifting on Mars likely occurs primarily as a result of the exchange of momentum between the atmosphere and the surface via saltation. During saltation, sand-sized particles are mobilized but do not enter into suspension. When these larger particles fall back to the surface, kinetic energy is transferred to smaller dust particles which are then lofted into suspension in the atmosphere. Depending on the altitude to which dust is lofted, it can have a significant effect on atmospheric temperatures. As a strong absorber and emitter in the infrared, dust can influence atmospheric heating and modify the global circulation and weather on Mars [1,2]. Although dust is present in Mars’ atmosphere throughout the year, the atmosphere is generally dustier during the second half of the year when Mars is near perihelion. Observations reveal that episodic global-scale dust storms and fairly regular regional-scale dust storms are superimposed on a well-defined and highly repeatable seasonal cycle of dust opacity and associated mid-level atmospheric temperature responses. Kass et al. (2016) used 50 Pa temperature observations from MRO/MCS to identify three highly repeatable time periods during which regional dust storms occur, and designated them the “A”, “B” and “C” storms. While “A” and “C” storms have been studied a fair amount to-date, “B” storms have not yet been investigated in detail. This study explores the generation and evolution of the annually recurring regional dust storm known as the “B” storm, which was identified and categorized by Kass et al. (2016) based on 25 km (50 Pa) temperature observations. The B storm is a southern-hemisphere (SH) phenomenon that originates at the cap edge just after perihelion and which reaches peak intensity during the SH summer solstice, Ls 270. It may originate from the cap edge storms that spawn near the edge of the seasonal CO2 cap during retreat, but the mechanisms for B storm genesis have yet to be determined definitively [1]. Methods: We will use observational data sets and a global climate model (GCM) to investigate “B” regional storms. The data analysis component will include the analysis of imagery from MGS/MOC and MRO/MARCI, and spectroscopic data sets of dust and temperatures from MGS/TES and MRO/MCS with the goal of fully characterizing the behavior of these storms. Both MGS and TES provide data well-suited for temperature analysis at 25 km. MCS measures atmospheric temperature, dust extinction, and water ice extinction at 5 km intervals from the surface to about 80 km. TES measured atmospheric temperatures, column dust and water ice opacities, and column water vapor abundances. Measurements made by TES extended from the surface to about 40 km [1]. At the 50 Pa (25 km) level, local dust events usually confined to shallower depths are effectively filtered out of the analysis leaving the regional dust events identifiable by their temperature signatures [1]. Our preliminary analysis makes use of the fact that the brightness temperature at 15 microns (T15 temperature) is a close approximation to observed temperature at 25 km. We first reproduce the zonal mean 50 Pa level temperature plots for MY 29-32 to establish a baseline for our procedures moving forward [1]. Expanding on Kass et al. (2016), we include recent MCS data from MY 33 and 34 as well. Preliminary Analysis: The daytime (3PM) T15 temperatures in Figure 1 indicate: in MY 29, a strong A storm at Ls 240, a B storm at high southern latitudes just after Ls 270, and a C storm at Ls 320; in MY 30, a B storm at Ls 270; in MY 31 & MY 32, a B storm just before Ls 270; in MY 33, a B storm at Ls 270; and in MY 34, a strong A storm in the northern hemisphere at Ls 210, and a B storm around Ls 270 although there is a data gap. For the B storms, each is indicative of lofted dust and resultant warming. The daytime temperature structure illustrates that the B storm occurs annually around Ls 270 and is confined to high southern latitudes. It reaches its peak intensity around SH summer solstice, Ls 270, consistently for all six MY assessed. Since direct solar heating is absent overnight, the nighttime T15 temperatures (Figure 2) are often useful for differentiating the heat signature of direct solar heating from the dynamical response to that heating. However, in the southern polar latitudes at perihelion the sun does not set and direct solar heating remains present throughout the night. Importantly for our study, dust lofted in the B storm experiences this direct heating day and night for the entirety of its lifetime. The B storm expands as far north as -60 latitude and decays in latitudinal extent more gradually than it grows. This feature is less obvious in the nighttime (3AM) T15 temperatures (Figure 2). The temperature signal is stronger at night for MY 30-33. The warm pool is larger in area relative to the background at night in these four cases. This more uniform warming masks the “tail” feature somewhat, such that it is barely noticeable during these years. Unfortunately, gaps in MCS data in MY 29 and 34 prevent confirmation of the tail feature during those years, however, the B storm temperature signature follows a very different pattern than that described for MY 30-33. MY 29 and 34 appear to show smaller centers of warming at night and larger centers of warming during the day. This is in opposition to that previously described for MY 30-33. Conclusions and Future Work: We will continue investigating the heat signatures of B storms by looking at the total column heating as recorded by TES. We will also look at lower altitudes for patterns that may describe the relationship between B storms and the cap edge storms that develop while the seasonal cap is retreating. In the future, we will use GCM simulations to determine the atmospheric and thermo-dynamic conditions associated with these storms.

Courtney Marylou Batterson↗

A gas chromatograph experiment for a Titan entry probe

Development of a gas chromatographic technique for analysis of aerosols and volatile organics from a Titan probe is now in progress. Preliminary investigations of aerosol collectors have shown that an electrostatic device should be the most efficient for the particle sizes expected in Titan's atmosphere. Such a device particularly lends itself to development of a simple pyrolyzer which can be used to break down any collected organic conglomerate structures into volatile fragments. Those fragments can subsequently be analyzed by GC providing information about the original chemical structure of the aerosols. Studies show that as little as 1 to 5 micrograms of model aerosol can be successfully analyzed. High altitude atmospheric gas sampling will also be important on Titan due to the great depth of the atmosphere. Studies show that a GC analysis of model Titan atmospheres at pressures approximating this altitude can be made with a sensitivity of a few ten's of parts-per-billion for the trace gases of interest.

Carle, G. C.↗

Using Dust from Asteroids as Regolith Microsamples

Meteorite science is rich with compositional indicators by which we classify parent bodies, but few sample groups are definitively linked with asteroid spectra. More robust links need to be forged between meteorites and their parent bodies to understand the composition, diversity and distribution. A major link can be sample analysis of the parent body material and comparison with meteorite data. Hayabusa, the first sample return mission of the Japanese Aerospace Exploration Agency (JAXA), was developed to rendezvous with and collect samples from asteroid Itokawa and return them to Earth. Thousands of sub-100 micron particles were recovered, apparently introduced during the spacecraft impact into the surface of the asteroid, linking the asteroid Itokawa to LL chondrites [1]. Upcoming missions Hayabusa 2 and OSIRIS-REx will collect more significant sample masses from asteroids. In all these cases, the samples are or will be a collection of regolith particles. Sample return to earth is not the only method for regolith particle analysis. Dust is present around all airless bodies, generated by micrometeorite impact into their airless surfaces, which in turn lofts regolith particles into a "cloud" around the body. The composition, flux, and size-frequency distribution of dust particles can provide significant insight into the geological evolution of airless bodies [2]. For example, the Cassini Cosmic Dust Analyzer (CDA) detected salts in Enceladus' icy plume material, providing evidence for a subsurface ocean in contact with a silicate seafloor [3]. Similar instruments have flown on the Rosetta, LADEE, and Stardust missions. Such an instrument may be of great use in obtaining the elemental, isotopic and mineralogical composition measurement of dust particles originating from asteroids without returning the samples to terrestrial laboratories. We investigated the ability of a limited sample analysis capability using a dust instrument to forge links between asteroid regolith particles and known meteorite groups. We further set limits on the number of individual particles statistically needed to robustly reproduce a bulk composition.

microsamples↗