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Mars volatile evolution - Implications of the recent measurement of O-17 in water from the SNC meteorites

Escape of oxygen to space on Mars is capable of producing a fractionation of oxygen isotopes in the remaining oxygen which is off of the fractionation line produced by the usual mass-dependent exchange processes. The magnitude of fractionation which can occur can be larger than that which was measured in oxygen in water derived from the SNC meteorites (thought to have come from Mars). In conjunction with the apparent lack of fractionation of O-18 in the atmosphere, this result suggests that less than 25 percent of the oxygen in the Martian climate system has been lost over geologic time. Other mechanisms also might be able to produce such a fractionation, so that this conclusion is not unique; however, it is consistent with other lines of evidence. There is no requirement for an initial volatile inventory with an isotopic composition different from that of the bulk planet (as might be the case for a late veneer of volatile-rich material).

Jakosky, Bruce M.↗

Mars atmospheric escape and isotopic fractionation: Synthesis of data and models

The present Mars atmosphere is relatively thin and cold. It is not at all like that which is presumed to have been responsible for the formation of valley networks and the heavy erosion of craters during the earliest epochs of martian history. An important goal of Mars exploration is to try to understand the properties of the early atmosphere, the initial inventory of volatiles at the planet's surface, the processes by which the atmosphere and climate have evolved over time, and the current location of volatiles presumed to have been in the atmosphere in the earlier times. The current status of understanding of the escape of volatiles to space over geologic time and the resulting fractionation of isotopes of stable atoms remaining in the atmosphere are described, and a scenario for volatile abundance and evolution that is consistent with the available information on the escape and fractionation of each species is constructed. In particular, the evolution of hydrogen, carbon, oxygen, and nitrogen, as contained in atmospheric (and non-atmospheric) water, carbon dioxide, and molecular nitrogen, is examined.

Jakosky, Bruce M.↗

Was early Mars warmed by ammonia?

Runoff channels and valley networks present on ancient, heavily cratered Martian terrain suggests that the climate of Mars was originally warm and wet. One explanation for the formation of these channels is that the surface was warmed by the greenhouse effect of a dense, CO2 atmosphere. However, recent work shows that this theory is not consistent for the early period of the solar system. One way to increase the surface temperature predicted is to assume that other greenhouse gases were present in Mars' atmosphere in addition to CO2 and H2O. This possible gas is ammonia, NH3. If ammonia was present in sufficient quantities, it could have raised the surface temperature to 273 K. An adequate source would have been volcanic outgassing if the NH3 produced was shielded from photolysis by an ultraviolet light absorber.

Kasting, J. F.↗

Investigation of Mars Rotational Dynamics Using Earth-based Radio Tracking of Mars Landers

The development of space geodetic techniques over the past two decades has made it possible to measure the rotational dynamics of the Earth at the milliarcsecond level, improving our geophysical models of the Earth 's interior and the interactions between the solid Earth and its atmosphere. We have found that the rotational dynamics of Mars can be determined to nearly the same level of accuracy by acquiring Earth-based two-way radio tracking observations of three or more landers globally distributed on the surface of Mars. Our results indicate that the precession and long-term obliquity changes of the Mars pole direction can be determined to an angular accuracy corresponding to about 15 cm/yr at the planet's surface. In addition, periodic nutations of the pole and seasonal variations in the spin rate of the planet can be determined to 10 cm or less. Measuring the rotation of Mars at this accuracy would greatly improve the determination of the planet' s moment of inertia and would resolve the size of a planetary fluid core, providing a valuable constraint on Mars interior models. Detecting seasonal variations in the spin rate of Mars would provide global constraints on atmospheric angular momentum changes due to sublimation of the Mars CO2 polar ice caps. Finally, observation of quasisecular changes in Mars obliquity would have significant implications for understanding long-term climatic change. The key to achieving these accuracies is a globally distributed network of Mars landers with stable, phase-coherent radio transponders. By simultaneously acquiring coherent two-way carrier phase observations between a single Earth tracking station and multiple Mars landers, Earth media errors are essentially eliminated, providing an extremely sensitive measure of changes in the differential path lengths between the Earth tracking station and the Mars landers due to Mars rotation. Time variability of the instrumental phase delay through the radio transponder may represent the limiting error source for this technique. Calibration of the transponder stability to about 0.1 ns or less, over a single tracking arc of up to 12 hr, is sufficient to provide the decimeter-level determination of Mars orientation parameters quoted above. We will provide a detailed description of the multilander tracking technique and the requirements it imposes on both the lander radio system and the Earth-based ground-tracking system. This concept is currently part of the strawman science plan for the Mars Environmental Survey (MESUR) mission and complements many of the other MESUR science goals.

Edwards, C. D., Jr.↗

Oxidation of dissolved iron under warmer, wetter conditions on Mars: Transitions to present-day arid environments

The copious deposits of ferric-iron assemblages littering the surface of bright regions of Mars indicate that efficient oxidative weathering reactions have taken place during the evolution of the planet. Because the kinetics of atmosphere-surface (gas-solid) reactions are considerably slower than chemical weathering reactions involving an aqueous medium, most of the oxidation products now present in the martian regolith probably formed when groundwater flowed near the surface. This paper examines how chemical weathering reactions were effected by climatic variations when warm, wet environments became arid on Mars. Analogies are drawn with hydrogeochemical and weathering environments on the Australian continent where present-day oxidation of iron is occurring in acidic ground water under arid conditions.

Burns, R. G.↗

Exploring Mars for Evidence of Habitable Environments and Life

The climate of Mars has been more similar to that of Earth than has the climate of any other planet in our Solar System. But Mars still provides a valuable alternative example of how planetary processes and environments can affect the potential presence of life elsewhere. For example, although Mars also differentiated very early into a core, mantle and crust, it then evolved mostly if not completely without plate tectonics and has lost most of its early atmosphere. The Martian crust has been more stable than that of Earth, thus it has probably preserved a more complete record of its earliest history. Orbital observations determined that near-surface water was once pervasive. Orbiters have identified the following diverse aqueous sedimentary deposits: layered phyllosilicates, phyllosilicates in intracrater fans, plains sediments potentially harboring evaporitic minerals, deep phyllosilicates, carbonate-bearing deposits, intracrater clay-sulfate deposits, Meridiani-type layered deposits, valles-type layered deposits, hydrated silica-bearing deposits, and gypsum plains. These features, together with evidence of more vigorous past geologic activity, indicate that early climates were wetter and perhaps also somewhat warmer. The denser atmosphere that was required for liquid water to be stable on the surface also provided more substantial protection from radiation. Whereas ancient climates might have favored habitable environments at least in some localities, clearly much of the Martian surface for most of its history has been markedly less favorable for life. The combination of dry conditions, oxidizing surface environments and typically low rates of sedimentation are not conducive to the preservation of evidence of ancient environments and any biota. Thus a strategy is required whereby candidate sites are first identified and then characterized for their potential to preserve evidence of past habitable environments. Rovers are then sent to explore the most promising candidates. The Mars Exploration Rover (MER) Opportunity revealed that water once flowed to the surface across the vast Meridiani plains, creating saline lakes whose waters were roiled by ancient winds that also sculptured their salt deposits into sand dunes. Opportunity then drove more than 30 km to explore even older deposits on a crater rim. MER Spirit found evidence that thermal waters (heated by volcanism or by impacts?) altered rocks to create sulfate salts, and siliceous sinters. These discoveries indicate that an early hydrological cycle apparently sustained precipitation, streams and lakes. Liquid water participated in rock weathering reactions, such as iron and sulfur oxidation, that created distinctive weathering regimes. Volcanism, impacts, groundwater and ice interacted at least locally. Redox chemical energy from volcanism, hydrothermal activity and weathering of crustal materials would have been available for any life. Thus conditions might have supported life in the past, at least locally. The main objective of the Mars Science Laboratory (MSL) Curiosity rover is to determine the extent to which Gale crater hosted environments capable of supporting microbial life. The rover has already found stream gravels as well as sediments that might have been deposited in an ancient lake. The rover is now traversing to Mt. Sharp, a 5 km-high mound that is located on the crater floor and that exhibits layered sedimentary rocks having diverse minerals (sulfates and clays) that apparently formed in the presence of liquid water. This rock sequence was deposited over an extended time period in diverse potentially habitable watery environments. Curiosity is poised to characterize a a well-preserved rock record of hundreds of millions of years of diverse environments and profound climate change.

layered phyllosilicates↗

The role of the geothermal gradient in the emplacement and replenishment of ground ice on Mars

Knowledge of the mechanisms by which ground ice is emplaced, removed, and potentially replenished, are critical to understanding the climatic and hydrologic behavior of water on Mars, as well as the morphologic evolution of its surface. Because of the strong temperature dependence of the saturated vapor pressure of H2O, the atmospheric emplacement or replenishment of ground ice is prohibited below the depth at which crustal temperatures begin to monotonically increase due to geothermal heating. In contrast, the emplacement and replenishment of ground ice from reservoirs of H2O residing deep within the crust can occur by at least three different thermally-driven processes, involving all three phases of water. In this regard, Clifford has discussed how the presence of a geothermal gradient as small as 15 K/km can give rise to a corresponding vapor pressure gradient sufficient to drive the vertical transport of 1 km of water from a reservoir of ground water at depth to the base of the cryosphere every 10(exp 6) - 10(exp 7) years. This abstract expands on this earlier treatment by considering the influence of thermal gradients on the transport of H2O at temperatures below the freezing point.

Clifford, Stephen M.↗

Estimated Refractive Indices of Calcite, Dolomite, and Magnesite: ~0.3-500 M.

Carbonate minerals are germane to questions involving volatile and climate history on Mars [e.g., 1-2]. In particular, the abundance of carbonate-bearing minerals can provide broad useful bounds on the amount of CO2 out-gassed into the atmosphere over its history and their spatial distribution and mineralogy can yield constraints on the environments in which they were produced. Earth-based, orbital, and landed spectral observations provide evidence for the presence of carbonates in the Martian environment [3-6]. Infrared observations made from spacecraft near Mars were interpreted to indicate the presence of carbonates. [6] associated the carbonates with the surface dust and interpreted the mineralogy as being consistent with magnesite (MgCO3). Near- infrared observations from Mars orbit have been interpreted to suggest magnesite outcrops in restricted locations [7-9]. Quantitative estimates of the abundance of carbonates on Mars range from 0-3% [3], 2-5% [6], less than a few percent [10], and <10% [8]. With the growing evidence for magnesite on Mars additional quantitative estimates can be provided via theoretical modeling of the reflectance from the Martian surface. Calcite (CaCO3) and dolomite ((Ca,Mg)CO3) are identified in Asian dust [2-17%], [10] and calcite in Saharan dust [~8-10% [12-15]. The importance of op- tical constants at visible and near-infrared wavelengths as proxies for estimating the effects at infrared wave- lengths, has been investigated [15]. The growing evidence for Mg-carbonates on Mars, the presence of calcite and dolomite in terrestrial aero- sols, and general lack of optical constants for these materials in the visible- to mid-infrared (VMIR, ~0.3-6 ❍m) has motivated the current effort to estimate the optical constants of calcite, dolomite, and magnesite in the VMIR.

Roush, T. L.↗

The Meteorological Experiment on the Mars Surveyor '98 Polar Lander

When it lands on Mars on December 3, 1999, the Mars Surveyor '98 Mars Polar Lander (MPL) will provide the first opportunity to make in-situ measurements of the near-surface weather climate, and volatile inventory in the Martian south polar region. To make the most of this opportunity, the MPL's Mars Volatiles and Climate Surveyor (MVACS) payload includes the most comprehensive complement of meteorological instruments ever sent to Mars. Like the Viking and the Mars Pathfinder Lander, the MVACS Meteorological (Met) package includes sensors for measuring atmospheric pressures, temperatures, and wind velocities. This payload also includes a 2-channel tunable diode laser spectrometer for in-situ measurements of the atmospheric water vapor abundance near the ground, and improved instruments for measuring the relative abundances of oxygen isotopes (in water vapor and CO2) and a surface temperature probe for measuring the surface and sub-surface temperatures. This presentation will provide a brief overview of the environmental conditions anticipated at the surface in the Martian regions. We will then provide an over-view of the MVACS Met instrument and describe the MET sensors in detail, including their principle of operation, range, resolution, accuracy, sampling strategy, heritage, accommodation on the Lander, and their control and data handling system. Finally, we will describe the operational sequences, resource requirements, and the anticipated data volumes for each of the Met instruments.

Crisp, D.↗

History and Progress of GCM Simulations on Recent Mars Climate Change

The Mars Global Surveyor and Odyssey spacecraft reveal evidence that Mars may have experienced significant climate change in the recent past (105-106 Myr ago). Examples include gullies [1], cold-based tropical glaciers [2], paleolakes [3], and youthful near-surface ice [4]. Except for the gullies, the evidence for recent climate change requires ice and/or liquid water at low latitudes. An obvious question, therefore, is how is it possible for ice and/or liquid water to exist at low latitudes which is not possible in the present climate system? There are several mechanisms to consider. An episode of intense volcanic activity could alter the mean composition of the atmosphere and, therefore, the climate system. Impacts, depending on the size, composition, and velocity of the impactor are another way to dramatically alter the climate system. Polar wander and solar variability are also possibilities. However, the most promising way to change the climate is through changes in orbital properties. Mars, because of its proximity to Jupiter and lack of a large stabilizing moon, experiences much greater changes in its orbit properties than the Earth.

Haberle, R. M.↗

History and Progress of GCM Simulations on Recent Mars Climate Change

The Mars Global Surveyor and Odyssey spacecraft reveal evidence that Mars may have experienced significant climate change in the recent past (10(exp 5) - 10(exp 6) Myr ago). Examples include gullies, cold-based tropical glaciers, paleolakes, and youthful near-surface ice. Except for the gullies, the evidence for recent climate change requires ice and/or liquid water at low latitudes. An obvious question, therefore, is how is it possible for ice and/or liquid water to exist at low latitudes which is not possible in the present climate system? There are several mechanisms to consider. An episode of intense volcanic activity could alter the mean composition of the atmosphere and, therefore, the climate system. Impacts, depending on the size, composition, and velocity of the impactor are another way to dramatically alter the climate system. Polar wander and solar variability are also possibilities. However, the most promising way to change the climate is through changes in orbital properties. Mars, because of its proximity to Jupiter and lack of a large stabilizing moon, experiences much greater changes in its orbit properties than the Earth.

Haberle, R. M.↗

Carl Sagan and the Exploration of Mars and Venus

Inspired by childhood readings of books by Edgar Rice Burroughs, Carl Sagan's first interest in planetary science focused on Mars and Venus. Typical of much of his career he was skeptical of early views about these planets. Early in this century it was thought that the Martian wave of darkening, a seasonal albedo change on the planet, was biological in origin. He suggested instead that it was due to massive dust storms, as was later shown to be the case. He was the first to recognize that Mars has huge topography gradients across its surface. During the spacecraft era, as ancient river valleys were found on the planet, he directed studies of Mars' ancient climate. He suggested that changes in the planets orbit were involved in climate shifts on Mars, just as they are on Earth. Carl had an early interest in Venus. Contradictory observations led to a controversy about the surface temperature, and Carl was one of the first to recognize that Venus has a massive greenhouse effect at work warming its surface. His work on radiative transfer led to an algorithm that was extensively used by modelers of the Earth's climate and whose derivatives still dominate the calculation of radiative transfer in planetary atmospheres today. Carl inspired a vast number of young scientists through his enthusiasm for new ideas and discoveries, his skeptical approach, and his boundless energy. I had the privilege to work in Carl's laboratory during the peak of the era of Mars' initial exploration. It was an exciting time, and place. Carl made it a wonderful experience.

Toon, Owen B.↗

Remote sensing of aerosols in the Martian atmosphere - Implications for terrestrial studies

Data provided by recent spacecraft missions to Mars include determinations of the properties and effects of aerosols suspended in the Martian atmosphere. Comparison of alternative procedures used to remotely sense the aerosol properties as well as analyses of these methodologies may have relevance for analogous procedures being developed to study terrestrial aerosols with satellite-borne sensors. In addition, Martian aerosols appear to have played a role in climate changes that may have terrestrial counterparts. Of particular concern are observations made from the Mariner 9 orbiter spacecraft, which studied Mars during 1971 and 1972, and the Viking orbiter and lander spacecraft, which conducted measurements commencing in the middle of 1976 and continuing through the present. Two global dust storms were observed from their commencement to their demise.

Pollack, J. B.↗

Intercomparison of Atmospheric Radiation Schemes for the Lower Martian Atmosphere

Interpretation of the vast data flow from the recent and ongoing Mars missions requires extensive modeling activity to support the investigations and conclusions drawn from the observations. We have initiated a campaign to compare atmospheric radiation schemes for the lower Martian atmosphere with leastcompromise reference line-by-line calculations (Meadows and Crisp 1996, Crisp 1986). By using fixed reference conditions we are introducing an intercomparison framework to enable atmospheric modeling teams to compare their modeling results with the reference line-by-line calculations, and to improve their models. The atmosphere of Mars is thin and therefore its response to local radiative forcing is strong when compared to that of the Earth s troposphere. Airborne dust and also the water vapor give significant contributions to the radiative fluxes. Thus models of the Martian atmosphere should have fairly accurate radiative transfer (RT) algorithms. This is specifically important for the net radiative flux at the surface, which is the main driver for the surface temperature evolution, since the surface turbulent fluxes are small due to the thin atmosphere (e.g. Haberle et al. 1993, Savij arvi 1991a, Savij arvi 1991b, Savij arvi 1999). However, the accuracy of the RT schemes has not been rigorously tested in many cases as reference calculations have been rare. We introduce a set of reference cases for Martian atmospheric conditions with profiles for temperature, pressure, dust optical depth (Conrath 1975, Clancy et al. 1995, OckertBell et al. 1997, Smith et al. 2000), water, CO2,O3,CO and O2 (Table 1). The reference atmosphere uses a diurnally and globally averaged thermal structure derived from Mariner 9 IRIS observations acquired during late southern summer. Thermal structures for nighttime and daytime conditions will be included shortly. Computationally expensive reference simulations were performed by applying a spectrum resolving (line-by-line multiple scattering) model, SRM, to give the least-compromise base for comparisons. We call for other groups to join in future comparisons. This resembles the International Comparison of Radiation Codes for Climate Models (ICRCCM; e.g. Ellingson and Fouquart 1991, Ellingson et al. 1991). The ICRCCM led to many improvements in the Earth GCM radiation codes. The intercomparison framework presented in this paper is a step toward that direction for Mars. We have already five modeling teams participating in this intercomparison exercice. Additional teams investigating the Martian atmosphere are cordially invited to join this effort of comparing the radiation schemes in fixed conditions. The results achieved will be reported and some additional features to be included in the intercomparison will be discussed.

A-M Harri↗

Micro weather stations for in situ measurements in the Martian planetary boundary layer

Viking Lander meteorology measurements show that the Martian planetary boundary layer (PBL) has large diurnal and seasonal variations in pressure, wind velocity, relative humidity, and airborne dust loading. An even larger range of conditions was inferred from remote sensing observations acquired by the Mariner 9 and Viking orbiters. Numerical models indicate that these changes may be accompanied by dramatic vertical and horizontal wind shears (100 m/s/km) and rapid changes in the static stability. In-situ measurements from a relatively small number surface stations could yield global constraints on the Martian climate and atmospheric general circulation by providing ground truth for remote sensing instruments on orbiters. A more complete understanding of the meteorology of the PBL is an essential precursor to manned missions to Mars because this will be their working environment. In-situ measurements are needed for these studies because the spatial and temporal scales that characterize the important meteorological processes near the surface cannot be resolved from orbit. The Mars Environmental Survey (MESUR) Program will provide the first opportunity to deploy a network of surface weather stations for a comprehensive investigation of the Martian PBL. The feasibility and utility of a network of micro-weather stations for making in-situ meteorological measurements in the Martian PBL are assessed.

Crisp, D.↗

Vertical Profiles of Mars 1.27 Micrometer O2 Dayglow from MRO CRISM Limb Spectra: Seasonal/global Behaviors, Comparisons to LMDGCM Simulations, and a Global Definition for Mars Water Vapor Profiles

Since July of 2009, The Compact Reconnaissance Imaging Spectral Mapper (CRISM) onboard the Mars Re- connaissance Orbiter (MRO) has periodically obtained pole-to-pole observations (i.e., full MRO orbits) of limb scanned visible/near IR spectra (lambda= 0.4 - 4.0 micrometers, delta lambda approx. 10 nm- Murchie et al., 2007). These CRISM limb observations support the first seasonally and spatially extensive set of Mars 1.27 micometers O2 (1 delta(sub g)) day-glow profile retrievals (approx. 1100) over greater than or equal to 8-80 km altitudes. Their comparison to Laboratoire de Meteorologie Dynamique (LMD) global climate model (GCM) simulated O2 (1 delta(sub g)) volume emission rate (VER) profiles, as a function of altitude, latitude, and season (solar longitude, L(sub s), supports several key conclusions regarding Mars atmospheric water vapor (which is derived from O2 (1 delta(sub g)) emission rates), Mars O3, and the collisional de-excitation of O2 (1 delta(sub g)) in the Mars CO2 atmosphere. Current (Navarro et al., 2014) LMDGCM simulations of Mars atmospheric water vapor fall 2-3 times below CRISM derived water vapor abundances at 20-40 km altitudes over low-to-mid latitudes in northern spring (L(sub s) = 30-60 deg), and northern mid-to-high latitudes over northern summer (L(sub s) = 60-140 deg). In contrast, LMDGCM simulated water vapor is 2-5 times greater than CRISM derived values at all latitudes and seasons above 40 km, within the aphelion cloud belt (ACB), and over high-southern to mid-southern latitudes in southern summer (L(sub s) = 190-340 deg) at 15-35 km altitudes. Overall, the solstitial summer-to-winter hemisphere gradients in water vapor are reversed between the LMDGCM modeled versus the CRISM derived water vapor abundances above 10-30 km altitudes. LMDGCM-CRISM differences in water vapor profiles correlate with LMDGCM-CRISM differences in cloud mixing profiles; and likely reflect limitations in simulating cloud microphysics and radiative forcing, both of which restrict meridional transport of water from summer- to-winter hemispheres on Mars (Clancy et al., 1996; Montmessin et al., 2004; Steele et al., 2014; Navarro et al., 2014) and depend on uncertain cloud microphysical properties (Navarro et al., 2014). The derived low-to-mid latitude changes in Mars water vapor vertical distributions should reduce current model- data disagreements in column O3 and H2O2 abundances over low-to-mid latitudes (e.g., within the ACB; Lefevre et al., 2008; Encrenaz et al., 2015; Clancy et al., 2016). Lastly, the global/seasonal average com- parison of CRISM and LMDGCM O2 (1 delta(sub g)) VER below 20 km altitudes indicates a factor of approx. 3 times lower value (0.25 x 10(exp -20) cu cm sec(exp -1)) for the CO2 collisional de-excitation rate coefficient of O2 (1 delta(sub g)) than derived recently by Guslyakova et al. (2016).

Clancy, R. Todd↗

Episodic vs. epochal release of SO2 on Mars

Erosion of the Martian surface by the flow of liquid water has apparently taken place at different times and locations on the planet. Many attempts were made to explain the valley networks by invoking a strong atmospheric CO2/H2O greenhouse early in the history of the planet. It was assumed that the large amounts of CO2 necessary to cause the greenhouse would have disappeared due to carbonate formation. Carbonates have yet to be positively identified. Volcanism has occurred throughout much of the history of Mars. Presumably gases such as SO2 were released along with CO2 and H2O. Estimates of amounts and rates with which SO2 were released into the Martian atmosphere, and how this would effect the global climate were made. Studies are continuing on the effects of SO2 and other volcanic gases on Martian climatic history.

Postawko, S. E.↗

Electrical Breakdown in a Martian Gas Mixture

The high probability for dust interactions during Martian dust storms and dust devils combined with the cold, dry climate of Mars most likely result in airborne dust that is highly charged. On Earth, potential gradients up to 5 kV/m have been recorded and in some cases resulted in lightning. Although the Martian atmosphere is not conducive to lightning generation, it is widely believed that electrical discharge in the form of a corona occurs. In order to understand the breakdown of gases, Paschen measurements are taken which relate the minimum potential required to spark across a gap between two electrodes. The minimum potential is plotted versus the pressure-distance value for electrodes of a given geometry. For most gases, the potential decreases as the pressure decreases. For CO2, the minimum in the curve happens to be at Mars atmospheric pressures (5-7 mm Hg) for many distances and geometries. However, a very small amount (<0.1%) of mixing gases radically changes the curve, as noted by Leach. Here, we present the first experimental results of a Paschen curve for a Mars gas mixture compared with 100% pure CO2.

Buhler, C. R.↗