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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 289 records · Page 16
All sourcesNASA NTRSDOE OSTI
NASA NTRS2007

High-Power, High-Efficiency Ka-Band Space Traveling-Wave Tube

The L-3 Communications Model 999H traveling-wave tube (TWT) has been demonstrated to generate an output power of 144 W at 60-percent overall efficiency in continuous-wave operation over the frequency band from 31.8 to 32.3 GHz. The best TWT heretofore commercially available for operation in the affected frequency band is characterized by an output power of only 35 W and an efficiency of 50 percent. Moreover, whereas prior TWTs are limited to single output power levels, it has been shown that the output power of the Model 999H can be varied from 54 to 144 W. A TWT is a vacuum electronic device used to amplify microwave signals. TWTs are typically used in free-space communication systems because they are capable of operating at power and efficiency levels significantly higher than those of solid-state devices. In a TWT, an electron beam is generated by an electron gun consisting of a cathode, focusing electrodes, and an anode. The electrons pass through a hole in the anode and are focused into a cylindrical beam by a stack of periodic permanent magnets and travel along the axis of an electrically conductive helix, along which propagates an electromagnetic wave that has been launched by an input signal that is to be amplified. The beam travels within the helix at a velocity close to the phase velocity of the electromagnetic wave. The electromagnetic field decelerates some of the electrons and accelerates others, causing the beam to become formed into electron bunches, which further interact with the electromagnetic wave in such a manner as to surrender kinetic energy to the wave, thereby amplifying the wave. The net result is to amplify the input signal by a factor of about 100,000. After the electrons have passed along the helix, they impinge on electrodes in a collector. The collector decelerates the electrons in such a manner as to recover most of the remaining kinetic energy and thereby significantly increase the power efficiency of the TWT.

Krawczyk, Richard↗
DOE OSTI2022

Symmetry of Cosmological Observables, a Mirror World Dark Sector, and the Hubble Constant

We find that a uniform scaling of the gravitational free-fall rates and photon-electron scattering rate leaves most dimensionless cosmological observables nearly invariant. This result opens up a new approach to reconciling cosmic microwave background and large-scale structure observations with high values of the Hubble constant H0: Find a cosmological model in which the scaling transformation can be realized without violating any measurements of quantities not protected by the symmetry. A “mirror world” dark sector allows for effective scaling of the gravitational free-fall rates while respecting the measured mean photon density today. Further model building might bring consistency with the two constraints not yet satisfied: the inferred primordial abundances of deuterium and helium.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS2022

Solar Flare Heating with Turbulent Suppression of Thermal Conduction

During solar flares plasma is typically heated to very high temperatures, and the resulting redistribution of energy via thermal conduction is a primary mechanism transporting energy throughout the flaring solar atmosphere. The thermal flux is usually modeled using Spitzer’s theory, which is based on local Coulomb collisions between the electrons carrying the thermal flux and those in the background. However, often during flares, temperature gradients become sufficiently steep that the collisional mean free path exceeds the temperature gradient scale size, so that thermal conduction becomes inherently non-local. Further, turbulent angular scattering, which is detectable in nonthermal widths of atomic emission lines, can also act to increase the collision frequency and so suppress the heat flux. Recent work by Emslie & Bian (2018) extended Spitzer’s theory of thermal conduction to account for both non-locality and turbulent suppression. We have implemented their theoretical expression for the heat flux (which is a convolution of the Spitzer flux with a kernel function) into the RADYN flare-modeling code and performed a parameter study to understand how the resulting changes in thermal conduction affect flare dynamics and hence the radiation produced. We find that models with reduced heat fluxes predict slower bulk flows, less intense line emission, and longer cooling times. By comparing features of atomic emission lines predicted by the models with Doppler velocities and nonthermal line widths deduced from a particular flare observation, we find that models with suppression factors between 0.3 to 0.5 relative to the Spitzer value best reproduce observed Doppmission lines forming over a wide range of temperatures. Interestingly, the model that best matches observed nonthermal line widths has a kappa-type velocity distribution function.

Joel C. Allred↗
NASA NTRS2022

Solar Flare Heating with Turbulent Suppression of Thermal Conduction

During solar flares plasma is typically heated to very high temperatures, and the resulting redistribution of energy via thermal conduction is a primary mechanism transporting energy throughout the flaring solar atmosphere. The thermal flux is usually modeled using Spitzer’s theory, which is based on local Coulomb collisions between the electrons carrying the thermal flux and those in the background. However, often during flares, temperature gradients become sufficiently steep that the collisional mean free path exceeds the temperature gradient scale size, so that thermal conduction becomes inherently non-local. Further, turbulent angular scattering, which is detectable in nonthermal widths of atomic emission lines, can also act to increase the collision frequency and so suppress the heat flux. Recent work by Emslie & Bian (2018) extended Spitzer’s theory of thermal conduction to account for both non-locality and turbulent suppression. We have implemented their theoretical expression for the heat flux (which is a convolution of the Spitzer flux with a kernel function) into the RADYN flare-modeling code and performed a parameter study to understand how the resulting changes in thermal conduction affect flare dynamics and hence the radiation produced. We find that models with reduced heat fluxes predict slower bulk flows, less intense line emission, and longer cooling times. By comparing features of atomic emission lines predicted by the models with Doppler velocities and nonthermal line widths deduced from a particular flare observation, we find that models with suppression factors between 0.3 to 0.5 relative to the Spitzer value best reproduce observed Doppler velocities across emission lines forming over a wide range of temperatures. Interestingly, the model that best matches observed nonthermal line widths has a kappa-type velocity distribution function

Solar flares↗
NASA NTRS2011

Capacitor Test, Evaluation. and Modeling Within NASA Electronic Parts and Packaging (NEPP) Program. "Why Ceramic Capacitors Fracture During Manual Soldering and How to Avoid Failures"

Presentation discusses: (1) Why Multi-Layer Ceramic Capacitors(MLCCs) crack during manual soldering? Workmanship and parts issues. (2) Do existing qualification requirements assure crack-free soldering? MIL-spec Thermal Shock (TS) testing. MIL-spec Resistance to Soldering Heat (RSH) test. (3) What test can assure reliable soldering? Mechanical characteristics of ceramics. Comparison of three TS techniques: LND, TSD, and IWT. (4) Simulation of TS conditions.

Teverovsky, Alexander↗
NASA NTRS1994

Model images of radio halos around supernova remnants

I present model calculations of profiles and two-dimensional images of the radio synchrotron emission of young supernova remnants, concentrating on observable effects of relativistic eletrons diffusing upstream of the shock wave. If the preshock electron scattering mean free path is sufficiently long, observable synchrotron halos outside the bulk of the radio emission can potentially result; their absence can constrain the mean free path from above. If scattering is primarily due, as expected, to Alfven waves with amplitude detla(B), the halo is expected to extend a distance of order r(sub g)c(delta(B)/B)(exp 2)/v(sub s) beyond the shock, where r(sub g) is the gyroradius of the electrons emitting at the observed frequency, B is the upstream magnetic field strength, v(sub s) is the shock velocity, and the amplitude delta(B) refers to wave with wavelength comparable to r(sub g), of order 10(exp 13) cm for typical supernova-remnant parameters. However, the detailed geometry of the halo varies with the assumptions about particle acceleration in the shock wave. I present an atlas of model profiles and images as a function of preshock diffusion length, of aspect angle between the magnetic field and the line of sight, and of other relevant parameters.

Reynolds, Stephen P.↗
DOE OSTI2025

Sulfate Promotes Compact CaCO 3 Formation and Protects Portland Cement from Supercritical CO 2 Attack

Supercritical (sc) CO 2 in geologic carbon sequestration (GCS) can chemically and mechanically deteriorate wellbore cement, raising concerns for long-term operations. In contrast to the conventional view of “sulfate attack” on cement, we found that adding 0.15 M sulfate to the acidic brine can significantly reduce the impact of scCO 2 attack on Portland cement, resulting in stronger cement than that found in a sulfate-free system. Scanning electron microscopy revealed a decreased total attack depth in reacted cement in the presence of sulfate. With a newly defined minimum porosity term in reactive transport modeling, our model suggests that sulfate caused CaCO 3 to fill more nanopore spaces in the cement. Small angle X-ray scattering experiments also showed that sulfate can decrease the pore sizes of the carbonate layer. The results suggest that the interactions between sulfate and cement can generate a less porous CaCO 3 layer, which better resists acidic brine. Using this mechanism as a proof-of-concept, we tested the incorporation of sodium sulfate into Portland cement and synthesized new cement composites that show stronger resistance against scCO 2 attacks. Finally, these newly discovered interfacial interactions between CaCO 3 and sulfate provide new insights into engineering mechanically strong and green materials for safer GCS.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2020

Dark Photon Oscillations in Our Inhomogeneous Universe

A dark photon kinetically mixing with the ordinary photon represents one of the simplest viable extensions to the standard model, and would induce oscillations with observable imprints on cosmology. Oscillations are resonantly enhanced if the dark photon mass equals the ordinary photon plasma mass, which tracks the free electron number density. Previous studies have assumed a homogeneous Universe; in this Letter, we introduce for the first time an analytic formalism for treating resonant oscillations in the presence of inhomogeneities of the photon plasma mass. We apply our formalism to determine constraints from cosmic microwave background photons oscillating into dark photons, and from heating of the primordial plasma due to dark photon dark matter converting into low-energy photons. Including the effect of inhomogeneities demonstrates that prior homogeneous constraints are not conservative, and simultaneously extends current experimental limits into a vast new parameter space.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2026

Design of monolithic piezoelectric bimorph mirrors made from lithium niobate

Recent advances in deformable mirrors based on monolithic piezoelectric substrates, such as lithium niobate, have the potential to improve the image quality of X-ray optical systems on synchrotron and free-electron laser beamlines and microscopes. However, the quantitative relationship between design parameters and the deformed shape has not been readily available in the literature. We present an analytical model, validated through finite element analysis, enabling calculation of tangential and sagittal curvatures based on mirror dimensions, crystallographic orientation, and applied voltage. We demonstrate that through the selection of material orientation, it is possible to achieve different deformed shapes (sphere, cylinder, or hyperbolic paraboloid). This methodology can be generalized to other piezoelectric materials and substrate-integrated actuator systems.

Marzari, Francesco [University of Trento (Italy); ↗
NASA NTRS1991

Tables of model atmospheres of bursting neutron stars

This paper presents tables of plane-parallel neutron star model atmospheres in radiative and hydrostatic equilibrium, with effective temperatures of 8 x 10 exp 6, 1.257 x 10 exp 7, 2 x 10 exp 7, and 3 x 10 exp 7 K, and surface gravities of 15.0 and less (cgs units). The equations of model atmospheres on which the tables are based fully account for nonisotropies of the radiation field and effects of noncoherent Compton scattering of thermal X-rays by free electrons. Both the effective temperatures and gravities listed above are measured on the neutron star surface.

Madej, Jerzy↗
NASA NTRS2004

Ionization Cross Sections and Dissociation Channels of the DNA Sugar-Phosphate Backbone by Electron Collisions

It has been suggested that the genotoxic effects of ionizing radiation in living cells are not caused by the highly energetic incident radiation, but rather are induced by less energetic secondary species generated, the most abundant of which are free electrons.' The secondary electrons will further react to cause DNA damage via indirect and direct mechanisms. Detailed knowledge of these mechanisms is ultimately important for the development of global models of cellular radiation damage. We are studying one possible mechanism for the formation cf DNA strand breaks involving dissociative ionization of the DNA sugar-phosphate backbone induced by secondary electron co!lisions. We will present ionization cross sections at electron collision energies between threshold and 10 KeV using the improved binary encounter dipole (iBED) formulation' Preliminary results of the possible dissociative ionization pathways will be presented. It is speculated that radical fragments produced from the dissociative ionization can further react, providing a possible mechanism for double strand breaks and base damage.

Dateo, Christopher↗
DOE OSTI2022

Dynamic Measurements of the Structural Evolution of Material Defects at the Mesoscale

This is a technical report to be published as part of the FY2021 annual overview package. We have designed experiments and developed analytical methods using images from x-ray and electron microscopy in order to quantify the behavior of crystal dislocation defects at their native nanometer-length and micro-length scales. The results of these analyses are used to directly inform theoretical physics models and guide interpretation of dark field x-ray microscopy (DFXM) images that offer spatial resolution surpassing the resolution of beamline optics. Additionally, we developed new analytical methods to automate the alignment of optics hardware used in both synchrotron and x-ray free electron laser beamline facilities. The tools and workflows developed for this project are now being deployed as proof-of-concept in reaction history analysis (RHA) for future programmatic integration.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
NASA NTRS1995

An empirical determination of the polytropic index for the free-streaming solar wind using Helios 1 data

Observations of solar wind proton temperatures indicate that the solar wind is heated as it moves outward toward the orbit of Earth. This heating, which may be the results of electron heat conduction and perhaps MHD waves, has proven difficult to quantify and hence is often neglected in MHD models of the solar wind. An alternate approach to finding explicit heating terms for the MHD energy equation is to use a polytropic approximation. This paper discusses the properties of the polytropic approximation and its application to the solar wind plasma. By using data from the Helios 1 spacecraft, an empirical value for the polytropic index of the free-streaming solar wind is determined. Various corrections to the data are made to account for velocity, nonuniformity in radial sampling, and stream interaction regions. The polytropic index, as derived from proton data, is found to indepedent of speed state, within statistical error, and has an average value of 1.46. If magnetic pressure is included, the polytropic index has an average value of 1.58.

Totten, T. L.↗
DOE OSTI2025

The structure of liquid carbon elucidated by in situ X-ray diffraction

Carbon has a central role in biology and organic chemistry, and its solid allotropes provide the basis of much of our modern technology. However, the liquid form of carbon remains nearly uncharted, and the structure of liquid carbon and most of its physical properties are essentially unknown. But liquid carbon is relevant for modelling planetary interiors and the atmospheres of white dwarfs, as an intermediate state for the synthesis of advanced carbon materials, inertial confinement fusion implosions, hypervelocity impact events on carbon materials and our general understanding of structured fluids at extreme conditions. Here we present a precise structure measurement of liquid carbon at pressures of around 1 million atmospheres obtained by in situ X-ray diffraction at an X-ray free-electron laser. Our results show a complex fluid with transient bonding and approximately four nearest neighbours on average, in agreement with quantum molecular dynamics simulations. The obtained data substantiate the understanding of the liquid state of one of the most abundant elements in the universe and can test models of the melting line. The demonstrated experimental abilities open the path to performing similar studies of the structure of liquids composed of light elements at extreme conditions.

74 ATOMIC AND MOLECULAR PHYSICS↗
DOE OSTI2026

Transfer Learning Meets Embedded Correlated Wavefunction Theory for Chemically Accurate Molecular Simulations: Application to Calcium Carbonate Ion Pairing

Achieving chemical accuracy for molecular simulations remains a central challenge in computational chemistry. Here, we present an embedded correlated wavefunction transfer learning (ECW-TL) framework for accurately simulating molecular dynamics in the condensed phase. ECW-TL incorporates high-level electron exchange and correlation effects in ECW theory while preserving the training and computational efficiency of machine-learned interatomic potentials. We demonstrate the framework on Ca 2+ –CO 3 2– ion pairing in aqueous solution, a key process underlying CO 2 mineralization in seawater. As proof of principle, we first show that fine-tuning a DFT-revPBE-D3(BJ) baseline model with embedded-DFT-SCAN data reproduces the DFT-SCAN free-energy surface within 1 kcal/mol across all solvation states. Extending the framework to embedded MP2 and localized natural-orbital CCSD(T) further refines the free-energy profile, revealing the crucial role of exact electron exchange and correlation in determining ion-pair stability and structure. The computed ion-pair association free energy is in quantitative agreement with experimental measurements, further validating the accuracy of the ECW-TL framework. ECW-TL thus provides a general, data-efficient route for transferring CW accuracy to efficient simulations of complex aqueous and interfacial chemical processes.

cluster chemistry↗
DOE OSTI2026

NiFeCo-based catalysts in high current zero-gap anion exchange membrane water electrolyzers

Understanding degradation mechanisms in pure water anion exchange membrane water electrolyzers is essential for developing durable and precious metal-free hydrogen production systems, yet electronic, chemical, and transport-driven pathways often occur simultaneously at the anode. To separate these effects, we establish a morphology invariant Ni/Fe/Co thin film model catalyst platform using physical vapor deposition and systematically compare composition-dependent behavior under both pure water and 0.1 M KOH feeds. Devices were operated under industrially relevant current density conditions, galvanostatically at 1 A cm −2 for 24 hours; metal dissolution, ionomer oxidation, and resistance growth were quantified using inductively coupled plasma mass spectrometry, X-ray photoelectron spectroscopy (XPS), and electrochemical impedance spectroscopy. Under pure-water operation, Ni-rich films showed voltage increases that correlated with rising total cell resistance (ΔV ≈ 243 mV, ΔR ≈ 0.17 Ω cm 2 ). Co-rich films maintained near constant voltages with minimal resistance change (ΔV < 10 mV, ΔR ≈ 0.03 Ω cm 2 ) but induced pronounced ionomer oxidation observed by XPS. In 0.1 M KOH, ionomer oxidation is suppressed, and impedance growth is minimized (<0.08 Ω cm 2 ) across all compositions, consistent with reduced transport limitations and improved ionic conduction relative to pure-water feeds. These results demonstrate how a controlled thin film model platform can isolate composition electrolyte relationships and provide mechanistic design principles for stable pure water anion exchange membrane electrolyzers.

Milenia Rojas Mendoza, B. [Stanford Univ., CA (Uni↗
DOE OSTI2022

First-principles equation of state of CHON resin for inertial confinement fusion applications

A wide-range (0 to 1044.0 g/ cm 3 and 0 to 10 9 K) equation-of-state (EOS) table for a CH 1.72 O 0.37 N 0.086 quaternary compound has been constructed based on density-functional theory (DFT) molecular-dynamics (MD) calculations using a combination of Kohn-Sham DFT MD, orbital-free DFT MD, and numerical extrapolation. The first-principles EOS data are compared with predictions of simple models, including the fully ionized ideal gas and the Fermi-degenerate electron gas models, to chart their temperature-density conditions of applicability. The shock Hugoniot, thermodynamic properties, and bulk sound velocities are predicted based on the EOS table and compared to those of C-H compounds. The Hugoniot results show the maximum compression ratio of the C-H-O-N resin is larger than that of CH polystyrene due to the existence of oxygen and nitrogen; while the other properties are similar between CHON and CH. Radiation hydrodynamic simulations have been performed using the table for inertial confinement fusion targets with a CHON ablator and compared with a similar design with CH. Here, the simulations show CHON outperforms CH as the ablator for laser-direct-drive target designs.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1975

Propagation of acoustic modes in the transitional ionosphere

Continuum theory is unsatisfactory for describing wave propagation in the transitional ionosphere, since the mean free path is of the same order as the characteristic length (i.e., Knudsen number in this region is of the order of unity). Therefore a transition model in which isotropic electrons behave as a fluid while the ions are governed by the kinetic equation modified by ion-electron collision effects is proposed to study acoustic wave propagation in the upper atmosphere in the altitude region from 500 to 2000 km. The results show that the dissipation of acoustic waves by electrons is through the viscous and thermal conduction effects, and the dissipation of acoustic waves by ions is through Landau damping. Comparisons of the characteristics of acoustic mode propagation and wave dissipation mechanisms in the collision-dominated, transitional from collisional to collisionless, and collisionless media are also discussed.

Hung, R. J.↗