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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 289 records · Page 16

Traveling Molten Zone Refining Process Development for Innovative Fuel Cycle Solutions

Considering the phase diagrams of metallic spent fuel constituents, the melting and solidifying of spent metallic fuel causes three immiscible layers (actinide-rich, lanthanide-rich, and Group II-rich) and the condensate phase (Group I) to form. We believe this anticipated immiscibility offers an untapped opportunity for innovative fuel cycle solutions. Through the proposed project, we anticipate confirming the expected phase behavior and develop a thermal treatment process to rapidly extract actinides from spent metallic fuels. The prime apparatus for both purposes is a traveling molten zone system with induction heating. We envision that one rapid pass of the molten zone from the bottom to the top of the metallic rod incorporating species of spent metallic fuels should produce the expected immiscible layer formation and provide species partitioning data effectively and cleanly. It will also demonstrate an actinide extraction process by concentrating the impurities at the top segment of the rod and leaving the actinide species behind as the bulk rod. The successful execution of the project will demonstrate proof of concept for a transformative process path for used metal fuels in terms of economics and safeguards.

36 MATERIALS SCIENCE↗

The Impact of the Halden Reactor Project on the Development of the Bison Fuel Performance Code

The Bison fuel performance code has been under development at Idaho National Laboratory by various programs within the U.S. Department of Energy since 2009. As part of any fuel performance code development, validation is necessary. To this end, several Halden experiments have been used. Early on, the focus was on validating the thermal mechanical behaviour, including pellet cladding mechanical interaction and fission gas release models implemented in Bison. Support for design-basis accident capabilities began in approximately 2014. Also in 2014, the development of models for accident tolerant fuel (ATF) concepts also began. This includes dopedUO2 fuel for which Halden has some experiments with temperature and fission gas release measurements. The Bison team has been fortunate to have two senior developers be secondees to Halden for a year: the late Dr. Giovanni Pastore from May 2015 to April 2016 and the now retired Dr. Richard Williamson in 2018. The paper will provide examples of Bison validation using Halden data for standard UO2 fuel under normal operation and loss-of-coolant accident condition, and ATF concepts. A tribute to the legacy that both the late Giovanni and retired Richard left on the Bison code is provided.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

An Overview of High Bandwidth Liquid Fuel Flow Modulators Developed for Active Combustion Control Research

This paper presents a description of the general construction of three high bandwidth liquid fuel modulators along with data corresponding to their respective modulation performance. These devices are a critical element of the National Aeronautics and Space Administration Glenn Research Center's (NASA GRC) Active Combustion Control (ACC) task. These devices are not commercially-off-the-shelf available, primarily due to a one kHz bandwidth requirement. Given their special nature, NASA GRC developed specifications for the modulation devices and then, through Small Business Innovative Research (SBIR) contracts, had vendors with expertise in valve design manufacture them. The modulators described in this paper are the Active Signal Modulator (ASM), the Jansen's Aircraft System Controls (JASC) modulator, and the WASK Engineering (WASK) modulator. These modulators utilize magnetostrictive, electric motor, or piezoelectric actuation, respectively. The specifications for these devices evolved over time to meet the needs of changing objectives in the ACC research task. This is primarily true with respect to flow number as their designs accommodate a range from one to eight (lbm./hr-psi0.5). These designs also exhibit relatively small volume, weight, and power consumption with an ability to modulate approximately +/- 30% from the mean on a pressure basis. The modulators have been characterized and have undergone laboratory performance tests by the vendors. Their data indicated suitability for continued use in ACC research testing.

Saus, Joseph R.↗

Fuel Cell Research and Development for Future NASA Missions

NASA has been using fuel cell systems since the early days of space flight. Polymer Exchange Membrane Fuel cells provided the primary power for the Gemini and Apollo missions and more recently, alkaline fuel cells serve as the primary power source for the Space Shuttle. NASA's current investments in fuel cell technology support both Exploration and Aeronautics programs. This presentation provides an overview of NASA's fuel cell development programs.

Manzo, Michelle A.↗

Subscale maturation of advanced reactor technologies (SMART): A path forward for nuclear thermal propulsion fuel and reactor development

Nuclear Thermal Propulsion (NTP) systems are actively being developed for future crewed missions to Mars. NTP systems excel in missions where both high thrust and high specific impulse are required, but modern NTP systems currently do not have a Technology Readiness Level (TRL) high enough for use in crewed space exploration. TRLs are used to demonstrate the level of rigor with which a component/system has been tested/demonstrated for its intended use. While space systems technology in general must be qualified as a unit, nuclear technology must be first demonstrated to meet qualification level requirements both at the fuel (component) level and the reactor (subsystem) level. Here, in this paper, historic NTP development programs are surveyed to identify a testing and development strategy that can be effectively implemented to allow for NTP reactor development. Based on this strategy, required facilities to enable such activities are identified. Current domestic experimental capabilities to support NTP qualification are limited to separate effects testing of individual components. Separate effects testing is found extensively in historic NTP development efforts but is not sufficient for full fuel and reactor qualification. Combined effects testing allows for an accurate assessment of fuel performance but is not achievable for NTP conditions in existing facilities. Assessment of historic development programs suggests that an intermediate, subscale test facility is necessary to advance NTP TRLs. A solution to meet this need is proposed, namely the Subscale Maturation of Advanced Reactor Technologies (SMART) facility. SMART will mitigate risk to NTP development by enabling performance and reactor physics demonstrations of NTP subsystems. A SMART facility could be built by modifying existing nuclear test facilities, which may potentially enable schedule and cost savings. To pursue reactor qualification beyond the subscale, a new ground test facility will be necessary. This ground test facility should be developed concurrently with SMART to allow for the facility to be operational in time for expedited NTP engine demonstration.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Development of an alkaline fuel cell subsystem

A two task program was initiated to develop advanced fuel cell components which could be assembled into an alkaline power section for the Space Station Prototype (SSP) fuel cell subsystem. The first task was to establish a preliminary SSP power section design to be representative of the 200 cell Space Station power section. The second task was to conduct tooling and fabrication trials and fabrication of selected cell stack components. A lightweight, reliable cell stack design suitable for the SSP regenerative fuel cell power plant was completed. The design meets NASA's preliminary requirements for future multikilowatt Space Station missions. Cell stack component fabrication and tooling trials demonstrated cell components of the SSP stack design of the 1.0 sq ft area can be manufactured using techniques and methods previously evaluated and developed.

Source record↗

Integrated model development for liquid fueled rocket propulsion systems

As detailed in the original statement of work, the objective of phase two of this research effort was to develop a general framework for rocket engine performance prediction that integrates physical principles, a rigorous mathematical formalism, component level test data, system level test data, and theory-observation reconciliation. Specific phase two development tasks are defined.

Santi, L. Michael↗

Mars Ascent Vehicle Hybrid Propulsion Effort

A technology development program was undertaken to determine if the benefits of hybrid rocket propulsion could be realized for a Mars Ascent Vehicle (MAV) application. Specifically, the goal of this program was to increase the Technology Readiness Level (TRL) of a hybrid propulsion system such that it could be considered for a potential Mars Sample Return Campaign. Over the course of approximately five years, a new, wax-based fuel was developed, characterized and tested with Mixed Oxides of Nitrogen (from MON-3 to MON-25). Various ignition mechanisms were tested and solid hypergolic additives were evaluated for their potential to ignite the hybrid motor. Several hot-fire test campaigns were completed at both sub- and full-scale. The technology development program was born out of a JPL study documented by Shotwell and Karp that identified the Single Stage to Orbit (SSTO) hybrid propulsion system for a potential Mars Ascent Vehicle to be the lowest Gross Lift Off Mass option from the ten configurations evaluated. Benefits of the hybrid option included its predicted favorable low temperature storage and operation behavior, high performance and ability to restart (enabling the SSTO). The main disadvantage of the hybrid option was its low TRL, as it essentially started as a blank sheet design with a new fuel development. Near the end of the technology development program, a Preliminary Architecture Assessment (PAA) was completed to evaluate a single-stage hybrid propulsion system and a two-stage solid propulsion system for a potential MAV. The solid propulsion system was selected for further study in 2019, primarily because of its flight heritage. While the hybrid technology development program made many strides, there was still a list of challenges to overcome. This paper will discuss the substantial progress and remaining challenges from the technology development effort from 2015 through 2019. This includes fuel development and reformulation, sub- and full-scale testing at Space Propulsion Group, full scale testing at Parabilis, full scale testing at Whittinghill Aerospace, hypergolic additive testing at Purdue and Penn State and the evaluation of adding hypergolic additives to a fullscale grain. It also includes a discussion of the design that resulted from the Preliminary Architecture Assessment.

hybrid rocket↗

Mars Ascent Vehicle Hybrid PropulsionEffort

A technology development program was undertaken to determine if the benefits of hybrid rocket propulsion could be realized for a Mars Ascent Vehicle (MAV) application. Specifically, the goal of this program was to increase the Technology Readiness Level (TRL) of a hybrid propulsion system such that it could be considered for a potential Mars Sample Return Campaign. Over the course of approximately five years, a new, wax-based fuel was developed, characterized and tested with Mixed Oxides of Nitrogen (from MON-3 to MON-25). Various ignition mechanisms were tested and solid hypergolic additives were evaluated for their potential to ignite the hybrid motor. Several hot-fire test campaigns were completed at both sub- and full-scale. The technology development program was born out of a JPL study documented by Shotwell and Karp that identified the Single Stage to Orbit (SSTO) hybrid propulsion system for a potential Mars Ascent Vehicle to be the lowest Gross Lift Off Mass option from the ten configurations evaluated. Benefits of the hybrid option included its predicted favorable low temperature storage and operation behavior, high performance and ability to restart (enabling the SSTO). The main disadvantage of the hybrid option was its low TRL,as it essentially started as a blank sheet design with a new fuel development. Near the end of the technology development program, a Preliminary Architecture Assessment (PAA) was completed to evaluate a single-stage hybrid propulsion system and a two-stage solid propulsion system for a potential MAV. The solid propulsion system was selected for further study in 2019, primarily because of its flight heritage. While the hybrid technology development program made many strides, there was still a list of challenges to overcome. This paper will discuss the substantial progress and remaining challenges from the technology development effort from 2015 through 2019. This includes fuel development and reformulation, sub- and full-scale testing at Space Propulsion Group, full scale testing at Parabilis, full scale testing at Whittinghill Aerospace, hypergolic additive testing at Purdue and Penn State and the evaluation of adding hypergolic additives to a full-scale grain. It also includes a discussion of the design that resulted from the Preliminary Architecture Assessment.

hybrid rocket↗

Hydrocarbon-fueled scramjet combustor component development tests

Technology is being developed for a hydrocarbon-fueled engine operating as a scramjet over the flight Mach number range from 5.6 to 7. A series of connected-pipe tests were performed to define scramjet combustor design criteria applicable to the United Technologies Research Center (UTRC) engine concept which comprises a pair of modular axisymmetric combustor underslung on a supersonic/hypersonic missile. The development of key pilot and fuel injector components of the combustor is pursued in a variable-geometry two-dimensional test section over a range of combustor entrance conditions simulating the intended flight regime. The applicability of the two-dimensional test results to the axisymmetric engine is ensured by maintaining a proper simulation of combustor entrance conditions and preserving the actual length scale in the two-dimensional test configuration. An air-breathing pilot was developed and tested to evaluate flame stabilization and flame propagation characteristics. A pilot configuration was developed that operated stably, with minimal flow spillage, at exhaust stagnation temperatures as high as 4500 R with ethylene fuel. It was demonstrated that the pilot promotes efficient combustion of either gaseous ethylene or preheated liquid Jet-A (JP-5) when they are injected into the supersonic mainstream flow as primary fuels. For the tests with Jet-A fuel, the fuel was heated in an array of internal cooling passages within the pilot walls to a thermodynamic condition such that it would flash-vaporize upon injection into the mainstream flow. The idea of using the air-breathing pilot and distributed primary and secondary fuel injectors to achieve efficient supersonic combustion over a wide range of equivalence ratios was also experimentally demonstrated during the program. During staged fuel injection tests with gaseous ethylene fuel, high secondary fuel combustion efficiencies were achieved and smooth transitions from fully supersonic to dual mode (supersonic/subsonic) operation were demonstrated at high overall equivalence ratios.

Kay, Ira W.↗

FNAS/summer faculty fellowship research continuation program. Task 6: Integrated model development for liquid fueled rocket propulsion systems. Task 9: Aspects of model-based rocket engine condition monitoring and control

The objective of Phase I of this research effort was to develop an advanced mathematical-empirical model of SSME steady-state performance. Task 6 of Phase I is to develop component specific modification strategy for baseline case influence coefficient matrices. This report describes the background of SSME performance characteristics and provides a description of the control variable basis of three different gains models. The procedure used to establish influence coefficients for each of these three models is also described. Gains model analysis results are compared to Rocketdyne's power balance model (PBM).

Santi, L. Michael↗

Development of nuclear fuels and materials for propulsion systems for SEI

A panel was organized by NASA/DOE/DOD to study nuclear fuels, materials, and related nuclear propulsion technologies for SEI, and the panel findings are discussed. The fuels/materials requirements for nuclear thermal propulsion and nuclear electric propulsions are reviewed, and the development items such as 'element' development and characterization, fabrication process development, nuclear capsule tests, nuclear loop tests, and nuclear furnace tests are examined for selected classes of fuels.

Bhattacharyya, S. K.↗

Cryogenic Fuel Valve Testbed Development

The goal for this project is to update the cryogenic valve testbed program in LabVIEW to schedule and automate tests and experiments. By using an automated system, tens or hundreds of tests may be performed. This will ensure that accurate data is being collected for testing of the remaining useful life and end of life predictions. From the data obtained, new diagnostic and prognostic methods will be developed to manage or predict potential leaks which may occur in the future. The Cryogenic valve testbed injects controlled faults into the cryogenic fuel valve system in order to accurately determine failure behavior.

Prognostics↗

Full scale phosphoric acid fuel cell stack technology development

The technology development for phosphoric acid fuel cells is summarized. The preparation, heat treatment, and characterization of carbon composites used as bipolar separator plates are described. Characterization included resistivity, porosity, and electrochemical corrosion. High density glassy carbon/graphite composites performed well in long-term fuel cell endurance tests. Platinum alloy cathode catalysts and low-loaded platinum electrodes were evaluated in 25 sq cm cells. Although the alloys displayed an initial improvement, some of this improvement diminished after a few thousand hours of testing. Low platinum loading (0.12 mg/sq cm anodes and 0.3 mg/sq cm cathodes) performed nearly as well as twice this loading. A selectively wetproofed anode backing paper was tested in a 5 by 15 inch three-cell stack. This material may provide for acid volume expansion, acid storage, and acid lateral distribution.

Christner, L.↗

Gas cooled fuel cell systems technology development

The work performed during the Second Logical Unit of Work of a multi-year program designed to develop a phosphoric acid fuel cell (PAFC) for electric utility power plant application is discussed. The Second Logical Unit of Work, which covers the period May 14, 1983 through May 13, 1984, was funded by the U.S. Department of Energy, Office of Fossil Energy, Morgantown Energy Technology Center, and managed by the NASA Lewis Research Center.

Feret, J. M.↗

Strong, Tough Glass Composites Developed for Solid Oxide Fuel Cell Seals

A fuel cell is an electrochemical device that continuously converts the chemical energy of a fuel directly into electrical energy. It consists of an electrolyte, an anode, and a cathode. Various types of fuel cells are available, such as direct methanol fuel cells, alkaline fuel cells, proton-exchange-membrane fuel cells, phosphoric acid fuel cells, molten carbonate fuel cells, and solid oxide fuel cells (SOFCs). The salient features of an SOFC are all solid construction and high-temperature electrochemical-reaction-based operation, resulting in clean, efficient power generation from a variety of fuels. SOFCs are being developed for a broad range of applications, such as portable electronic devices, automobiles, power generation, and aeronautics.

Bansal, Narottam P.↗

Oxygen Reduction at PtNi Alloys in Direct Methanol Fuel Cells—Electrode Development and Characterization

Catalyst layers made from novel catalysts must be fabricated in a way that the catalyst can function to its full potential. To characterize a PtNi alloy catalyst for use in the cathode of Direct Methanol Fuel Cells (DMFCs), the effects of the manufacturing technique, ink composition, layer composition, and catalyst loading were here studied in order to reach the maximum performance potential of the catalyst. For a more detailed understanding, beyond the DMFCs performance measurements, we look at the electrochemically active surface area of the catalyst and charge-transfer resistance, as well as the layer quality and ink properties, and relate them to the aspects stated above. As a result, we make catalyst layers with optimized parameters by ultrasonic spray coating that shows the high performance of the catalyst even when containing less Pt than commercial products. Using this approach, we can adjust the catalyst layers to the requirements of DMFCs, hydrogen fuel cells, or polymer electrolyte membrane electrolysis cells.

30 DIRECT ENERGY CONVERSION↗

Technology development for phosphoric acid fuel cell powerplant, phase 2

The development of materials, cell components, and reformers for on site integrated energy systems is described. Progress includes: (1) heat-treatment of 25 sq cm, 350 sq cm and 1200 sq cm cell test hardware was accomplished. Performance of fuel cells is improved by using this material; (2) electrochemical and chemical corrosion rates of heat-treated and as-molded graphite/phenolic resin composites in phosphoric acid were determined; (3) three cell, 5 in. x 15 in. stacks operated for up to 10,000 hours and 12 in. x 17 in. five cell stacks were tested for 5,000 hours; (4) a three cell 5 in. x 15 in. stack with 0.12 mg Pt/sq cm anodes and 0.25 mg Pt/sq cm cathodes was operated for 4,500 hours; and (5) an ERC proprietary high bubble pressure matrix, MAT-1, was tested for up to 10,000 hours.

Christner, L.↗