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At least 289 records · Page 16
All sourcesNASA NTRSDOE OSTI
NASA NTRS1990

Simultaneous HF-radar and DMSP observations of the cusp

The Geospace Environment Modeling (GEM) Program is directed toward modeling the coupled solar wind/magnetosphere/ionosphere system. The inter-calibration of ground-based observations of the ionosphere and satellite observations has been identified as an essential step in tying together the data to produce a global picture of geospace. On October 10, 1988 the DMSP-F9 satellite passed through the Southern Hemisphere cusp while a coheret scatter HF-radar was observing 10-m scale irregularities present in the ionosphere. The combined data indicate that these irregularities were being generated in the cusp, and that the cusp was a region of greater than normal electric field turbulence. The radar data indicate that the cusp was colocated with the region where the ionospheric convection rotated from sunward to anti-sunward with increasing latitude. These observations provide an unambiguous case where simultaneous satellite and ground-based observations of the cusp can be compared.

Baker, K. B.↗
NASA NTRS1991

HF radar observations of Pc 5 field line resonances in the midnight/early morning MLT sector

The technique of F region sounding by HF coherent radar is applied to the study of field line resonances equatorward of a region of shear flow in the early morning sector. The motions were predominantly in the geomagnetic east-west direction, indicating north-south electric fields. These oscillations had pronounced peaks in their latitudinal power distribution. For the pulsation at 1.95 mHz, a latitudinal phase shift of 180 deg was observed across the peaks in all the look directions of the radar, and a longitudinal wavelength corresponding to an m value of 3 was obtained. For the 2.6-mHz pulsation, the phase shifts across the peaks had a variation with a look direction that indicated a significant longitudinal as well as latitudinal variation; for this activity, an m value of about 16 is estimated. These features are interpreted in terms of the field line resonance theory, and the possible sources of the pulsation energy are discussed.

Ruohoniemi, J. M.↗
NASA NTRS1991

Total integral reactive cross sections for F + H2 yielding HF + H - Comparison of converged quantum, quasiclassical trajectory and experimental results

The paper reports converged quantum total integral reactive cross sections for the reaction F + H2 yielding HF + H, for initial rotational states j sub i = 0 and 1, using a time-dependent method. The results are compared to classical results and to the experimental results of Neumark et al. (1985). Strong quantum effects are found in the threshold region for both initial states (i.e., in the dependence of the reaction on initial state for low energies). The classical results agree better with experiment than do the quantum results; this appears to be due to errors in the potential used.

Neuhauser, Daniel↗
NASA NTRS1991

Microstructure and mechanical properties of a single crystal NiAl alloy with Zr or Hf rich G-phase precipitates

The possibility of producing NiAl reinforced with the G-phase (Ni16X6Si7), where X is Zr or Hf, has been investigated. The microstructure of these NiAl alloys have been characterized in the as-cast and annealed conditions. The G-phases are present as fine cuboidal precipitates (10 to 40 nm) and have lattice parameters almost four times that of NiAl. They are coherent with the matrix and fairly resistant to coarsening during annealing heat treatments. Segregation and nonuniform precipitate distribution observed in as-cast materials were eliminated by homogenization at temperatures near 1600 K. Slow cooling from these temperatures resulted in large plate shaped precipitates, denuded zones, and a loss of coherency in some of the large particles. Faster cooling produced a homogeneous fine distribution of cuboidal G-phase particles in the matrix. Preliminary mechanical properties for the Zr-doped alloy are presented and compared to binary single crystal NiAl. The presence of these precipitates appears to have an important strengthening effect at temperatures not less than 1000 K compared to binary NiAl single crystals.

Locci, I. E.↗
NASA NTRS1992

Spatial and temporal behavior of ULF pulsations observed by the Goose Bay HF radar

Techniques which allow the instantaneous amplitude and phase to be determined as functions of geomagnetic lattitude, longitude, and time are employed to carry out a detailed analysis of HF radar data of a ULF pulsation event in the postmidnight sector on January 11, 1989. Field line resonances with several different frequencies occur simultaneously at different latitudes. These can be associated with cavity mode frequencies of 1.3 mHz, 1.9 mHz, 2.7 mGz, and 3.3 mHz. These frequencies are constant to better than 10 percent over a local time period of nearly 4 hr. The field-aligned currents driven by the resonances can be as large as 5 micro-A/sq m at ionospheric heights. The data support a picture of modes driven by solar wind impulses.

Walker, A. D. M.↗
NASA NTRS1993

Direct observation of porous SiC formed by anodization in HF

A process for forming porous SiC from single-crystal SiC wafers has been demonstrated. Porous SiC can be fabricated by anodizing n-type 6H-SiC in HF under UV illumination. TEM reveals pores of sizes 10-30 nm with interpore spacings ranging from roughly 5 to 150 nm. This is the first reported direct observation of porous SiC formation.

Shor, Joseph S.↗
NASA NTRS1993

An analysis of isothermal, bithermal, and thermomechanical fatigue data of Haynes 188 and B1900+Hf by energy considerations

The low-cycle fatigue behavior of Haynes 188 and B1900+Hf under isothermal, bithermal, and thermomechanical loading conditions has been analyzed on the basis of the total hysteresis energy expended per cycle. It has been observed that in the case of isothermal fatigue the total hysteresis energy correlates well with the fatigue life. In the case of bithermal 'high rate' fatigue, for a given total hysteresis energy per cycle, the fatigue life is equal to or greater than the isothermal fatigue life at the maximum bithermal temperature. This observation could be used to establish a lower bound on life for design purposes. In one case of bithermal creep-fatigue and in thermomechanical fatigue, the life is shorter than that corresponding to the isothermal life at the maximum temperature. The energy supplied, per se, may not always give a systematic correlation with the fatigue life in the cases where time-dependent creep and environmental effects are encountered. Thus, in bithermal creep-fatigue and thermomechanical fatigue, the role of creep and environment and their dependence on the energy supplied have to be properly accounted for before the energy term can be used for life prediction.

Radhakrishnan, V. M.↗
NASA NTRS1995

HF radar signatures of the cusp and low-latitude boundary layer

Continuous ground-based observations of ionospheric and magnetospheric regions are critical to the Geospace Environmental Modeling (GEM) program. It is therefore important to establish clear intercalibrations between different ground-based instruments and satellites in order to clearly place the ground-based observations in context with the corresponding in situ satellite measurements. HF-radars operating at high latitudes are capable of observing very large spatial regions of the ionosphere on a nearly continuous basis. In this paper we report on an intercalibration study made using the Polar Anglo-American Conjugate Radar Experiment radars located at Goose Bay, Labrador, and Halley Station, Antarctica, and the Defense Meteorological Satellite Program (DMSP) satellites. The DMSP satellite data are used to provide clear identifications of the ionospheric cusp and the low-latitude boundary layer (LLBL). The radar data for eight cusp events and eight LLBL events have been examined in order to determine a radar signature of these ionospheric regions. This intercalibraion indicates that the cusp is always characterized by wide, complex Doppler power spectra, whereas the LLBL is usually found to have spectra dominated by a single component. The distribution of spectral widths in the cusp is of a generally Gaussian form with a peak at about 220 m/s. The distribution of spectral widths in the LLBL is more like an exponential distribution, with the peak of the distribution occurring at about 50 m/s. There are a few cases in the LLBL where the Doppler power spectra are strikingly similar to those observed in the cusp.

Baker, K. B.↗
NASA NTRS1998

Burner Rig Hot Corrosion of a Single Crystal Ni-48Al-Ti-Hf-Ga Alloy

The hot corrosion resistance of a single crystal Ni-48Al-1Ti-0.5Hf-0.2Ga alloy was examined in a Mach 0.3 burner rig at 900 C for 300 hours. The combustion chamber was doped with 2 ppmw synthetic sea salt. The hot corrosion attack produced a random mound morphology on the surface. Microstructurally, the hot corrosion attack appeared to initiate with oxide-filled pits which were often broad and shallow. At an intermediate stage, the pits increased in size to incorporate unoxidized Ni islands in the corrosion product. The rampant attack stage, which was observed only at sharp sample corners, was characterized by rapid inward growth of alumina in finger-like protrusions incorporating significant amounts of Al-depleted Ni islands. Aluminum consumption in the oxide fingers resulted in the growth of a gamma' layer ahead of the advancing oxide fingers.

Nesbitt, James A.↗
NASA NTRS1993

Near-Threshold Rovibrational Excitation of HF by Electron Impact

The pronounced threshold peaks found in cross sections for electron-impact excitation of the vibrational levels of HF have been studied using an R-matrix method, in which electron exchange, correlation effects and polarization are included. Vibration is modelled inside the R-matrix sphere using the energy-modified adiabatic phase matrix method (EMAP). Rotation of the target molecule is treated outside the R-matrix sphere, using the frame transformation method. The external rovibronic close-coupling equations are solved by analytic methods. Analysis of the multichannel threshold structures indicates that the peaks found for rovibrational excitation of nu = 1 can be interpreted as virtual states while those for nu = 2 correspond to nuclear-excited Feshbach resonances. These two different results correspond simply to a change of sign of a small parameter that is determined by the threshold analysis. Whereas the overall shapes of the excitation peaks agree with earlier theoretical results, we have found detailed rotational fine structures for scattering energies on the order of the rotational constant above and below the opening of the vibrational channels. The partial and total cross sections for rovibrational state-to-state transitions in the energy region of the peaks are analysed. Characteristic cusp structures and excitation peaks are found at the rovibrational thresholds for transitions with small angular momentum transfer (Delta)j =0, 1 and 2. Differential cross sections are similar to recent measurements. These experimental data do not show the relatively sharp rise at the vibrational thresholds indicated by theory. Theory and experiment are in good agreement for the shape and magnitude of the angular dependence of cross sections for rovibrational state-to-state transitions, especially at larger energies.

Thummel, Helmar T.↗
NASA NTRS2003

Pt and Hf Additions to NiAl Bond Coats and Their Effect on the Lifetime of Thermal Barrier Coatings

The lifetimes of thermal barrier coatings (TBC's) with various NiAlPt(HfZr) bond coats were determined by cyclic oxidation testing at 1163 C (2125 F). The bond coats were sprayed from powders by low pressure plasma spraying onto Rene N5 superalloy substrates. Yttria stabilized zirconia (8YSZ) top coats were applied by air plasma spraying. Surprisingly, there was not a strong correlation between TBC lifetime and Pt or Hf content although Zr additions decreased lifetimes. TBC failure morphologies and bond coat microstructures were examined and are discussed with respect to the bond coat compositions.

Nesbitt, J. A.↗
NASA NTRS2004

Site preference of ternary alloying additions to NiTi: Fe, Pt, Pd, Au, Al, Cu, Zr and Hf

Atomistic modeling of the site substitution behavior of Pd in NiTi (J. Alloys and Comp. (2004), in press) has been extended to examine the behavior of several other alloying additions, namely, Fe, Pt, Au, Al, Cu, Zr and Hf in this important shape memory alloy. It was found that all elements, to a varying degree, displayed absolute preference for available sites in the deficient sublattice. How- ever, the energetics of the different substitutional schemes, coupled with large scale simulations indicate that the general trend in all cases is for the ternary addition to want to form stronger ordered structures with Ti.

Bozzolo, Guillermo↗
NASA NTRS2007

Coupled Nd-142, Nd-143 and Hf-176 Isotopic Data from 3.6-3.9 Ga Rocks: New Constraints on the Timing of Early Terrestrial Chemical Reservoirs

Increasingly precise data from a range of isotopic decay schemes, including now extinct parent isotopes, from samples of the Earth, Mars, Moon and meteorites are rapidly revising our views of early planetary differentiation. Recognising Nd-142 isotopic variations in terrestrial rocks (which can only arise from events occurring during the lifetime of now extinct Sm-146 [t(sub 1/2)=103 myr]) has been an on-going quest starting with Harper and Jacobsen. The significance of Nd-142 variations is that they unequivocally reflect early silicate differentiation processes operating in the first 500 myr of Earth history, the key time period between accretion and the beginning of the rock record. The recent establishment of the existence of Nd-142 variations in ancient Earth materials has opened a new range of questions including, how widespread is the evidence of early differentiation, how do Nd-142 compositions vary with time, rock type and geographic setting, and, combined with other types of isotopic and geochemical data, what can Nd-142 isotopic variations reveal about the timing and mechanisms of early terrestrial differentiation? To explore these questions we are determining high precision Nd-142, Nd-143 and Hf-176 isotopic compositions from the oldest well preserved (3.63- 3.87 Ga), rock suites from the extensive early Archean terranes of southwest Greenland and western Australia.

Bennett, Vickie C.↗
NASA NTRS2009

LU-HF Age of Martian Meteorite Larkman Nunatek 06319

Lu-Hf isotopic data were collected on mineral separates and bulk rock powders of LAR 06319, yielding an age of 197+/- 29 Ma. Sm-Nd isotopic data and in-situ LA-ICP-MS data from a thin section of LAR 06319 are currently being collected and will be presented at the 2009 LPSC. These new data for LAR 06319 extend the existing data set for the enriched shergottite group. Martian meteorites represent the only opportunity for ground truth investigation of the geochemistry of Mars [1]. At present, approximately 80 meteorites have been classified as Martian based on young ages and distinctive isotopic signatures [2]. LAR 06319 is a newly discovered (as part of the 2006 ANSMET field season) martian meteorite that represents an important opportunity to further our understanding of the geochemical and petrological constraints on the origin of Martian magmas. Martian meteorites are traditionally categorized into the shergottite, nakhlite, and chassignite groups. The shergottites are further classified into three distinct isotopic groups designated depleted, intermediate, and enriched [3,4] based on the isotope systematics and compositions of their source(s).

Shafer, J. T.↗
NASA NTRS2014

Humic Acid Complexation of Th, Hf and Zr in Ligand Competition Experiments: Metal Loading and Ph Effects

The mobility of metals in soils and subsurface aquifers is strongly affected by sorption and complexation with dissolved organic matter, oxyhydroxides, clay minerals, and inorganic ligands. Humic substances (HS) are organic macromolecules with functional groups that have a strong affinity for binding metals, such as actinides. Thorium, often studied as an analog for tetravalent actinides, has also been shown to strongly associate with dissolved and colloidal HS in natural waters. The effects of HS on the mobilization dynamics of actinides are of particular interest in risk assessment of nuclear waste repositories. Here, we present conditional equilibrium binding constants (Kc, MHA) of thorium, hafnium, and zirconium-humic acid complexes from ligand competition experiments using capillary electrophoresis coupled with ICP-MS (CE- ICP-MS). Equilibrium dialysis ligand exchange (EDLE) experiments using size exclusion via a 1000 Damembrane were also performed to validate the CE-ICP-MS analysis. Experiments were performed at pH 3.5-7 with solutions containing one tetravalent metal (Th, Hf, or Zr), Elliot soil humic acid (EHA) or Pahokee peat humic acid (PHA), and EDTA. CE-ICP-MS and EDLE experiments yielded nearly identical binding constants for the metal- humic acid complexes, indicating that both methods are appropriate for examining metal speciation at conditions lower than neutral pH. We find that tetravalent metals form strong complexes with humic acids, with Kc, MHA several orders of magnitude above REE-humic complexes. Experiments were conducted at a range of dissolved HA concentrations to examine the effect of [HA]/[Th] molar ratio on Kc, MHA. At low metal loading conditions (i.e. elevated [HA]/[Th] ratios) the ThHA binding constant reached values that were not affected by the relative abundance of humic acid and thorium. The importance of [HA]/[Th] molar ratios on constraining the equilibrium of MHA complexation is apparent when our estimated Kc, MHA values attained at very low metal loading conditions are compared to existing literature data. Overall, experimental data suggest that the tetravalent transition metal/-actinide-humic acid complexation is important over a wide range of pH values, including mildly acidic conditions, and thus, these complexes should be included in speciation models.

humic acid↗
NASA NTRS2015

Qualification of a Multi-Channel Infrared Laser Absorption Spectrometer for Monitoring CO, HCl, HCN, HF, and CO2 Aboard Manned Spacecraft

Monitoring of specific combustion products can provide early-warning detection of accidental fires aboard manned spacecraft and also identify the source and severity of combustion events. Furthermore, quantitative in situ measurements are important for gauging levels of exposure to hazardous gases, particularly on long-duration missions where analysis of returned samples becomes impractical. Absorption spectroscopy using tunable laser sources in the 2 to 5 micrometer wavelength range enables accurate, unambiguous detection of CO, HCl, HCN, HF, and CO2, which are produced in varying amounts through the heating of electrical components and packaging materials commonly used aboard spacecraft. Here, we report on calibration and testing of a five-channel laser absorption spectrometer designed to accurately monitor ambient gas-phase concentrations of these five compounds, with low-level detection limits based on the Spacecraft Maximum Allowable Concentrations. The instrument employs a two-pass absorption cell with a total optical pathlength of 50 cm and a dedicated infrared semiconductor laser source for each target gas. We present results from testing the five-channel sensor in the presence of trace concentrations of the target compounds that were introduced using both gas sources and oxidative pyrolysis (non-flaming combustion) of solid material mixtures.

environmental monitoring↗
NASA NTRS2018

A Complex History of Silicate Differentiation of Mars from Nd and Hf Isotopes in Crustal Breccia NWA 7034

Resolving the possible mantle and crustal sources for shergottite meteorites is crucial for understanding the formation and early differentiation of Mars. Orbiter and rover characterization of the martian surface reveal that the major element composition of most of its surface does not match the shergottites (McSween et al., 2009)leaving the relationship between them poorly understood. The identification of the meteorite NWA 7034 and its pairs as a Mars surface rock (Cartwright et al., 2014)provides access to a representative sample of Mars' crust (Agee et al., 2013;Humayun et al., 2013). Utilizing the short-lived Sm-146 - Nd-142, and long-lived Sm-142 - Nd-142 and Lu-176 - Hf-176 chronometers, which are sensitive to silicate differentiation, we analyzed three fragments of NWA 7034. The very negative mean isotopic compositions for this breccia, μNd-142(sub JNdi-1)=−45 +/-5(2SD), εNd-143(sub CHUR)=−16.7 +/-0.4(2SD) and εHf176(sub CHUR)=−61 +/-9(2SD) point to an ancient origin for this martian crust. However, modeling of the data shows that the crust sampled by NWA 7034 possesses a Hf/Nd ratio and coupled εNd-143 - μNd-142 model age that are incompatible with this crustal reservoir being an end-member that generated the shergottite source mixing array. In addition, this crust is not juvenile, despite its rare earth element profile, but has had a multistage formation history. Therefore, early crustal extraction alone was not responsible for the creation of the reservoirs that produced the shergottites. Instead mantle reservoirs formed via other early differentiation processes such as in a Mars magma ocean must be responsible for the trace element and isotopic signatures present in shergottites.

Rosalind M. G. Armytage↗
DOE OSTI2020

Materials Data on Hf(MoO4)2 by Materials Project

Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

36 MATERIALS SCIENCE↗