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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 289 records · Page 16

Optical Design and Validation of an Infrared Transmissive Spectrum Splitting Concentrator Photovoltaic Module

A new modular, hybrid solar power system is designed to generate both electrical and thermal energy by utilizing the full solar spectrum. The key element, an infrared-transparent concentrator photovoltaic (CPV) module, acts as a spectrum splitter, dividing solar radiation into two parts. The ultraviolet and visible light (“in-band”) are converted to electricity with high efficiency in CPV cells, while the infrared light (“out-of-band”) is transmitted directly to a thermal receiver, where thermal power may be converted to electricity by a suitable heat engine or used directly for industrial process heat applications whenever needed. Here, we describe the optical design, modeling, fabrication, and performance validation of this novel spectrum splitting CPV module. A transfer matrix style approach, cumulative transmission model, is built to study the reflection, absorption, and transmission in each layer of the CPV module. To optimize the optical performance, different materials for module superstrate/substrate, encapsulant, cell substrate, and cooling fluids are compared in order to enhance the transmission of out-of-band light through the CPV module by minimizing absorption. Six antireflection coatings along with front and backside electrical contact grids are designed to maximize transmittance of in-band light to the cell and out-of-band light to the thermal receiver. Here, the final design, currently being prototyped, predicts out-of-band light transmission to the thermal receiver of 74.1% (for the passively cooled version) and 65.3% (for the actively cooled version). When epitaxial liftoff technology is applied, the transmission will change to 80.8% (passively cooled) and 71.9% (actively cooled). Experimental prototypes show good agreement with modeled optical performance.

14 SOLAR ENERGY↗

Statistical Comparison of the Baseline Mechanical Properties of NBG-18 and PCEA Graphite

High-purity graphite is the core structural material of choice in the Very High Temperature Reactor (VHTR), a graphite-moderated, helium-cooled design that is capable of producing process heat for power generation and for industrial process that require temperatures higher than the outlet temperatures of present nuclear reactors. The Baseline Graphite Characterization Program is endeavoring to minimize the conservative estimates of as-manufactured mechanical and physical properties by providing comprehensive data that captures the level of variation in measured values. In addition to providing a comprehensive comparison between these values in different nuclear grades, the program is also carefully tracking individual specimen source, position, and orientation information in order to provide comparisons and variations between different lots, different billets, and different positions from within a single billet. This report is a preliminary comparison between the two grades of graphite that were initially favored in the two main VHTR designs. NBG-18, a medium-grain pitch coke graphite from SGL formed via vibration molding, was the favored structural material in the pebble-bed configuration, while PCEA, a smaller grain, petroleum coke, extruded graphite from GrafTech was favored for the prismatic configuration. An analysis of the comparison between these two grades will include not only the differences in fundamental and statistically-significant individual strength levels, but also the differences in variability in properties within each of the grades that will ultimately provide the basis for the prediction of in-service performance. The comparative performance of the different types of nuclear grade graphites will continue to evolve as thousands more specimens are fully characterized from the numerous grades of graphite being evaluated.

36 MATERIALS SCIENCE↗

RFA for Solar/Geothermal Hybrid Thermal Energy Storage Modeling: Cooperative Research and Development Final Report, CRADA Number CRD-16-646

Hyperlight Energy is an innovative concentrated solar power (CSP) company whose business charter is to commercialize a disruptively low-cost, CSP collector system that is ultimately for providing heat for solar thermal/geothermal hybrid power plants, process heat applications (e.g., enhanced oil recovery), and solar thermal power generation. Hyperlight's CSP collector system utilizes a linear Fresnel reflector (LFR) configuration. This LFR configuration consists of mirrors mounted in low-cost, precision plastic extrusions, which are integrated into raft assemblies and floated on low-cost, sealed waterbeds. Hyperlight's CSP collector technology has been developed under private equity investment, government grant and commercial funding. Hyperlight has been awarded a 1.5-million DOE COLLECTS contract with an additional 1.6 million in matched funds from private investment and the California Energy Commission. This DOE project will support the final steps of product development for bulk commercialization and deployment of the Hyperlight CSP collector system. The work will culminate in a final operational deployment at a commercially relevant site. Several such site options are currently under evaluation, including two geothermal sites. Hyperlight identified a very low-cost way to put renewable energy electrons on the grid at peak times, upgrading underutilized geothermal plants with Hyperlight's low cost CSP and thermal energy storage (TES). While Hyperlight's CSP collector work is maturing quickly for commercial pilot launch, an optimal TES system for solar thermal/geothermal hybridization needs to be evaluated and ultimately developed so Hyperlight can develop commercial retrofit projects at a scale of hundreds of megawatts of renewable energy power output at sites across the United States, followed by greenfield projects in a multi-GW sized market.

15 GEOTHERMAL ENERGY↗

Thermal resistance of naturally occurring airborne bacterial spores

Simulation of a heat process used in the terminal dry-heat decontamination of the Viking spacecraft is reported. Naturally occurring airborne bacterial spores were collected on Teflon ribbons in selected spacecraft assembly areas and subsequently subjected to dry heat. Thermal inactivation experiments were conducted at 105, 111.7, 120, 125, 130, and 135 C with a moisture level of 1.2 mg of water per liter. Heat survivors were recovered at temperatures of 135 C when a 30-h heating cycle was employed. Survivors were recovered from all cycles studied and randomly selected for identification. The naturally occurring spore population was reduced an average of 2.2 to 4.4 log cycles from 105 to 135 C. Heating cycles of 5 and 15 h at temperature were compared with the standard 30-h cycle at 111.7, 120, and 125 C. No significant differences in inactivation (alpha = 0.05) were observed between 111.7 and 120 C. The 30-h cycle differs from the 5- and 15-h cycles at 125 C. Thus, the heating cycle can be reduced if a small fraction (about 0.001 to 0.0001) of very resistant spores can be tolerated.

Puleo, J. R.↗

Cusp altitudinal electron temperature gradient - Dynamics Explorer 2 implications for heating mechanisms

Curtis et al. (1982) have shown that the levels of wave turbulence observed by Dynamics Explorer 2 (DE 2) are too low by several orders of magnitude to explain the high temperatures of the polar cusp ionosphere in terms of local deposition of energy. The low altitude plasma instrument (LAPI) showed high levels of superthermal electron fluxes. The present investigation has the objective to examine the arising questions more quantitatively by using the DE 2 electron temperature and superthermal electron flux measurements. It is shown that on the basis of DE 2 observations in the polar cusp, a consistent picture can be drawn regarding the ionospheric electron heating process. It is pointed out that the heating involves the generation of plasma waves by field-aligned electron beams of magnetosheath origin.

Curtis, S. A.↗

Modeling of Interaction Layer Growth Between U-Mo Particles and an Al Matrix

Interaction layer growth between U-Mo alloy fuel particles and Al in a dispersion fuel is a concern due to the volume expansion and other unfavorable irradiation behavior of the interaction product. To reduce interaction layer (IL) growth, a small amount of Si is added to the Al. As a result, IL growth is affected by the Si content in the Al matrix. In order to predict IL growth during fabrication and irradiation, empirical models were developed. For IL growth prediction during fabrication and any follow-on heating process before irradiation, out-of-pile heating test data were used to develop kinetic correlations. Two out-of-pile correlations, one for the pure Al matrix and the other for the Al matrix with Si addition, respectively, were developed, which are Arrhenius equations that include temperature and time. For IL growth predictions during irradiation, the out-of-pile correlations were modified to include a fission-rate term to consider fission enhanced diffusion, and multiplication factors to incorporate the Si addition effect and the effect of the Mo content. The in-pile correlation is applicable for a pure Al matrix and an Al matrix with the Si content up to 8 wt%, for fuel temperatures up to 200 degrees C, and for Mo content in the range of 6 – 10wt%. In order to cover these ranges, in-pile data were included in modeling from various tests, such as the US RERTR-4, -5, -6, -7 and -9 tests and Korea’s KOMO-4 test, that were designed to systematically examine the effects of the fission rate, temperature, Si content in Al matrix, and Mo content in U-Mo particles. A model converting the IL thickness to the IL volume fraction in the meat was also developed.

99 GENERAL AND MISCELLANEOUS↗

US DOE In-Plant Trainings to Develop Expertise and Replicate Success

In-Plant Trainings (INPLTs) offered by the US Department of Energy Better Buildings, Better Plants (Better Plants) program are multi-day workshops performed by industry-recognized experts. INPLTs include both classroom- and field-based sessions that train attendees to identify energy conservation opportunities, quantify savings from these opportunities, and implement projects to realize the savings. These training workshops enhance the attendees’ understanding of working principles, knowledge of best practices, and capability to analyze the energy performance of industrial energy systems. INPLTs are competitively awarded and focus on a wide range of topics, including traditional industrial systems such as steam, process heating and motor-driven systems, and processes such as energy treasure hunts and municipal water and wastewater treatment. Partners that are awarded INPLTs can invite external stakeholders, such as employees of other manufacturers, utility representatives, and vendors. The Better Plants program had delivered 123 INPLTs as of spring 2019, trained more than 2,000 participants, and identified more than $37 million in energy cost savings. This paper provides an overview of INPLTs, some key statistics, the top identified energy savings opportunities, and success stories from INPLTs delivered from 2011 to 2018. Finally, the vision for future INPLTs is discussed based on participants’ feedback and the long-term and strategic goals of the Better Plants program.

Guo, Wei↗

Thermodynamics and Transport Phenomena in High Temperature Steam Electrolysis Cells

Hydrogen can be produced from water splitting with relatively high efficiency using high temperature electrolysis. This technology makes use of solid-oxide cells, running in the electrolysis mode to produce hydrogen from steam, while consuming electricity and high temperature process heat. The overall thermal-to-hydrogen efficiency for high temperature electrolysis can be as high as 50%, which is about double the overall efficiency of conventional low-temperature electrolysis. Current large-scale hydrogen production is based almost exclusively on steam reforming of methane, a method that consumes a precious fossil fuel while emitting carbon dioxide to the atmosphere. An overview of high temperature electrolysis technology will be presented, including basic thermodynamics, experimental methods, heat and mass transfer phenomena, and computational fluid dynamics modeling.

03 NATURAL GAS↗

Manufacturing Thermal Energy Use in 2014

The first data set estimates thermal energy use (i.e., fuels combusted for process heating, boilers, and combined heat and power/cogeneration) by end use, temperature, county, and facility employment size class for all U.S. manufacturing industries in 2014. The estimation methodology builds off of prior estimates of industrial energy use (https://dx.doi.org/10.7799/1481899, https://dx.doi.org/10.7799/1461488). The second data set estimates hourly heat load (as a fraction of annual energy used for heat) using hourly observations of industrial boiler and combined heat and power/cogeneration heat load from EPA's Air Markets Program Data (https://ampd.epa.gov/ampd/), weekly operating hours in 2014 from Census Quarterly Survey of Plant Capacity Utilization (https://www.census.gov/programs-surveys/qpc/data.html), and annual production hours reported by assessments conducted by Industrial Assessment Centers (https://iac.university/).

14 SOLAR ENERGY↗

Manufacturing Thermal Energy Use in 2014

The first data set estimates thermal energy use (i.e., fuels combusted for process heating, boilers, and combined heat and power/cogeneration) by end use, temperature, county, and facility employment size class for all U.S. manufacturing industries in 2014. The estimation methodology builds off of prior estimates of industrial energy use (https://dx.doi.org/10.7799/1481899, https://dx.doi.org/10.7799/1461488). The second data set estimates hourly heat load (as a fraction of annual energy used for heat) using hourly observations of industrial boiler and combined heat and power/cogeneration heat load from EPA's Air Markets Program Data (https://ampd.epa.gov/ampd/), weekly operating hours in 2014 from Census Quarterly Survey of Plant Capacity Utilization (https://www.census.gov/programs-surveys/qpc/data.html), and annual production hours reported by assessments conducted by Industrial Assessment Centers (https://iac.university/).

14 SOLAR ENERGY↗

System Advisor Model (SAM) Improvements for Emerging Solar Thermal Applications

The System Advisor Model (SAM) is an open-source tool developed by NREL to simulate the techno-economic performance of technologies like photovoltaics, solar thermal, wind, and geothermal. NREL has recently completed, active, and planned projects to improve the solar thermal models in SAM and its underlying code base to represent emerging component technologies, systems, and applications. This poster describes new capabilities in the SolarPILOT optical modeling tool, supercritical carbon dioxide (sCO2) power cycles, and solar industrial process heat.

14 SOLAR ENERGY↗

Energy Assessments under the Top 10,000 Program - A Case Study for a Steel Mill in China

One of the largest energy-savings programs for the Chinese industrial sector was the Top-1,000 Program, which targeted the 1,000 largest industrial enterprises in China. This program was launched in 2006, implemented through 2010, and covered 33% of national energy usage. Because of the success of the Top-1000 initiative, the program has now been expanded to the Top-10,000 program in the 12th Five-Year Plan period (2011-2015). The Top-10,000 program covers roughly 15,000 industrial enterprises, or about two-thirds of China s total energy consumption. Implementing energy audit systems and conducting industrial energy efficiency assessments are key requirements of the Top-10,000 program. Previous research done by Lawrence Berkeley National Laboratory (LBNL) has shown that there is a significant potential for improvement in energy assessment practices and applications in China. Issues such as lack of long term policy mechanisms, insufficient motivation for industrial enterprises, limited technical scope of energy assessments, and lack of systematic standardization have been identified. Through the support of the U.S. Department of Energy (DOE) and the U.S. State Department (with additional co-funding from the Energy Foundation China), LBNL, Oak Ridge National Laboratory, the Institute for Sustainable Communities (ISC), and DOE Energy Experts worked collaboratively with Chinese local organizations and conducted a series of industrial energy efficiency assessment demonstrations in selected Chinese industrial plants. The project aimed to not only introduce standardized methodologies and tools for energy assessments, but also to bring the systems approach for energy system analysis to the Top 10,000 enterprises. Through the project, five energy system assessments were conducted, and more than 300 Chinese experts from local energy conservation centers, universities, research organizations, energy service companies, and plant engineers were trained. This paper begins by introducing China s national energy intensity and carbon intensity reduction targets. Then, this paper explains the development of Top 10,000 program, including program requirements, the method for target allocation, key supporting policies, as well as challenges in implementing the program. By focusing on a process heating energy system assessment conducted in a Chinese steel mill, this paper presents an example of an energy system assessment conducted on steel reheating furnaces, including overall energy efficiency levels, areas of heat loss, and the potential for energy savings. In addition, the paper provides energy-savings recommendations that were identified during the assessment, as well as potential energy and energy costs savings. To conclude, this paper presents key findings that could further improve the Top 10,000 program by implementing a systems approach for energy assessments.

China Energy Efficiency↗

Fuels and Materials Challenges for the Very High Temperature Reactor

High Temperature Gas-cooled Reactors (HTGRs) featuring particle fuel are a very mature technology. Commercial deployment occurred in the mid-1980's with the Fort St.Vrain and Thorium Hochtemperatur Reaktor by providing electricity to the grids in the United States and West Germany, respectively. The technology was then adopted by Japan and China with the operation of the High Temperature Test Reactor in Oarai, Japan and the High Temperature Reactor (HTR-10) in China. These commercial reactors typically operate with an outlet coolant temperature of 750 deg. C to 800 deg. C. Increasing the outlet temperature of the HTGR to even higher temperatures above 900 deg. C will improve the thermodynamic efficiency of the system and enable application of a new class of gas reactor, the very high temperature reactor (VHTR), to provide process heat, electricity, and hydrogen to a broad range of industrial customers with the attendant benefits of improved energy security and reduced CO{sub 2} emissions. However, the increase in coolant outlet temperature presents a number of technical challenges associated with fuels and materials. For over a decade, the U.S. Department of Energy has been sponsoring a broad program of research and development with a goal of addressing the technical fuels and materials challenges to support deployment of a VHTR that could safely and economically operate at outlet temperatures of 750 to 950 deg. C. In summary, fuels and materials challenges exist with deploying a VHTR with an outlet temperature of 950 deg. C in the areas of structural materials, graphite and TRISO fuel. However, R and D is underway or has recently been completed suggesting that technical solutions are possible. (authors)

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Human Reliability Considerations for Small Modular Reactors

Small modular reactors (SMRs) are a promising approach to meeting future energy needs. Although the electrical output of an individual SMR is relatively small compared to that of typical commercial nuclear plants, they can be grouped to produce as much energy as a utility demands. Furthermore, SMRs can be used for other purposes, such as producing hydrogen and generating process heat. The design characteristics of many SMRs differ from those of current conventional plants and may require a distinct concept of operations. The U.S. Nuclear Regulatory Commission (NRC) conducted research to examine the human factors engineering and the operational aspects of SMRs. The research identified thirty potential human-performance issues that should be considered in the NRC's reviews of SMR designs and in future research activities. The purpose of this report is to illustrate how the issues can support SMR probabilistic risk analyses and their review by identifying potential human failure events for a subset of the issues. As part of addressing the human contribution to plant risk, human reliability analysis practitioners identify and quantify the human failure events that can negatively impact normal or emergency plant operations. The results illustrated here can be generalized to identify additional human failure events for the issues discussed and can be applied to those issues not discussed in this report.

08 HYDROGEN↗

Phenomena Identification and Ranking Table (PIRT) for Fluoride High-Temperature Reactor (FHR) Neutronics

The deployment of Fluoride (salt-cooled) High Temperature Reactors (FHRs) has many potential benefits such as improved safety, improved economics, and a diversification of the energy portfolio because of its capability to supply industrial process heat. However, significant challenges remain before this class of reactors can be deployed, mostly related to its technology readiness. A recent study identified several areas in need of further development in order to advance the technology. These include the verification and validation of neutronics and thermal hydraulics modeling and simulation tools in support of design, safety analysis and licensing. The focus of this paper is to summarize the issues for verification and validation of neutronics tools. Current tools for neutronics analysis of LWRs are inadequate for the simulation of salt cooled reactors. The methodologies developed for the high temperature gas cooled reactors (HTGRs) have some relevance for FHRs because of the similarities between the two reactors such as graphite block structure, encapsulated fuel particles, and high operating temperatures. However, they are not sufficient for the accuracy desired of a code for licensing as they have a number of important differences neutronically, such as the use of liquid salt containing beryllium as a coolant and their unique fuel configuration. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Materials corrosion in molten LiF-NaF-KF eutectic salt under different reduction-oxidation conditions

Molten fluoride salts such as FLiNaK (LiF-NaF-KF: 46.5-11.5-42 mol %) have been proposed for use as secondary reactor coolants, media for transfer of high temperature process heat from nuclear reactors to chemical plants, and for concentrated solar power thermal energy storage. In molten fluoride salts, passive oxide films are chemically unstable, and corrosion is driven largely by the thermodynamically driven dissolution of alloying elements into the molten salt environment. Two alloys, Hastelloy{sup R} N and 316L stainless steel were exposed to molten FLiNaK salt in a 316L stainless steel crucible under argon cover gas for 1000 hours at 850 deg. C. Graphite was present in some of the crucibles with the goal of studying corrosion behavior of relevant reactor material combinations. In addition, a technique to reduce alloy corrosion through modification of the reduction-oxidation state was tested by the inclusion of zirconium to the system. Corrosion of 316L stainless steel was noted to occur primarily through surface depletion of chromium, an effect that was enhanced by the presence of graphite. Hastelloy{sup R} N experienced weight gain through electrochemical plating of corrosion products derived from the 316L stainless steel crucible. In the presence of zirconium, both alloys gained weight through plating of zirconium and as a result formed intermetallic layers. (authors)

36 MATERIALS SCIENCE↗

Scaling and Design Analysis of a Sub-Scale, Reduced Temperature Stratified Flow Separate Effects Test Facility for the Experimental Investigation of Air Ingress in a High Temperature Reactor System

High temperature gas reactors (HTGR) are poised to spearhead the next generation of nuclear reactors, due to their passive safety characteristics and their applications flexibility. Able to provide base load power or process heat for industrial applications, HGTRs may be a critical component to reducing greenhouse gas emissions in the United States and abroad. However, increased interest and development has also highlighted areas requiring further investigation, one of which being the air-ingress accident. Air ingress may occur following a break in the coaxial cross duct and pressure vessel depressurization. The initial mode of ingress is hypothesized to be density driven cross flow as the cold air enters the lower plenum, at which point molecular diffusion and/or local buoyancy phenomena will dominate until a global natural circulation current is established. While computational simulations support this progression, little or no experimental data exists to validate and support this phenomenology. Therefore, it is necessary to generate such data; this research seeks to do so through the use of a sub-scale separate effects test facility - the Stratified Flow Separate Effects Test Facility (SFSETF). The goal of this facility is more specifically to focus on the transition to global natural circulation starting from air ingress after a double-ended guillotine break (DEGB) while neglecting depressurization. This paper will provide analyses performed in the design of this facility, including the geometric and hydraulic scaling analyses, safety analysis and instrumentation selection. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

A transmissive, spectrum-splitting concentrating photovoltaic module for hybrid photovoltaic-solar thermal energy conversion

Here, a spectrum splitting, transmissive concentrating photovoltaic (tCPV) module is proposed and designed for a hybrid photovoltaic-solar thermal(PV/T) system. This module enables the system to more fully utilize the full spectrum of incoming sunlight. By utilizing III-V triple junction solar cells with bandgaps of 2.1eV/1.7eV/1.4eVin the module, ultraviolet (UV) and visible light will be absorbed and converted to electricity, while infrared (IR) light will pass through and be captured by a solar thermal receiver and stored as heat. The stored heat energy may be dispatched as electricity or process heat, as needed.Numerical analysis based on the Finite Elemental Method (FEM), ray tracing, circuit analysis, device modelling, and more is employed to design this tCPV module. According to these simulations, the tCPV module can perform with overall power conversion efficiency exceeding 43.5% for above bandgap (in-band)light under a standard AM1.5D solar spectrum, under an average concentration ratio of 400 suns.Passive and active cooling methods, keeping cells below 110°C, are also investigated and discussed, indicating that a transparent active cooling design could improve the CPV module efficiency by around 1%(absolute), relative to a passive design,by reducing the maximum cell working temperature by ~16°C. Furthermore, cost analysis shows that installation cost of around 1.9/W–2.2/W could be reached for the tCPV based PV/T system,which shows a competitive economic advantage compared to a more conventional PV with battery system.

14 SOLAR ENERGY↗