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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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286 records · Page 16

Early Results from the Solar-Minimum 2019 Total Solar Eclipse

We observed the 2 July 2019 total solar eclipse with a variety of imaging and spectroscopic instruments recording from three sites in mainland Chile: on the centerline at La Higuera, from the Cerro Tololo Inter-American Observatory, and from La Serena, as well as from a chartered flight at peak totality in mid-Pacific. Our spectroscopy monitored Fe X, Fe XIV, and Ar X lines, and we imaged Ar X with a Lyot filter adjusted from its original H-alpha bandpass. Our composite imaging has been compared with predictions based on modeling using magnetic-field measurements from the pre-eclipse month. Our time-differenced sites will be used to measure motions in coronal streamers.

Jay M Pasachoff↗

Moss Tolerance of Deep Space-Like Ionizing Radiation, Singular or Combined With Spaceflight Microgravity-Preparation for the BRIC-27 Experiment to the ISS

Understanding how terrestrial life perceives and tolerates deep space environments is essential to advancing human space exploration missions and searching for life beyond our solar system. Throughout evolution moss adapted to living in extreme environments from the edge of habitability. Moss inhabits areas with high UVB/UVC photon levels such as polar regions subject to ozone holes, high elevation mountain environments, and sites with elevated ionizing particle levels such as those found at nuclear plant accident sites, atomic bomb test sites or radioactive element-rich regions. We investigate if moss tolerance of ionizing radiation encounter terrestrially extends to resistance to deep space ionizing radiation. We exposed moss to high energy ion beams simulating Galactic Cosmic Ray (GCRSim) and Solar Particle Event (SPESim) (NSRL, BNL) that permeate deep space, and moss was unharmed. We also exposed moss to high doses of gamma rays as released in astrophysical events, and moss survived absorption of extremely high doses. Next, we ask if moss tolerance of deep space-like ionizing radiation observed terrestrially differs from that in other deep space environments. In the upcoming BRIC-27 spaceflight experiment we will sequentially expose Antarctic moss C.purpureus to GCRSim and SPESim followed by exposure to spaceflight microgravity and compare gene expression profiles in deep space-like ionizing radiation, singular or combined with spaceflight microgravity. Additionally, we will compare gene expression profiles in spaceflight microgravity, singular or combined with deep space-like ionizing radiation. Hence, BRIC-27 will advance our understanding of the combined effects of both deep space ionizing radiation and microgravity, which may have different and more profound effects on plant physiology and performance than each condition separately.

Agata Klaudia Zupanska↗

Recalibration of the Sunspot-Number: Status Report

We report progress on the ongoing recalibration of the Wolf sunspot number (S N ) and group-sunspot number (G N ) following the release of version 2.0 of S N in 2015. This report constitutes both an update of the efforts reported in the 2016 Topical Issue of Solar Physics and a summary of work by the International Space Science Institute (ISSI) International Team formed in 2017 to develop optimal S N and G N reconstruction methods while continuing to expand the historical sunspot-number database. Significant progress has been made on the database side while more work is needed to bring the various proposed S N and (primarily) G N reconstruction methods closer to maturity, after which the new reconstructions (or combinations thereof) can be compared with (a) “benchmark” expectations for any normalization scheme (e.g., a general increase in observer normalization factors going back in time), and (b) independent proxy data series such as F10.7 and the daily range of variations of Earth’s undisturbed magnetic field. New versions of the underlying databases for S N and G N will shortly become available for years through 2022 and we anticipate the release of the next versions of these two time series in 2024.

F. Clette↗

Slow Solar Wind Connection Science during Solar Orbiter's First Close Perihelion Passage

The Slow Solar Wind Connection Solar Orbiter Observing Plan (Slow Wind SOOP) was developed to utilize the extensive suite of remote-sensing and in situ instruments on board the ESA/NASA Solar Orbiter mission to answer significant outstanding questions regarding the origin and formation of the slow solar wind. The Slow Wind SOOP was designed to link remote-sensing and in situ measurements of slow wind originating at open–closed magnetic field boundaries. The SOOP ran just prior to Solar Orbiter's first close perihelion passage during two remote-sensing windows (RSW1 and RSW2) between 2022 March 3–6 and 2022 March 17–22, while Solar Orbiter was at respective heliocentric distances of 0.55–0.51 and 0.38–0.34 au from the Sun. Coordinated observation campaigns were also conducted by Hinode and IRIS. The magnetic connectivity tool was used, along with low-latency in situ data and full-disk remote-sensing observations, to guide the target pointing of Solar Orbiter. Solar Orbiter targeted an active region complex during RSW1, the boundary of a coronal hole, and the periphery of a decayed active region during RSW2. Postobservation analysis using the magnetic connectivity tool, along with in situ measurements from MAG and SWA/PAS, showed that slow solar wind originating from two out of three of the target regions arrived at the spacecraft with velocities between ∼210 and 600 km s −1 . The Slow Wind SOOP, despite presenting many challenges, was very successful, providing a blueprint for planning future observation campaigns that rely on the magnetic connectivity of Solar Orbiter.

Slow solar wind↗

Designing Payload and Spaceflight Operations for Plants From Extreme 1 Terrestrial Environments

Terrestrial plants from the edges of the limits of life are likely to harbor genes that confer an advantage in deep space environments. These plants are seemingly capable of performing mission critical functions under prevailing deep space conditions while informing directed gene manipulation in target plant species. However, their adaptations to physiologically extreme habitats may hinder efficacy of routine laboratory techniques established for model plants. Here we present the development of Antarctic moss Ceratodon purpureus payload and flight operations for the ARTEMOSS experiment to the ISS astute of limited physical space and crew time. We demonstrate that the hydrophobic surface of Antarctic moss impedes chemical tissue fixation and precludes usage of RNAlater coupled with payload hardware deployed in standard plant spaceflight experiments. We show that deep-freezing the moss tissue on Petri plates provides adequate tissue fixation and allows for extraction of high-quality RNA suitable for gene expression profiling. We replaced hardware with stacks of Petri plates housing Antarctic moss and chemical fixation with deep-freeze in cryogenic GLACIER freezer. Our design can be translated to other plant species, expanding current techniques of experimentation with plants from extreme terrestrial environments aimed toward advancing human space exploration.

Agata K Zupanska↗

From Atom to Engine: Understanding Fundamental Effects of Structure on Combustion Using Tandem Experiment and Computation

The ability to tie structural features to a fuel candidate’s ignition properties provides a path for rational design of advantaged fuels that facilitate higher-efficiency, lower-emitting combustion in engines. The time evolution of a fuel’s radical population directly correlates with global combustion parameters, and because the generated radicals depend on the initial structure and reaction pathways of the fuel molecule, it follows that the molecular structure of a fuel has a direct impact on this cascade, and therefore salient ignition-tied fuel properties. This work aims to understand the impact of structural features in the context of global combustion properties for direct application to emerging engine technologies. Specifically, we highlight the ability to identify potential fuel blendstocks for specific engine strategies by examining and elucidating the radical cascade tied to ignition. A representative subset of alcohols possessing a variety of structural features (e.g. branching, chain length) was selected for study using a robust combination of experimental and computational methods. The approach begins with identifying short-lived radicals and likely abstraction sites upon pyrolysis in a microreactor coupled with photoionization mass spectrometry for direct detection of product species. In tandem, electronic structure calculations were performed to calculate the relevant potential energy surfaces for fuel pyrolysis as well as the subsequent O2 addition-isomerization reactions, which govern ignition behavior. Furthermore, the theoretical energetic and ro-vibrational data are used to calculate rate constants for direct ignition modeling to explore how structural effects impact NTC behavior. The microreactor data combined with electronic structure theory calculations provide a well-informed picture of the reactions relevant to ignition for each fuel in this study, as well as the most likely radicals generated under engine conditions. This thorough fundamental picture of fuel decomposition and ignition chemistry is used to correlate the observed ignition behavior to molecular structural effects.

advanced biofuels↗

Architecture and Performance of Perlmutter’s 35 PB ClusterStor E1000 All-Flash File System

NERSC's newest system, Perlmutter, features a 35 PB all-flash Lustre file system built on HPE Cray ClusterStor E1000. We present its architecture, early performance figures, and performance considerations unique to this architecture. We demonstrate the performance of E1000 OSSes through low-level Lustre tests that achieve over 90% of the theoretical bandwidth of the SSDs at the OST and LNet levels. We also show end-to-end performance for both traditional dimensions of I/O performance (peak bulk-synchronous bandwidth) and non-optimal workloads endemic to production computing (small, incoherent I/Os at random offsets) and compare them to NERSC's previous system, Cori, to illustrate that Perlmutter achieves the performance of a burst buffer and the resilience of a scratch file system. Finally, we discuss performance considerations unique to all-flash Lustre and present ways in which users and HPC facilities can adjust their I/O patterns and operations to make optimal use of such architectures.

Lockwood, Glenn K↗

Compositions and methods of promoting organic photocatalysis

The invention provides novel compounds and methods that are useful in promoting reactions that proceed through an oxidative quenching pathway. In certain embodiments, the reactions comprise atom transfer radical polymerization.

Miyake, Garret M.↗

Compositions and methods of promoting organic photocatalysis

The invention provides novel compounds and methods that are useful in promoting reactions that proceed through an oxidative quenching pathway. In certain embodiments, the reactions comprise atom transfer radical polymerization.

Miyake, Garret↗

Silicone modified lubricant

A silicone modified lubricant includes a Group I, II, III, IV or V base oil in combination with a minor amount of a silicone oil. Further, the lubricant includes a dispersant such as a dispersant olefin copolymer which maintains the silicone oil dispersed in the base oil. The silicone oil reduces the surface tension of the lubricant thereby reducing power loss. Preferably the lubricant formation has a surface tension less than 28 mN/m, making it particularly suitable for dip lubrication systems.

Kolekar, Anant S.↗

Amphiphilic Block Copolymers for Flocculation and Hydrophobization of Legacy Waste Suspensions in Flotation Driven Dewatering Operations

There exists a degrading legacy fuel pond at the Sellafield site (UK), known as the First-Generation Magnox Storage Pond (FGMSP). After being placed into a passive care and maintenance regime resulting in a long storage period, the fuel rods, primarily their cladding, corroded in the pond forming magnesium hydroxide based sludges and suspended material. These ponds are a grave concern to the British government in terms of hazard and risk reduction. Therefore, decommissioning of these ponds is a top priority beginning with the contaminant retrievals process [1]. The pond has accumulated significant quantities of waste materials amongst the skips of fuel, including but not limited to: large inventories of corroded Magnox sludge, fuel rod fragments, metal fragments (from fuel skips), concrete degradation products (from the pond infrastructure), wind-blown sand, and other materials such as bird guano and animal remains. This challenge requires a chemically robust technology to complete sludge retrievals [2]. As nuclear is different, a more stringent process operation criteria is required. From the criteria, flotation was selected as a viable technology. Flotation involves the application of collector molecules which modify the hydrophobicity of suspended particles allowing them to adsorb to rising bubbles. As some particles lack inertia for flotation due to their size, dual flocculant/collector agents can be deployed for greater particle recovery, in this case, amphiphilic diblock copolymers. Two copolymers of Poly(acrylic acid)-b-poly(n-butyl acrylate) (or PAA-b-PnBA), of different hydrophobic chain lengths (PBA) were synthesized for flotation campaigns. Flotation has shown promise to be a valuable rapid dewatering strategy for decommissioning of legacy waste ponds whilst upholding the required operational criteria. This research has shown: PAA-b-PnBA copolymers promote flocculation of Mg(OH){sub 2} particulates. Diblock copolymers retain more fluid than traditional surfactant based collectors wrt. relative particulate recovery performance- where longer PnBA chain length polymers performed best. Performance appears to be hydrodynamically limited due to over-flocculation of Mg(OH){sub 2}. Potential to combine with sedimentation for high particle recovery with low fluid carryover.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Amphiphilic Block Copolymers for Flocculation and Hydrophobization of Legacy Waste Suspensions in Flotation Driven Dewatering Operations - 20162

Flotation has been effectively demonstrated as a low footprint, high efficiency separation process when utilising simple anionic surface modifying agents such as sodium dodecyl sulphate (SDS). These agents increase hydrophobicity to remove suspended cationic surface charged particulates such as Mg(OH){sub 2} from waste suspensions similar to those at British nuclear fuel management sites- where corrosion processes have degraded fuel cladding. The technology is advantageous as it could effectively be retrofitted into existing waste management facilities at nuclear waste management sites such Sellafield and Hanford as the simplicity (no moving parts) and size of this technology coupled with low cost of construction could be rapidly deployed to aid in risk and hazard reduction decommissioning operations with minimum impact to secondary waste generation. Previously, sodium dodecyl sulphate has been deployed as a collector agent to increase the hydrophobicity of Mg(OH){sub 2} suspended particles, achieving a maximum particulate extraction percentage of 93%. To achieve further particulate extraction, flotation performance has been determined to be a function of the hydrodynamic limitations extracting fine material (>20 μm). Fine particulates have been shown in the minerals industry to have an inability to overcome slipstreams created from rising bubbles in flotation cells, likely due to the low mass and thus momentum of the colloidal material, preventing interaction between the hydrophobized particles and air-water interfaces (bubbles). To combat this mass transfer resistance poly(acrylic acid)-block-poly(n-butyl acrylate) amphiphilic diblock copolymers were synthesised via reversible addition-fragmentation chain-transfer (RAFT) polymerisation. The anticipated mode of action of these polymers involves the hydrophilic poly(acrylic acid) block polymer acting as a flocculation agent to increase the mass of the aggregates, and the hydrophobic poly(n-butyl acrylate) modifies the hydrophobicity of the resulting flocs. The concentration of this polymer (termed a macro-collector) was varied and the change in particle size distribution of the particulate suspension was analysed using static light scattering. The flotation performance was then characterised by several methods including percentage particulate recovery, volume reduction factor and residual bulk particulate concentration. This was then benchmarked against the traditional surfactant collector agent SDS. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

TensorFlow Quantum: A Software Framework for Quantum Machine Learning

We introduce TensorFlow Quantum (TFQ), an open source library for the rapid prototyping of hybrid quantum-classical models for classical or quantum data. This framework offers high-level abstractions for the design and training of both discriminative and generative quantum models under TensorFlow and supports high-performance quantum circuit simulators. We provide an overview of the software architecture and building blocks through several examples and review the theory of hybrid quantum-classical neural networks. We illustrate TFQ functionalities via several basic applications including supervised learning for quantum classification, quantum control, simulating noisy quantum circuits, and quantum approximate optimization. Moreover, we demonstrate how one can apply TFQ to tackle advanced quantum learning tasks including meta-learning, layerwise learning, Hamiltonian learning, sampling thermal states, variational quantum eigensolvers, classification of quantum phase transitions, generative adversarial networks, and reinforcement learning. We hope this framework provides the necessary tools for the quantum computing and machine learning research communities to explore models of both natural and artificial quantum systems, and ultimately discover new quantum algorithms which could potentially yield a quantum advantage.

Broughton, Michael↗