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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 289 records · Page 16
All sourcesNASA NTRSDOE OSTI
NASA NTRS2018

Oxidation Study of an Ultra High Temperature Ceramic Coatings Based on HfSiCN

High temperature fiber-reinforced ceramic matrix composites (CMCs) are important for aerospace applications because of their low density, high strength, and significantly higher-temperature capabilities compared to conventional metallic systems. The use of the SiCf/SiC and Cf/SiC CMCs allows the design of lighter-weight, more fuel efficient aircraft engines and also more advanced spacecraft airframe thermal protection systems. However, CMCs have to be protected with advanced environmental barrier coatings when they are incorporated into components for the harsh environments such as in aircraft engine or spacecraft applications. In this study, high temperature oxidation kinetics of an advanced HfSiCN coating on Cf/SiC CMC substrates were investigated at 1300 C, 1400 C, and 1500 C by using thermogravimetric analysis (TGA). The coating oxidation reaction parabolic rate constant and activation energy were estimated from the experimental results. The oxidation reaction studies showed that the coatings formed the most stable, predominant HfSiO4-HfO2 scales at 1400 C. A peroxidation test at 1400 C then followed by subsequent oxidation tests at various temperatures also showed more adherent scales and slower scale growth because of reduced the initial transient oxidation stage and increased HfSiO4-HfO2 content in the scales formed on the HfSiCN coatings.

Environmental Barrier Coatings↗
NASA NTRS2018

Oxidation Study of an Ultra High Temperature Ceramic Coatings Based on HfSiCN

High temperature fiber-reinforced ceramic matrix composites (CMCs) are important for aerospace applications because of their low density, high strength, and significantly higher-temperature capabilities compared to conventional metallic systems. The use of the SiCf/SiC and Cf/SiC CMCs allows the design of lighter-weight, more fuel efficient aircraft engines and also more advanced spacecraft airframe thermal protection systems. However, CMCs have to be protected with advanced environmental barrier coatings when they are incorporated into components for the harsh environments such as in aircraft engine or spacecraft applications. In this study, high temperature oxidation kinetics of an advanced HfSiCN coating on Cf/SiC CMC substrates were investigated at 1300 C, 1400 C, and 1500 C by using thermogravimetric analysis (TGA). The coating oxidation reaction parabolic rate constant and activation energy were estimated from the experimental results. The oxidation reaction studies showed that the coatings formed the most stable, predominant HfSiO4-HfO2 scales at 1400 C. A peroxidation test at 1400 C then followed by subsequent oxidation tests at various temperatures also showed more adherent scales and slower scale growth because of reduced the initial transient oxidation stage and increased HfSiO4-HfO2 content in the scales formed on the HfSiCN coatings.

Ultra High Temperature Ceramics (UHTC)↗
NASA NTRS2018

Oxidation Study of an Ultra High Temperature Ceramic Coatings Based on HfSICN

High temperature fiber-reinforced ceramic matrix composites (CMCs) are important for aerospace applications because of their low density, high strength, and significantly higher-temperature capabilities compared to conventional metallic systems. The use of the SiC(sub f)/SiC and C(sub f)/SiC CMCs allows the design of lighter-weight, more fuel efficient aircraft engines and also more advanced spacecraft airframe thermal protection systems. However, CMCs have to be protected with advanced environmental barrier coatings when they are incorporated into components for the harsh environments such as in aircraft engine or spacecraft applications. In this study, high temperature oxidation kinetics of an advanced HfSiCN coating on C(sub f)/SiC CMC substrates were investigated at 1300 C, 1400 C, and 1500 C by using thermogravimetric analysis (TGA). The coating oxidation reaction parabolic rate constant and activation energy were estimated from the experimental results. The oxidation reaction studies showed that the coatings formed the most stable, predominant HfSiO4-HfO2 scales at 1400 C. A peroxidation test at 1400 C then followed by subsequent oxidation tests at various temperatures also showed more adherent scales and slower scale growth because of reduced the initial transient oxidation stage and increased HfSiO4-HfO2 content in the scales formed on the HfSiCN coatings.

environmental barrier coatings (EBCs)↗
DOE OSTI2023

Efficient Reversible Operation and Stability of Novel Solid Oxide Cells

This project aims to develop and test novel Reversible Solid Oxide Cells (ReSOCs) specifically designed to yield low area specific resistance, as required to achieve high round trip efficiency in reversible operation at high current density. A key objective is to improve long-term reversible SOC durability; mechanistic degradation models will be used to predict long-term durability using input data from accelerated testing that combines electrochemical life testing with quantitative microstructural and chemical evaluation. The modeling tasks seek to design low-loss, low-cost ReSOC systems using input data from the experimental cell studies. A key challenge is to develop a thermal management strategy that maintains thermally self-sustaining operation while operating the stack at a potential lower than the thermo-neutral steam electrolysis voltage of ~1.3 V, to maintain high efficiency.

08 HYDROGEN↗
NASA NTRS2013

Nitric Oxide PLIF Measurements in the Hypersonic Materials Environmental Test System (HYMETS)

Planar laser-induced fluorescence (PLIF) of naturally occurring nitric oxide (NO) has been used to obtain instantaneous flow visualization images, and to make both radial and axial velocity measurements in the HYMETS (Hypersonic Materials Environmental Test System) 400 kW arc-heated wind tunnel at NASA Langley Research Center. This represents the first application of NO PLIF flow visualization in HYMETS. Results are presented at selected facility run conditions, including some in a simulated Earth atmosphere (75% nitrogen, 20% oxygen, 5% argon) and others in a simulated Martian atmosphere (71% carbon dioxide, 24% nitrogen, 5% argon), for specific bulk enthalpies ranging from 6.5 MJ/kg to 18.4 MJ/kg. Flow visualization images reveal the presence of large scale unsteady flow structures, and indicate nitric oxide fluorescence signal over more than 70% of the core flow for specific bulk enthalpies below about 11 MJ/kg, but over less than 10% of the core flow for specific bulk enthalpies above about 16 MJ/kg. Axial velocimetry was performed using molecular tagging velocimetry (MTV). Axial velocities of about 3 km/s were measured along the centerline. Radial velocimetry was performed by scanning the wavelength of the narrowband laser and analyzing the resulting Doppler shift. Radial velocities of +/- 0.5 km/s were measured.

Inman, Jennifer A.↗
NASA NTRS1982

Test verification of LOX/RP-1 high-pressure fuel/oxidizer-rich preburner designs

Two fuel-rich and two oxidizer-rich preburner injectors are tested with LOX/RP-1 in an investigation of performance, stability and gas temperature uniformity over a chamber pressure range from 1292 to 2540 psia. Fuel-rich mixture ratios range from 0.238 to 0.367 and oxidizer-rich mixture ratios range from 27 to 48, and carbon deposition data are collected by measuring the pressure drop across a turbine simulator flow device. The oxidizer-rich testing demonstrates the feasibility of oxidizer-rich preburners, indicating equilibrium combustion as predicted, and the measured fuel-rich gas composition and C-asterisk performance are in excellent agreement with kinetic model predictions indicating kinetically-limited combustion.

Lawver, B. R.↗
NASA NTRS1974

Dynamic oxidation behavior at 1000 and 1100 C of four nickel-base cast alloys, NASA-TRW VIA, B-1900, 713C, and 738X

The superalloys NASA-TRW VIA, B-1900, 713C, and 738X were tested cyclically and isothermally for resistance to oxidation in high velocity gas streams for 100 hours at specimen temperatures of 1000 C and 1100 C. Alloys VIA and B-1900, which were the most oxidation resistant, displayed slight and very similar weight changes and metal losses. Alloy 713C also sustained only slight metal losses, but it exhibited some tendency to spall. Alloy 738X was found to be the most susceptible to cyclic oxidation; this resulted in heavy spalling, which in turn caused high weight losses and high metal losses. Oxidation test results are related to the amounts of chromium aluminum, and the refractory metals in the alloys investigated.

Sanders, W. A.↗
NASA NTRS1992

The cyclic oxidation resistance at 1200 C of beta-NiAl, FeAl, and CoAl alloys with selected third element additions

The intermetallic compounds Beta-NiAl, FeAl, and CoAl were tested in cyclic oxidation with selected third element alloy additions. Tests in static air for 200 1-hr cycles at 1200 C indicated by specific weight change/time data and x-ray diffraction analysis that the 5 at percent alloy additions did not significantly improve the oxidation resistance over the alumina forming baseline alloys without the additions. Many of the alloy additions were actually deleterious. Ta and Nb were the only alloy additions that actually altered the nature of the oxide(s) formed and still maintained the oxidation resistance of the protective alumina scale.

Barrett, C. A.↗
NASA NTRS1996

Durability Testing of Commercial Ceramic Materials

Technical efforts by AlliedSignal Engines in DOE/NASA-funded project from February, 1978 through December, 1995 are reported in the fields ceramic materials for gas turbine engines and cyclic thermal durability testing. A total of 29 materials were evaluated in 40 cyclic oxidation exposure durability tests. Ceramic test bars were cyclically thermally exposed to a hot combustion environment at temperatures up to 1371 C (2500 F) for periods of up to 3500 hours, simulating conditions typically encountered by hot flowpath components in an automotive gas turbine engine. Before and after exposure, quarter-point flexure strength tests were performed on the specimens, and fractography examinations including scanning electron microscopy (SEM) were performed to determine failure origins.

Schienle, J. L.↗
NASA NTRS2000

Oxidation of Reinforced Carbon-Carbon Subjected to Hypervelocity Impact

This paper presents results from arc jet tests conducted at the NASA Johnson Space Center on reinforced carbon-carbon (RCC) samples subjected to hypervelocity impact. The RCC test specimens are representative of RCC components used on the Space Shuttle Orbiter. The arc jet testing established the oxidation characteristics of RCC when hypervelocity projectiles, simulating meteoroid/orbital debris, impact the RCC material. In addition to developing correlations for use in trajectory simulations, we discuss analytical modeling of the increased material oxidation in the impacted area using measured hole growth data. Entry flight simulations are useful in assessing the increased Space Shuttle RCC component degradation as a result of impact damage and the hot gas flow through an enlarging hole into the wing leading-edge cavity.

Curry, Donald M.↗
NASA NTRS1979

Internally coated air-cooled gas turbine blading

Ten candidate modified nickel-aluminide coatings were developed using the slip pack process. These coatings contain additives such as silicon, chromium and columbium in a nickel-aluminum coating matrix with directionally solidified MAR-M200 + Hf as the substrate alloy. Following a series of screening tests which included strain tolerance, dynamic oxidation and hot corrosion testing, the Ni-19A1-1Cb (nominal composition) coating was selected for application to the internal passages of four first-stage turbine blades. Process development results indicate that a dry pack process is suitable for internal coating application resulting in 18 percent or less reduction in air flow. Coating uniformity, based on coated air-cooled blades, was within + or - 20 percent. Test results show that the presence of additives (silicon, chromium or columbium) appeared to improve significantly the ductility of the NiA1 matrix. However, the environmental resistance of these modified nickel-aluminides were generally inferior to the simple aluminides.

Hsu, L.↗
DOE OSTI2020

U 3 Si 2 and UO 2 composites densified by spark plasma sintering for accident-tolerant fuels

This work reports the synthesis and characterization of the U 3 Si 2 and UO 2 composites sintered by spark plasma sintering (SPS) with controlled microstructures for accident-tolerant fuel application. The U 3 Si 2 and UO 2 composites with different silicide and oxide ratios were synthesized by SPS at temperatures from 1000 to 1300 °C for 5 minutes. The microstructure and phase composition of the SPS densified composite fuels were characterized with scanning electron microscopy, X-ray diffraction (XRD), and energy dispersed spectroscopy (EDS). A systematic study of the thermal and mechanical properties was conducted using microhardness testing and laser flash apparatus, along with oxidation resistance measurements using thermogravimetric analysis (TGA). The results show that the synthesis of composite fuels can be achieved with a 90% theoretical density (TD) at 1000 °C and over 95% TD when sintered at 1300 °C. XRD and EDS results confirmed that the dominant phases in the composites are U 3 Si 2 and UO 2 . Improved physical density generally leads to improved hardness, fracture toughness, thermal diffusivity, and onset temperature during the oxidation process. U 3 Si 2 was found to play a dominant role in determining the mechanical and oxidation properties of the composite fuels, whereas UO 2 had a more important impact on controlling the thermal diffusivity of the composites. The composite with 50 wt% UO 2 sintered at 1300 °C displayed the onset oxidation temperature of 500 °C by dynamic oxidation testing using TGA at a ramp degree of 10 °C/min. The composite also achieved a high fracture toughness of ~3.5 MPa m ½ . Finally, these results highlight the potential of composite fuel forms densified by SPS with simultaneously enhanced fissile element density, fracture toughness, thermal transport properties, and oxidation resistance.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
NASA NTRSDate not supplied

Mars Ascent Vehicle Hybrid Propulsion Effort

A technology development program was undertaken to determine if the benefits of hybrid rocket propulsion could be realized for a Mars Ascent Vehicle (MAV) application. Specifically, the goal of this program was to increase the Technology Readiness Level (TRL) of a hybrid propulsion system such that it could be considered for a potential Mars Sample Return Campaign. Over the course of approximately five years, a new, wax-based fuel was developed, characterized and tested with Mixed Oxides of Nitrogen (from MON-3 to MON-25). Various ignition mechanisms were tested and solid hypergolic additives were evaluated for their potential to ignite the hybrid motor. Several hot-fire test campaigns were completed at both sub- and full-scale. The technology development program was born out of a JPL study documented by Shotwell and Karp that identified the Single Stage to Orbit (SSTO) hybrid propulsion system for a potential Mars Ascent Vehicle to be the lowest Gross Lift Off Mass option from the ten configurations evaluated. Benefits of the hybrid option included its predicted favorable low temperature storage and operation behavior, high performance and ability to restart (enabling the SSTO). The main disadvantage of the hybrid option was its low TRL, as it essentially started as a blank sheet design with a new fuel development. Near the end of the technology development program, a Preliminary Architecture Assessment (PAA) was completed to evaluate a single-stage hybrid propulsion system and a two-stage solid propulsion system for a potential MAV. The solid propulsion system was selected for further study in 2019, primarily because of its flight heritage. While the hybrid technology development program made many strides, there was still a list of challenges to overcome. This paper will discuss the substantial progress and remaining challenges from the technology development effort from 2015 through 2019. This includes fuel development and reformulation, sub- and full-scale testing at Space Propulsion Group, full scale testing at Parabilis, full scale testing at Whittinghill Aerospace, hypergolic additive testing at Purdue and Penn State and the evaluation of adding hypergolic additives to a fullscale grain. It also includes a discussion of the design that resulted from the Preliminary Architecture Assessment.

hybrid rocket↗
NASA NTRS1974

Some injector element detail effects on screech in hydrogen-oxygen rockets

An experimental investigation was conducted to learn more about how the specific details of a concentric tube injection element affect the screech characteristics of a hydrogen-oxygen rocket engine. The four variables investigated were (1) impingement angle, (2) oxidizer tube blunt base thickness, (3) oxidizer tube recess and extension, and (4) oxidizer tube-annulus concentricity. Tests were made using a 27.34-cm (10.77-in.) diameter heat sink combustor at nominally 300-psia chamber pressure. All of the test variables were investigated using a 157 element circular pattern injector. Additional oxidizer tube recess tests were made with a 421 element hexagonal pattern injector. Tests were conducted over the oxidant-fuel ratio range of 4 to 6. Stability evaluation for each configuration was made using the hydrogen temperature rating technique. Several element configurations were also cold flow tested using nitrogen and water as simulants. The element detail changes resulted in changes in hydrogen injector pressure drop even though the physical injection area was constant for all similar tests in both hot firing and cold flow tests. These changes in injector pressure drop produced changes in combustion stability. The data were correlated with a modified version of a previously reported injection area ratio correlation. By interpreting changes in injector pressure drop as changes in injector hydrogen flow resistance, the data were compared with a hydrogen flow response stability model and were found to be in agreement.

Hannum, N. P.↗
NASA NTRS1984

Epitaxial thinning process

A method is described for thinning an epitaxial layer of a wafer that is to be used in producing diodes having a specified breakdown voltage and which also facilitates the thinning process. Current is passed through the epitaxial layer, by connecting a current source between the substrate of the wafer and an electrolyte in which the wafer is immersed. When the wafer is initially immersed, the voltage across the wafer initially drops and then rises at a steep rate. When light is applied to the wafer the voltage drops, and when the light is interrupted the voltage rises again. These changes in voltage, each indicate the breakdown voltage of a Schottky diode that could be prepared from the wafer at that time. The epitaxial layer is thinned by continuing to apply current through the wafer while it is immersed and light is applied, to form an oxide film and when the oxide film is thick the wafer can then be cleaned of oxide and the testing and thinning continued. Uninterrupted thinning can be achieved by first forming an oxide film, and then using an electrolyte that dissolves the oxide about as fast as it is being formed, to limit the thickness of the oxide layer.

Siegel, C. M.↗
NASA NTRSDate not supplied

Mars Ascent Vehicle Hybrid PropulsionEffort

A technology development program was undertaken to determine if the benefits of hybrid rocket propulsion could be realized for a Mars Ascent Vehicle (MAV) application. Specifically, the goal of this program was to increase the Technology Readiness Level (TRL) of a hybrid propulsion system such that it could be considered for a potential Mars Sample Return Campaign. Over the course of approximately five years, a new, wax-based fuel was developed, characterized and tested with Mixed Oxides of Nitrogen (from MON-3 to MON-25). Various ignition mechanisms were tested and solid hypergolic additives were evaluated for their potential to ignite the hybrid motor. Several hot-fire test campaigns were completed at both sub- and full-scale. The technology development program was born out of a JPL study documented by Shotwell and Karp that identified the Single Stage to Orbit (SSTO) hybrid propulsion system for a potential Mars Ascent Vehicle to be the lowest Gross Lift Off Mass option from the ten configurations evaluated. Benefits of the hybrid option included its predicted favorable low temperature storage and operation behavior, high performance and ability to restart (enabling the SSTO). The main disadvantage of the hybrid option was its low TRL,as it essentially started as a blank sheet design with a new fuel development. Near the end of the technology development program, a Preliminary Architecture Assessment (PAA) was completed to evaluate a single-stage hybrid propulsion system and a two-stage solid propulsion system for a potential MAV. The solid propulsion system was selected for further study in 2019, primarily because of its flight heritage. While the hybrid technology development program made many strides, there was still a list of challenges to overcome. This paper will discuss the substantial progress and remaining challenges from the technology development effort from 2015 through 2019. This includes fuel development and reformulation, sub- and full-scale testing at Space Propulsion Group, full scale testing at Parabilis, full scale testing at Whittinghill Aerospace, hypergolic additive testing at Purdue and Penn State and the evaluation of adding hypergolic additives to a full-scale grain. It also includes a discussion of the design that resulted from the Preliminary Architecture Assessment.

hybrid rocket↗