Measured drift of irradiated and unirradiated W3 percent Re/W25 percent Re thermocouples at a nominal 2000 K
Neutron irradiated and unirradiated Ta sheathed BeO insulated grounded junction thermocouples drift measurement
SEARCH · Engineering Papers
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.
Neutron irradiated and unirradiated Ta sheathed BeO insulated grounded junction thermocouples drift measurement
A propulsion concept is presented that can achieve specific impulses of 1000 to 2000 seconds for thrust levels on the order of 100 pounds (445 N) and maintain a small (1.22 m) reactor diameter for a total power-plant weight of approximately 10,000 kg. The concept combines a small (0.61 m) diameter spherical gas core centrally located, followed by a moderator (BeO-15 cm), surrounded by a driver fuel region and contained in a pressure vessel (ID of 1.22 m). Best results (i.e., highest ratio of cavity power to total power) occur with U-233 isotope as the fuel in both the cavity and the driver, although U-235 can also be used. Concept may also have application in the testing of a gas-core reactor and MHD devices and in high temperature-pressure materials research.
Heating rate measurements made in a mock-up of a BeO heat shield for a gas core nuclear rocket engine yields results nominally a factor of two greater than calculated by two different methods. The disparity is thought to be caused by errors in neutron capture cross sections and gamma spectra from the low cross-section elements, D, O, and Be.
A propulsion concept is presented that can achieve specific impulses of 1000 to 2000 seconds for thrust levels on the order of 100 pounds (445 N) and maintain a small (1.22 m) reactor diameter for a total power-plant weight of approximately 10,000 kg. The concept combines a small (0.61 m) diameter spherical gas core centrally located, followed by a moderator (BeO-15 cm), surrounded by a driver fuel region and contained in a pressure vessel (ID of 1.22 m). Best results (i.e., highest ratio of cavity power to total power) occur with U-233 isotope as the fuel in both the cavity and the driver, although U-235 can also be used. Concept may also have application in the testing of a gas-core reactor and MHD devices and in high temperature-pressure materials research.
Seven tantalum sheathed, BeO insulated, 0.157-cm-diam, grounded-junction W-3%Re/W-25%Re thermocouples were irradiated in a helium-argon environment at a temperature of 1900 to 2100 K. Six other thermocouples from the same lot were operated out-of-pile with the same temperature history as the in-pile thermocouples. Drift-in-pile was determined by periodically replacing a 'reference' thermocouple in the irradiation capsule. Drift out-of-pile was determined with an optical pyrometer. After 8000 hours irradiation, the estimated neutron fluence was 4 x 10 to the 21st power thermal neutrons/sq cm and 0.9 x 10 to the 21st power fast neutrons/sq cm (E greater than 0.18 MeV). At this time the in-pile group had decreased in output the equivalent of 340 K at 2073 K, while the out-of-pile group had decreased in output the equivalent of 54 K at 2073 K. The maximum deviation in drift between thermocouples of the in-pile group and between thermocouples of the out-of-pile group was less than plus or minus 15 K and less than plus or minus 10 K, respectively.
Assessment of grain growth kinetics at temperatures near the melting point and investigation into the use of potential nucleating agents in combination with the naturally occurring BeO led to the definition of critical low-g experiments which would help to determine whether one or both of these possibilities are valid and whether space processing would be able to yield fine grain ingot beryllium.
BeO dispersed nickel alloys, produced by powder metallurgy techniques, were studied extensively in stress rupture at 815, 982, and 1093 C (1088, 1255, and 1366 K) and by transmission electron microscopy. The alloys were subjected to a variety of thermomechanical treatments (TMT) to determine the benefits of TMT on properties. It is shown that the use of intermediate annealing treatments after 10 pct reduction steps is highly beneficial on both low and high temperature properties. It is indicated that the high temperature strength is not primarily dependent on the grain aspect ratio or texture but depends strongly on the dislocation density and distribution of dislocations in a stable substructure which is pinned by the fine oxide dispersion.
A heat-pipe-cooled nuclear reactor has been designed to provide 3.2 MWth to an out-of-core thermionic conversion system. The reactor is a fast reactor designed to operate at a nominal heat-pipe temperature of 1675 K. Each reactor fuel element consists of a hexagonal molybdenum block which is bonded along its axis to one end of a molybdenum/lithium-vapor heat pipe. The block is perforated with an array of longitudinal holes which are loaded with UO2 pellets. The heat pipe transfers heat directly to a string of six thermionic converters which are bonded along the other end of the heat pipe. An assembly of 90 such fuel elements forms a hexagonal core. The core is surrounded by a thermal radiation shield, a thin thermal neutron absorber, and a BeO reflector containing boron-loaded control drums.
Some nuclear safety aspects of a 3.2 mWt heat pipe cooled fast reactor with out-of-core thermionic converters are discussed. Safety related characteristics of the design including a thin layer of B4C surrounding the core, the use of heat pipes and BeO reflector assembly, the elimination of fuel element bowing, etc., are highlighted. Potential supercriticality hazards and countermeasures are considered. Impacts of some safety guidelines of space transportation system are also briefly discussed, since the currently developing space shuttle would be used as the primary launch vehicle for the nuclear electric propulsion spacecraft.
Two BeO dispersed iron alloys containing about 2.5 and 5.5 v/o dispersoid were produced by attritting, internally oxidizing, and extruding dilute, prealloyed Fe-Be powders. As-extruded alloys were given various thermomechanical treatments involving room temperature swaging and annealing above and below the allotropic transformation temperature. The elevated temperature rupture strengths were measured and correlated with changes in structure; strengthening trends were examined in the light of proposed models for such strengthening. The results obtained showed that the elevated temperature strength was determined by the oxide interparticle spacing (IPS) in recrystallized material and IPS as well as prior deformation in swaged specimens. In fact, a parametric correlation was found between rupture strength values in the longitudinal direction with prestrain during swaging. The overall pattern in strength and microstructural observations were more consistent with a strength-stored energy (substructure) dependence than a strength-grain shape (grain aspect ratio) relation.
One of the well-defined applications for nuclear power in space is nuclear electric propulsion (NEP). Mission studies have identified the optimum power level (400 kWe). A single Shuttle launch requirement and science-package integration have added additional constraints to the design. A reactor design which will meet these constraints has been studied. The reactor employs 90 fuel elements, each heat pipe cooled. Reactor control is obtained with BeO/B4C drums in a BeO reflector. The balance of the spacecraft is shielded from the reactor with LiH. Power conditioning and reactor control drum drives are located behind the LiH with the power conditioning. Launch safety, mechanical design and integration with the power conversion subsystem are discussed.
It has been found that the convergence problems for many ill conditioned single-configuration SCF calculations arise from mixing among only a small number of orbitals. This orbital set includes the highest closed, the partially filled, and (possibly) a few of the lowest virtual orbitals. The fact that convergence problems can be, in very large measure, linked to a small orbital set is used to design a hybrid MCSCF procedure in which these orbitals are treated using a second-order MCSCF method, while other mixings are treated with a lower-order method which avoids the time consuming integral transformation. Tests on BeO show that the hybrid method yields convergence even when the simple lower-order treatment diverges. The method is expected to facilitate determination of MCSCF wave functions for large basis problems and for the construction of potential energy surfaces.
Glass compositions having a Young's modulus of at least 15 million psi and a specific modulus of at least 110 million inches consisting essentially of, in mols, 10-45% SiO2, 2-15% Li2O, 3-34% BeO, 12-36% of at least one bivalent oxide selected from the group consisting of CaO, ZnO, MgO and CuO, 10-39% of at least one trivalent oxide selected from the group consisting of Al2O3, B2O3, La2O3, Y2O3 and the mixed rare earth oxides, the total number of said bivalent and trivalent oxides being at least three, and up to 10% of a tetravalent oxide selected from the group consisting of ZrO2, TiO2 and CeO2.
This article gives an outline of sintering techniques of silicon carbide and refers to recent developments. These techniques are also applicable to other oxides with a high melting point and particularly high sinterability, namely MgO and BeO.
A brief review of containerless processing activities sponsored by NASA's Microgravity Science Division is presented. Attention is given to ground based systems such as shot tower processing of molten materials, single axis levitation and flight processing concepts including BeO processing aboard the Space Shuttle, a medium temperature three-axis acoustic positioning system and a high temperature single axis acoustic positioning system. In the future, more sophisticated experiments will be conducted using improved measurement techniques which will quantitatively define the advantages of containerless processing, as well as improve the understanding of nuclear kinetics and of the thermophysical properties of materials at high temperatures.
The 20-W S-band power amplifiers aboard the GOES E and F spacecraft exemplify the problems that type-IIa diamond heat sinks have been developed to solve, including the requirement for junction temperatures to be kept below 125 C. Diamond heat sinks allow high power S-band semiconductors to operate at a flange temperature of 70 C without exceeding the stipulated maximum junction temperature. Type-IIA diamond, which is an excellent electrical insulator, possesses a thermal conductivity four times better than pure copper at 100 C, and outperforms BeO by an even greater margin. Higher costs are offset by high reliability. Attention is presently given to the results of tests conducted by the NASA Goddard Space Flight Center.
A partial description of the technology, hardware, and facilities developed by NASA in support of space-based containerless processing experiments in the early 1970s is presented, along with recent results. Supercooling was necessary, at a rate of 500 K over a 400 ft span, in early drop tower and molten sample experiments. Placing an electromagnetic levitation coil/chamber at the top of the tube avoided contamination of the sample by guide wires. Recent tests have been performed in attempts to produce metastable bulk A-15 Nb3Ge. The use of copper coils for levitation is suspected to have induced stirring motions in samples. Aerodynamic levitation, needed for nonconducting materials, has been employed to process glass beads at temperatures over 1000 K. An electromagnetic levitation device used to process a gram of BeO on a sounding rocket flight will be carried on a Shuttle flight, as will an acoustic suspension system.
The RF excited 2 to 3W CW CO2 waveguide lasers with lifetimes of the order of 10(4) to 2.10(4) hours were produced. This was achieved with CO and N2 bearing gas mixtures and with internal as well as external discharge electrodes. It is noted that these tests were conducted with unstabilized lasers which drift around in their signatures. The average power output was reduced to about one half of the highest peak power output in the signature. One of the lasers, no. 1.1, still shows 60% of its original output power after it was cycled on and off every 10 minutes for more than 50,000 times. The starting voltage and driving point impedance of the RF excited gas discharge structure for different gas pressures and mixtures were measured. These data will serve as a basis for the matching and starting network optimization. The second laser body was frit and indium sealed. To our a vacuum leak between the bore and electrode holes was noted. The leak seems to be due to a defect or crack in the BeO body.