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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 289 records · Page 16
All sourcesNASA NTRSDOE OSTI
NASA NTRS1993

Comparison of reflectance spectra of C asteroids and unique C chondrites Y86720, Y82162, and B7904

Reflectance spectra (0.3-2.6 microns) of 11 carbonaceous (C) chondrite powders (less than 100 or less than 125 microns) including 'unique' ones Y86720, Y82162, and B7904, have been measured and compared with those of 14 C asteroids. Among those C chondrites, only three 'unique' ones had close counterparts among C asteroids (Y86720 and 1 Ceres, Y82162 and 704 Interamnia, and B7904 and 31 Euphrosyne). Mixing calculations of those C chondrites by Hapke's isotropic model were also performed to improve fits of reflectance spectra of all the 14 C asteroids. If the grain-size distributions of those asteroid surfaces are similar to those C chondrite powders, the result suggests that all tested C asteroids contain a high amount of heated C chondrite material, such as Y86720, Y82162, and B7904.

Hiroi, T.↗
DOE OSTI2025

Search for resonance-enhanced C P and angular asymmetries in the Λ c + → p μ + μ − decay at LHCb

The first measurement of the C P asymmetry of the decay rate ( A C P ) and the C P average ( Σ A FB ) and C P asymmetry ( Δ A FB ) of the forward-backward asymmetry in the muon system of Λ c + → p μ + μ − decays is reported. The measurement is performed using a data sample of proton-proton collisions, recorded by the LHCb experiment from 2016 to 2018 at a center-of-mass energy of 13 TeV, which corresponds to an integrated luminosity of 5.4 fb − 1 . The asymmetries are measured in two regions of dimuon mass near the ϕ -meson mass peak. The dimuon-mass integrated results are A C P = ( − 1.1 ± 4.0 ± 0.5 ) % , Σ A FB = ( 3.9 ± 4.0 ± 0.6 ) % , Δ A FB = ( 3.1 ± 4.0 ± 0.4 ) % , where the first uncertainty is statistical and the second systematic. The results are consistent with the conservation of C P symmetry and the Standard Model expectations. © 2025 CERN, for the LHCb Collaboration 2025 CERN

Aaij, R. (ORCID:0000000305331952)↗
DOE OSTI2024

Measurement of Λ b 0 , Λ c + , and Λ Decay Parameters Using Λ b 0 → Λ c + h − Decays

A comprehensive study of the angular distributions in the bottom-baryon decays Λ b 0 → Λ c + h − ( h = π , K ) , followed by Λ c + → Λ h + with Λ → p π − or Λ c + → p K S 0 decays, is performed using a data sample of proton-proton collisions corresponding to an integrated luminosity of 9 fb − 1 collected by the LHCb experiment at center-of-mass energies of 7, 8, and 13 TeV. The decay parameters and the associated charge-parity ( C P ) asymmetries are measured, with no significant C P violation observed. For the first time, the Λ b 0 → Λ c + h − decay parameters are measured. The most precise measurements of the decay parameters α , β , and γ are obtained for Λ c + decays and an independent measurement of the decay parameters for the strange-baryon Λ decay is provided. The results deepen our understanding of weak decay dynamics in baryon decays. © 2024 CERN, for the LHCb Collaboration 2024 CERN

Aaij, R. (ORCID:0000000305331952)↗
DOE OSTI2016

Bond-rearrangement and ionization mechanisms in the photo-double-ionization of simple hydrocarbons (C 2 H 4 , C 2 H 3 F, and 1,1-C 2 H 2 F 2 ) near and above threshold

We have investigated bond-rearrangement driven by photo-double-ionization (PDI) near and above the double ionization threshold in a sequence of carbon-carbon double bonded hydrocarbon molecules: ethylene, fluoroethylene, and 1,1-difluoroethylene. We employ the kinematically complete cold target recoil ion momentum spectroscopy (COLTRIMS) method to resolve all photo-double-ionization events leading to two-ionic fragments. We observe changes in the branching ratios of different dissociative ionization channels depending on the presence of none, one, or two fluorine atoms. The role of the fluorine atom in the bond-rearrangement channels is intriguing as evident by the re-ordering of the threshold energies of the PDI in the fluorinated molecules. These effects offer a compelling argument that the electronegativity of the fluorine (or the polarity of the molecule) strongly influences the potential energy surfaces of the molcules and drives bond-rearrangement during the dissociation process. The energy sharing and the relative angle between the 3D-momentum vectors of the two electrons provide clear evidence of direct and indirect PDI processes.

74 ATOMIC AND MOLECULAR PHYSICS↗
DOE OSTI2015

Modeling impacts of changes in temperature and water table on C gas fluxes in an Alaskan peatland: Modeling C Gas Fluxes in Peatland

Northern peatlands have accumulated a large amount of organic carbon (C) in their thick peat profile. Climate change and associated variations in soil environments are expected to have significant impacts on the C balance of these ecosystems, but the magnitude is still highly uncertain. Verifying and understanding the influences of changes in environmental factors on C gas fluxes in biogeochemical models are essential for forecasting feedbacks between C gas fluxes and climate change. In this study, we applied a biogeochemical model, DeNitrification-DeComposition (DNDC), to assess impacts of air temperature (T A ) and water table (WT) on C gas fluxes in an Alaskan peatland. DNDC was validated against field measurements of net ecosystem exchange of CO 2 (NEE) and CH 4 fluxes under manipulated surface soil temperature and WT conditions in a moderate rich fen. The validation demonstrates that DNDC was able to capture the observed impacts of the manipulations in soil environments on C gas fluxes. To investigate responses of C gas fluxes to changes in T A and soil water condition, we conducted a series of simulations with varying T A and WT. The results demonstrate that (1) uptake rates of CO 2 at the site were reduced by either too colder or warmer temperatures and generally increased with increasing soil moisture; (2) CH 4 emissions showed an increasing trend as TA increased or WT rose toward the peat surface; and (3) the site could shift from a net greenhouse gas (GHG) sink into a net GHG source under some warm and/or dry conditions. A sensitivity analysis evaluated the relative importance of T A and WT to C gas fluxes. The results indicate that both T A and WT played important roles in regulating NEE and CH 4 emissions and that within the investigated ranges of the variations in T A and WT, changes in WT showed a greater impact than changes in T A on NEE, CH 4 fluxes, and net C gas fluxes at the study fen.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2018

Projected Changes in the Asian‐Australian Monsoon Region in 1.5°C and 2.0°C Global‐Warming Scenarios

Abstract In light of the Paris Agreement, it is essential to identify regional impacts of half a degree additional global warming to inform climate adaptation and mitigation strategies. We investigate the effects of 1.5°C and 2.0°C global warming above preindustrial conditions, relative to present day (2006–2015), over the Asian‐Australian monsoon region (AAMR) using five models from the Half a degree Additional warming, Prognosis and Projected Impacts (HAPPI) project. There is considerable intermodel variability in projected changes to mean climate and extreme events in 2.0°C and 1.5°C scenarios. There is high confidence in projected increases to mean and extreme surface temperatures over AAMR, as well as more‐frequent persistent daily temperature extremes over East Asia, Australia, and northern India with an additional 0.5°C warming, which are likely to occur. Mean and extreme monsoon precipitation amplify over AAMR, except over Australia at 1.5°C where there is uncertainty in the sign of the change. Persistent daily extreme precipitation events are likely to become more frequent over parts of East Asia and India with an additional 0.5°C warming. There is lower confidence in projections of precipitation change than in projections of surface temperature change. These results highlight the benefits of limiting the global‐mean temperature change to 1.5°C above preindustrial, as the severity of the above effects increases with an extra 0.5°C warming.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2020

The Critical Role of Reductive Steps in the Nickel-Catalyzed Hydrogenolysis and Hydrolysis of Aryl Ether C-O Bonds

Hydrogenolysis of the aromatic C-O bond in aryl ethers is catalyzed by Ni in decalin or water at 150 °C. Observations of a significant kinetic isotope effect (kH/kD = 5.7) for the reactions of diphenyl ether under H2 and D2 and a positive dependence of the rate on H2 chemical potential in decalin indicate that addition of H to the aromatic ring is the rate-limiting step rather than C-O scission. Hydrogen addition occurs on the metal before C-O bond scission. DFT calculations indicate that hydrogen atom addition to the ortho position followed by C-O scission is energetically more feasible than C-O scission followed by H addition to either phenoxyl or phenyl moieties. Hydrogenolysis initiated via H addition in water is more selective (~75 %) compared to reactions in decalin (~30 %). The high selectivity for hydrogenolysis is attributed to stabilization of polar transition state by water as a polar solvent.

Wang, Meng↗
DOE OSTI2021

Switching CO 2 Electroreduction Selectivity Between C 1 and C 2 Hydrocarbons on Cu Gas-Diffusion Electrodes

We report that regulating the selectivity toward a target hydrocarbon product is still the focus of CO 2 electroreduction. Here, we discover that the original surface Cu species in Cu gas-diffusion electrodes plays a more important role than the surface roughness, local pH, and facet in governing the selectivity toward C 1 or C 2 hydrocarbons. The selectivity toward C 2 H 4 progressively increases, while CH 4 decreases steadily upon lowering the Cu oxidation species fraction. At a relatively low electrodeposition voltage of 1.5 V, the Cu gas-diffusion electrode with the highest Cu δ+ /Cu 0 ratio favors the pathways of hydrogenation to form CH 4 with maximum Faradaic efficiency of 65.4% and partial current density of 228 mA cm -2 at -0.83 V vs RHE. At 2.0 V, the Cu gas-diffusion electrode with the lowest Cu δ+ /Cu 0 ratio prefers C–C coupling to form C 2+ products with Faradaic efficiency topping 80.1% at -0.75 V vs RHE, where the Faradaic efficiency of C 2 H 4 accounts for 46.4% and the partial current density of C 2 H 4 achieves 279 mA cm -2 . This work demonstrates that the selectivity from CH 4 to C 2 H 4 is switchable by tuning surface Cu species composition of Cu gas-diffusion electrodes.

36 MATERIALS SCIENCE↗
DOE OSTI2017

Effect of strain on evolution of dynamic recrystallization in Nb-1 wt%Zr-0.1 wt%C alloy at 1500 and 1600 °C

Uniaxial compression tests were carried out on Nb-1 wt%Zr-0.1 wt%C alloy at temperature of 1500 and 1600 °C and strain rate of 0.1 s{sup −1} to study the evolution of dynamic recrystallization with strain. Electron back scatter diffraction was used to quantify the microstructural evolution. Nb-1Zr-0.1C alloy showed a necklace structure at a strain of 0.9 when deformed at 1500 °C and at strain of 0.6 when deformed at 1600 °C, both at strain rate of 0.1 s{sup −1}. This suggested the occurrence of dynamic recrystallization. At 1500 °C and strain of 0.9 the local average misorientation and the grain orientation spread was low confirming the presence of dynamic recrystallization at this deformation condition. At both 1500 and 1600 °C and all measured strains the recrystallized grains had a strong fiber component of <001>. - Highlights: • Necklace formation of dynamically recrystallized grains occurred at strain of 0.6 and 0.9 for 1500 and 1600 °C, respectively. • Equiaxed microstructures were seen with increase in strain for both 1500 and 1600 °C. • At large strains the predominant recrystallized texture evolved to <001> pole.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Long-Term 13 C Uptake by 12 C-Enriched Calcite

Knowledge of the exchange of carbon isotopes between dissolved inorganic carbon and calcite minerals is of long-standing importance for the interpretation of sedimentary paleoclimate records and 14 C transport in the geosphere. To assess the mechanism and rates of carbon isotope exchange, we equilibrated 12 C-pure synthetic calcite particles in water, first in a glovebox and then in contact with atmospheric P CO 2 and 13 C/ 12 C ratio, at two different temperatures. Cavity ring-down infrared spectroscopy δ 13 C measurements of the solid revealed sustained 13C incorporation for over a period of 500 days (21 °C) and 125 days (50 °C). We developed a quantitative model for recrystallization and isotope exchange, assuming that the interfacial free energy provides a thermodynamic driving force for the growth of larger particles at the expense of smaller ones. Furthermore, this Ostwald ripening model did not reproduce the kinetics of 13C uptake and required greater coarsening than observed. Rather, the data were best explained by a mechanism involving surface exchange and solid-phase diffusion of 13C into the particles with an inferred effective diffusion constant at 21 °C of about 10 –25 m 2 /s. Although this work cannot rule out the possibility that structural or chemical aspects of the synthetic particles enabled faster 13 C uptake than could be observed in natural systems, this study adds to the body of the recent work, suggesting that fast exchange processes are possible, likely through grain boundaries and other defects.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2016

Full-dimensional quantum dynamics study of the H{sub 2} + C{sub 2}H → H + C{sub 2}H{sub 2} reaction on an ab initio potential energy surface

This work performs a time-dependent wavepacket study of the H{sub 2} + C{sub 2}H → H + C{sub 2}H{sub 2} reaction on a new ab initio potential energy surface (PES). The PES is constructed using neural network method based on 68 478 geometries with energies calculated at UCCSD(T)-F12a/aug-cc-pVTZ level and covers H{sub 2} + C{sub 2}H↔H + C{sub 2}H{sub 2}, H + C{sub 2}H{sub 2} → HCCH{sub 2}, and HCCH{sub 2} radial isomerization reaction regions. The reaction dynamics of H{sub 2} + C{sub 2}H → H + C{sub 2}H{sub 2} are investigated using full-dimensional quantum dynamics method. The initial-state selected reaction probabilities are calculated for reactants in eight vibrational states. The calculated results showed that the H{sub 2} vibrational excitation predominantly enhances the reactivity while the excitation of bending mode of C{sub 2}H slightly inhibits the reaction. The excitations of two stretching modes of C{sub 2}H molecule have negligible effect on the reactivity. The integral cross section is calculated with J-shift approximation and the mode selectivity in this reaction is discussed. The rate constants over 200-2000 K are calculated and agree well with the experimental measured values.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2014

Photon-dominated region modeling of the [C I], [C II], and CO Line Emission From A Boundary In The Taurus molecular cloud

We present [C I] and [C II] observations of a linear edge region in the Taurus molecular cloud, and model this region as a cylindrically symmetric photon-dominated region (PDR) exposed to a low-intensity UV radiation field. The sharp, long profile of the linear edge makes it an ideal case to test PDR models and determine cloud parameters. We compare observations of the [C I], {sup 3} P {sub 1} → {sup 3} P {sub 0} (492 GHz), [C I] {sup 3} P {sub 2} → {sup 3} P {sub 1} (809 GHz), and [C II] {sup 2} P {sub 3/2} → {sup 2} P {sub 1/2} (1900 GHz) transitions, as well as the lowest rotational transitions of {sup 12}CO and {sup 13}CO, with line intensities produced by the RATRAN radiative transfer code from the results of the Meudon PDR code. We constrain the density structure of the cloud by fitting a cylindrical density function to visual extinction data. We study the effects of variation of the FUV field, {sup 12}C/{sup 13}C isotopic abundance ratio, sulfur depletion, cosmic ray ionization rate, and inclination of the filament relative to the sky-plane on the chemical network of the PDR model and resulting line emission. We also consider the role of suprathermal chemistry and density inhomogeneities. We find good agreement between the model and observations, and that the integrated line intensities can be explained by a PDR model with an external FUV field of 0.05 G {sub 0}, a low ratio of {sup 12}C to {sup 13}C ∼43, a highly depleted sulfur abundance (by a factor of at least 50), a cosmic ray ionization rate (3-6) × 10{sup –17} s{sup –1}, and without significant effects from inclination, clumping or suprathermal chemistry.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2015

Soft X‐ray Spectromicroscopic Investigation of Synthetic C‐S‐H and C 3 S Hydration Products

Calcium silicate hydrates (C‐S‐H), the primary binding phase in concrete, is the most prominent physiochemical factor controlling the mechanical and chemical properties in the production of concrete. This paper reports the local‐binding structure and morphological details of C‐S‐H as determined by high‐resolution X‐ray spectromicroscopy. Hydrated tricalcium silicate (C 3 S) was used to determine the properties and role of the outer products (Op) of C 3 S. C‐S‐H with different molar ratios of Ca/Si, were synthesized (Syn‐ CSH ) to quantitatively evaluate the effect of silicate polymerization on Ca L and Si K edge of C‐S‐H. Near edge X‐ray absorption fine structure ( NEXAFS ) spectroscopy of Syn‐ CSH showed no variation in peak positions and energy separation for CaL III, II edge for the Ca/Si ratios investigated. Compared to Syn‐ CSH , C 3 S, when hydrated for 17 d, had a similar local structure around Ca. Si K edge NEXAFS analysis on Syn‐ CSH showed a tendency for the peak positions of both the Si K edge and the peak induced by multiple scattering to shift to higher energy levels. The results also indicated that the distance between the two peaks increased with a decrease of the Ca/Si ratio in Syn‐ CSH . Silicate polymerization influenced the multiple scattering of distant shell atoms more than the binding energy of the core atoms. Op of C 3 S had a uniform and higher degree of silicate polymerization compared to the core area. The results imply that Op reduces the hydration process of C 3 S into the core area thereby playing a key role on the properties of concrete upon formation.

Bae, Sungchul↗
NASA NTRS1972

Boundary lubrication of formulated C-ether in air to 300 deg C. 1: Phosphorus ester additives

Friction and wear measurements were made on CVM M-50 steel lubricated with three C-ether (modified polyphenyl ether) formulations in dry and wet air. Results were compared to those obtained with a formulated Type 2 ester and the C-ether base fluid. A ball-on-disk sliding friction apparatus was used. Experimental conditions were a 1-kilogram load, a 17-meter-perminute (100-rpm) surface speed, and a 25 to 300 C (77 to 572 F) disk temperature range. The C-ether base fluid and the three formulated C-ether fluids yielded lower wear than the Type 2 ester over the entire temperature range. All C-ether fluids exhibited slightly higher friction coefficients than the ester from 150 to 300 C (302 to 572 F) and similar values from 25 to 150 C (77 to 302 F). In general, lower wear rates were observed with the C-ethers when tested in wet air as compared to a dry air atmosphere.

Jones, W. R., Jr.↗