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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 289 records · Page 16

Nb 3 Sn Superconducting RF Cavities: R&D Progress at Fermilab and Opportunities

Nb 3 Sn becomes superconducting at twice as high temperature as our standard SRF material niobium. This allows us to efficiently operate Nb 3 Sn cavities at 4.4 K instead of the usual 2 K. This reduces cryogenic costs and even makes it possible to use a cryocooler instead of a large, complex cryogenic plant. The superheating field H sh of Nb 3 Sn is twice that of niobium. H sh is thought to be the ultimate limit for a defect-free superconductor. Nb 3 Sn cavities being made today are still about a factor of 4 away from this ultimate limit, but R&D has been leading to substantial progress towards this goal.

43 PARTICLE ACCELERATORS↗

Refrigerants: Market Trends and Supply Chain Assessment

The National Renewable Energy Laboratory (NREL), in partnership with ORNL, under the Clean Energy Manufacturing Analysis Center (CEMAC www.manufacturingcleanenergy.org) umbrella, assessed the current state of existing and low-GWP refrigerants for major end-use applications, including HVAC and those outside of the HVAC industry. The project incorporated a market overview, and supply chain assessment to determine the production, distribution, consumption, costs, and potential operating efficiency impacts of new and alternative refrigerants entering the market. Market trends and ongoing research are also documented. This work supplements other DOE efforts to support research activities on refrigerants and their applications including a refrigerant R&D roadmap and outlook into global air conditioning markets (Goetzler et al. 2014, 2016).

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Nb 3 Sn Superconducting RF Cavities: R&D Progress at Fermilab and Opportunities [Poster]

Nb 3 Sn becomes superconducting at twice as high temperature as our standard SRF material niobium. This allows us to efficiently operate Nb 3 Sn cavities at 4.4 K instead of the usual 2 K. This reduces cryogenic costs and even makes it possible to use a cryocooler instead of a large, complex cryogenic plant. The superheating field Hsh of Nb 3 Sn is twice that of niobium. Hsh is thought to be the ultimate limit for a defect-free superconductor. Nb 3 Sn cavities being made today are still about a factor of 4 away from this ultimate limit, but R&D has been leading to substantial progress towards this goal

43 PARTICLE ACCELERATORS↗

Simulation of Cross-Border Renewable Energy Trading in South Asia [Slides]

India's national renewable energy zones for wind power and solar photovoltaics (PV) could become regional green power resources if South Asian countries liberalize their rules for cross-border energy trading (CBET). Similarly, Nepal's wealth of hydropower could be more valuable to Nepal and its neighbors with greater market integration. These are the findings of a study by the U.S. National Renewable Energy Laboratory (NREL) that tested trading scenarios for wind power, solar power, and hydropower among Bangladesh, India, Nepal, and Sri Lanka. The NREL study found that wheeling power through India's interstate transmission system (ISTS) could be just as efficient operationally as building new high-voltage direct current (HVDC) lines from the renewable energy zones directly to the importing country. This means that CBET integration could substitute for new long-distance HVDC transmission - which could cost billions of dollars - while delivering to all participating countries the same benefits for renewable energy development and decarbonization.

13 HYDRO ENERGY↗

Cross-Border Electricity Trading and Renewable Energy Zones

India's national renewable energy zones for wind power and solar photovoltaics (PV) could become regional green power resources if South Asian countries liberalize their rules for cross-border energy trading (CBET). Similarly, Nepal's wealth of hydropower could be more valuable to Nepal and its neighbors with greater market integration. These are the findings of a study by the U.S. National Renewable Energy Laboratory (NREL) that tested trading scenarios for wind power, solar power, and hydropower among Bangladesh, India, Nepal, and Sri Lanka. The NREL study found that wheeling power through India's interstate transmission system (ISTS) could be just as efficient operationally as building new high-voltage direct current (HVDC) lines from the renewable energy zones directly to the importing country. This means that CBET integration could substitute for new long-distance HVDC transmission - which could cost billions of dollars - while delivering to all participating countries the same benefits for renewable energy development and decarbonization.

14 SOLAR ENERGY↗

Challenges for and Pathways Toward Solid-State Batteries

Solid-state batteries utilizing lithium metal anodes have the potential to enable batteries with a specific energy of >500 Wh/kg and an energy density of >1,500 Wh/L for thousands of cycles. When optimized they will improve the energy efficiency, operating temperature range, sustainability, and safety at a lower cost compared to projections for advanced Li-ion batteries. This improved performance is critical for the widespread adoption of electric vehicles and may enable future applications such as electric aviation. Expectations for solid-state batteries are high, there are significant materials and processing challenges that need to be overcome. Some of these challenges are well known; others are more subtle and are just becoming known. The challenges and their solutions must be clearly identified to realize high-energy solid-state Li metal batteries. In the United States, the U.S. Department of Energy (DOE) funds the majority of energy storage research and development, including solid state battery research. Web of Science publication analysis shows that worldwide DOE is second largest funder. Work on solid state batteries is distributed across different arms of DOE and is coordinated at headquarters to ensure a broad national portfolio for advanced batteries, including lithium batteries and solid-state battery devices. We note that university and national laboratory researchers in the US with a long-standing interest in solid state batteries is a small, integrated community with recognized impact for publications, patents and startup companies. The opportunity for this group to engage for research with international colleagues is growing, fostered by periodic bilateral meetings supported by DOE and by the recent joint US German research program for lithium battery interface studies. These are valuable opportunities to speed solid-state battery development. The ORNL led virtual workshop, overviewed here, confirms the community’s shared vision of the exciting advances, opportunities, and challenges. Further, we are seeing that this workshop has spawned several new informal collaborations and draft proposals. This encourages us to propose future discussion. On May 11, 2020, Oak Ridge National Laboratory (ORNL) hosted a 6-hour, on-line national workshop to discuss recent advances and most the prominent obstacles to realizing solid-state Li metal batteries. The workshop included more than 30+ experts from national laboratories, universities, and companies, all of whom have worked on solid-state batteries for multiple years. The participants shared recent advances, many not yet in print, illustrating that the community has gained significant new insights for solid-state Li battery materials over the last 5 years. In this report, the major outcomes of the workshop are organized to identify the gaps in our scientific knowledge for four core materials science areas: (1) Li metal anodes, (2) the solid electrolyte in contact with Li metal, (3) active cathode materials and solid-state composite cathodes, and (4) solid electrolytes. Illustrative examples and discussions are reported with the more comprehensive issues in the report. Discussion of additional challenges related to processing of solid-state battery materials and to the designs and architectures for mechanically robust, long-lived batteries received less attention due to time constraints. These are good themes for deeper discussion at a follow-on workshop, where a complete list of critical research topics can be identified.

25 ENERGY STORAGE↗

The Virtual Blast Furnace - An Integrated High Performance Computing Modeling, Simulation, and Visualization Capability for Steel Manufacturing (Final Report)

Many manufacturing industries require substantial capital and utilize energy intensive processes that involve complex phenomena. One example of such an industry is the steel industry, which is the fourth largest energy consuming industry in the U.S. By harnessing the power of High-Performance Computing (HPC) to enhance current simulation and visualization methods in the steel industry, it should be possible to increase resolution and/or decrease time of these methods by a factor of 1000. In this way, information can be obtained in a time frame that is useful for making business and engineering decisions, optimizing manufacturing processes and, ultimately, improving the completeness of U.S. industries. For example, if coke usage in blast furnaces were optimized such that the average coke rate was reduced from 797 lb/net tonne of hot metal (NTHM) to 604 lb/NTHM, costs could be reduced by $894 million/year. Additionally, members of the steel industry need the flexibility to efficiently operate blast furnaces at a range of production rates in order to meet fluctuating market demands. Large scale parameter studies can be utilized to discover workable operating parameters at a range of production rates.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Creep-fatigue Behavior and Damage Accumulation of a Candidate Structural Material for Concentrating Solar Power Solar Thermal Receiver (Final Technical Report)

Creep-fatigue deformation is an important consideration for a thermal receiver in Concentrating Solar Power systems due to the constant static stress or pressure, diurnal cycling, and elevated service temperatures required for efficient operation. An accurate description of the creep-fatigue behavior, not available for five of the six candidate materials, is important for assessment of preliminary designs. This project has provided a detailed analysis of the creep-fatigue behavior and damage accumulation of Alloy 740H, a candidate structural material for a CSP solar thermal receiver to address a critical knowledge barrier for receiver designs identified in the CSP Gen3 Demonstration Roadmap. This project was divided in to three tasks, split between two general categories: Experimental and design methodology. Tasks 1 and 3, relating to the collection of data on Alloy 740H plate and sheet forms, respectively, were performed at the Idaho National Laboratory and used as input to Task 2, the development of design methodology performed at Argonne National Laboratory. Experimental work covered limited tensile and creep testing to fill gaps in available data that is currently available and to demonstrate how the plate of Alloy 740H tested in this work compared to historical data. A more substantial testing program for fatigue and creep-fatigue was performed, with particular emphasis on creep-fatigue as there is little available data and it is necessary to understand the creep-fatigue interaction and develop related design models. This effort includes the development of rules for the design of solar receiver components against high temperature creep-fatigue and ratcheting failure modes. The ASME Code rules for high temperature nuclear components was used to the basis of the method but adjustments will be made to reflect the generally shorter, diurnal operating cycles of thermal receivers and the relative consequences of failure, comparing nuclear to solar components. This work has provided guidance for the design of components for concentrating power facilities operating at high temperatures and undergoing high, secondary thermal stresses relative to the applied primary pressure stress. The design rules were developed for the design of Generation 3 CSP tubular receivers manufactured from Alloy 740H, but are generally applicable to a wide range of component types undergoing similar loads. Procedural design rules for components to be used in conjunction with the 2019 edition of the ASME Boiler & Pressure Vessel Code and the corresponding design data for Alloy 740H have been developed. A commentary describing the rationale behind the design rules and the data underlying the design material properties, as well as an extensive set of worked sample problems detailing the application of the rules to CSP components were developed as a part of this project, with a separate report covering these aspects in detail and included in the Appendix of this report.

14 SOLAR ENERGY↗

Development of a Framework for Data Integration, Assimilation, and Learning for Geological Carbon Sequestration (DIAL-GCS) (Final Report)

This project aimed to develop and demonstrate a Data Integration, Assimilation, and Learning framework for geologic carbon sequestration projects (DIAL-GCS). DIAL-GCS is an intelligence monitoring system (IMS) for automating GCS closed-loop management by leveraging recent developments in machine learning technologies, complex event processing (CEP), and reduced-order modeling. The safe and efficient operation of GCS repositories requires integrated monitoring to track the injected CO¬2 as it moves within a storage reservoir. GCS projects are data intensive, as a result of proliferation of digital instrumentation and smart-sensing technologies. GCS projects are also resource intensive, often requiring multidisciplinary teams performing different monitoring, verification, accounting (MVA) tasks throughout the lifecycle of a project to ensure secure containment of injected CO2. The success of GCS thus depends in a large part on our ability to access, assimilate, and analyze heterogeneous data and information sources in a timely manner. This project included a number of meaningful and necessary tasks to transform the human domain knowledge into machine-interpretable rules for automating knowledge extraction and discovery in GCS. The specific technical objectives of the proposed DIAL-GCS project were to develop an ontology-driven GCS data management module for storing, querying, and exchanging GCS data (both historic and live sensor data) from multiple sources and in heterogeneous formats. Incorporate a CEP engine for detecting abnormal situations by seamlessly combining expert knowledge, rule-based reasoning, and machine learning. Enable uncertainty quantification and predictive analytics using a combination of coupled-process modeling, AI/ML methods, and reduced-order modeling, and integrate and demonstrate the system’s capabilities with both real and simulated data. As far as we know, this is one of the first projects aimed to develop intelligent monitoring systems (IMS) targeting the GCS. Under this project, the team had developed a large number of web applications and scientific algorithms that contribute the main theme of intelligent monitoring. The team has published more than a dozen peer reviewed papers and disseminated the research results at multiple technical meetings.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Testing of Instrumentation and Control Sensors and Cables for Small Modular Reactors

As advanced reactor concepts like small modular reactors (SMRs) progress towards design maturity and commercial deployment, it is important to assess their instrumentation and control (I&C) system sensors and cables to assure their safe, reliable, and efficient operation throughout their service lifetimes. The I&C system of any nuclear power plant (NPP) is the central nervous system of the plant and is made up of field devices such as sensors which are connected via cables to analog and/or digital systems. These systems are responsible for control and/or protection of the plant. The performance of I&C sensors and cables is dependent on several factors, including plant operating conditions. In particular, the plant operation can affect the static (accuracy) and dynamic (response) performance of the sensor, whereas the surrounding ambient environment can impact the remaining useful life of the cables, connectors, and other associated components within I&C sensor circuits.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Domestic Hot Water Temperature Maintenance Technology Review

Domestic hot water temperature maintenance (HWTM) is an important topic in facility management, and there are often opportunities to optimize systems to achieve energy, water, and maintenance savings. The main purpose of an HWTM system is to provide reliable hot water temperature at all fixtures with minimal wait time. This is done by replacing the standby heat losses from hot water sitting idle in pipes during periods of low demand. Traditionally, most commercial buildings do this by having water recirculate back to the water heater to be reheated. Other currently available HWTM systems are also discussed in this resource. HWTM systems can help maintain water at appropriate temperatures, minimize heat loss, and minimize delivery times to fixtures to improve the function of a building. This webpage includes a summary of HWTM options along with important considerations regarding occupant safety and comfort, and maintenance strategies for optimal and efficient operations. Domestic hot water (DHW) generation systems are referred to but are not the focus of this resource.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Energy Savings Performance Contracting for Small Projects

Energy Savings Performance Contracting (ESPC) is a budget-neutral approach to make building improvements that reduce energy and water use and increase operational efficiency. ESPC can help public-sector planners use tomorrow’s energy savings to fund today's facility and infrastructure upgrades. This resource highlights strategies and case studies for implementing ESPC in smaller towns, rural counties, and small school districts to complete energy upgrades and maximize energy and cost savings.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Application of NEAMS Codes to Capture MSR Phenomena

This report documents work completed in FY21 under the Nuclear Energy Advanced Modeling and Simulation (NEAMS) program’s Molten Salt Reactor (MSR) Application Drivers activity at Argonne. The common focus was on identifying the modeling and simulation functional requirements for designing, licensing, and operating MSRs and applying those capabilities already developed in NEAMS tools to example problems of interest. The four main parts of this report each focuses on a specific area of simulation physics as it relates to MSR phenomena: fuel evolution, chemistry, computational fluid dynamics (CFD), and systems analysis. In terms of fuel evolution, which includes depletion, decay, on-line separations, and transmutation, the current state of computational capabilities for modeling this behavior in liquid-fueled molten salt reactor is discussed. Some of the functional requirements to accomplish the various applications of MSR fuel depletion modeling are highlighted, followed by a summary of recent approaches and code development activities. The chemistry functional requirements were discussed in the context of several applications of high importance for MSRs, such as corrosion, salt chemistry, and species transport. Each of these types of chemistry modeling have considerable impact on various aspects of reactor applications, including informing on reactor designs, improving operational efficiencies, analyzing safety and reactivity concerns, and estimating the mechanistic source term of the reactor. A brief overview is also provided on code development activities ongoing under NEAMS relevant to chemistry modeling of MSRs. In terms of CFD applications, the state-of-the-art spectral element code, Nek5000 was used to model the fluid dynamics within a full core of the Molten Salt Fast Reactor (MSFR) concept designed as part of the Euratom EVOL project. This concept was selected as the challenge problem because of its similar features to several U.S. industry concepts. The goal was to model some of the fast MSR design challenges, including potential large internal re-circulations, the need of accurate tracking of delayed neutron precursors (DNP), and the lack of relevant thermal-hydraulics models/correlations, etc. Therefore, a series of CFD models were created for the MSFR core cavity using a k – τ model two-equation model for the turbulence. These first full core results demonstrated that any potential recirculation zones could be properly identified with the current NEAMS CFD capabilities. The development of these models will also set the stage for future testing of Nek5000’s functionalities to model other MSR thermal-fluid phenomena. Lastly, the validation of SAM against experimental data from the Molten Salt Reactor Experiment, which started in FY19, continues with the inclusion of modeling the reactivity insertion tests. This involved using SAM and its point kinetics model for flowing fuel salt to recreate the time dependent power changes and response after positive reactivity insertions at the 1, 5, and 8 MWt power levels. Through these exercises, several code modifications were suggested to the SAM development team and accommodated to enable closer agreement with solid technical and physical justifications. These include adding a moderator reactivity feedback coefficient as an available input and modifying the solution approach for the point kinetics model. Additional SAM development suggestions for flowing fuel MSRs include adding the capability to allow the moderator power change proportionally with the reactor power and enabling specification of the power and DNP distributions separately.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Comprehensive Assessment of On-And Off-Board Vehicle-To-Grid Technology Performance and Impacts on Battery and the Grid

This project defined, developed, and tested the open standards-based requirements, engineering design and system integration of on and off-vehicle Vehicle-to-Grid technologies both on the grid and on the PEV, to assess their effectiveness in implementing the use cases that create value for the grid, which in turn, can be passed on to the ratepayers and the PEV owners. The project comprised of three key categories of work and four key sub-areas of work. The three key categories were: On-Vehicle V2G, Off-Vehicle V2G, and impact of V2G operation on the battery capacity degradation. The four key sub-areas of work under each of these categories were: defining requirements, implementing the technology, performing system integration testing, and estimating the value of each of the grid services under specific assumptions, on a per-vehicle and on an aggregated basis. The technical implementation demonstrated the validity of standards-based approach to grid integration that led to interoperability, in addition to assessing the operational details with grid constraints imposed at the transformer level. The technology implementation also identified the subtle gaps in the standards definition to close the feedback loop on the accuracy of the standards as written, which are being implemented as revisions to the appropriate protocols. The battery impacts assessment developed a test cycle that the batteries from a real PHEV were subjected to for both the mobility-only and mobility with V2G specific energy cycling. While the battery impact results show a clear incremental degradation in response to additional throughput for V2G application purposes, the amount of additional kWh that can be made available without exceeding the end-of-life capacity definition of the battery at its 10-year warranty period was found to be significant. Given that the PEV battery being exercised during testing was a PHEV battery (smaller energy capacity), and 44% of its usable energy (i.e., SOC) was utilized daily for V2G applications, the EVs with much larger batteries will fare much better, either in terms of extracting more value in terms of incremental kWh for V2G, or in terms of relative incremental degradation of the capacity through the battery lifespan. Further, this battery was the second-generation Lithium-Ion chemistry circa 2015, which is at least two generations ago. Continual improvements in electrochemistry and manufacturing techniques as well as on-board capacity will enable the future batteries to provide even more energy for non-mobility-related services. Finally, the valuation of V2G energy services at the premise, distribution, and the ISO/market level was carried out for both the on-vehicle and off-vehicle cases, to understand both the GHG mitigation and operational efficiency improvements in quantitative terms. The analysis indicates that between $\$400$ and $\$1400$ per year of total value to the grid can be realized. When netted of costs to implement V2G either on or off-vehicle, the net value is available to be shared between the ratepayers and the EV owners. Over the life of the EV, therefore, this value becomes significant and can easily provide both ratepayer and EV owner benefits more than the cost of the equipment, either on or off-board, in addition to providing GHG mitigation benefits both on the grid and on the mobility sides. For these benefits to accrue, the key learnings from both the on- and off-vehicle V2G parts of the project indicate the need for at-scale demonstrations through involvement of real EV owners to validate both the technical feasibility, interoperability, as well as real grid benefits by performing extensive data collection and analysis. This will help inform the grid planners, the program designs, and tariff designers, as well as automotive and equipment manufacturers how best to create their products to maximize grid, ratepayer, and EV owner value.

30 DIRECT ENERGY CONVERSION↗

Introducing Small Scale Waste-to-Energy Technology in Microgrids (Cooperative Research and Development Final Report, CRADA Number CRD-17-00703)

Cogent has developed an innovative, proprietary waste-to-energy (WTE) system, the HelioStorm(TM) Gasifier, capable of efficiently operating on small amounts of heterogeneous municipal solid waste feedstocks, converting them into a clean syngas that can be used to fuel an electricity generator, all with rapid on/off cycle times. NREL will work with Cogent to complete a computer simulation of an integrated HelioStorm(TM) plasma gasifier system and dual fuel diesel generator. Cogent will test the performance of an actual HelioStorm(TM) WTE system and dual fuel diesel generator at their test facility using steady state electrical loads and provide a report describing the performance of the integrated system.

09 BIOMASS FUELS↗

Improve Performance and Cost for Steam Turbine Maintenance, Repair, and Overhaul Using Additive Manufacturing

The overall objective was to develop additive-manufacturing-enabled repair solutions for last stage bucket (LSB) and additive-manufacturing-enabled packing rings (PRs) for coal-fired steam turbines with the goal of reducing routine maintenance, repair, and overhaul (MRO) cost and improving the operating efficiency of steam turbines. GE Steam Power (GESP) and GE Gas Power (GEGP) provided technical and commercial consulting to GER with insights on steam turbine MRO design requirements, MRO duration and costs, and an overall commercialization strategy for the additive manufacturing technologies developed in the proposed effort.

20 FOSSIL-FUELED POWER PLANTS↗

WISP: Watching grid Infrastructure Stealthily through Proxies (Final Technical Report)

The complex interdependencies of cyber systems (sensors and communications), physical grids and associated electricity market operations make protecting electric power grids a significant challenge. The energy sector is constantly under new, targeted, advanced and dangerous cyber-attacks that have the potential to result in the loss of human life. These threats are further exacerbated by our need to modernize the grid. One focus of cyber security research in smart grids is the securing of the SCADA system through advanced intrusion detection systems (IDS) and bad data detection algorithms in state estimation. These methods either require full knowledge of the system topology and parameters or fail to understand the physical behaviors under attack. WISP (Watching grid Infrastructure Stealthily through Proxies) is designed to provide additional protection to the power grid using only publicly available data. In particular, WISP exploits the spatio-temporal nature of the real time locational marginal prices (LMPs), in conjunction with other information such as bids, weather, outages and load data to analyze anomalous power pricing behaviors and then correlate those observations to localize regions of interest and identify potential cyber events. WISP is non-intrusive as the tool is deployed as a service in the Cloud or on premise and provides reliable information to system operators for enhanced situational awareness, without impeding energy delivery functions. The WISP technology comprises three modules: the data-driven anomaly detection core, the vulnerability and risk analysis and the root cause analysis. The data-driven anomaly detection core performs the tasks of feature selection, anomaly detection and attack region localization. The vulnerability and risk analysis module provides system level information of the vulnerable variables and times, assisting the operators in selecting monitoring and protection nodes. The root cause analysis module takes the detection results and identifies potential operational conditions that contribute to the detected anomalies. In Phase I, we have demonstrated the feasibility and effectiveness of WISP. We developed a realistic electricity market simulator capable of generating normal and attack market data under various operational conditions. We developed a series of cyber-attack detection and analysis algorithms and evaluated them under multiple data sources. Finally, we integrated all modules into an end-to-end software, providing functions for data management, data analytics and visualization. Specifically, we have achieved: (i) real-time data acceptance from external utility interfaces with >99% acceptance rate; (ii) high performance anomaly detection algorithms with >98% detection accuracy and <0.1% false alarm rate; and (iii) ultra-low computing delay <50 milliseconds. Additionally, our team developed algorithms to identify the vulnerable variables in electricity market operations and root cause analysis functions to identify major contributors to the price spikes. These ancillary modules are necessary when deploying WISP in real world industry environment. In Phase II, we have demonstrated the effectiveness of WISP software on realistic largescale power systems. We performed red team testing for the Phase I WISP software and identified software vulnerabilities and implemented corresponding mitigation solutions. We adapted the electricity market simulator for the Texas synthetic 2000-bus system and generated datasets for the false data injection attacks. We created database and visualization interfaces for the Texas system and the ISO New England system. We performed software optimization in terms of operation efficiency, computing speed and detection accuracy. Finally, we tested the software on the Texas system and the ISO New England system and evaluated the detection performance. Overall, we achieved above 89% detection rate, below 3% false alarm rate and below 37 seconds of end-to-end detection delay.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Enrichment of H2 to CO2 ratio using formic acid as a hydrogen carrier - CRADA 581 (Abstract)

The collaboration between PNNL and OCOchem will investigate approaches to enhance the hydrogen (H2) content from a stream of H2 and carbon dioxide (CO2) gases produced in the catalytic decomposition of aqueous formic acid (FA85). OCOchem uses an electrochemical process to generate FA85 from captured CO2 using electricity from renewable resources. The FA85 is a liquid organic hydrogen carrier (LOHC) that provides the opportunity to transport and store hydrogen, in liquid form, at volumetric densities significantly greater than compressed H2 gas, i.e., 50 grams H2/liter FA. PNNL has developed and tested catalytic reactors to release H2 from LOHCs like FA and aqueous formate salts (FS). The H2 released from the LOHC can be oxidized in a proton-exchange membrane fuel cell (PEM-FC) to generate electricity with water as the only by-product. The purpose of the proposed project is to increase the purity of the hydrogen released from the LOHC to enhance the operation efficiency of the PEM FC. The PEM FC in combination with the LOHC provides an approach to demonstrate a portable generator that utilizes hydrogen as the energy carrier instead of conventional diesel generator. The ‘hydrogen generator’ can be used to supply emergency backup power and significantly reduce CO2 emissions relative to a diesel generator.

30 DIRECT ENERGY CONVERSION↗