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At least 289 records · Page 16

Laboratory comparisons of organic materials to interstellar dust and the Murchison meteorite

Spectra of objects which lie along several lines of sight through the diffuse interstellar medium (DISM) reveal an absorption feature near 3.4 micrometers, which has been attributed to saturated aliphatic hydrocarbons on interstellar grains. The similarity of the absorption bands near 3.4 micrometers (2950 cm-1) along different lines of sight indicates that the carrier of this band lies in the diffuse dust. Several materials have been proposed as "fits" to the 3.4 micrometers feature over the years. A comparison of these identifications is presented. These comparisons illustrate the need for high resolution, high signal-to-noise observational data as a means of distinguishing between laboratory organics as matches to the interstellar material. Although any material containing hydrocarbons will produce features in the 3.4 micrometers region, the proposed "matches" to the DISM do differ in detail. These differences may help in the analyses of the chemical composition and physical processes which led to the production of the DISM organics, although ISO Observations through the 5-8 micrometers spectral region are essential for a definitive identification. A remarkable similarity between the spectrum of the diffuse dust and an organic extract from the Murchison meteorite suggests that some of the interstellar organic material may be preserved in primitive solar system bodies. The 3.4 micrometers absorption feature (in the rest frame) has recently been detected in external galaxies, indicating the widespread availability of organic material for incorporation into planetary systems.

NASA Center ARC↗

Interstellar molecules - Formation in solar nebulae

Herbig's (1970) hypothesis that solar nebulae might be the principal source of interstellar grains and molecules is investigated. The investigation includes the determination of physical and chemical conditions in the early solar system. The production of organic compounds in the solar nebula is studied, and the compounds in meteorites are compared with those obtained in Miller-Urey and Fischer-Tropsch-type (FTT) reactions, taking into consideration aliphatic hydrocarbons, aromatic hydrocarbons, purines, pyrimidines, amino acids, porphyrins, and aspects of carbon-isotope fractionation. It is found that FTT reactions account reasonably well for all well-established features of organic matter in meteorites investigated. The distribution of compounds produced by FTT reactions is compared with the distribution of interstellar molecules. Biological implications of the results are considered.

Anders, E.↗

The search for extraterrestrial life: Recent developments; Proceedings of the Symposium, Boston University, MA, June 18-21, 1984

The conference presents papers on the history of the search for extraterrestrial life, the scientific rationale and methods used in the search for other planetary systems, the detection of distant planets with the Space Telescope, planetary searches using optical astrometric interferometers, and infrared spectral identification of complex organic molecules in interstellar grains. Also considered are universal protein ancestors from hydrogen cyanide and water, astronomical sources of polarized light and their role in determining molecular chirality on earth, the universal diagrams and life in the universe, the precambrian evolution of terrestrial life and a thermodynamic approach to the occurrance and appearance of galactic life forms. Papers are also presented on the Ohio Seti program, lunar reflections of terrestrial radio leakage, the multichannel spectrum analyzer, software implementation of detection algorithms for the MCSA, the Serendip II design, galactic colonization and competition in a young galactic disk, implications of ancient and future migrations, extraterrestrial intelligence, the ineviability and the possible structures of supercivilizations, planetary, interplanetary and interstellar organic matter, and universal aspects of biological evolution.

Papagiannis, M. D.↗

Formation of Planetary Systems

Stars are observed to be forming within cold regions of the galaxy called molecular clouds. A clump of gas and dust within a molecular cloud can collapse into a rotationally- supported disk orbiting the pre s sure -supported star. Such a disk has the same initial elemental composition as the growing star. At sufficient distances from the central star, it is cool enough for approx. 1 - 2% of this material to be in solid form, either remnant interstellar grains or condensates formed within the disk. During the infall stage, the disk is very active and probably highly turbulent. When the infall slows substantially or stops, the disk becomes more quiescent. The dust grows from micron-sized dust to kilometer-sized planetesimals by physical collisions, possibly aided by collective gravity. The dynamics of larger solid bodies within protoplanetary disks are better characterized. The primary perturbations on the orbits of kilometer-sized and larger planetesimals in protoplanetary disks are mutual gravitational interactions and physical collisions. These interactions lead to accretion (and in some cases erosion and fragmentation) of planetesimals. The most massive planets have the largest gravitationally-enhanced collision cross-sections, and accrete almost everything with which they collide. The size distribution of solid bodies becomes quite skewed, with a few large bodies growing much faster than the rest of the swarm, until they have accumulated most of the small bodies within their gravitational reach. Slower growth continues (at least for solid, earth-like planets) as the eccentricities of planetary embryos are pumped up by long-range mutual gravitational perturbations. As planetary masses increase, they become more efficient at stirring random velocities of neighboring bodies. If sufficiently massive and dense planets exist far enough from the star, they can eject material into interstellar space. In most models, giant planets begin their growth like terrestrial planets, but if they become massive enough before the protoplanetary disk dissipates, then they are able to accumulate substantial amounts of gas. Giant planet growth times predicted by current models are similar to estimates of the lifetime of the gaseous protoplanetary disk, so we don't know whether or not giant planets form in most protoplanetary disks. However, planets that become massive while a substantial amount of gas remains in the disk may migrate into the star as a consequence of their gravitational interactions with the disk.

Lissauer, Jack J.↗

Gas–Phase Preparation of the 14π Hückel Polycyclic Aromatic Anthracene and Phenanthrene Isomers (C 14 H 10 ) via the Propargyl Addition–BenzAnnulation (PABA) Mechanism

Polycyclic aromatic hydrocarbons (PAHs) imply the missing link between resonantly stabilized free radicals and carbonaceous nanoparticles, commonly referred to as soot particles in combustion systems and interstellar grains in deep space. Whereas gas phase formation pathways to the simplest PAH – naphthalene (C 10 H 8 ) – are beginning to emerge, reaction pathways leading to the synthesis of the 14π Hückel aromatic PAHs anthracene and phenanthrene (C 14 H 10 ) are still incomplete. Here, by utilizing a chemical microreactor in conjunction with vacuum ultraviolet (VUV) photoionization (PI) of the products followed by detection of the ions in a reflectron time-of-flight mass spectrometer (ReTOF-MS), the reaction between the 1'- and 2'-methylnaphthyl radicals (C 11 H 9 •) with the propargyl radical (C 3 H 3 •) accesses anthracene (C 14 H 10 ) and phenanthrene (C 14 H 10 ) via the Propargyl Addition–BenzAnnulation (PABA) mechanism in conjunction with a hydrogen assisted isomerization. Furthermore, the preferential formation of the thermodynamically less stable anthracene isomer compared to phenanthrene suggests a kinetic, rather than a thermodynamics control of the reaction.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

3D distribution of interstellar medium in the Galaxy: Preparation for analysis of Gaia observations

Accurate and detailed three-dimensional (3D) maps of Galactic interstellar medium (ISM) are still lacking. One way to obtain such 3D descriptions is to record a large set of individual absorption or reddening measurements toward target stars located at various known distances and directions. The inversion of these measurements using a tomographic method can produce spatial distribution of the ISM. Until recently absorption data were very limited and distances to the target stars are still uncertain, but the situation will greatly improve thanks to current and future massive stellar surveys from ground, and to Gaia mission. To prepare absorption data for inversion from a huge number of stellar spectra, automated tools are needed. We have developed various spectral analysis tools adapted to different type of spectra, early- or late- type star. We also have used diffuse interstellar bands (DIBs) to trace IS structures and kinematics. Although we do not know yet their carriers, they can be a promising tool to trace distant interstellar clouds or Galactic arms. We present some examples of the interstellar fitting and show the potentiality of DIBs in tracing the ISM. We will also briefly show and comment the latest 3D map of the local ISM which reveal nearby cloud complexes and cavities.

79 ASTRONOMY AND ASTROPHYSICS↗

THE TRANSIT LIGHT CURVE OF AN EXOZODIACAL DUST CLOUD

Planets embedded within debris disks gravitationally perturb nearby dust and can create clumpy, azimuthally asymmetric circumstellar ring structures that rotate in lock with the planet. The Earth creates one such structure in the solar zodiacal dust cloud. In an edge-on system, the dust 'clumps' periodically pass in front of the star as the planet orbits, occulting and forward-scattering starlight. In this paper, we predict the shape and magnitude of the corresponding transit signal. To do so, we model the dust distributions of collisional, steady-state exozodiacal clouds perturbed by planetary companions. We examine disks with dusty ring structures formed by the planet's resonant trapping of in-spiraling dust for a range of planet masses and semi-major axes, dust properties, and disk masses. We synthesize edge-on images of these models and calculate the transit signatures of the resonant ring structures. The transit light curves created by dusty resonant ring structures typically exhibit two broad transit minima that lead and trail the planetary transit. We find that Jupiter-mass planets embedded within disks hundreds of times denser than our zodiacal cloud can create resonant ring structures with transit depths up to {approx}10{sup -4}, possibly detectable with Kepler. Resonant rings produced by planets more or less massive than Jupiter produce smaller transit depths. Observations of these transit signals may provide upper limits on the degree of asymmetry in exozodiacal clouds.

79 ASTRONOMY AND ASTROPHYSICS↗

METALLICITIES, DUST, AND MOLECULAR CONTENT OF A QSO-DAMPED Ly{alpha} SYSTEM REACHING log N(H I) = 22: AN ANALOG TO GRB-DLAs

We present the elemental abundance and H{sub 2} content measurements of a damped Ly{alpha} (DLA) system with an extremely large H I column density, log N(H I) (cm{sup -2}) = 22.0 {+-} 0.10, at z{sub abs} = 3.287 toward the QSO SDSS J081634+144612. We measure column densities of H{sub 2}, C I, C I*, Zn II, Fe II, Cr II, Ni II, and Si II from a high signal-to-noise and high spectral resolution VLT-UVES spectrum. The overall metallicity of the system is [Zn/H] = -1.10 {+-} 0.10 relative to solar. Two molecular hydrogen absorption components are seen at z = 3.28667 and 3.28742 (a velocity separation of Almost-Equal-To 52 km s{sup -1}) in rotational levels up to J = 3. We derive a total H{sub 2} column density of log N(H{sub 2}) (cm{sup -2}) = 18.66 and a mean molecular fraction of f = 2N(H{sub 2})/[2N(H{sub 2}) + N(H I)] = 10{sup -3.04{+-}0.37}, typical of known H{sub 2}-bearing DLA systems. From the observed abundance ratios we conclude that dust is present in the interstellar medium of this galaxy, with an enhanced abundance in the H{sub 2}-bearing clouds. However, the total amount of dust along the line of sight is not large and does not produce any significant reddening of the background QSO. The physical conditions in the H{sub 2}-bearing clouds are constrained directly from the column densities of H{sub 2} in different rotational levels, C I and C I*. The kinetic temperature is found to be T Almost-Equal-To 75 K and the particle density lies in the range n{sub H} = 50-80 cm{sup -3}. The neutral hydrogen column density of this DLA is similar to the mean H I column density of DLAs observed at the redshift of {gamma}-ray bursts (GRBs). We explore the relationship between GRB-DLAs and the high column density end of QSO-DLAs finding that the properties (metallicity and depletion) of DLAs with log N(H I) > 21.5 in the two populations do not appear to be significantly different.

79 ASTRONOMY AND ASTROPHYSICS↗

THERMAL REACTIONS OF OXYGEN ATOMS WITH ALKENES AT LOW TEMPERATURES ON INTERSTELLAR DUST

Laboratory experiments show that the thermal heterogeneous reactions of oxygen atoms may contribute to the synthesis of epoxides in interstellar clouds. The data set also indicates that the contribution of these pathways to epoxide formation, in comparison to non-thermal routes, is likely to be strongly temperature dependent. Our results indicate that an increased abundance of epoxides, relative to the corresponding aldehydes, could be an observational signature of a significant contribution to molecular oxidation via thermal O atom reactions with alkenes. Specifically surface science experiments show that both C{sub 2}H{sub 4}O and C{sub 3}H{sub 6}O are readily formed from reactions of ethene and propene molecules with thermalized oxygen atoms at temperatures in the range of 12-90 K. It is clear from our experiments that these reactions, on a graphite surface, proceed with significantly reduced reaction barriers compared with those operating in the gas phase. For both the C{sub 2}H{sub 4} + O and the C{sub 3}H{sub 6} + O reactions, the surface reaction barriers we determine are reduced by approximately an order of magnitude compared with the barriers in the gas phase. The modeling of our experimental results, which determines these reaction barriers, also extracts desorption energies and rate coefficients for the title reactions. Our results clearly show that the major product from the O + C{sub 2}H{sub 4} reaction is ethylene oxide, an epoxide.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DYNAMO ACTION IN THERMALLY UNSTABLE INTERSTELLAR FLOWS

Numerous studies have investigated the role of thermal instability in regulating the phase transition between the cold cloudy and warm diffuse medium of the interstellar medium. Considerable interest has also been devoted to investigating the properties of turbulence in thermally unstable flows, with a special emphasis on molecular clouds and the possibility of star formation. In this study, we investigate another setting in which this instability may be important, namely its effect on dynamo action in interstellar flows. The setup we consider is a three-dimensional periodic cube of gas with an initially weak magnetic field, subject to heating and cooling, the properties of which are such that thermal instability is provoked in a certain temperature regime. Dynamo action is established through external forcing on the flow field. By comparing the results with a cooling function with exactly the same net effect but no thermally unstable regime, we find the following. Reference runs with non-helical forcing were observed to produce no small-scale dynamo action below the Reynolds number 97. Therefore, we expect the magnetic fields generated in the helical runs to be purely due to the action of a large-scale dynamo mechanism. The critical Reynolds number for the onset of the large-scale dynamo was observed to roughly double between the thermally stable versus unstable runs, the conclusion being that the thermal instability makes large-scale dynamo action more difficult. Whereas density and magnetic fields were observed to be almost completely uncorrelated in the thermally stable cases investigated, the action of thermal instability was observed to produce a positive correlation of the form B{proportional_to}{rho}{sup 0.2}. This correlation is rather weak, and in addition it was observed to break down at the limit of highest densities.

79 ASTRONOMY AND ASTROPHYSICS↗

THE LOW-TEMPERATURE NUCLEAR SPIN EQUILIBRIUM OF H{sup +} {sub 3} IN COLLISIONS WITH H{sub 2}

Recent observations of H{sub 2} and H{sup +} {sub 3} in diffuse interstellar sightlines revealed a difference in the nuclear spin excitation temperatures of the two species. This discrepancy comes as a surprise, as H{sup +} {sub 3} and H{sub 2} should undergo frequent thermalizing collisions in molecular clouds. Non-thermal behavior of the fundamental H{sup +} {sub 3}/H{sub 2} collision system at low temperatures was considered as a possible cause for the observed irregular populations. Here, we present measurements of the steady-state ortho/para ratio of H{sup +} {sub 3} in collisions with H{sub 2} molecules in a temperature-variable radiofrequency ion trap between 45 and 100 K. The experimental results are close to the expected thermal outcome and they agree very well with a previous micro-canonical model. We briefly discuss the implications of the experimental results for the chemistry of the diffuse interstellar medium.

74 ATOMIC AND MOLECULAR PHYSICS↗

THE INTERSTELLAR MEDIUM IN THE KEPLER SEARCH VOLUME

The properties of the interstellar medium (ISM) surrounding a planetary system can impact planetary climate through a number of mechanisms, including changing the size of the astrosphere (one of the major shields for cosmic rays) as well as direct deposition of material into planetary atmospheres. In order to constrain the ambient ISM conditions for exoplanetary systems, we present observations of interstellar Na i and K i absorption toward seventeen early type stars in the Kepler prime mission field of view (FOV). We identify 39 Na i and 8 K i velocity components, and attribute these to 11 ISM clouds. Six of these are detected toward more than one star, and for these clouds we put limits on the cloud properties, including distance and hydrogen number density. We identify one cloud with significant (≳1.5 cm{sup −3}) hydrogen number density located within the nominal ∼100 pc boundary of the Local Bubble. We identify systems with confirmed planets within the Kepler FOV that could lie within these ISM clouds, and estimate upper limits on the astrosphere sizes of these systems under the assumption that they do lie within these clouds. Under this condition, the Kepler-20, 42, and 445 multiplanet systems could have compressed astrospheres much smaller than the present-day heliosphere. Among the known habitable zone planet hosts, Kepler-186 could have an astrosphere somewhat smaller than the heliosphere, while Kepler-437 and KOI-4427 could have astrospheres much larger than the heliosphere. The thick disk star Kepler-444 may have an astrosphere just a few AU in radius.

79 ASTRONOMY AND ASTROPHYSICS↗

CORRECTING FOR INTERSTELLAR SCATTERING DELAY IN HIGH-PRECISION PULSAR TIMING: SIMULATION RESULTS

Light travel time changes due to gravitational waves (GWs) may be detected within the next decade through precision timing of millisecond pulsars. Removal of frequency-dependent interstellar medium (ISM) delays due to dispersion and scattering is a key issue in the detection process. Current timing algorithms routinely correct pulse times of arrival (TOAs) for time-variable delays due to cold plasma dispersion. However, none of the major pulsar timing groups correct for delays due to scattering from multi-path propagation in the ISM. Scattering introduces a frequency-dependent phase change in the signal that results in pulse broadening and arrival time delays. Any method to correct the TOA for interstellar propagation effects must be based on multi-frequency measurements that can effectively separate dispersion and scattering delay terms from frequency-independent perturbations such as those due to a GW. Cyclic spectroscopy, first described in an astronomical context by Demorest (2011), is a potentially powerful tool to assist in this multi-frequency decomposition. As a step toward a more comprehensive ISM propagation delay correction, we demonstrate through a simulation that we can accurately recover impulse response functions (IRFs), such as those that would be introduced by multi-path scattering, with a realistic signal-to-noise ratio (S/N). We demonstrate that timing precision is improved when scatter-corrected TOAs are used, under the assumptions of a high S/N and highly scattered signal. We also show that the effect of pulse-to-pulse “jitter” is not a serious problem for IRF reconstruction, at least for jitter levels comparable to those observed in several bright pulsars.

79 ASTRONOMY AND ASTROPHYSICS↗

ABSORPTIONS IN THE VISIBLE OF PROTONATED PYRENE COLLISIONALLY COOLED TO 15 K

Protonated polycyclic hydrocarbons have been added to the list of suggested carriers of diffuse interstellar absorptions. To test this proposition requires laboratory spectra measured under interstellar conditions, in particular with the rotational and vibrational degrees of freedom equilibrated to low temperatures. This has been achieved for protonated pyrene with absorption bands in the visible, using an ion trap and collisional cooling to ≈15 K. A two-photon excitation-dissociation scheme was employed to record the (1) {sup 1} A' ← X {sup 1} A' electronic spectrum on around 10{sup 5} ions per duty cycle. The origin band of the absorption spectrum of this relatively large polycyclic aromatic species with 27 atoms is located at 4858.86 Å. Two further comparably intense spectral features are present at 4834.48 and 4809.32 Å. This is one of the largest protonated aromatics studied in the gas phase and compared to astronomical observations; however, it is not a carrier of known diffuse interstellar bands.

74 ATOMIC AND MOLECULAR PHYSICS↗

CARBON DIOXIDE INFLUENCE ON THE THERMAL FORMATION OF COMPLEX ORGANIC MOLECULES IN INTERSTELLAR ICE ANALOGS

Interstellar ices are submitted to energetic processes (thermal, UV, and cosmic-ray radiations) producing complex organic molecules. Laboratory experiments aim to reproduce the evolution of interstellar ices to better understand the chemical changes leading to the reaction, formation, and desorption of molecules. In this context, the thermal evolution of an interstellar ice analogue composed of water, carbon dioxide, ammonia, and formaldehyde is investigated. The ice evolution during the warming has been monitored by IR spectroscopy. The formation of hexamethylenetetramine (HMT) and polymethylenimine (PMI) are observed in the organic refractory residue left after ice sublimation. A better understanding of this result is realized with the study of another ice mixture containing methylenimine (a precursor of HMT) with carbon dioxide and ammonia. It appears that carbamic acid, a reaction product of carbon dioxide and ammonia, plays the role of catalyst, allowing the reactions toward HMT and PMI formation. This is the first time that such complex organic molecules (HMT, PMI) are produced from the warming (without VUV photolysis or irradiation with energetic particles) of abundant molecules observed in interstellar ices (H{sub 2}O, NH{sub 3}, CO{sub 2}, H{sub 2}CO). This result strengthens the importance of thermal reactions in the ices’ evolution. HMT and PMI, likely components of interstellar ices, should be searched for in the pristine objects of our solar system, such as comets and carbonaceous chondrites.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

FLASH SPECTROSCOPY: EMISSION LINES FROM THE IONIZED CIRCUMSTELLAR MATERIAL AROUND <10-DAY-OLD TYPE II SUPERNOVAE

Supernovae (SNe) embedded in dense circumstellar material (CSM) may show prominent emission lines in their early-time spectra (≤10 days after the explosion), owing to recombination of the CSM ionized by the shock-breakout flash. From such spectra (“flash spectroscopy”), we can measure various physical properties of the CSM, as well as the mass-loss rate of the progenitor during the year prior to its explosion. Searching through the Palomar Transient Factory (PTF and iPTF) SN spectroscopy databases from 2009 through 2014, we found 12 SNe II showing flash-ionized (FI) signatures in their first spectra. All are younger than 10 days. These events constitute 14% of all 84 SNe in our sample having a spectrum within 10 days from explosion, and 18% of SNe II observed at ages <5 days, thereby setting lower limits on the fraction of FI events. We classified as “blue/featureless” (BF) those events having a first spectrum that is similar to that of a blackbody, without any emission or absorption signatures. It is possible that some BF events had FI signatures at an earlier phase than observed, or that they lack dense CSM around the progenitor. Within 2 days after explosion, 8 out of 11 SNe in our sample are either BF events or show FI signatures. Interestingly, we found that 19 out of 21 SNe brighter than an absolute magnitude M{sub R} = −18.2 belong to the FI or BF groups, and that all FI events peaked above M{sub R} = −17.6 mag, significantly brighter than average SNe II.

74 ATOMIC AND MOLECULAR PHYSICS↗

AN APPARENT PRECESSING HELICAL OUTFLOW FROM A MASSIVE EVOLVED STAR: EVIDENCE FOR BINARY INTERACTION

Massive, evolved stars play a crucial role in the metal enrichment, dust budget, and energetics of the interstellar medium; however, the details of their evolution are uncertain because of their rarity and short lifetimes before exploding as supernovae. Discrepancies between theoretical predictions from single-star evolutionary models and observations of massive stars have evoked a shifting paradigm that implicates the importance of binary interaction. We present mid- to far-infrared observations from the Stratospheric Observatory for Infrared Astronomy of a conical “helix” of warm dust (∼180 K) that appears to extend from the Wolf–Rayet star WR102c. Our interpretation of the helix is a precessing, collimated outflow that emerged from WR102c during a previous evolutionary phase as a rapidly rotating luminous blue variable. We attribute the precession of WR102c to gravitational interactions with an unseen compact binary companion whose orbital period can be constrained to 800 days < P < 1400 days from the inferred precession period, τ{sub p} ∼ 1.4 × 10{sup 4} yr, and limits imposed on the stellar and orbital parameters of the system. Our results concur with the range of orbital periods (P ≲ 1500 days) where spin-up via mass exchange is expected to occur for massive binary systems.

79 ASTRONOMY AND ASTROPHYSICS↗

TEMPORAL VARIABILITY OF INTERSTELLAR Na I ABSORPTION TOWARD THE MONOCEROS LOOP

We report the first evidence of temporal variability in the interstellar Na i absorption toward HD 47240, which lies behind the Monoceros Loop supernova remnant (SNR). Analysis of multi-epoch Kitt Peak coudé feed spectra from this sight line taken over an eight-year period reveals significant variation in both the observed column density and the central velocities of the high-velocity gas components in these spectra. Given the ∼1.3 mas yr{sup −1} proper motion of HD 47240 and an SNR distance of 1.6 kpc, this variation would imply ∼10 au fluctuations within the SNR shell. Similar variations have been previously reported in the Vela SNR, suggesting a connection between the expanding SNR gas and the observed variations. We speculate on the potential nature of the observed variations toward HD 47240 in the context of the expanding remnant gas interacting with the ambient interstellar medium.

79 ASTRONOMY AND ASTROPHYSICS↗