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At least 289 records · Page 16
All sourcesNASA NTRSDOE OSTI
NASA NTRS1985

Role of GaAs surface clearing in plasma deposition of silicon nitride films for encapsulated annealing

The role of GaAs surface cleaning and plasma reactor cleaning prior to deposition of silicon nitride films for encapsulated annealing has been investigated. X-ray photoelectron spectroscopy was employed to determine the surface characteristics of GaAs treated with HCl, HF, and NH4OH solutions preceded by a degreasing procedure. The HCl clean left the least amount of oxygen on the surface. Fluorine contamination resulting from the CF4 plasma used to clean the reactor was found to be located at the film-substrate interface by Auger electron spectroscopy with argon-ion sputtering. A modified deposition procedure was developed to eliminate the fluorine contamination. Plasma deposition of silicon nitride encapsulating films was found to modify the I-V characteristics of Schottky diodes subsequently formed on GaAs surface. The reverse current of the diodes was slightly reduced. Substrates implanted with Si at 100 keV and a dose of 5 x 10 to the 12th/sq cm showed a peak electron concentration of 1.7 x 10 to the 17th/cu cm at a depth of 0.1-micron with 60 percent activation after encapsulation and annealing at 800 C for 7 min.

Valco, G. J.↗
NASA NTRS1986

Boron determination in steels by Inductively-Coupled Plasma spectometry (ICP)

The sample is treated with 5N H2SO4 followed by concentrated HNO3 and the diluted mixture is filtered. Soluble B is determined in the filtrate by Inductively-Coupled Plasma (ICP) spectrometry after addition HCl and extraction of Fe with ethyl-ether. The residue is fused with Na2CO3 and, after treatment with HCl, the insoluble B is determined by ICP spectrometry as before. The method permits determination of ppm amounts of B in steel.

Coedo, A. G.↗
NASA NTRS1987

Infrared spectroscopic measurements of halogenated sink and reservoir gases in the stratosphere with the ATMOS instrument

The Atmospheric Trace Molecule Spectroscopy (ATMOS) instrument recorded 19 sets of interferograms during solar occultations in both the Northern and Southern Hemispheres over the course of the Spacelab 3 mission. The resulting IR spectra furnish concentration profiles for over 25 atmospheric species. Attention is presently given to the volume mixing ratio profiles for HCl and HF in the 15-60-km altitude region, retrieved from northern sunsets and southern sunrises. The HF/HCl ratios deduced are in good agreement with model predictions. The total atmospheric chlorine at 50 km is nearly all in the form of HCl.

Raper, O. F.↗
NASA NTRS1988

Antarctic chlorine chemistry - Possible global implications

Occurrence of heterogeneous reactions on the surface of polar stratospheric clouds (PSC) is a necessary component of the Cl-related chemical mechanisms proposed to explain the recently observed decrease of O3 during Antarctic spring. A one-dimensional model is used to assess the impact of these heterogeneous reactions on future global O3 trends if they were to occur on the global aerosol layer. The impact of these reactions on the concentration of Cl species in the present-day atmosphere is also calculated. The reaction (ClNO3 + HCl) could have a large impact on stratospheric O3. A fast rate for this reaction would greatly enhance the present concentration of ClO and reduce the abundance of HCl in the lower stratosphere. Because of the large differences between the Antarctic and global environments, the calculated global O3 trends are smaller than those calculated for Antarctica.

Rodriguez, Jose M.↗
NASA NTRS1988

Heterogeneous chemistry related to Antarctic ozone depletion: Reaction of ClONO2 and N2O5 on ice surfaces

Laboratory studies of heterogeneous reactions of possible importance for Antarctic ozone depletion were performed. In particular, the reactions of chlorine nitrate (ClONO2) and dinitrogen pentoxide (N2O5) were investigated on ice and HCl/ice surfaces. These reactions occur on the surfaces of polar stratospheric clouds (PSCs) over Antarctica. One reaction transforms the stable chlorine reservoir species (ClONO2 and HCl) into photochemically active chlorine in the form of HOCl and Cl2. Condensation of HNO3 in the reactions removes odd nitrogen from the stratosphere, a requirement in nearly all models of Antarctic ozone depletion. Other reactions may also be important for Antarctic ozone depletion. Like the reactions of chlorine nitrate, these reactions deplete odd nitrogen through HNO3 condensation. In addition, one reaction converts a stable chlorine reservior species (HCl) into photochemically active chlorine (ClNO2). These reactions were studied with a modified version of a Knudsen cell flow reactor.

Tolbert, Margaret A.↗
NASA NTRS1989

Self-limiting physical and chemical effects in volcanic eruption clouds

One-dimensional aerosol microphysical and photochemical models are used to study the chemistry of stratospheric volcanic clouds. The results indicate that the aerosol microphysical processes of condensation and coagulation produce larger particles as the SO2 injection rate is increased. Larger particles have a smaller optical depth per unit mass and settle out of the stratosphere at a faster rate than smaller ones, restricting the total number of particles in the stratosphere. The microphysical processes moderate the impact of volcanic clouds on the earth's radiation budget and climate, suggesting that volcanic effects may be self limiting. It is noted that the injection of HCl into the stratosphere, which could lead to large ozone changes, is limited by a cold trap effect in which HCl and water vapor condense on ash particles in the rising volcanic plume and fall out as ice.

Pinto, Joseph P.↗
NASA NTRS1989

Study of metal corrosion using ac impedance techniques in the STS launch environment

AC impedance measurements were performed to investigate the corrosion resistance of 19 alloys under conditions similar to the STS launch environment. The alloys were: Zirconium 702, Hastelloy C-22, Inconel 625, Hastelloy C-276, Hastelloy C-4, Inconel 600, 7Mo + N, Ferralium 255, Inco Alloy G-3, 20Cb-3, SS 904L, Inconel 825, SS 304LN, SS 316L, SS 317L, ES 2205, SS 304L, Hastelloy B-2, and Monel 400. AC impedance data were gathered for each alloy after one hour immersion time in each of the following three electrolyte solutions: 3.55 percent NaCl, 3.55 percent NaCl-0.1N HCl, and 3.55 percent NaCl-1.0N HCl. The data were analyzed qualitatively using the Nyquist plot and quantitatively using the Bode plot. Polarization resistance, Rp, values were obtained using the Bode plot. Zirconium 702 was the most corrosion resistant alloy in the three electrolytes. The ordering of the other alloys according the their resistance to corrosion varied as the concentration of hydrochloric acid in the electrolyte increased. The corrosion resistance of Zirconium 702 and Ferralium 255 increased as the concentration of hydrochloric acid in the electrolyte increased. The corrosion resistance of the other 17 alloys decreased as the concentration of the hyrdochloric acid in the electrolyte increased.

Calle, Luz M.↗
NASA NTRS1989

Surface composition of solid-rocket exhausted aluminum oxide particles

Particulate samples of aluminum oxide were collected on Teflon filters from the exhaust plume of the Space Shuttle (STS-61A, October 30, 1985) over the altitude interval 4.6-7.6 km immediately after launch. These particles were analyzed using SEM, energy-dispersive X-ray analysis, electron spectroscopy for chemical analysis, X-ray fluorescent spectroscopy, and conventional wet-chemical techniques. The samples were 0.6-1.0 percent surface-chlorided (chlorided meaning predominantly aluminum chlorides and oxychlorides, possibly including other adsorbed forms of chloride) by weight. This level of chloriding is about one-third of the amount determined previously from laboratory-prepared alumina and surface site samples of solid-rocket-produced alumina (SRPA) after both had been exposed to moist HCl vapor at temperatures down to ambient. This level is equivalent to previous laboratory results with samples exposed to moist HCl at temperatures above the boiling point of water. It is suggested that the present lower chloriding levels, determined for samples from a 'dry' Shuttle exhaust cloud, underscore the importance of a liquid water/hydrochloric acid phase in governing the extent of surface chloriding of SRPA. The reduced chloriding is not trivial with respect to potential physical/chemical modification of the SRPA particle surfaces and their corresponding interaction with the atmosphere.

Cofer, Wesley R., III↗
NASA NTRS1989

Three dimensional simulation of spatial and temporal variability of stratospheric hydrogen chloride

Spatial and temporal variability of atmospheric HCl columns are calculated for January 1979 using a three-dimensional chemistry-transport model designed to provide the best possible representation of stratospheric transport. Large spatial and temporal variability of the HCl columns is shown to be correlated with lower stratospheric potential vorticity and thus to be of dynamical origin. Systematic longitudinal structure is correlated with planetary wave structure. These results can help place spatially and temporally isolated column and profile measurements in a regional and/or global perspective.

Kaye, Jack A.↗
NASA NTRS1990

The deep atmosphere of Venus revealed by high-resolution nightside spectra

The first high-resolution spectroscopic observations of the night side of Venus obtained in two narrow spectral windows centered at 1.74 and 2.3 microns, where the nightside is anomalously bright, are reported. Absorption features from CO2, CO, H2O, HDO, HCl, HF, and COS are detected, and there are a number of unidentified features. A preliminary analysis indicates that the observed radiation is thermal emission from atmospheric layers in the eight-bar pressure region for the 2.3 micron window and even deeper at 1.7 micron. The derived CO and H2O abundances agree with in situ Pioneer measurements in the deep troposphere and are consistent with the high deuterium enrichment inferred from Pioneer data. The first measurements of HCl and HF below the clouds are reported along with the first firm detection of COS.

Bezard, Bruno↗
NASA NTRS1991

Recovery of precious metals from space

The overall objective is to develop efficient and economical separation and recovery methods for the platinum group and other precious metals. The separation of Pd(II) from Pt(II), Ir(III), and Rh(III) with trioctylphosphine oxide (TOPO) in heptane using centrifugal partition chromatography (CPC) was investigated. Activities to achieve this objective focussed on selection and evaluation of extraction systems for the PGM and modification of selected systems for multistage operation with a view to scaling up to desired macro levels. On the basis of preliminary evaluation of a series of simple metal complexing agents and chelating agents, the TOPO in heptane was selected as a likely system for isolating of Pd(II) and Pt(II) from the other PGM. A multistage apparatus capable of configuration as a simple rugged device, a centrifugal partition chromatograph (CPC), was shown to be effective. The extraction of Pd(II) was studied by CPC and batch solvent extraction. The distribution ratios for Pd(II) determined by both methods agree well. In low HCl concentrations (less than 0.1 M), the extracted species was PdCl2.(TOPO)2, irrespective of the chloride concentration, while at acid concentrations above 0.1 M, the Pd was extracted as the ion pair, 2(TOPO.H+).(PdCl4)2-. Base line separation of Pd(II) and Pt(II) in CPC was obtained under a variety of chloride and HCl concentration. It was demonstrated that the efficiency of CPC for metal separation was limited by chemical kinetic factors rather than instrumental factors, strongly suggesting that dramatic improvements can be achieved by studying reaction kinetics of formation and dissociation of the extractable metal complex.

Freiser, Henry↗
NASA NTRS1989

Proposed reference models for CO2 and halogenated hydrocarbons

The vertical distribution of carbon dioxide, halocarbons and their sink products, HCl and HF, have become available, mainly by means of balloon measurements. Most measurements were made at northern mid-latutudes, but some constituents were measured at tropical latitudes and in the Southern Hemisphere as well. An attempt is made here to combine the available data for presentation of reference models for CO2, CCl4 CCl3F, CCl2F2, CClF3, CF4, CCl2F-CClF2, CClF2-CClF2, CClF2-CF3, CF3-CF3, CH3Cl, CHClF2, CH3-CCl3, CBrClF2, CBrF3, HCl and HF.

Fabian, P.↗
NASA NTRS1991

Inferring the abundances of ClO and HO2 from Spacelab 3 atmospheric trace molecule spectroscopy observations

The vertical distributions of the important highly reactive stratospheric species, ClO and HO2, have been inferred from Spacelab 3 (May 1985) Atmospheric Trace Molecule Spectroscopy (ATMOS) measurements of more detectable radical and reservoir species. A simple steady state algebraic expression for ClO, utilizing the observed ClONO2/NO2 abundance ratio, approximates the ClO results of a time-dependent photochemical model at sunset (30 deg N). Balloon measurements of ClO and comparisons of time-dependent photochemical model calculations of ClONO2 and HCl with the corresponding ATMOS profiles suggest that the actual ClO values are less than the time-dependent model profiles for ClO at sunset and sunrise (47 deg S). Errors in the current model simulation of the partitioning among the principal free chlorine species (HCl, ClONO2, and ClO) are indicated. The accuracy of the time-dependent model calculations of HO2 is suggested by the agreement between model results and ATMOS observations for HO2NO2 and balloon measurements of HO2. This confirms for the first time the procedure suggested previously by a number of authors of deriving HO(x) abundances from observed fields of O3 and H2O.

Allen, Mark↗
NASA NTRS1991

Heterogeneous reactions with NaCl in the El Chichon volcanic aerosols

Previous investigations of the effects of the 1982 eruption of the El Chichon volcano could not explain all the observations of changes in O3, HCl, NO and NO2 simultaneously without proposing unproven chemical reactions. Since reactions between solid NaCl and gaseous ClNO3 and N2O5 rapidly produce photochemically active chlorine species and solid NaNO3 in laboratory experiments, it is suggested that these reactions could have occurred with the NaCl observed to be present in the El Chichon sulfuric acid areosols. As a consequence, it is predicted that HCl should increase substantially, while NO(x) should decrease, in agreement with the measurements after the eruption. Ozone should be only slightly affected by these reactions. Reactions between solid NaCl and the acids H2SO4 and HNO3 might prove to be important, but sufficient evidence regarding their efficiency and the pressure of HNO3 in the aerosols is lacking.

Michelangeli, Diane V.↗
NASA NTRS1991

Application of physical adsorption thermodynamics to heterogeneous chemistry on polar stratospheric clouds

Laboratory isotherms for the binding of several nonheterogeneously active atmospheric gases and for HCl to water ice are translated into adsorptive equilibrium constants and surface enthalpies. Extrapolation to polar conditions through the Clausius Clapeyron relation yields coverage estimates below the percent level for N2, Ar, CO2, and CO, suggesting that the crystal faces of type II stratospheric cloud particles may be regarded as clean with respect to these species. For HCl, and perhaps HF and HNO3, estimates rise to several percent, and the adsorbed layer may offer acid or proton sources alternate to the bulk solid for heterogeneous reactions with stratospheric nitrates. Measurements are lacking for many key atmospheric molecules on water ice, and almost entirely for nitric acid trihydrate as substrate. Adsorptive equilibria enter into gas to particle mass flux descriptions, and the binding energy determines rates for desorption of, and encounter between, potential surface reactants.

Elliott, Scott↗
NASA NTRS1991

X-ray photoelectron spectroscopy study of chemically-etched Nd-Ce-Cu-O surfaces

Acetic acid, Br2, and HCl solutions are investigated for removing insulating species from Nd(1.85)Ce(0.15)CuO(4-delta) (NCCO) thin film surfaces. X-ray photoelectron spectroscopy (XPS) shows that the HCl etch is most effective, yielding O 1s spectra comparable to those obtained from samples cleaned in vacuum and a clear Fermi edge in the valence band region. Reduction and oxidation reversibly induces and eliminates, respectively, Fermi level states for undoped samples, but has no clearly observable effect on the XPS spectra for doped samples. Reactivity to air is much less for NCCO compared to hole superconductors, which is attributed to the lack of reactive alkaline earth elements in NCCO.

Vasquez, R. P.↗
NASA NTRS1990

Quantification of hydrochloric acid and particulate deposition resulting from Space Shuttle launches at John F. Kennedy Space Center, Florida, U.S.A.

Results are presented from studies designed to identify deposition patterns and quantify the ecosystem loading rates of exhaust constituents (which are primarily Al2O3 and HCl) from the Space Shuttle solid rocket motors in the area of the Kennedy Space Center launch pad. Results of measurements indicate that, under certain meteorological conditions, as much as 7.1 x 10 exp 3 kg of particulates and 3.4 x 10 exp 3 kg HCL can be deposited to the near-field environment beyond the launch pad perimeter fence during one STS launch.

Dreschel, Thomas W.↗
NASA NTRS1992

Anodic etching of p-type cubic silicon carbide

p-Type cubic silicon carbide was anodically etched using an electrolyte of HF:HCl:H2O. The etching depth was determined versus time with a fixed current density of 96.4 mA/sq cm. It was found that the etching was very smooth and very uniform. An etch rate of 22.7 nm/s was obtained in a 1:1:50 HF:HCl:H2O electrolyte.

Harris, G. L.↗