Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Drying”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 289 records · Page 16
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

From K‐O 2 to K‐Air Batteries: Realizing Superoxide Batteries on the Basis of Dry Ambient Air

Abstract Although using an air cathode is the goal for superoxide‐based potassium‐oxygen (K‐O 2 ) batteries, prior studies were limited to pure oxygen. Now, the first K‐air (dry) battery based on reversible superoxide electrochemistry is presented. Spectroscopic and gas chromatography analyses are applied to evaluate the reactivity of KO 2 in ambient air. Although KO 2 reacts with water vapor and CO 2 to form KHCO 3 , it is highly stable in dry air. With this knowledge, rechargeable K‐air (dry) batteries were successfully demonstrated by employing dry air cathode. The reduced partial pressure of oxygen plays a critical role in boosting battery lifespan. With a more stable environment for the K anode, a K‐air (dry) battery delivers over 100 cycles (>500 h) with low round‐trip overpotentials and high coulombic efficiencies as opposed to traditional K‐O 2 battery that fails early. This work sheds light on the benefits and restrictions of employing the air cathode in superoxide‐based batteries.

Qin, Lei↗
DOE OSTI2024

Mechanical and Electrochemical Implications of Drying Temperature on Lithium‐Ion Battery Electrodes

Abstract Lithium‐ion battery (LIB) electrodes are typically produced with n‐methyl‐2‐pyrrolidone, a toxic solvent that is a known carcinogen and reproductive hazard. Accordingly, aqueous processing has been an expanding area of research interest in the field of LIB manufacturing. Although aqueous processing has been widely successful in anode processing, serious challenges remain in processing the cathode. In this work, the drying mechanics of cathode processed with both solvents is investigated though implementation of a chemical‐engineering‐based model to better understand the utilization of heat provided by experimentally determining the heat and mass transfer coefficients. Electrochemical performance is also evaluated to determine the impact of drying temperature on cycling performance. Binder distribution is determined via various methods to confirm differences in binder homogeneity as a function of both solvent and drying temperature. Identified is the large difference in the efficiency in which the heat is used as well as an ideal drying temperature for both aqueous and non‐aqueous processed cathodes. Also identified is the increased sensitivity to processing temperature for aqueous processed electrodes compared to non‐aqueous processed counterparts, pointing to the possibility of tuned drying regimes which would capitalize on the potential cost savings of aqueous processing for cathodes.

25 ENERGY STORAGE↗
DOE OSTI2018

Heat and Mass Transfer in the Drying of a Cylindrical Body in an Oscillating Magnetic Field

A problem on the heating of a cylindrical body of infinite length in an oscillating electromagnetic field in the process of its drying has been formulated and solved analytically with account of the intermittence of irradiation of the body defined by the Heaviside unit function, the exponential-law absorption of electromagnetic energy by it, and the convective heat and mass exchange between the surface of the body and the environment having constant parameters. The intensity of evaporation of moisture from the surface of the body was determined on the basis of analytical solution of the problem on the mass transfer (moisture diffusion) in it on the assumption that the phase transformations of the body proceed near its surface. Solutions of the problem on the heating of the cylindrical body have been obtained for the cases of nonuniform and uniform distributions of its local temperature, the temperature of the body averaged over its volume, and the temperature gradient near the surface of the body. The 'serviceability' of these solutions was verified on the basis of numerical simulation, with them, of the drying of a seed shaped as a cylinder under the action of an oscillating infrared radiation. As a result of the numerical simulation performed, a technological regime of drying of seeds at minimum and maximum temperatures of their heating by on oscillating infrared radiation for a definite period of time in a cycle, providing not only the drying of the seeds but also substantial improvement of their sowing properties (the sprouting energy and the germination power), has been found. It is shown that the oscillating infrared heating of seeds can be used for their drying in pseudofluidized and vibrofluidized beds.

42 ENGINEERING↗
DOE OSTI2017

Physics of direct-contact ultrasonic cloth drying process

Existing methods of drying fabrics involve energy-intensive thermal evaporation of moisture from clothes. Drying fabrics using high-frequency vibrations of piezoelectric transducers can substantially reduce drying time and energy consumption. In this method, vibrational energy generates instability on the liquid-air interface and mechanically ejects water from a wet fabric. For the first time, the physics of the ultrasonic fabric drying process in direct-contact mode is studied. The kinematic and thermal responses of water droplets and fabrics on piezoelectric crystal transducers and metal mesh–based transducers are studied. The results suggest that on piezoelectric crystal transducers, the response of a droplet subjected to ultrasonic excitation is dictated by the relative magnitude of the surface tension and the ultrasonic excitation forces. The drying process for a fabric on the studied transducers consists of two regimes—vibrational and thermal. When the water content is high, the vibrational forces can eject bulk water rapidly. But the more strongly bound water within the smaller fabric pores evaporates by the thermal energy generated as a result of the viscous losses. Our study finds that a metal mesh–based transducer is more suitable for dewatering fabrics, as it facilitates the ejection of water from the fabric–transducer interface to the opposite side of the mesh. A demonstration unit developed consumes 10–20% of the water latent heat energy at water contents greater than 20%.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2016

Effect of drying temperatures on structural performance and photocatalytic activity of BiOCl synthesized by a soft chemical method

A group of BiOCl photocatalysts with different drying temperatures were prepared by a soft chemical method. The effects of drying temperatures on the crystalline phase, morphology, surface area and optical property of as-prepared samples were investigated in detail by XRD, SEM, N{sub 2} absorption–desorption and DRS. Moreover, their photocatalytic activities on the degradation of rhodamine B were evaluated under visible light irradiation. It was found that the sample dried at 120 °C had the best photocatalytic activity, which was mainly attributed to the highest exposing proportion of {001} facets correspond to BiOCl, largest BET and minimum bandgap. The degradation mechanism was explored that superoxide radicals were mainly contributed to the degradation of chromophore, however, holes and hydroxyl were mainly contributed to the photo degradation. Moreover, holes and hydroxyl dominated the degradation of RhB. - Graphical abstract: Holes, hydroxyl and superoxide radicals can attribute to the degradation process but take different degradation pathways. Superoxide radicals mainly contribute to the degradation of chromophore, however, holes and hydroxyl mainly contribute to the photo degradation. Display Omitted - Highlights: • BiOCl nanosheets were prepared by a soft chemical method. • Effect of drying temperatures on as-prepared BiOCl samples was studied. • The highest removal efficiency of RhB was obtained over the sample dried at 120 °C.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Frictional Contacts Between Individual Woody Biomass Particles under Wet and Dry Conditions

Friction between wood particles can be a critical property when designing processing equipment for creating cellulosic biofuels and similar natural products. Also, as wood processing is likely to occur year-round, understanding the friction between wet as well as dry wood particles can help design and model equipment, such as screw feeders. Here, a tribo-rheometry method was developed using a commercial rheometer that measured the torque required to rotate two contacting millimeter-scale wood chip particles. First, a range of normal forces were used to find the limits of the experimental method. Torque values were measured for seven pairs of wood chip particles at 1 N normal force under both dry and wet conditions, at both ambient conditions and in a humidity-controlled chamber. The torque required to rotate the wet particles was consistently higher than that of the dry particles, although differences were not quite statistically significant when measurements were performed at ambient conditions. Using humidity control resulted in torque values for wet particles of 1900 uNm and 900 uNm for dry particles. Finally, the friction coefficient was calculated as 0.23 for wet particles and 0.11 for dry particles when humidity was controlled. These frictions coefficients agreed with values for wood reported in the literature. Overall, controlling humidity is strongly recommended to quantify the range of friction for particles that uptake water, including granular systems from biomass to food to powders.

biomass↗
DOE OSTI2018

Dry-Season Greening and Water Stress in Amazonia: The Role of Modeling Leaf Phenology

Large uncertainties on the sensitivity of Amazon forests to drought exist. Even though water stress should suppress photosynthesis and enhance tree mortality, a green-up has been often observed during the dry season. This interplay between climatic forcing and forest phenology is poorly understood and inadequately represented in most of existing dynamic global vegetation models calling for an improved description of the Amazon seasonal dynamics. Recent findings on tropical leaf phenology are incorporated in the state-of-the-art eco-hydrological model Thetys & Chloris. The new model accounts for a mechanistic light-controlled leaf development, synchronized dry-season litterfall, and an age-dependent leaf photosynthetic capacity. Simulation results from 32 sites in the Amazon basin over a 15-year period successfully mimic the seasonality of gross primary productivity; evapotranspiration (ET); as well as leaf area index, leaf age, and leaf productivity. Representation of tropical leaf phenology reproduces the observed dry-season greening, reduces simulated gross primary productivity, and does not alter ET, when compared with simulations without phenology. Tolerance to dry periods, with the exception of major drought events, is simulated by the model. Deep roots rather than leaf area index regulation mechanisms control the response to short-term droughts, but legacy effects can exacerbate multiyear water stress. Our results provide a novel mechanistic approach to model leaf phenology and flux seasonality in the tropics, reconciling the generally observed dry-season greening, ET seasonality, and decreased carbon uptake during severe droughts.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2022

Dry Deposition Methods Based on Turbulence Kinetic Energy: 1. Evaluation of Various Resistances and Sensitivity Studies Using a Single‐Point Model

Different functions are used to account for turbulence strength in the atmospheric boundary layer for different stability regimes. These functions are one of the sources for differences among different atmospheric models' predictions and associated biases. Also, turbulence strength is underrepresented in some of the resistance formulations. Here, to address these issues with dry deposition, firstly we take advantage of three‐dimensional (3‐D) turbulence information in estimating resistances by proposing and validating a 3‐D turbulence velocity scale that is relevant for different stability regimes of boundary layer. Secondly, we hypothesize and validate that friction velocity measured by 3‐D sonic anemometer can be effectively replaced by the new turbulence velocity scale multiplied by the von Karman constant. Finally, we (a) present a set of resistance formulations for ozone (O 3 ) based on the 3‐D turbulence velocity scale; (b) intercompare estimations of such resistances with those obtained using existing formulations; and, (c) evaluate simulated O 3 fluxes using a single‐point dry deposition model against long‐term observations of O 3 fluxes at the Harvard Forest (MA) site. Results indicate that the new resistance formulations work very well in simulating surface latent heat and O 3 fluxes when compared to respective existing formulations and measurements at a decadal time scale. Findings from this research may help to improve the capability of dry deposition schemes for better estimation of dry deposition fluxes and create opportunities for the development of a community dry deposition model for use in regional/global air quality models.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Tripogon loliiformis tolerates rapid desiccation after metabolic and transcriptional priming during initial drying

Abstract Crop plants and undomesticated resilient species employ different strategies to regulate their energy resources and growth. Most crop species are sensitive to stress and prioritise rapid growth to maximise yield or biomass production. In contrast, resilient plants grow slowly, are small, and allocate their resources for survival in challenging environments. One small group of plants, termed resurrection plants, survive desiccation of their vegetative tissue and regain full metabolic activity upon watering. However, the precise molecular mechanisms underlying this extreme tolerance remain unknown. In this study, we employed a transcriptomics and metabolomics approach, to investigate the mechanisms of desiccation tolerance in Tripogon loliiformis , a modified desiccation-tolerant plant, that survives gradual but not rapid drying. We show that T. loliiformis can survive rapid desiccation if it is gradually dried to 60% relative water content (RWC). Furthermore, the gene expression data showed that T. loliiformis is genetically predisposed for desiccation in the hydrated state, as evidenced by the accumulation of MYB, NAC, bZIP, WRKY transcription factors along with the phytohormones, abscisic acid, salicylic acid, amino acids (e.g., proline) and TCA cycle sugars during initial drying. Through network analysis of co-expressed genes, we observed differential responses to desiccation between T. loliiformis shoots and roots. Dehydrating shoots displayed global transcriptional changes across broad functional categories, although no enrichment was observed during drying. In contrast, dehydrating roots showed distinct network changes with the most significant differences occurring at 40% RWC. The cumulative effects of the early stress responses may indicate the minimum requirements of desiccation tolerance and enable T. loliiformis to survive rapid drying. These findings potentially hold promise for identifying biotechnological solutions aimed at developing drought-tolerant crops without growth and yield penalties.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2014

A Review and Perspective of Recent Bio-Oil Hydrotreating Research

The pathway for catalytic hydrodeoxygenation of biomass derived fast pyrolysis oil represents a compelling route for production of liquid transportation fuels. There has been continued progress and advancements in both the public and private research areas towards driving this technology to completion. Published research and patent literature have demonstrated that continued development of HDO as a part of a processes for production liquid transportation using biomass is being advanced for both fuel blend stocks and for refinery intermediates for co-processing. Much of the research has still focused on “quality” metrics around single or groups of unit operations generating partially treated bio-oil streams without assessing upstream and downstream implications. However, there is an encouraging amount of research that is now being targeted and assessed with attempts to understand the impact on the final fuel product, regardless of the route. Much of the most important research is moving towards continuous, industrially relevant processes where data can be generated to adequately inform process and economic modeling. As the technology for producing liquid transportation fuels from pyrolysis/HDO/coprocessing is driving towards commercialization, further research should be prioritized on the basis of impact to a techno-economic analyses.

bio-oil↗
DOE OSTI2014

Purely dry mergers do not explain the observed evolution of massive early-type galaxies since z ∼ 1

Several studies have suggested that the observed size evolution of massive early-type galaxies (ETGs) can be explained as a combination of dry mergers and progenitor bias, at least since z ∼ 1. In this paper we carry out a new test of the dry-merger scenario based on recent lensing measurements of the evolution of the mass density profile of ETGs. We construct a theoretical model for the joint evolution of the size and mass density profile slope γ' driven by dry mergers occurring at rates given by cosmological simulations. Such dry-merger model predicts a strong decrease of γ' with cosmic time, inconsistent with the almost constant γ' inferred from observations in the redshift range 0 < z < 1. We then show with a simple toy model that a modest amount of cold gas in the mergers—consistent with the upper limits on recent star formation in ETGs—is sufficient to reconcile the model with measurements of γ'. By fitting for the amount of gas accreted during mergers, we find that models with dissipation are consistent with observations of the evolution in both size and density slope, if ∼4% of the total final stellar mass arises from the gas accreted since z ∼ 1. Purely dry merger models are ruled out at >99% CL. We thus suggest a scenario where the outer regions of massive ETGs grow by accretion of stars and dark matter, while small amounts of dissipation and nuclear star formation conspire to keep the mass density profile constant and approximately isothermal.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2020

Coupling of electroelastic dynamics and direct contact ultrasonic drying formulation for annular piezoelectric bimorph transducers

A newly developed technique for drying clothes without thermal energy has been developed through the utilization of ultrasonic vibrations from piezoelectric transducers. The novel technique incorporates the actuation of a thin stainless steel disk in contact with wet fabric via annular piezoelectric rings, where water in the liquid form is atomized, transported through microchannels in the disk, and ejected as a mist. In such a system, resonance matching between the actuation portion of the transducer and the portion contacting fabric must be realized, with theoretical results from the developed electromechanical model showing a reduction in energy consumption by 50% when resonance matching is achieved. The electrically coupled distributed parameter model for an annular bimorph piezoelectric transducer is developed for optimization of ultrasonic drying technology. The thickness mode vibrations are shown to dominate the behavior of the system, where the analytically developed model can be optimized to increase the output acceleration of the transducer, thus increasing drying performance. Here, the electromechanical equation developed will be connected to the drying rates of fabrics in contact with said vibrations, where the novelty of the coupled equations and its description of the physics of ultrasonic drying will be discussed.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Age-dependent leaf physiology and consequences for crown-scale carbon uptake during the dry season in an Amazon evergreen forest

Satellite and tower-based metrics of forest-scale photosynthesis generally increase with dry season progression across central Amazônia, but the underlying mechanisms lack consensus. We conducted demographic surveys of leaf age composition, and measured age-dependence of leaf physiology in broadleaf canopy trees of abundant species at a central eastern Amazon site. Using a novel leaf-to-branch scaling approach, we used this data to independently test the much-debated hypothesis—arising from satellite and tower-based observations—that leaf phenology could explain the forest-scale pattern of dry season photosynthesis. Stomatal conductance and biochemical parameters of photosynthesis were higher for recently mature leaves than for old leaves. Most branches had multiple leaf age categories simultaneously present, and the number of recently mature leaves increased as the dry season progressed because old leaves were exchanged for new leaves. These findings provide the first direct field evidence that branch-scale photosynthetic capacity increases during the dry season, with a magnitude consistent with increases in ecosystem-scale photosynthetic capacity derived from flux towers. In conclusion, interaction between leaf age-dependent physiology and shifting leaf age-demographic composition are sufficient to explain the dry season photosynthetic capacity pattern at this site, and should be considered in vegetation models of tropical evergreen forests.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2014

SU-E-T-294: Simulations to Investigate the Feasibility of ‘dry’ Optical-CT Imaging for 3D Dosimetry

Purpose: To perform simulations investigating the feasibility of “dry” optical-CT, and determine optimal design and scanning parameters for a novel dry tank telecentric optical-CT 3D dosimetry system. Such a system would have important advantages in terms of practical convenience and reduced cost. Methods: A Matlab based ray-tracing simulation platform, ScanSim, was used to model a telecentric system with a polyurethane dry tank, cylindrical dosimeter, and surrounding fluid. This program's capabilities were expanded for the geometry and physics of dry scanning. To categorize the effects of refractive index (RI) mismatches, simulations were run for several dosimeter (RI = 1.5−1.48) and fluid (RI = 1.55−1.33) combinations. Additional simulations examined the effect of increasing gap size (1–5mm) between the dosimeter and tank wall, and of changing the telecentric lens tolerance (0.5°−5°). The evaluation metric is the usable radius; the distance from the dosimeter center where the measured and true doses differ by less than 2%. Results: As the tank/dosimeter RI mismatch increases from 0–0.02, the usable radius decreases from 97.6% to 50.2%. The fluid RI for matching is lower than either the tank or dosimeter RI. Changing gap sizes has drastic effects on the usable radius, requiring more closely matched fluid at large gap sizes. Increasing the telecentric tolerance through a range from 0.5°–5.0° improved the usable radius for every combination of media. Conclusion: Dry optical-CT with telecentric lenses is feasible when the dosimeter and tank RIs are closely matched (<0.01 difference), or when data in the periphery is not required. The ScanSim tool proved very useful in situations when the tank and dosimeter have slight differences in RI by enabling estimation of the optimal choice of RI of the small amount of fluid still required. Some spoiling of the telecentric beam and increasing the tolerance helps recover the usable radius.

07 ISOTOPE AND RADIATION SOURCES↗
DOE OSTI2023

Low ozone dry deposition rates to sea ice during the MOSAiC field campaign: Implications for the Arctic boundary layer ozone budget

Dry deposition to the surface is one of the main removal pathways of tropospheric ozone (O 3 ). We quantified for the first time the impact of O 3 deposition to the Arctic sea ice on the planetary boundary layer (PBL) O 3 concentration and budget using year-round flux and concentration observations from the Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) campaign and simulations with a single-column atmospheric chemistry and meteorological model (SCM). Based on eddy-covariance O 3 surface flux observations, we find a median surface resistance on the order of 20,000 s m –1 , resulting in a dry deposition velocity of approximately 0.005 cm s –1 . This surface resistance is up to an order of magnitude larger than traditionally used values in many atmospheric chemistry and transport models. The SCM is able to accurately represent the yearly cycle, with maxima above 40 ppb in the winter and minima around 15 ppb at the end of summer. However, the observed springtime ozone depletion events are not captured by the SCM. In winter, the modelled PBL O 3 budget is governed by dry deposition at the surface mostly compensated by downward turbulent transport of O 3 towards the surface. Advection, which is accounted for implicitly by nudging to reanalysis data, poses a substantial, mostly negative, contribution to the simulated PBL O 3 budget in summer. During episodes with low wind speed (<5 m s –1 ) and shallow PBL (<50 m), the 7-day mean dry deposition removal rate can reach up to 1.0 ppb h –1 . Our study highlights the importance of an accurate description of dry deposition to Arctic sea ice in models to quantify the current and future O 3 sink in the Arctic, impacting the tropospheric O 3 budget, which has been modified in the last century largely due to anthropogenic activities.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2020

Wet and dry plastic deposition data for western US National Atmospheric Deposition Program sites (2017-2019)

Raw plastic counts and calculated plastic deposition rates for 11 National Atmospheric Deposition Program (NADP) sites in the western USA recorded from 2017-2019. Samples were collected to determine plastic deposition rates in remote locations and identify the potential sources of plastic to the atmosphere. Samples were collected using an Aerochem Metrics Wet and Dry sampler. Wet deposition refers to the material retained on a 0.45-micron filter. Dry deposition refers to the dry only deposition collected using a Dry Side Insert (DSI) (Brahney et al. 2020). Plastics are identified as either fibers or particles (includes small colored films). Wet deposition rates are recorded weekly and dry plastic deposition rates are based on monthly sampling intervals. Sites included are Grand Canyon National Park (AZ03), Joshua Tree National Park (CA67), Rocky Mountain National Park (CO98), Niwot Ridge (CO02), Ashley National Forest (UT95), East River SFA (CO10)), Craters of the Moon National Park (ID03), Great Basin National Park (NV05), Canyonlands National Park (UT09), Bryce Canyon Nationa Park (UT99), and Wind River Range (WY06). Data collection is being published in collaboration with the Department of Energy's research project, "Constraining physical understanding of aerosol loading, biogeochemistry, and snowmelt hydrology from hillslope to watershed scale in the East River Scientific Focus Areas.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2015

Select Generic Dry-Storage Pilot Plant Design for Safeguards and Security by Design (SSBD) per Used Fuel Campaign

As preparation to the year-end deliverable (Provide SSBD Best Practices for Generic Dry-Storage Pilot Scale Plant) for the Work Package (FT-15LA040501–Safeguards and Security by Design for Extended Dry Storage), the initial step was to select a generic dry-storage pilot plant design for SSBD. To be consistent with other DOE-NE Fuel Cycle Research and Development (FCR&D) activities, the Used Fuel Campaign was engaged for the selection of a design for this deliverable. For the work Package FT-15LA040501–“Safeguards and Security by Design for Extended Dry Storage”, SSBD will be initiated for the Generic Dry-Storage Pilot Scale Plant described by the layout of Reference 2. SSBD will consider aspects of the design that are impacted by domestic material control and accounting (MC&A), domestic security, and international safeguards.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2015

Report on UQ and PCMM Analysis of Vacuum Drying for UFD S&T Gaps

This report discusses two phenomena that could affect the safety, licensing, transportation, storage, and disposition of the spent fuel storage casks and their contents (radial hydriding during drying and water retention after drying) associated with the drying of canisters for dry spent fuel storage. The report discusses modeling frameworks and evaluations that are, or have been, developed as a means to better understand these phenomena. Where applicable, the report also discusses data needs and procedures for monitoring or evaluating the condition of storage containers during and after drying. A recommendation for the manufacturing of a fully passivated fuel rod, resistant to oxidation and hydriding is outlined.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗