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At least 289 records · Page 16

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NASA NTRS1983

Some fundamental aspects of solidification in a supercooled melt

A model of dendritic growth in both supercooled pure and alloy melts is presented. In a pure melt, dendrite morphology is determined by the value of the dimensionless parameter sigma = 2 alpha (L)d(o)/sq Rr(t) whereas, in an alloy melt it is determined by the parameter sigma = 2 lambda (c)D(L)/sq Rr(t). The application of the above analysis to cylindrical and spherical growth morphologies obtained in highly supercooled melts has been discussed. An upper and lower bound for the particle or tip radius in this case has been obtained in terms of the growth rate and the initial bath supercooling.

Laxmanan, V.↗

NASA NTRS1984

Alkali gabbronorite, ultra-KREEPy melt rock and the diverse suite of clasts in North Ray crater feldspathic fragmental breccia 67975

Lunar breccia 67975 is a feldspathic fragmental breccia from North Ray crater, Apollo 16. It contains clasts of alkali gabbronorite and ultra-KREEPy mafic fragment-laden melt breccias, which are unique among Apollo 16 samples. Both are alkali- and iron-rich rocks with moderate to high REE concentrations. They more strongly resemble Apollo 14 gabbronorites and alkali anorthosites and KREEP-rich rocks than they do other Apollo 16 samples. The other clasts in 67975 are the ferroan anorthosites, feldspathic melt rocks, and magnesian granulites, which are typical of other feldspathic fragmental breccias. Examination of bulk and mineral compositions of other breccias and melt rocks suggests that alkali gabbronorite may be a minor component in other North Ray crater breccias and feldspathic melt rocks. This implies that alkali gabbronorite was a fairly early (4.0 b.y.) crustal component in the North Ray crater region.

Lindstrom, M. M.↗

NASA NTRS1984

Apollo 16 site geology and impact melts - Implications for the geologic history of the lunar highlands

The geology of the Apollo 16 site is reconsidered on the basis of data from photogeology, geochemical remote sensing, and lunar samples. The site possesses an upper surface of anorthositic gabbro and related rocks. Mafic components were deposited as basin ejecta. The events involved in its geological evolution were the Nectaris impact and the Imbrium impact. The role of large, local craters in the history of the region was to serve as topographic depressions to accumulate basin ejecta. The most abundant melt composition at Apollo 16 is an aluminous variety of LKFM basalt supplied by the Nectaris impact as ejected basin impact melt. The mafic LKFM melt may have been supplied by the Imbrium impact. More aluminous melt groups are probably derived from local, small craters. The remainder of the deposits in the region are composed of anorthositic clastic debris derived from the Nectaris basin, the local crustal substrate, and Imbrium and other basins.

Spudis, P. D.↗

NASA NTRS1984

The case for a melt matrix in plagioclase-POIK mesosiderites

Reasons are given for reclassifying former 'poikiloblastic' mesosiderites as 'poikilitic' in order to better represent their thermal histories. Attention is focused on the plagioclase-POIK mesosiderites Bondoc, Budulan, and Mincy, which all display silicate melt matrices similar to the Palisades sill and Apollo 17 mare basalts. The poikilitic textures, resorbed olivine grains, and the crystallization sequence are sufficient to reclassify the three specimens from 3B to 4B mesosiderites. Because the 4B mesosiderites are clast-laden melt rocks, their origins were probably in impact melts, which would have combined hot melts with cold clasts.

Hewins, R. H.↗

NASA NTRS1984

Mineralogical comparison and cooling history of lunar and chondritic vesicular melt breccias

Lunar sample 77135, an impact melt breccia full of vesicles, has been reinvestigated by electron microprobe and X-ray diffraction techniques and compared with a vesicular melt LL chondrite, Yamato 790964, in an attempt to understand their impact heating processes and subsequent cooling history. Notable similarities between the lunar and chondritic melt breccias include: abundant vesicles, similar pyroxene chemical zoning trends, the presence of variable amounts of clastic material, and similar chemical compositions except for K and Na contents of glass and mesostasis. Some constraints on the cooling history are estimated from Mg-Fe diffusion profiles in olivine and pyroxene. The burial depth of lunar sample 77135 during cooling was 0.2-100 m; the depth for the chondrite was probably smaller. Impact melts were probably produced and a layer of regolith retained on the parent body sufficiently thick to allow the olivines to homogenize during slow cooling.

Miyamoto, M.↗

NASA NTRS1984

Morphological stability in the presence of fluid flow in the melt

Recent experiments have shown that the presence of a vertical buoyancy-driven flow adjacent to an initially cylindrical crystal-melt interface may produce a time-dependent helical deformation of the interface, with a rotation period ranging from several minutes to many hours, depending upon the width of the melt. The temperature distribution is such that the interface is expected to be morphologically stable in the absence of fluid flow. A linear stability analysis reveals that the instability is due to a coupling between a basic hydrodynamic instability in the buoyant flow and the deformable boundary separating the two phases. The crystal-melt interface lowers the critical Grashof number of an analogous rigid-walled system by an order of magnitude for succinonitrile with a Prandtl number P = 22.8; furthermore, the hydrodynamic mode that is actually destabilized by the interface is not the least stable mode in the rigid-walled system for P = 22.8. The results show that the instability may be regarded either as a rather large alteration of a basic hydrodynamic instability by the crystal-melt interface, or as a significant modification of the morphological stability of the interface by the presence of the buoyant flow.

Mcfadden, G. B.↗

NASA NTRS1985

Processes and imagery of first-year fast sea ice during the melt season

In June and July 1982, a field program was conducted in the Canadian Arctic on Prince Patrick Island to study sea ice during the melt season with in situ measurements and microwave instrumentation operated near the surface and from aircraft. The objective of the program was to measure physical characteristics together with microwave backscatter and emission coefficients of sea ice during this major period of transition. The present paper is concerned with a study of both surface measurements and imagery of first-year fast ice during the melt season. The melting process observed in first-year fast ice was found to begin with the gradual reduction of the snow cover. For a two- to three-day period in this melt stage, a layer of superimposed ice nodules formed at the snow/ice interface as meltwater froze around ice and snow grains.

Holt, B.↗

NASA NTRS1985

Containerless Processing of Glass Forming Melts in Space

The major objectives of this work are: (1) obtain quantitative evidence for the suppression of heterogeneous nucleation/crystallization in containerless melts in micro-g; (2) study melt homogenization in the absence of gravity driven convection; (3) develop the procedures for preparing precursor samples suitable for flight experiments; (4) perform comparative property analysis of glasses melted on Earth and in micro-g; (5) determine the feasibility of preparing glass shells in micro-g for use as laser fusion targets; and (6) assess the operational performance of the single axis acoustic levitator/furnace apparatus for processing multicomponent, glass forming melts in micro-g. Ways of obtaining these goals are discussed.

Day, D. D.↗

NASA NTRS1986

Convective effects in float-zone and Czochralski melts

The hydrodynamics of crystal-growth melts is a relatively new research area. Numerical modeling of these processes is necessary. The work discussed herein is in two parts: numerical simulations of the flow in a Czochralski melt, and also of that in a float zone. In addition, for the float-zone case, energy stability theory will be used to determine stability bounds for the onset of oscillatory thermo-capillary flow. Convective effects in crystal-growth melts arise from a variety of mechanisms. Temperature gradients both in the direction of gravity and normal to it give rise to convection due to buoyancy effects. Rotation of the crucible and/or crystal causes a forced convection which may augment or oppose the buoyancy-driven flow. Finally, thermo-capillary forces (due to the variation of surface tension with temperature) drive surface motions which in turn generate convection in the bulk fluid. All of these mechanisms are present in either Czochralski or float-zone growth. The objective of the Czochralski modeling is to develop an accurate numerical simulation of the flow in a Czochralski silicon melt and to investigate the effects of various parameters on the flow properties. Like some earlier investigations, the intent is to simulate the effects of buoyancy, forced and thermo-capillary convection, including unsteady effects. Unlike earlier work, the aim is to include the effects of a variable free surface and freezing interface and, possibly incorporate nonaxisymmetric effects.

Neitzel, G. P.↗

NASA NTRS1985

An experimental investigation of agglutinate melting mechanisms - Shocked mixtures of sodium and potassium feldspars

The results of an experiment designed to test the validity of the model for agglutinate formation involving fusion of the finest fraction or F3 are reported. Impact glasses were formed from various mixes of orthoclase and albite powders, which were used as analogs for soils with chemically constrasting coarse and fine fractions. The results showed that the single most important factor displacing the composition of a small-scale impact melt from the bulk composition of the source regolith is the fractionated composition of the finest soil fraction. Volatile loss and the amount of melting, which in turn are determined by the degree of shock, are also important. As predicted by the model, the lower pressure melts are the most fractionated, and higher pressure is accompanied by increased melting causing glass compositions to approach the bulk. In general, the systematics predicted by the model are observed; the model appears to be valid.

Simon, S. B.↗

NASA NTRS1987

Chemical composition and origin of Apollo 15 impact melts

Fourteen Apollo 15 impact melt rocks were analyzed for major (fused bead microprobe) and trace element (INAA) abundances, and the compositions of these Apennine Front rocks were compared with samples from other landing sites. The rocks show a wide range in trace element abundances, although all but one have a typical KREEP incompatible element pattern and have low-K Fra Mauro basaltic or medium-K Fra Mauro basaltic compositions. The melt chemistries appear to form five groups (labeled A to E in order of decreasing incompatible elements), with the compositions unlike nearly all other impact melts and regoliths from highland sites. All groups except Group A may represent single impact events (either Imbrian or post-Imbrian). One unique sample has a non-KREEP incompatible element pattern, with low abundances and a positive Eu anomaly. Its target is believed to be either a pre-Imbrian melt or exotic.

Ryder, Graham↗

NASA NTRS1987

The meteorite component of Apollo 16 noritic impact melt breccias

The compositions of noritic melt breccias from Apollo 16 were compared with those of noritic impact melt breccias from other landing sites (A14 14310, A15 LKFM, and A17 stations 2 and 3). It was found that the Apollo 16 breccias contain greater concentrations of siderophile elements than the other noritic melt breccias, due to a large amount of Fe-Ni metal and Ni (1150 micrograms/g in the A16 Type-2 DB). The Fe-Ni metal is the carrier of the chemical signature of the ancient meteorite group 1H of Hertogen et al. (1977), with the bulk composition dissimilar to metal found in ordinary chondrites but similar to that found in some iron meteorites. It is argued that the meteorites that produced the impact melts were irons.

Korotev, Randy L.↗

NASA NTRS1985

Surface-tension-driven flow in a glass melt

Motion driven by surface tension gradients was observed in a vertical capillary liquid bridge geometry in a sodium borate melt. The surface tension gradients were introduced by maintaining a temperature gradient on the free melt surface. The flow velocities at the free surface of the melt, which were measured using a tracer technique, were found to be proportional to the applied temperature difference and inversely proportional to the melt viscosity. The experimentally observed velocities were in reasonable accord with predictions from a theoretical model of the system.

Mcneil, Thomas J.↗

NASA NTRS1987

Polar basal melting on Mars

The thermal requirements and implications of polar basal melting on Mars are discussed in detail. The composition, geology, origin, and evolution of the Martian polar terrains are summarized. Thermal calculations and flow calculations of the basal melt are discussed. The significance of the basal melting for the origin of major polar reentrants, the storage of an ancient Martian ice sheet, the mass balance of the polar terrain, and basal melting at temperate latitudes is examined.

Clifford, Stephen M.↗

NASA NTRS1984

Coupled convective instabilities at crystal-melt interfaces

The stability of the parallel flow between a vertical crystal-melt interface and a vertical wall held at a temperature above the melting point of the crystal is analyzed for Prandtl numbers, P, ranging from 0.01 to 100. Three modes of instability occur: (1) a buoyant mode, (2) a shear mode, and (3) a coupled crystal-melt mode. The buoyant and shear modes are similar to those that occur for flow between two vertical rigid walls held at different temperatures. For Prandtl numbers greater than approximately two, the coupled crystal-melt mode occurs at a lower Grashof number than the other two modes. Specific results are given for succinonitrile (P = 22.8) and lead (P = 0.0225). These calculations and similar calculations for a cylindrical geometry were motivated by and are in general agreement with recent experiments on succinonitrile.

Coriell, S. R.↗

NASA NTRS1987

Gravity and conduction driven melting in a sphere

In the Stefan and Neumann problems fundamentally characterizing melting, unmolten portions of a solid undergoing phase changes within spherical containers are assumed to remain stationary. An approach to these issues that is related to the theories of lubrication and film condensation is presently employed in conjunction with an approximate, closed-form solution of melting within spheres. It is shown that a group of dimensionless parameters containing Prandtl, Archimides and Stefan numbers can describe the melting process. Also given are the results of fundamental heat transfer experiments performed on the melting of a phase-change medium in a spherical shell.

Bahrami, P. A.↗

NASA NTRS1989

Gravitation- And Conduction-Driven Melting In A Sphere

Simplifying assumptions lead to approximate closed-form solution. Theoretical paper discusses melting of solid sphere in spherical container. Develops mathematical model of melting process, based in part on simplifying assumptions like those used in theories of lubrication and film condensation. Resulting equation for melting speed as function of melting distance solved approximately in closed form.

Bahrami, Parviz A.↗

NASA NTRS1989

Iridium in the Vredefort Bronzite Granophyre - Impact melting and limits on a possible extraterrestrial component

The Bronzite Granophyre was analyzed for Ir and other elements to examine whether its origin was due to impact melting or conventional igneous assimilation and to search for a possible extraterrestrial component in the melt. No such component is identified. Ir values range from 50-130 pg/g, equivalent to less than 0.05 percent C1 material. Further evidence against an extraterrestrial source of siderophiles are the low Ir/Au ratios and the absence of systematic correlations between Ir and other elements. However, the Granophyre is significantly enriched in Ir over other Vredefort granitic rocks, implying a fundamental difference between them. Geochemical mixing models indicate that the Ir observed in the Granophyre can be supplied from high-Ir local shales and quartzites during an impact melting event. The results are consistent with the view that the Granophyre is an impact melt and that Vredefort is an impact structure.

French, B. M.↗