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All sourcesNASA NTRSDOE OSTI
NASA NTRS1999

Combustion of Metals in Reduced-Gravity and Extraterrestrial Environment

As a result of the ongoing exploration of Mars and the several unmanned and manned missions planned for the future, increased attention has been given to the use of the natural resources of the planet for rocket propellant production and energy generation. Since the atmosphere of Mars consists of approximately 95% carbon dioxide (CO2), this gas is the resource of choice to be employed for these purposes. Unfortunately, CO2 is also a final product in most combustion reactions, requiring further processing to extract useful reactants such as carbon monoxide (CO), oxygen (O2), and hydrocarbons. An exception is the use Of CO2 as an oxidizer reacting directly with metal fuel. Since many metals burn vigorously with CO2, these may be used as an energy source and as propellants for an ascent/descent vehicle in sample-collection missions on Mars. In response to NASA's Human Exploration and Development of Space (HEDS) Enterprise to search for appropriate in-situ resource utilization techniques, this investigation will study the burning characteristics of promising metal/CO2 combinations. The use of reduced gravity is essential to eliminate the intrusive buoyant flows that plague the high-temperature metal reactions, to remove the destructive effect of gravity on the shape of molten metal samples, and to study the influence of radiative heat transfer from solid oxides undisturbed by natural convection. In studies with large metal specimens, the burning process is invariably influenced by strong convective currents that accelerate the reaction and shorten the burning times. Although these currents are nearly absent from small burning particles, the high emissivity of the flames, rapid reaction, small length scales, and intermittent explosions make the gathering of any useful information on burning rates and flame structure very difficult. This investigation has the ultimate goal of providing a careful probing of flame structure and dynamics by taking advantage of large, free-floating spherical metal samples and their corresponding long burning times available in reduced gravity. The first set of experiments has been conducted with magnesium (Mg) samples burning in the low-gravity environment generated by an aircraft flying parabolic trajectories. Owing to its high adiabatic flame temperature, oxidizer/fuel ratio, and heat per unit mass of fuel, as well as its low toxicity and low ignition temperature, Mg has been identified as a promising metal fuel with CO2 as oxidizer. The experimental effort is complemented by the development of a numerical model combining gas-phase chemical kinetics and transport mechanisms.

Abbud-Madrid, A.↗
NASA NTRS1996

Titan's 5 micrometers spectral window: carbon monoxide and the albedo of the surface

We have measured the spectrum of Titan near 5 micrometers and have found it to be dominated by absorption from the carbon monoxide 1-0 vibration-rotation band. The position of the band edge allows us to constrain the abundance of CO in the atmosphere and/or the location of the reflecting layer in the atmosphere. In the most likely case, 5 micrometers radiation is reflected from the surface and the mole fraction of CO in the atmosphere is qCO=10(+10/-5) ppm, significantly lower than previous estimates for tropospheric CO. The albedo of the reflecting layer is approximately 0.07(+0.02/-0.01) in the 5 micrometers continuum outside the CO band. The 5 micrometers albedo is consistent with a surface of mixed ice and silicates similar to the icy Galilean satellites. Organic solids formed in simulated Titan conditions can also produce similar albedos at 5 micrometers.

Saturn↗
NASA NTRS2002

Racemic amino acids from the ultraviolet photolysis of interstellar ice analogues

The delivery of extraterrestrial organic molecules to Earth by meteorites may have been important for the origin and early evolution of life. Indigenous amino acids have been found in meteorites-over 70 in the Murchison meteorite alone. Although it has been generally accepted that the meteoritic amino acids formed in liquid water on a parent body, the water in the Murchison meteorite is depleted in deuterium relative to the indigenous organic acids. Moreover, the meteoritical evidence for an excess of laevo-rotatory amino acids is hard to understand in the context of liquid-water reactions on meteorite parent bodies. Here we report a laboratory demonstration that glycine, alanine and serine naturally form from ultraviolet photolysis of the analogues of icy interstellar grains. Such amino acids would naturally have a deuterium excess similar to that seen in interstellar molecular clouds, and the formation process could also result in enantiomeric excesses if the incident radiation is circularly polarized. These results suggest that at least some meteoritic amino acids are the result of interstellar photochemistry, rather than formation in liquid water on an early Solar System body.

Amino Acids/chemistry↗
NASA NTRS2017

Treatment of Solid Rocket Motors that Complies with Established Protocols to Ensure Planetary Protection

This presentation discusses recent work being conducted by the National Aeronautics and Space Administration (NASA) at Marshall Space Flight Center (MSFC) to evaluate various methods that could be employed to provide for planetary protection of those solar system bodies that are candidates for extraterrestrial life, thus preventing contamination of such bodies. MSFC is presently involved in the development phase of the Europa Lander De-Orbital Stage (DOS) braking motor. In order to prevent bio-contamination of this Jovian satellite, three paths are currently being considered. The first is (1) Bio-Reduction of those microscopic organisms in or on the vehicle (in this case a solid rocket motor (SRM)) that might otherwise be transported during the mission. Possible methods being investigated include heat sterilization, application or incorporation of biocide materials, and irradiation. While each method can be made to work, effects on the SRM's components (propellant, liner, insulation, etc.) could well prove deleterious. A second path would be use of (2) Bio-Barrier material(s). So long as such barrier(s) can maintain their integrity, planetary protection should be afforded. Under the harsh conditions encountered during extended spaceflight (vacuum, temperature extremes, radiation), however, such barrier(s) could well experience a breach. Finally, a third path would be to perform (3) Pyrotechnic Sterilization of the SRM during its end-of-mission phase. Multiple pyrotechnic units would be triggered to ensure activation of such an event and provide for a final sterilization before vehicle impact. In light of Europa's stringent bio-reduction targets, the final and best choice to minimize risk will probably be some combination of the above.

Stefanski, Philip L.↗
NASA NTRS2018

Aerothermodynamics for Dragonfly's Titan Entry

Dragonfly is a proposed spacecraft and mission that would send a mobile robotic rotorcraft lander to Titan, the largest moon of Saturn, in order to study prebiotic chemistry and extraterrestrial habitability at various locations. Titan is unique in having an abundant, complex, and diverse carbon-rich chemistry on the surface of a water-ice-dominated world with an interior water ocean, making it a high priority target for astrobiology and origin of life studies. The mission was initially proposed in April 2017 to NASA's New Frontiers program by the Johns Hopkins Applied Physics Laboratory. In December 2017, it was selected as one of two finalists (out of twelve proposals) to further refine the mission's concept. NASA Ames Research Center and NASA Langley Research Center are partnering as the leads for the Dragonfly's entry system to provide the completed EDL Assembly. The aerothermal analysis for Dragonfly utilizes four simulation tools from NASA Ames Research Center. Traj for calculating the trajectory, DPLR 4.04.0 for calculating the flowfield around the vehicle and convective heating, NEQAIR V15.0 for calculating the radiative heating, and FIAT for calculating the material response and thermal protection system (TPS) sizing for the heatshield. The entry conditions are relatively benign and can readily be accommodated with a tiled PICA heatshield similar to MSL and a number of flight proven materials for the backshell. This work will demonstrate that the aerothermal entry environments can be readily solved using heritage materials and techniques.

New Frontiers↗
NASA NTRS2018

N2 Chemistry in Interstellar and Planetary Ices: Radiation-Driven Oxidation

As part of our work on nitrogen-rich ices, the IR spectra and band strengths used in a recent paper to identify and quantify radiation-induced changes in an N2+H2O ice near 15 K are examined, along with reports of (i) a chemical tracer for N2+H2O ices, (ii) a new IR feature of solid N2, and (iii) a striking 15N isotopic enrichment. Problems are found for each IR band strength used and for each of the three claims made, to the extent that none are supported by the results presented to date. In contrast, new work presented here, combined with several older investigations, strongly supports the formation of di- and triatomic nitrogen oxides in irradiated N2-rich ices. Observations and trends in the chemistry of N2-rich icy solids are described, and conclusions are drawn. A considerable amount of material from previous chemical studies of N2-rich systems, spanning more than a century, is brought together for the rst time and used to examine the chemistry of N2-rich ices in extraterrestrial environments. Needs are identied and suggestions made for future studies of N2-rich interstellar and planetary ice analogs.

astrobiology↗
NASA NTRS2018

N2 Chemistry in Interstellar and Planetary Ices: Radiation-Driven Oxidation

As part of our work on nitrogen-rich ices, the IR spectra and band strengths used in a recent paper to identify and quantify radiation-induced changes in an N2+H2O ice near 15 K are examined, along with reports of (i) a chemical tracer for N2+H2O ices, (ii) a new IR feature of solid N2, and (iii) a striking 15N isotopic enrichment. Problems are found for each IR band strength used and for each of the three claims made, to the extent that none are supported by the results presented to date. In contrast, new work presented here, combined with several older investigations, strongly supports the formation of di- and triatomic nitrogen oxides in irradiated N2-rich ices. Observations and trends in the chemistry of N2-rich icy solids are described, and conclusions are drawn. A considerable amount of material from previous chemical studies of N2-rich systems, spanning more than a century, is brought together for the first time and used to examine the chemistry of N2-rich ices in extraterrestrial environments. Needs are identified and suggestions made for future studies of N2-rich interstellar and planetary ice analogs

astrobiology – astrochemistry – infrared: ISM – IS↗
NASA NTRS2008

Effect of shadowing on survival of bacteria under conditions simulating the Martian atmosphere and UV radiation

Spacecraft-associated spores and four non-spore-forming bacterial isolates were prepared in Atacama Desert soil suspensions and tested both in solution and in a desiccated state to elucidate the shadowing effect of soil particulates on bacterial survival under simulated Martian atmospheric and UV irradiation conditions. All non-spore-forming cells that were prepared in nutrient-depleted, 0.2-μm-filtered desert soil (DSE) microcosms and desiccated for 75 days on aluminum died, whereas cells prepared similarly in 60-μm-filtered desert soil (DS) microcosms survived such conditions. Among the bacterial cells tested, Microbacterium schleiferi and Arthrobacter sp. exhibited elevated resistance to 254-nm UV irradiation (low-pressure Hg lamp), and their survival indices were comparable to those of DS- and DSE-associated Bacillus pumilus spores. Desiccated DSE-associated spores survived exposure to full Martian UV irradiation (200 to 400 nm) for 5 min and were only slightly affected by Martian atmospheric conditions in the absence of UV irradiation. Although prolonged UV irradiation (5 min to 12 h) killed substantial portions of the spores in DSE microcosms (~5- to 6-log reduction with Martian UV irradiation), dramatic survival of spores was apparent in DS-spore microcosms. The survival of soil-associated wild-type spores under Martian conditions could have repercussions for forward contamination of extraterrestrial environments, especially Mars.

Venkateswaran, Kasthuri↗
NASA NTRS1993

The natural thermoluminescence of meteorites. V - Ordinary chondrites at the Allan Hills ice fields

Natural thermoluminescence (TL) data have been obtained for 167 ordinary chondrites from the ice fields in the vicinity of the Allan Hills in Victoria Land, Antarctica, in order to investigate their thermal and radiation history, pairing, terrestrial age, and concentration mechanisms. Natural TL values for meteorites from the Main ice field are fairly low, while the Farwestern field shows a spread with many values 30-80 krad, suggestive of less than 150-ka terrestrial ages. There appear to be trends in TL levels within individual ice fields which are suggestive of directions of ice movement at these sites during the period of meteorite concentration. These directions seem to be confirmed by the orientations of elongation preserved in meteorite pairing groups. The proportion of meteorites with very low natural TL levels at each field is comparable to that observed at the Lewis Cliff site and for modern non-Antarctic falls and is also similar to the fraction of small perihelia orbits calculated from fireball and fall observations. Induced TL data for meteorites from the Allan Hills confirm trends which show that a select group of H chondrites from the Antarctic experienced a different extraterrestrial thermal history to that of non-Antarctic H chondrites.

Benoit, Paul H.↗
NASA NTRS2014

Stardust Interstellar Preliminary Examination IV: Scanning Transmission X-Ray Microscopy Analyses of Impact Features in the Stardust Interstellar Dust Collector

We report the quantitative characterization by synchrotron soft X-ray spectroscopy of 31 potential impact features in the aerogel capture medium of the Stardust Interstellar Dust Collector. Samples were analyzed in aerogel by acquiring high spatial resolution maps and high energy-resolution spectra of major rock-forming elements Mg, Al, Si, Fe, and others. We developed diagnostic screening tests to reject spacecraft secondary ejecta and terrestrial contaminants from further consideration as interstellar dust candidates. The results support an extraterrestrial origin for three interstellar candidates: I1043,1,30 (Orion) is a 3 pg particle with Mg-spinel, forsterite, and an iron-bearing phase. I1047,1,34 (Hylabrook) is a 4 pg particle comprising an olivine core surrounded by low-density, amorphous Mg-silicate and amorphous Fe, Cr, and Mn phases. I1003,1,40 (Sorok) has the track morphology of a high-speed impact, but contains no detectable residue that is convincingly distinguishable from the background aerogel. Twenty-two samples with an anthropogenic origin were rejected, including four secondary ejecta from impacts on the Stardust spacecraft aft solar panels, nine ejecta from secondary impacts on the Stardust Sample Return Capsule, and nine contaminants lacking evidence of an impact. Other samples in the collection included I1029,1,6, which contained surviving solar system impactor material. Four samples remained ambiguous: I1006,2,18, I1044,2,32, and I1092,2,38 were too dense for analysis, and we did not detect an intact projectile in I1044,3,33. We detected no radiation effects from the synchrotron soft X-ray analyses; however, we recorded the effects of synchrotron hard X-ray radiation on I1043,1,30 and I1047,1,34.

Dust↗
NASA NTRS2000

Microreactor System Design for a NASA In Situ Propellant Production Plant on Mars

The NASA In Situ Resource Utilization (ISRU) program is planning near-term missions to Mars that will include chemical processes for converting the carbon dioxide (CO2) and possibly water from the Martian environment to propellants, oxygen, and other useful chemicals. The use of indigenous resources reduces the size and weight of the payloads from Earth significantly, representing enormous cost savings that make human exploration of Mars affordable. Extraterrestrial chemical processing plants will need to be compact, lightweight, highly efficient under reduced gravity, and extraordinarily reliable for long periods. Microchemical and thermal systems represent capability for dramatic reduction in size and weight, while offering high reliability through massive parallelization. In situ propellant production (ISPP), one aspect of the ISRU program, involves collecting and pressurizing atmospheric CO2, conversion reactions, chemical separations, heat exchangers, and cryogenic storage. A preliminary system design of an ISPP plant based on microtechnology has demonstrated significant size, weight, and energy efficiency gains over the current NASA baseline. Energy management is a strong driver for Mars-based processes, not only because energy is a scarce resource, but because heat rejection is problematic; the low pressure environment makes convective heat transfer ineffective. Energy efficiency gains are largely achieved in the microchemical plant through extensive heat recuperation and energy cascading, which has a small size and weight penalty because the added micro heat exchangers are small. This leads to additional size and weight gains by reducing the required area of waste heat radiators. The microtechnology-based ISPP plant is described in detail, including aspects of pinch analysis for optimizing the heat exchanger network. Three options for thermochemical compression Of CO2 from the Martian atmosphere, adsorption, absorption, and cryogenic freezing, are presented, as well as three options for water decomposition, low temperature electrolysis, high temperature electrolysis, and thermochemical decomposition. Other elements of the plant include Sabatier and reverse water gas shift reactors, water recovery, chemical separations, and cryogenic storage. Data are presented supporting preliminary sizing of components, and results of the system design are compared to the existing NASA baseline that is based on conventional technologies.

TeGrotenhuis, W. E.↗
NASA NTRS1990

Reproduction in the space environment: Part II. Concerns for human reproduction

Long-duration space flight and eventual colonization of our solar system will require successful control of reproductive function and a thorough understanding of factors unique to space flight and their impact on gynecologic and obstetric parameters. Part II of this paper examines the specific environmental factors associated with space flight and the implications for human reproduction. Space environmental hazards discussed include radiation, alteration in atmospheric pressure and breathing gas partial pressures, prolonged toxicological exposure, and microgravity. The effects of countermeasures necessary to reduce cardiovascular deconditioning, calcium loss, muscle wasting, and neurovestibular problems are also considered. In addition, the impact of microgravity on male fertility and gamete quality is explored. Due to current constraints, human pregnancy is now contraindicated for space flight. However, a program to explore effective countermeasures to current constraints and develop the required health care delivery capability for extended-duration space flight is suggested. A program of Earth- and space-based research to provide further answers to reproductive questions is suggested.

Review, Tutorial↗
NASA NTRS2021

In Situ Performance of the Low Frequency Array for Advanced ACTPol

The Advanced Atacama Cosmology Telescope Polarimeter (AdvACT) is an upgrade for the Atacama Cosmology Telescope using Transition Edge Sensor (TES) detector arrays to measure cosmic microwave background (CMB) temperature and polarization anisotropies in multiple frequencies. The low frequency (LF) array was deployed early 2020. It consists of 292 TES bolometers observing in two bands centered at 27 GHz and 39 GHz. At these frequencies, it is sensitive to synchrotron radiation from our galaxy as well as to the CMB, and complements the AdvACT arrays operating at 90, 150 and 230 GHz. We present the initial LF array on-site characterization, including the time constant, optical efficiency and array sensitivity.

Superconducting detectors↗
NASA NTRS2000

Deuterium enrichment of polycyclic aromatic hydrocarbons by photochemically induced exchange with deuterium-rich cosmic ices

The polycyclic aromatic hydrocarbon (PAH) coronene (C24H12) frozen in D2O ice in a ratio of less than 1 part in 500 rapidly exchanges its hydrogen atoms with the deuterium in the ice at interstellar temperatures and pressures when exposed to ultraviolet radiation. Exchange occurs via three different chemical processes: D atom addition, D atom exchange at oxidized edge sites, and D atom exchange at aromatic edge sites. Observed exchange rates for coronene (C24H12)-D2O and d12-coronene (C24D12)-H2O isotopic substitution experiments show that PAHs in interstellar ices could easily attain the D/H levels observed in meteorites. These results may have important consequences for the abundance of deuterium observed in aromatic materials in the interstellar medium and in meteorites. These exchange mechanisms produce deuteration in characteristic molecular locations on the PAHs that may distinguish them from previously postulated processes for D enrichment of PAHs.

NASA Center ARC↗
NASA NTRS1991

An examination of astrophysical habitats for targeted SETI

Planetary atmospheric radiative transfer models have recently given valuable insights into the definition of the solar system's ecoshell. In addition, however, results have indicated that constraints on solar evolution also need to be addressed, with even minor solar variations, (mass loss, for example), having important consequences from an exobiological standpoint. Following the definition of the solar system's ecoshell evolution, the ecoshells around different stellar spectral types can then be modeled. In this study the astrophysical constraints on the definition of ecoshells and possible exobiological habitats includes: (1) the investigation of the evolution of the solar system's ecoshell under different initial solar/stellar model conditions as indicated by both solar abundance considerations as well as planetary evidence; (2) an outline of considerations necessary to define the ecoshells around the most abundant spectral-type stars, the K and M stars looking at the effects on exobiological habitats of planetary rotational tidal locking effects, and stellar flare/chromospheric-activity cycles, among other effects; (3) a preliminary examination of the factors defining the expected ecoshells around binary stars determining the of regular stellar eclipses, and the expected shortening of the semi-major axis. These results can then be applied to the targeted microwave search for extraterrestrial intelligent signals by constraining the ecoshell space in the solar neighborhood.

Doyle, Laurance R.↗
NASA NTRS2005

Disk-averaged synthetic spectra of Mars

The principal goal of the NASA Terrestrial Planet Finder (TPF) and European Space Agency's Darwin mission concepts is to directly detect and characterize extrasolar terrestrial (Earthsized) planets. This first generation of instruments is expected to provide disk-averaged spectra with modest spectral resolution and signal-to-noise. Here we use a spatially and spectrally resolved model of a Mars-like planet to study the detectability of a planet's surface and atmospheric properties from disk-averaged spectra. We explore the detectability as a function of spectral resolution and wavelength range, for both the proposed visible coronograph (TPFC) and mid-infrared interferometer (TPF-I/Darwin) architectures. At the core of our model is a spectrum-resolving (line-by-line) atmospheric/surface radiative transfer model. This model uses observational data as input to generate a database of spatially resolved synthetic spectra for a range of illumination conditions and viewing geometries. The model was validated against spectra recorded by the Mars Global Surveyor-Thermal Emission Spectrometer and the Mariner 9-Infrared Interferometer Spectrometer. Results presented here include disk-averaged synthetic spectra, light curves, and the spectral variability at visible and mid-infrared wavelengths for Mars as a function of viewing angle, illumination, and season. We also considered the differences in the spectral appearance of an increasingly ice-covered Mars, as a function of spectral resolution, signal-to-noise and integration time for both TPF-C and TPFI/ Darwin.

Mars↗
NASA NTRS1997

Radiative heating of interstellar grains falling toward the solar nebula: 1-D diffusion calculations

As the dense molecular cloud that was the precursor of our Solar System was collapsing to form a protosun and the surrounding solar-nebula accretion disk, infalling interstellar grains were heated much more effectively by radiation from the forming protosun than by radiation from the disk's accretion shock. Accordingly, we have estimated the temperatures experienced by these infalling grains using radiative diffusion calculations whose sole energy source is radiation from the protosun. Although the calculations are 1-dimensional, they make use of 2-D, cylindrically symmetric models of the density structure of a collapsing, rotating cloud. The temperature calculations also utilize recent models for the composition and radiative properties of interstellar grains (Pollack et al. 1994. Astrophys. J. 421, 615-639), thereby allowing us to estimate which grain species might have survived, intact, to the disk accretion shock and what accretion rates and molecular-cloud rotation rates aid that survival. Not surprisingly, we find that the large uncertainties in the free parameter values allow a wide range of grain-survival results: (1) For physically plausible high accretion rates or low rotation rates (which produce small accretion disks), all of the infalling grain species, even the refractory silicates and iron, will vaporize in the protosun's radiation field before reaching the disk accretion shock. (2) For equally plausible low accretion rates or high rotation rates (which produce large accretion disks), all non-ice species, even volatile organics, will survive intact to the disk accretion shock. These grain-survival conclusions are subject to several limitations which need to be addressed by future, more sophisticated radiative-transfer models. Nevertheless, our results can serve as useful inputs to models of the processing that interstellar grains undergo at the solar nebula's accretion shock, and thus help address the broader question of interstellar inheritance in the solar nebula and present Solar System. These results may also help constrain the size of the accretion disk: for example, if we require that the calculations produce partial survival of organic grains into the solar nebula, we infer that some material entered the disk intact at distances comparable to or greater than a few AU. Intriguingly, this is comparable to the heliocentric distance that separates the C-rich outer parts of the current Solar System from the C-poor inner regions.

NASA Center ARC↗
NASA NTRS2005

Temperatures, winds, and composition in the saturnian system

Stratospheric temperatures on Saturn imply a strong decay of the equatorial winds with altitude. If the decrease in winds reported from recent Hubble Space Telescope images is not a temporal change, then the features tracked must have been at least 130 kilometers higher than in earlier studies. Saturn's south polar stratosphere is warmer than predicted from simple radiative models. The C/H ratio on Saturn is seven times solar, twice Jupiter's. Saturn's ring temperatures have radial variations down to the smallest scale resolved (100 kilometers). Diurnal surface temperature variations on Phoebe suggest a more porous regolith than on the jovian satellites.

Saturn↗