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At least 289 records · Page 16

All sources NASA NTRS DOE OSTI

DOE OSTI2016

Wear resistance and friction reduction in acrylo nitrile butadiene rubber through hybrid combination of graphite flakes and nano tungsten disulphide

Friction and wear have considerable role in the life span of two interacting parts. Incorporation of nanofillers in polymers/elastomers matrix causes commendable changes in its tribologicalproperties. The main purpose of this work is to reduce the coefficient of friction and wear rate of Acrylo Nitrile Butadiene rubber (NBR). To achieve such objective traditionally well knownlubricants graphite(G), tungsten disulphide (WS{sub 2}) and there hybrid combination was incorporated in NBR matrix. Effect of applied load (force) and concentration of fillers on tribological properties of NBR had been studied. The filler incorporation enhanced the hardnessby 8%, showed resistance to hydraulic oil and aging effect also got improved significantly. A particular optimized concentration of NBR with hybrid combination of 2% WS{sub 2} and 4% Graphite showed minimum coefficient of friction as well as wear rate. A hypothesis could be attributed that similar lamellar structure of WS{sub 2} and Graphite along with formation of a stable nanoscale disulfide tribofilmcould result in lowering of friction. These substantially improved properties of nanoreinforced rubber materials would definitely pave promising path for plethora of potential technological applications.

36 MATERIALS SCIENCE↗

DOE OSTI2019

Electronic friction in interacting systems

We consider the effects of strong light-matter interaction on electronic friction in molecular junctions within the generic model of a single molecule nanocavity junction. Results of the Hubbard nonequilibrium Green function (NEGF) simulations are compared with mean-field NEGF and generalized Head-Gordon and Tully (HGT) approaches. Mean-field NEGF is shown to fail qualitatively at strong intrasystem interactions, while accuracy of the generalized HGT results is restricted to situations of well separated intramolecular excitations when bath induced coherences are negligible. Numerical results show effects of bias and cavity mode pumping on electronic friction. Here, we demonstrate nonmonotonic behavior of the friction on the bias and intensity of the pumping field and indicate possibility of engineering friction control in single molecule junctions.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

DOE OSTI2024

Protocol-dependent frictional granular jamming simulations: cyclical, compression, and expansion

Granular matter takes many paths to pack in natural and industrial processes. The path influences the packing microstructure, particularly for frictional grains. We perform discrete element modeling simulations of different paths to construct packings of frictional spheres. Specifically, we explore four stress-controlled protocols implementing packing expansions and compressions in various combinations thereof. We characterize the eventual packed states through their dependence of the packing fraction and coordination number on packing pressure, identifying non-monotonicities with pressure that correlate with the fraction of frictional contacts. These stress-controlled, bulk-like particle simulations access very low-pressure packings, namely, the marginally stable limit, and demonstrate the strong protocol dependence of frictional granular matter.

36 MATERIALS SCIENCE↗

DOE OSTI2024

Chloride-Induced Stress Corrosion Cracking of Friction Stir-Welded 304L Stainless Steel: Effect of Microstructure and Temperature

Dry storage canisters of used nuclear fuels are fabricated using SUS 304L stainless steel. Chloride-induced stress corrosion cracking (CISCC) is one of the major failure modes of dry storage canisters. The cracked canisters can be repaired by friction stir welding (FSW), a low-heat input ‘solid-phase’ welding process. It is important to evaluate the ClSCC resistance of the friction stir welded material. Stress corrosion cracking (SCC) studies were carried out on mill-annealed base materials and friction stir welded 304L stainless U-bend specimens in 3.5% NaCl + 5 N H2SO4 solution at room temperature and boiling MgCl2 solution at 155 °C. The engineering stress on the outer fiber of the FSW U-bend specimen was ~60% higher than that of the base metal (BM). In spite of the higher stress level of the FSW, both materials (FSW and BM) showed almost similar SCC failure times in the two different test solutions. The SCC occurred in the thermo-mechanically affected zone (TMAZ) of the FSW specimens in the 3.5% NaCl + 5 N H2SO4 solution at room temperature, while the stirred zone (SZ) was relatively crack-free. The failure occurred at the stirred zone when tested in the boiling MgCl2 solution. Hydrogen reduction was the cathodic reaction in the boiling MgCl2 solution, which promoted hydrogen-assisted cracking of the heavily deformed stirred zone. The emergence of the slip step followed by passive film rupture and dissolution of the slip step could be the SCC events in the 3.5% NaCl + 5 N H2SO4 solution at room temperature. However, the slip step height was not sufficient to cause passivity breakdown in the fine-grained SZ. Therefore, the SCC occurred in the partially recrystallized softer TMAZ. Overall, the friction-stirred 304L showed higher tolerance to ClSCC than the 304L base metal.

304L austenitic stainless steel↗

DOE OSTI2024

Additive Friction Stir Deposition of a Tantalum–Tungsten Refractory Alloy

Additive friction stir deposition (AFSD) is a solid-state metal additive manufacturing technique, which utilizes frictional heating and plastic deformation to create large deposits and parts. Much like its cousin processes, friction stir welding and friction stir processing, AFSD has seen the most compatibility and use with lower-temperature metals, such as aluminum; however, there is growing interest in higher-temperature materials, such as titanium and steel alloys. In this work, we explore the deposition of an ultrahigh-temperature refractory material, specifically, a tantalum–tungsten (TaW) alloy. The solid-state nature of AFSD means refractory process temperatures are significantly lower than those for melt-based additive manufacturing techniques; however, they still pose difficult challenges, especially in regards to AFSD tooling. In this study, we perform initial deposition trials of TaW using twin-rod-style AFSD with a high-temperature tungsten–rhenium-based tool. Many challenges arise because of the high temperatures of the process and high mechanical demand on AFSD machine hardware to process the strong refractory alloy. Despite these challenges, successful deposits of the material were produced and characterized. Mechanical testing of the deposited material shows improved yield strength over that of the annealed reference material, and this strengthening is mostly attributed to the refined recrystallized microstructure typical of AFSD. These findings highlight the opportunities and challenges associated with ultrahigh-temperature AFSD, as well as provide some of the first published insights into twin-rod-style AFSD process behaviors.

36 MATERIALS SCIENCE↗

NASA NTRS1996

Measurement of Gear Tooth Dynamic Friction

Measurements of dynamic friction forces at the gear tooth contact were undertaken using strain gages at the root fillets of two successive teeth. Results are presented from two gear sets over a range of speeds and loads. The results demonstrate that the friction coefficient does not appear to be significantly influenced by the sliding reversal at the pitch point, and that the friction coefficient values found are in accord with those in general use. The friction coefficient was found to increase at low sliding speeds. This agrees with the results of disc machine testing.

GEAR TEETH↗

NASA NTRS2024

Protocol Dependent Frictional Granular Jamming Simulations: Cyclical, Compression and Expansion

DEM↗

DOE OSTI2016

Two-sided friction stir riveting by extrusion: A process for joining dissimilar materials

Two-sided friction stir riveting (FSR) by extrusion is an innovative process developed to rapidly, efficiently, and securely join dissimilar materials. This process extends a previously developed one sided friction stir extrusion process to create a strong and robust joint by producing a continuous, rivet-like structure through a preformed hole in one of the materials with a simultaneous, two-sided friction stir spot weld. The two-sided FSR by extrusion process securely joins the dissimilar materials together and effectively locks them in place without the use of any separate materials or fasteners. Lastly, in this paper we demonstrate the process by joining aluminum to steel and illustrate its potential application to automotive and aerospace manufacturing processes.

36 MATERIALS SCIENCE↗

DOE OSTI2018

Tribological behavior prediction of friction materials for ultrasonic motors using Monte Carlo‐based artificial neural network

ABSTRACT In this article, the relationship of complexity, diversity, and uncertainty between components and tribological properties of friction materials based on a Monte Carlo‐based artificial neural network (MC‐ANN) model was predicted precisely. Meanwhile, the grey relational analysis was applied to figure out weight of factors, optimize formulation design, and calculate nonlinear dependency of ingredients. The accuracy of model was studied by comparing experimental and simulated values on the basis of statistical methods (root‐mean‐squared error). It was found that the model exhibited an excellent performance in predicting and fitting effect. Moreover, comprehensive analysis of weight indicated that nano‐SiO 2 and mica exerted a significant role in improving the friction stability and wear resistance. According to different contents of each ingredient, the corresponding friction coefficient and specific wear rate could be obtained by virtue of a well‐trained MC‐ANN model without experiments, which saved a lot of time and money. It can be expected that the results of this work will extend the current research and pave a route for further in‐depth studies of friction materials. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136 , 47157.

Li, Song↗

DOE OSTI2018

Parametric Modeling of AZ31-Mg Alloy Friction Stir Weld Temperature Histories

A parametric model of friction stir weld temperature histories is presented that uses constraint conditions, which are three-dimensional isothermal boundary conditions on the calculated temperature fields. This study describes further extension, with respect to formulation, of a parametric-modeling methodology, which is relatively optimal in terms of representation for application to friction stir welding and processing. These parametric representations of temperature histories can be used for modeling friction stir welds whose process conditions are similar to those in this study. Calculations of AZ31-Mg alloy friction stir weld temperature histories are presented, which use temperature-field constraint conditions based on measured weld cross sections and a model for the estimation of weld stir zone temperatures.

36 MATERIALS SCIENCE↗

DOE OSTI2018

Investigation of the influence of frictional viscosity regularization on quasi-static gas-solid flow predictions in a conical spouted bed with non-porous draft tube

The stress in the quasi-static particle flow is often modeled through the Mohr-Coulomb failure criterion. In the extension to complex three-dimensional flows, a granular viscosity is introduced through a tensorial rheology and the deviatoric frictional stress tensor is assumed aligned with the strain rate tensor. This granular viscosity is singular as the shear rate approaches zero, regardless of the local rheology. We discuss the influence of regularizing such a frictional viscosity on the particle circulation rate and other measured characteristics in a laboratory scale draft tube spouted bed. Here, the friction between particles is modeled either with a constant Coulomb rheology or using a local particle pressure and strain-rate based friction known as μ ( I )-rheology. The predictions appear very dependent on the regularization parameter introduced by the method. The mean properties of the flow (e.g. circulation and pressure drop) monotonically converge towards the measurements when the regularization parameter tends to zero. In other respects, the two regularization models regarded in this study induced similar hydrodynamics within the spouted bed of interest. But the analysis of the conditional averages of the inertial number and the fraction of the solids in the quasi-static regime shows that the extent and staticity of the quasi-static region is sensitive to changes to the regularization parameter or regularization function.

36 MATERIALS SCIENCE↗

DOE OSTI2018

Lateral bearing capacity of hybrid monopile-friction wheel foundation for offshore wind turbines by centrifuge modelling

The hybrid monopile-friction wheel foundation is an innovative alternative for offshore wind turbines. The concept has wider adaptability and can be used as reinforcement method for existing monopiles. A series of centrifuge tests was performed to investigate the lateral bearing capacities of the hybrid foundation under monotonic loads. Five foundation models and two soil types were considered. According to the recorded responses, the hybrid foundation demonstrated better lateral behaviors that both lateral bearing capacity and stiffness are enhanced. Two analytical methods were proposed and compared with the centrifuge test results. The bearing capacity of the hybrid foundation is smaller than the sum of individual pile and friction wheel, and a reduction factor is suggested for both friction wheels. The friction wheel restrains rotations of monopile and provides extra restoring moments; their effects are idealized as equivalent moments acting on the pile head. The analytical results provide possible solutions in estimating the lateral bearing capacity of the innovative hybrid foundation system for offshore wind turbines by using traditional theories.

17 WIND ENERGY↗

DOE OSTI2016

Friction behavior of a multi-interface system and improved performance by AlMgB 14 –TiB 2 –C and diamond-like-carbon coatings

We investigated friction behavior of a bearing system with two interfaces involved: a roller component experiencing rolling–sliding interaction against twin cylinders under point contacts while simultaneously undergoing pure sliding interaction against a socket under a conformal contact. Lubrication modeling predicted a strong correlation between the roller's rolling condition and the system's friction behavior. Experimental observations first validated the analytical predictions using steel and iron components. Diamond-like-carbon (DLC) coating and AlMgB 14 –TiB 2 coating with a carbon topcoat (BAMC) were then applied to the roller and twin cylinders, respectively. In conclusion, testing and analysis results suggest that the coatings effectively decreased the slip ratio for the roller–cylinder contact and the sliding friction at both bearing interfaces and, as a result, significantly reduced the system frictional torque.

42 ENGINEERING↗

DOE OSTI2022

On the enhancement of boundary layer skin friction by turbulence: an angular momentum approach

Turbulence enhances the wall shear stress in boundary layers, significantly increasing the drag on streamlined bodies. Other flow features such as free stream pressure gradients and streamwise boundary layer growth also strongly influence the local skin friction. In this paper, an angular momentum integral (AMI) equation is introduced to quantify these effects by representing them as torques that alter the shape of the mean velocity profile. This approach uniquely isolates the skin friction of a Blasius boundary layer in a single term that depends only on the Reynolds number most relevant to the flow's engineering context, so that other torques are interpreted as augmentations relative to the laminar case having the same Reynolds number. The AMI equation for external flows shares this key property with the so-called FIK relation for internal flows (Fukagata et al. , Phys. Fluids , vol. 14, 2002, pp. L73–L76). Without a geometrically imposed boundary layer thickness, the length scale in the Reynolds number for the AMI equation may be chosen freely. After a brief demonstration using Falkner–Skan boundary layers, the AMI equation is applied as a diagnostic tool on four transitional and turbulent boundary layer direct numerical simulation datasets. Regions of negative wall-normal velocity are shown to play a key role in limiting the peak skin friction during the late stages of transition, and the relative strengths of terms in the AMI equation become independent of the transition mechanism a very short distance into the fully turbulent regime. The AMI equation establishes an intuitive, extensible framework for interpreting the impact of turbulence and flow control strategies on boundary layer skin friction.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

DOE OSTI2022

Transient evolution of permeability and friction in a slowly slipping fault activated by fluid pressurization

The mechanisms of permeability and friction evolution in a natural fault are investigated in situ. During three fluid injection experiments at different places in a fault zone, we measured simultaneously the fluid pressure, fault displacements and seismic activity. Changes in fault permeability and friction are then estimated concurrently. Results show that fault permeability increases up to 1.58 order of magnitude as a result of reducing effective normal stress and cumulative dilatant slip, and 19-to-60.8% of the enhancement occurs without seismic emissions. When modeling the fault displacement, we found that a rate-and-state friction and a permeability dependent on both slip and slip velocity together reasonably fit the fault-parallel and fault-normal displacements. This leads to the conclusion that the transient evolution of fault permeability and friction caused by a pressure perturbation exerts a potentially dominant control on fault stability during fluid flow.

58 GEOSCIENCES↗

DOE OSTI2022

Relation between interfacial shear and friction force in 2D materials

Understanding the interfacial properties between an atomic layer and its substrate is of key interest at both the fundamental and technological levels. From Fermi level pinning to strain engineering and superlubricity, the interaction between a single atomic layer and its substrate governs electronic, mechanical and chemical properties. Here, we measure the hardly accessible interfacial transverse shear modulus of an atomic layer on a substrate. By performing measurements on bulk graphite, and on epitaxial graphene films on SiC with different stacking orders and twisting, as well as in the presence of intercalated hydrogen, we find that the interfacial transverse shear modulus is critically controlled by the stacking order and the atomic layer–substrate interaction. Importantly, we demonstrate that this modulus is a pivotal measurable property to control and predict sliding friction in supported two-dimensional materials. The experiments demonstrate a reciprocal relationship between friction force per unit contact area and interfacial shear modulus. As a result, the same relationship emerges from simulations with simple friction models, where the atomic layer– substrate interaction controls the shear stiffness and therefore the resulting friction dissipation.

36 MATERIALS SCIENCE↗

DOE OSTI2019

Enhancement of oil flow in shale nanopores by manipulating friction and viscosity

We report that understanding the viscosity and friction of a fluid under nanoconfinement is the key to nanofluidics research. Existing work on nanochannel flow enhancement has been focused on simple systems with only one to two fluids considered such as water flow in carbon nanotubes, and large slip lengths have been found to be the main factor for the massive flow enhancement. In this study, we use molecular dynamics simulations to study the fluid flow of a ternary mixture of octane–carbon dioxide–water confined within two muscovite and kerogen surfaces. The results indicate that, in a muscovite slit, supercritical CO 2 (scCO 2 ) and H 2 O both enhance the flow of octane due to (i) a decrease in the friction of octane with the muscovite wall because of the formation of thin layers of H 2 O and scCO 2 near the surfaces; and (ii) a reduction in the viscosity of octane in nanoconfinement. Water reduces octane viscosity by weakening the interaction of octane with the muscovite surface, while scCO 2 reduces octane viscosity by weakening both octane–octane and octane–surface interactions. In a kerogen slit, water does not play any significant role in changing the friction or viscosity of octane. In contrast, scCO 2 reduces both the friction and the viscosity of octane, and the enhancement of octane flow is mainly caused by the reduction of viscosity. In conclusion, our results highlight the importance of multicomponent interactions in nanoscale fluid transport. The results presented here also have a direct implication in enhanced oil recovery in unconventional reservoirs.

58 GEOSCIENCES↗

DOE OSTI2016

A many-body states picture of electronic friction: The case of multiple orbitals and multiple electronic states

We present a very general form of electronic friction as present when a molecule with multiple orbitals hybridizes with a metal electrode. To develop this picture of friction, we embed the quantum-classical Liouville equation (QCLE) within a classical master equation (CME). Thus, this article extends our previous work analyzing the case of one electronic level, as we may now treat the case of multiple levels and many electronic molecular states. We show that, in the adiabatic limit, where electron transitions are much faster than nuclear motion, the QCLE-CME reduces to a Fokker-Planck equation, such that nuclei feel an average force as well as friction and a random force—as caused by their interaction with the metallic electrons. Finally, we show numerically and analytically that our frictional results agree with other published results calculated using non-equilibrium Green’s functions. Numerical recipes for solving this QCLE-CME will be provided in a subsequent paper.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗