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At least 289 records · Page 16
All sourcesNASA NTRSDOE OSTI
NASA NTRS1994

Infrared optical constants of H2O ice, amorphous nitric acid solutions, and nitric acid hydrates

We determined the infrared optical constants of nitric acid trihydrate, nitric acid dihydrate, nitric acid monohydrate, and solid amorphous nitric acid solutions which crystallize to form these hydrates. We have also found the infrared optical constants of H2O ice. We measured the transmission of infrared light throught thin films of varying thickness over the frequency range from about 7000 to 500/cm at temperatures below 200 K. We developed a theory for the transmission of light through a substrate that has thin films on both sides. We used an iterative Kramers-Kronig technique to determine the optical constants which gave the best match between measured transmission spectra and those calculated for a variety of films of different thickness. These optical constants should be useful for calculations of the infrared spectrum of polar stratospheric clouds.

Toon, Owen B.↗
NASA NTRS1995

A tentative detection of the 183-GHz water vapor line in the martian atmosphere: Constraints upon the H2O abundance and vertical distribution

The 183-GHz water vapor line was tentatively detected on Mars in January 1991, with the IRAM 30-m millimeter antenna, under extremely dry atmospheric conditions. The measurement refers to the whole disk. The spectral line, although marginally detected, can be fit with a constant H2O mixing ratio of 1.0 x 10(exp -5), which corresponds to a water abundance of 1 pr-microns; in any case, an upper limit of 3 pr-microns is inferred. This value is comparable to the very small abundances measured by Clancy (1992) 5 weeks before our observation and seems to imply both seasonal and long-term variations in the martian water cycle.

Encrenaz, TH.↗
NASA NTRS1995

Comparison of HALOE O3 and H2O observations from UARS with ground and balloonborne measurements

The HALogen Occultation Experiment (HALOE) was launched on the Upper Atmosphere Research Satellite (UARS) by the Space Shuttle Discovery at 7:11:04 EDT on September 12, 1991. After allowing for a period of outgassing, HALOE began taking routine science observations on October 11. HALOE uses the experiment approach of solar occultation and the gas filter and broad band radiometer instruments techniques to measure vertical profiles of HCl, HF, CH4, NO, NO2, H2O, O3, aerosol, and temperature versus pressure. The measurements cover a broad altitude range from the upper troposphere in some cases to the lower thermosphere in the case of nitric oxide. Latitude coverage provided by the occultation geometry ranges from 80 deg S to 80 deg N over the course of one year. The experiment has operated essentially without flaw for more than three years. Instrument stability over this time, as judged by the maximum signal change when viewing the sun exoatmospherically is less than or equal to 2 to 3%.

Russell, James M., III↗
NASA NTRS1998

Troposphere-to-Stratosphere Transport in the Lowermost Stratosphere from Measurements of H2O, CO2, N2O and O3

The origin of air in the lowermost stratosphere is investigated with measurements from the NASA ER-2 aircraft. Air with high water vapor mixing ratios was observed in the stratosphere at theta about 330-380 K near 40N in May 1995, indicating the influence of intrusions of tropospheric air. Assuming that observed tracer-tracer relationships reflect mixing lines between tropospheric and stratospheric air masses, we calculate mixing ratios of H2O (12-24 ppmv) and CO2 for the admixed tropospheric air at theta =352-364 K. Temperatures on the 355 K surface at 20-40 N were low enough to dehydrate air to these values. while most ER-2 CO2 data in both hemispheres are consistent with tropical or subtropical air entering the lowermost stratosphere, measurements from May 1995 for theta <362 K suggest that entry of air from the midlatitude upper troposphere can occur in conjunction with mixing processes near the tropopause.

Hintsa, E. J.↗
NASA NTRS1998

Troposphere-to-Stratosphere Transport in the Lowermost Stratosphere from Measurements of H2O, CO2, N2O and O3

The origin of air in the lowermost stratosphere is investigated with measurements from the NASA ER-2 aircraft. Air with high water vapor mixing ratios was observed in the stratosphere at theta-330-380 K near 40 N in May 1995, indicating the influence of intrusions of tropospheric air. Assuming that observed tracer-tracer relationships reflect mixing lines between tropospheric and stratospheric air masses, we calculate mixing ratios of H2O (12-24 ppmv) and CO2 for the admixed tropospheric air at theta=352-364 K. Temperatures on the 355 K surface at 20-40 N were low enough to dehydrate air to these values. While most ER-2 CO2 data in both hemispheres are consistent with tropical or subtropical air entering the lowermost stratosphere, measurements from May 1995 for theta<362 K suggest that entry of air from the midlatitude upper troposphere can occur in conjunction with mixing processes near the tropopause.

Hintsa, E. J.↗
NASA NTRS1998

Troposphere-to-Stratosphere Transport in the Lowermost Stratosphere from Measurements of H2O, CO2, N2O, and O3

The origin of air in the lowermost stratosphere is investigated with measurements from the NASA ER-2 aircraft. Air with high water vapor mixing ratios was observed in the stratosphere at theta approximately 330-380 K near 40 N in May 1995, indicating the influence of intrusions of tropospheric air. Assuming that observed tracer-tracer relationships reflect mixing lines between tropospheric and stratospheric air masses, we calculate mixing ratios of H2O (12-24 ppmv) and CO2 for the admixed tropospheric air at theta = 352-364 K. Temperatures on the 355 K surface 20-40 N were low enough to dehydrate air to these values. While most ER-2 CO2 data in both hemispheres are consistent with tropical or subtropical air entering the lowermost stratosphere, measurements from May 1995 for theta < 362 K suggest that entry of air from the midlatitude upper troposphere can occur in conjunction with mixing processes near the tropopause.

Hintsa, E. J.↗
NASA NTRS2000

H2O Adsorption Kinetics on Smectites

The adsorptive equilibration of H2O with montomorillonite has been measured. At low temperatures and pressures equilibration can require many hours, effectively preventing smectites at the martian surface from responding to diurnal pressure and temperature variations.

Zent, Aaron P.↗
NASA NTRS2000

H2O Adsorption Kinetics on Smectites

The adsorptive equilibration of H2O a with montomorillonite, a smectite clay has been measured. At low temperatures and pressures, equilibration can require many hours, effectively preventing smectites at the martian surface from responding rapidly to diurnal pressure and temperature variations.

Zent, Aaron P.↗
NASA NTRS1998

Troposphere-to-Stratosphere Transport in the Lowermost Stratosphere from Measurements of H2O, CO2, N2O and O3

The origin of air in the lowermost stratosphere is investigated with measurements from the NASA ER-2 aircraft. Air with high water vapor mixing ratios was observed in the stratosphere at theta = 330-380 K near 40 N in May 1995, indicating the influence of intrusions of tropospheric air. Assuming that observed tracer-tracer relationships reflect mixing lines between tropospheric and stratospheric air masses, we calculate mixing ratios of H2O (12-24 ppmv) and CO2 for the admixed tropospheric air at theta = 352-364 K. Temperatures on the 355 K surface at 20-40 N were low enough to dehydrate air to these values. While most ER-2 CO2 data in both hemispheres are consistent with tropical or subtropical air entering the lowermost stratosphere, measurements from May 1995 for theta < 362 K suggest that entry of air from the midlatitude upper troposphere can occur in conjunction with mixing processes near the tropopause.

Hintsa, E. J.↗
NASA NTRS2000

On the reaction CH2O + NH3 Yields CH2NH + H2O

We study the energetics of CH2O + NH3-Yields CH2NH + H2O in the gas phase at the B3LYP and CCSD(T)levels. This reaction is shown to have a sizeable barrier. Ionization of NH3 reduces the barrier to about 5 kcal/mol. We also show that in water, a proton catalyzed mechanism yields no barriers in excess of the reaction endothermicity. Since this reaction has been proposed as one of the steps in interstellar synthesis of glycine, the simplest amino acid, this work suggests that the formation of amino acids is occurring in and/or on interstellar water ice grains, and not in the gas phase.

Walch, Stephen P.↗
NASA NTRS1997

An Accurate Potential Energy Surface for H2O

We have carried out extensive high quality ab initio electronic structure calculations of the ground state potential energy surface (PES) and dipole moment function (DMF) for H2O. A small adjustment is made to the PES to improve the agreement of line positions from theory and experiment. The theoretical line positions are obtained from variational ro-vibrational calculations using the exact kinetic energy operator. For the lines being fitted, the root-mean-square error was reduced from 6.9 to 0.08 /cm. We were then able to match 30,092 of the 30,117 lines from the HITRAN 96 data base to theoretical lines, and 80% of the line positions differed less than 0.1 /cm. About 3% of the line positions in the experimental data base appear to be incorrect. Theory predicts the existence of many additional weak lines with intensities above the cutoff used in the data base. To obtain results of similar accuracy for HDO, a mass dependent correction to the PH is introduced and is parameterized by simultaneously fitting line positions for HDO and D2O. The mass dependent PH has good predictive value for T2O and HTO. Nonadiabatic effects are not explicitly included. Line strengths for vibrational bands summed over rotational levels usually agree well between theory and experiment, but individual line strengths can differ greatly. A high temperature line list containing about 380 million lines has been generated using the present PES and DMF

Schwenke, David W.↗
NASA NTRS2002

First Principle Predictions of Isotopic Shifts in H2O

We compute isotope independent first and second order corrections to the Born-Oppenheimer approximation for water and use them to predict isotopic shifts. For the diagonal correction, we use icMRCI wavefunctions and derivatives with respect to mass dependent, internal coordinates to generate the mass independent correction functions. For the non-adiabatic correction, we use scaled SCF/CIS wave functions and a generalization of the Handy method to obtain mass independent correction functions. We find that including the non-adiabatic correction gives significantly improved results compared to just including the diagonal correction when the Born-Oppenheimer potential energy surface is optimized for H2O-16. The agreement with experimental results for deuterium and tritium containing isotopes is nearly as good as our best empirical correction, however, the present correction is expected to be more reliable for higher, uncharacterized levels.

Schwenke, David W.↗
NASA NTRS2003

Tropospheric Wind Profiles Obtained with the GLOW Molecular Doppler Lidar during the 2002 International H2O Project

The Goddard Lidar Observatory for Winds (GLOW) is a mobile direct detection Doppler lidar system which uses the double edge technique to measure the Doppler shift of the molecular backscattered laser signal at a wavelength of 355 nm. In the spring of 2002 GLOW was deployed to the western Oklahoma profiling site (36 deg 33.500 min N, 100 deg 36.371 min W) to participate in the International H2O Project (IHOP). During the IHOP campaign over 240 hours of wind profiles were obtained with the GLOW lidar in support of a variety of scientific investigations.

Gentry, Bruce M.↗
NASA NTRS2003

Tropospheric Wind Profiles Obtained with the GLOW Molecular Doppler Lidar during the 2002 International H2O Project

The Goddard Lidar Observatory for Winds (GLOW) is a mobile direct detection Doppler lidar system hich uses the double edge technique to measure the Doppler shift of the molecular backscattered laser signal at a wavelength of 355 nm. In the spring of 2002 GLOW was deployed to the western Oklahoma profiling site (36 deg 33.500 min N, 100 deg 36.371 min W) to participate in the International H2O Project (MOP). During the MOP campaign over 240 hours of wind profiles were obtained with the GLOW lidar in support of a variety of scientific investigations.

Gentry, Bruce M.↗
NASA NTRS1996

Effects of H2O Vapor on Vibrational Relaxation in Expanding and Contracting Flows

As opposed to previous explanations based on the effects of anharmonicity of simple diatomic molecules, traces of water vapor are suggested to be the most likely cause of the anomalously fast vibrational relaxation of such gases observed in supersonic and hypersonic nozzles. The mechanism is the strong V-VR coupling with H2O molecules that dramatically facilitates the collisional transfer of vibrational energy. Slight moisture content is thus a real world aspect of gas dynamics that must be considered in characterizations of shock tubes, reflected shock tunnels, and expansion tubes.

Meador, Willard E.↗
NASA NTRS2005

Direct Detection Doppler Lidar Wind Measurements Obtained During the 2002 International H2O Project (IHOP)

The Goddard Lidar Observatory for Winds (GLOW) is a mobile Doppler lidar system that uses direct detection techniques for profiling winds in the troposphere and lower stratosphere. In May and June of 2002 GLOW was deployed to the Southern Great Plains of the US to participate in the International H2O Project (IHOP). GLOW was located at the Homestead profiling site in the Oklahoma panhandle about 15 km east of the SPOL radar. Several other Goddard lidars, the Scanning Raman Lidar (SRL) and HARLIE, as well as radars and passive instruments were permanently operated from the Homestead site during the IHOP campaign providing a unique cluster of observations. During the IHOP observation period (May 14, 2002 to June 25, 2002) over 240 hours of wind profile measurements were obtained with GLOW. In this paper we will describe the GLOW instrument as it was configured for the IHOP campaign and we will present examples of wind profiles obtained.

Gentry, Bruce↗
NASA NTRS2005

Raman Lidar Measurements During the International H2O Project: Instrument Comparisons and Case Studies - 2

The NASA/GSFC Scanning Raman Lidar (SRL) participated in the International H2O Project (IHOP) that occurred in May and June, 2002 in the midwestern part of the U. S. The SRL system configuration and methods of data analysis were described in part I of this paper. In this second part, comparisons of SRL water vapor measurements and those of chilled mirror radiosonde and LASE airborne water vapor lidar are performed. Two case studies are presented; one for daytime and one for nighttime. The daytime case study is of a convectively driven boundary layer event and is used to characterize the SRL water vapor random error characteristics. The nighttime case study is of a thunderstorm-generated cirrus cloud case that is studied in it s meteorological context. Upper tropospheric humidification due to precipitation from the cirrus cloud is quantified as is the cirrus cloud ice water content and particle depolarization ratio. These detailed cirrus cloud measurements are being used in a cirrus cloud modeling study.

Whiteman, D. N.↗
NASA NTRS2005

Li, B - Behavior in Lunar Basalts During Shock and Thermal Metamorphism: Implications for H2O in Martian Magmas

Introduction: The water-content of Martian magmas is a topic of debate among researchers. Some Martian basalts are characterized with melt inclusions of biotite, apatite and amphibole; phases typically associated with hydration reactions on Earth [1-3]. However, the H-content of melt inclusions from these basalts is low, and bulk-rock H2O-contents range from a meager 0.013 to 0.035 wt. % in Shergotty [4]. Nonetheless, researchers note that low present-day water contents do not preclude a once hydrous past [5]. Since light lithophile elements (LLE), such as Li and B, partition into aqueous fluids at T > 350 C, workers proposed that Li-B depletions in pyroxene rims of Nakhlite and Shergottite basalts reflect the loss of several weight percent water from Martian magmas during crystallization [6]. Since similar depletions were observed in pyroxene rims from completely dry lunar basalts, it is likely that alternative mechanisms also contribute to the distribution of elements such as Li and B [7]. Given that many Martian basalts have experienced considerable shock pressures (15-45 GPa), it is possible that shock and subsequent thermal metamorphism may have influenced the volatile element records of these basalts [8]. In order to better understand the distribution of Li and B, we are studying the effects of crystal chemistry, shock pressure, and thermal metamorphism in pyroxenes from lunar basalts. Below, we discuss results from experimentally shocked and thermally metamorphosed Apollo 11, 10017 (A-11) and Apollo 17, 75035 (A-17) basalts.

Chaklader, Johny↗